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SINGULUS & STANGL - Singulus Technologies AG

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<strong>SINGULUS</strong> & <strong>STANGL</strong><br />

Smart Solutions for<br />

Crystalline Silicon & Thin-Film Photovoltaics<br />

Smart Solutions to Drive the Future.


02<br />

<strong>SINGULUS</strong> PHOTOVOLTAICS<br />

<strong>SINGULUS</strong> TECHNOLOGIES Headquarters, Kahl/Main, Germany <strong>SINGULUS</strong> <strong>STANGL</strong> SOLAR, Fürstenfeldbruck, Germany<br />

<strong>SINGULUS</strong> TECHNOLOGIES – Transition from Machine Supplier to System Provider<br />

<strong>SINGULUS</strong> TECHNOLOGIES is the<br />

world market leader in manufacturing mass<br />

production equipment for Optical Discs<br />

CD/DVD/Blu-ray. With the acquisition of<br />

the solar company <strong>STANGL</strong>, the foundation<br />

was laid to establish <strong>SINGULUS</strong> in the<br />

photovoltaics market. Since 2007 <strong>STANGL</strong><br />

is part of the <strong>SINGULUS</strong> TECHNOLOGIES<br />

Group and has become a 100 % subsidiary<br />

of <strong>SINGULUS</strong> on December 7, 2009. The<br />

international network supports customers<br />

by working closely with them as partners.<br />

The reliable, efficient and cost-saving<br />

function of the systems takes priority here.<br />

Numerous new products were developed<br />

and made marketable at <strong>SINGULUS</strong> and<br />

<strong>SINGULUS</strong> <strong>STANGL</strong> SOLAR.<br />

The company’s target is to position itself<br />

at the forefront for the introduction of new<br />

technologies with respect to silicon and<br />

thin film solar technology. <strong>SINGULUS</strong><br />

will offer a broad product range of new<br />

machines for the photovoltaics industry,<br />

which will offer manufacturers of silicon<br />

cells new production technologies and<br />

therefore particular cost advantages.<br />

Especially during times of cost pressures<br />

in the photovoltaics market the interest<br />

regarding new cost efficient concepts<br />

increases.<br />

<strong>SINGULUS</strong> and <strong>SINGULUS</strong> <strong>STANGL</strong><br />

SOLAR are cooperating with leading cell<br />

manufacturers in the development of new<br />

technologies and new machine designs<br />

for improved cell concepts with higher<br />

efficiency and manufacturing technologies<br />

with decreasing production costs. The<br />

company’s target is to position itself at<br />

the forefront for the introduction of new<br />

technologies with respect to silicon as<br />

well as thin film solar technology.<br />

<strong>SINGULUS</strong> and <strong>SINGULUS</strong> <strong>STANGL</strong><br />

SOLAR will systematically expand<br />

the solar activities. Both companies<br />

complement each other ideally in being<br />

able to offer a broad product range of<br />

equipment and advanced production<br />

solutions for the photovoltaics industry<br />

in the coming years.


<strong>SINGULUS</strong> APPROACH<br />

Design of Dedicated PV Equipment<br />

Improvement of Productivity Improvement of Cell Efficiency<br />

High Yield High Uptime<br />

Small<br />

Footprint<br />

Fast<br />

Ramp-up<br />

Time<br />

<strong>SINGULUS</strong> offers single products<br />

and integrated systems for Si-Cell<br />

Manufacturing<br />

Today´s dominating solar cell concept<br />

bases on cells made from crystalline<br />

silicon. <strong>STANGL</strong> provides completely<br />

automated solutions for poly silicon<br />

<strong>SINGULUS</strong> enables cost-effective<br />

CIS/CIGS & CdTe Thin Film Cell<br />

Manufacturing<br />

New<br />

Processes<br />

Thin film solar panels offer specific<br />

advantages compared to the silicon solar<br />

technology. Amongst them is the fact that<br />

the efficiency is retained during periods of<br />

weak sun intensity and that they are very<br />

Low Number<br />

of Handling<br />

Steps<br />

Layer<br />

Stacks<br />

03<br />

Crystalline Silicon Solar Technology<br />

etching as well as treatment for Si<br />

wafers & cells in standard and highefficiency<br />

production lines. <strong>SINGULUS</strong><br />

e.g. has developed the SINGULAR<br />

machine, a PECVD coating system<br />

which meets the demands for both<br />

current and future PV cell production.<br />

Thin Film Solar Technology<br />

easily integrated into architectural design<br />

elements. <strong>SINGULUS</strong> is the market leader<br />

for the wet-chemical cleaning applying<br />

CIS and CdTe processes.<br />

<strong>SINGULUS</strong> TECHNOLOGIES develops<br />

and assembles new machine concepts<br />

for the vacuum coating, selenisation,<br />

diffusion and other "dry processes".


04<br />

CRYSTALLINE SILICON SOLAR<br />

Wafer Inspection<br />

System<br />

Business<br />

<strong>SINGULUS</strong> System Business: From Wafer to Si-Solar Cells<br />

<strong>SINGULUS</strong> & <strong>SINGULUS</strong> <strong>STANGL</strong> SOLAR<br />

provide completely automated solutions for<br />

poly silicon etching as well as treatment<br />

for Si wafers & cells in standard and highefficiency<br />

production lines as well AR<br />

coating systems for both current and<br />

future PV cell production.<br />

<strong>SINGULUS</strong> entered strategic partnerships<br />

to offer front-end technology for<br />

the production of silicon solar cells as a<br />

one-stop supplier as well as complete,<br />

integrated production systems. Such<br />

complete systems cover all individual<br />

production steps from the first cleaning<br />

process of the silicon wafer to the<br />

finished silicon solar cell. In the future<br />

<strong>SINGULUS</strong> will focus rigorously on the<br />

Saw Damage Edge<br />

Texturisation<br />

SILEX/LINEA 1<br />

Phosphorus<br />

Diffusion<br />

Partner<br />

Cell Sorting<br />

Partner<br />

Contact Firing<br />

Partner<br />

system activities with production<br />

equipment for solar cells and leverage<br />

the know-how of coating and automation<br />

technology, the wet-chemical processes<br />

as well as system concepts.<br />

<strong>SINGULUS</strong> and <strong>STANGL</strong> already<br />

possess the necessary basic<br />

expertise for wet-chemical<br />

and AR-coating processes.<br />

This enhancement of<br />

the business model<br />

from single machines<br />

towards systems was<br />

also successful in the<br />

Optical Disc market<br />

some years ago.<br />

2<br />

Phosphorus Removal<br />

Edge Isolation<br />

SILEX/LINEA<br />

3<br />

SiN Deposition<br />

SINGULAR<br />

Screen Printing<br />

Partner<br />

<strong>SINGULUS</strong><br />

Partner


05<br />

<strong>SINGULUS</strong> SYSTEM BUSINESS<br />

SOLARE System for Batch Production of Crystalline Silicon Solar Cells<br />

1<br />

Wafer Inspection<br />

3<br />

Phosphorus Diffusion<br />

4 SILEX<br />

PSG Removal<br />

5 SINGULAR<br />

AR Coating & Passivation<br />

6<br />

Printing<br />

SOLARE System for Inline Production of Crystalline Silicon Solar Cells<br />

1<br />

Wafer Inspection<br />

2 SILEX<br />

SDE and Texturing<br />

2 LINEA<br />

SDE and Texturing<br />

Crystalline Silicon Solar Technology –<br />

Transition from Machine Supplier<br />

to System Provider with the new<br />

SOLARE Production Line<br />

The company's target is to position itself<br />

at the forefront for the introduction of new<br />

technologies with respect to silicon solar<br />

technology. <strong>SINGULUS</strong> will offer a broad<br />

product range of new machines for the<br />

photovoltaics industry, which will offer<br />

manufacturers of silicon cells new<br />

production technologies and therefore<br />

particular cost advantages. Especially<br />

during times of cost pressures in the<br />

photovoltaics market the interest<br />

regarding new plant concepts increases.<br />

<strong>SINGULUS</strong> & <strong>SINGULUS</strong> <strong>STANGL</strong> SOLAR<br />

provide completely automated solutions<br />

for polysilicon etching as well as treatment<br />

of Si wafers & cells in standard and high-<br />

3<br />

Phosphorus Diffusion<br />

4 LINEA<br />

PSG Removal/Edge Isolation<br />

5 SINGULAR<br />

AR Coating & Passivation –<br />

2 Systems<br />

efficiency production lines as well as<br />

AR coating systems for both current and<br />

future PV cell production. <strong>SINGULUS</strong><br />

entered strategic partner-ships to offer<br />

front-end technology for the production of<br />

silicon solar cells as a one-stop supplier<br />

as well as complete, integrated production<br />

systems. Such complete systems cover all<br />

individual production steps from the first<br />

cleaning process of the silicon wafer to<br />

the finished silicon solar cell. In the<br />

future <strong>SINGULUS</strong> will focus rigorously<br />

on the system activities with production<br />

equipment for solar cells and leverage,<br />

the know-how of coating and automation<br />

technology, wet-chemical processes as<br />

well as system concepts.<br />

Combined with <strong>STANGL</strong>'s machines,<br />

<strong>SINGULUS</strong> TECHNOLOGIES offers the<br />

key-technology for a crystalline silicon<br />

solar cell production line with wet-chemical<br />

7<br />

Firing<br />

6<br />

Printing<br />

8<br />

Edge Isolation & Testing/Sorting<br />

7<br />

Firing<br />

8<br />

Testing/Sorting<br />

systems from <strong>STANGL</strong> for saw damage<br />

edge & texturisation as well as PSG<br />

removal and the <strong>SINGULUS</strong> vacuum<br />

coating and wafer handling technology.<br />

This enhancement of the business model<br />

from single machines towards systems<br />

was also successful in the Optical Disc<br />

market some years ago.<br />

<strong>SINGULUS</strong> TECHNOLOGIES is a<br />

_ Specialist for special metallization<br />

processes utilizing the PECVD and<br />

PVD technology<br />

_ Specialist for inline process technology<br />

_ Provider of worldwide sales and service<br />

_ World market leader for Blu-ray disc<br />

and DVD/CD replication lines<br />

_ Manufacturer of molding machines<br />

and mastering systems


Crystalline Silicon Solar<br />

06<br />

GERULUS<br />

Wafer Block Pre-Clean & Deglue System<br />

1 Transport cart<br />

2 Input buffer<br />

3 Pre clean-bath<br />

4 Deglue chamber<br />

5 Output buffer<br />

6 Installation area<br />

7 Waste water pump stations (optional)<br />

8 Hot DI water station (optional)<br />

9 Surfactant dosage<br />

10 Dirt and pure water tanks<br />

11 Centrifuge<br />

GERULUS<br />

1 2 3 4 5<br />

1<br />

Virtually all silicon based wafers are<br />

cutted by wire saw technology. The<br />

<strong>STANGL</strong> GERULUS Pre-clean & Deglue<br />

system processes the wafers after being<br />

cut. This includes removal of slurry as<br />

well as degluing the wafers from their<br />

carrier beam.<br />

The GERULUS system can be configured<br />

in a wide range to adapt to all kinds<br />

of slurry and glue types. To guarantee<br />

lowest possible water and surfactant<br />

consumption, the system can be<br />

equipped with a water & SiC recycling<br />

system.<br />

6<br />

8<br />

7<br />

9<br />

10 11<br />

Main Features<br />

_ Patented wafer block cleaning<br />

_ Proven, highly integrated design<br />

_ High throughput up to 7,200 wph<br />

_ Built for non-stop utilization: 24/7,<br />

360 days/year<br />

_ High availability (uptime > 95 %)<br />

_ Sophisticated pre-cleaning concept<br />

for best process results and minimal<br />

process times<br />

_ Compliance with international safety<br />

regulations


WB-<br />

PreCLEAN<br />

WB-<br />

ALTEX<br />

WB-SDE<br />

WB-<br />

ISOTEX<br />

WB-<br />

COMBI<br />

WB-<br />

PSG+<br />

LOAD<br />

(SCALE)<br />

LOAD<br />

(SCALE)<br />

LOAD<br />

SCALE<br />

LOAD<br />

SCALE<br />

LOAD<br />

Today´s dominating solar cell concept<br />

bases on cells made from crystalline silicon.<br />

<strong>STANGL</strong> provides complete automated<br />

dry-in/dry-out solutions for wet treatment<br />

of Si-wafers in standard and high-efficiency<br />

cell lines.<br />

Batch-type working Wet Benches (WBseries)<br />

are the “workhorses” for cleaning<br />

and etching processes in Si-cell technology.<br />

07<br />

SILEX<br />

Batch-Type Wet Process Equipment for c-Si Solar Cell Production<br />

PRECLEAN RINSE<br />

DRY<br />

POST<br />

RINSE SDE+ALTEX RINSE<br />

CLEAN<br />

RINSE<br />

ISOTEX RINSE ISOTEX RINSE PorSi RINSE POST RINSE<br />

CLEAN<br />

ISOTEX<br />

PSG<br />

ECH<br />

LOAD<br />

(SCALE)<br />

SDE<br />

RINSE<br />

RINSE<br />

ISOTEX<br />

RINSE CLEAN<br />

RINSE<br />

RINSE<br />

POST<br />

CLEAN<br />

DRY<br />

UNLOAD<br />

RINSE<br />

UNLOAD<br />

Our machines are matched to the demands<br />

of solar cell mass production by<br />

_ lowest cost of ownership<br />

_ outstanding machine and process<br />

reliability<br />

_ state-of-the-art design and<br />

technology<br />

Main Features<br />

_ Proven, highly integrated design<br />

_ High throughput up to max. 1,500 or<br />

3,000 wph<br />

DRY UNLOAD<br />

SCALE<br />

DRY<br />

UNLOAD<br />

SCALE<br />

DRY<br />

RINSE ALTEX RINSE POST RINSE<br />

CLEAN<br />

Crystalline Silicon Solar<br />

UNLOAD<br />

SCALE<br />

DRY UNLOAD<br />

SCALE<br />

_ High availability (uptime > 95 %)<br />

_ Low breakage rate (< 0,05 %)<br />

_ High flexibility in process sequence,<br />

wafer type, wafer size<br />

_ Wafer thickness down to 150 µm<br />

_ Internal automatic chemical bath<br />

management<br />

_ Reproducible process results by<br />

complex process parameter control<br />

_ Network communication support<br />

_ Carrier tracking and data logging<br />

_ Compliance with international safety<br />

regulations


Crystalline Silicon Solar<br />

08<br />

LINEA<br />

Inline Wet Process Equipment for c-Si Solar Cell Production<br />

WL-ISOTEX<br />

Acidic SDE / Isotexturing LOAD ISOTEX RINSE PorSi RINSE CLEAN RINSE DRY<br />

WL-PSG<br />

P-SiO2-Glass / Removal<br />

WL-PSG-EE<br />

P-SiO2-Glass / Removal / Edge Isolation<br />

WL-FC<br />

US-Clean / Alkaline / Acidic<br />

Manufacturing lines of multicrystalline solar<br />

cells preferably apply acidic texturing<br />

processes on inline-working machines.<br />

PSG Removal processes are running<br />

successfully in batch and inline-type<br />

equipment.<br />

Additionally inline equipment permits singleside<br />

etching, applicable for edge isolation<br />

or side-selective surface treatment. LINEA<br />

is a horizontally working inline wet process<br />

platform for cleaning and etching of crystalline<br />

solar wafers. <strong>STANGL</strong>’s LINEA inline<br />

etching system can be configured up to max.<br />

1,700 or 3,400 wafers per hour (156 mm)<br />

which equals a production capacity of<br />

LOAD<br />

EMITTER<br />

ETCH<br />

50 and 100 MW. LINEA completes the<br />

portfolio of <strong>STANGL</strong>’s integrated wet<br />

process solutions for solar cell manufacturing<br />

lines.<br />

RINSE<br />

LOAD<br />

The LINEA design is based on a newly<br />

developed sophisticated transport system<br />

and a special chemical flow system to<br />

process the wafers horizontally with a<br />

very low breakage rate and a high etching<br />

uniformity. <strong>STANGL</strong>’s new system LINEA<br />

follows the trend towards handling solar<br />

wafers down to 150 µm.<br />

PorSi RINSE<br />

US<br />

CLEAN<br />

LOAD<br />

RINSE<br />

PSG<br />

ETCH<br />

PSG<br />

ETCH<br />

US<br />

CLEAN<br />

RINSE DRY<br />

RINSE DRY<br />

RINSE DRY<br />

UNLOAD<br />

UNLOAD<br />

UNLOAD<br />

UNLOAD<br />

Main Features<br />

_ Strongly modular, highly integrated design<br />

_ High availability (uptime > 95 %)<br />

_ Low breakage rate (< 0,1 %)<br />

_ Wafer thickness down to 150 μm<br />

_ Newly developed, sophisticated lowcontact<br />

wafer transport system<br />

_ No mechanical contact on top side<br />

_ Up to 6 lanes 156 mm/125 mm wafer<br />

_ Homogeneous reproducible etching<br />

process by high volume chemical<br />

up- and downstream distribution system<br />

_ High chemical exchange rate<br />

_ Automatic chemical bath management


Solar cell production is making the<br />

transition from the pioneering stage<br />

towards mass production. Innovative and<br />

flexible cell concepts demand a mass<br />

production concept which is equally<br />

innovative and flexible, as the leap there<br />

from the laboratory is the most expensive<br />

step in the development process.<br />

SINGULAR is a PECVD coating tool for<br />

anti reflection coatings (ARC) for cystalline<br />

silicon solar cells. The tool offers an<br />

innovative static inline concept, which<br />

combines the advantages of static<br />

processing and inline substrate transport.<br />

During static ICP-PECVD process the<br />

substrates are not moved, therefore layer<br />

stacks and gradient layers are easily<br />

possible.<br />

The SINGULAR PECVD coating system<br />

meets the demands for both current<br />

09<br />

SINGULAR<br />

Static Inline Tool for High Uptime ICP-PECVD Anti Reflection Coatings<br />

One SINGULAR Two SINGULAR Three SINGULAR<br />

_ Capacity up to 1,500<br />

wafers/h depending on<br />

technical equipment<br />

_ Up to 3,000 wafers/h as<br />

net output capacity<br />

and future PV cell production. The<br />

SINGULAR is a fully automated inline<br />

system consisting of independent modules.<br />

The essential benefit of the inline<br />

technology is the transport and process<br />

of small substrate production lots, which<br />

guarantees stable processes, continuous<br />

output, flexibility and a small footprint.<br />

In November 2009 <strong>SINGULUS</strong> delivered<br />

the first SINGULAR inline coating machine<br />

for anti-reflective coating of silicon solar<br />

cells as well as <strong>STANGL</strong>’s newly developed<br />

inline cleaning system LINEA with the<br />

corresponding fully-automated wafer<br />

handling system.<br />

The first SINGULAR inline coating<br />

machine for anti-reflective coating of silicon<br />

solar cells was successfully commissioned<br />

at a European customer in February 2010.<br />

The cells produced with a SINGULAR<br />

_ Up to 4,500 wafers/h as<br />

net output capacity<br />

Crystalline Silicon Solar<br />

machine achieve excellent efficiency.<br />

In addition, the cells are characterized<br />

by a very homogenous coloring.<br />

The <strong>SINGULUS</strong> inline coating machine is<br />

used in production lines for the<br />

manufacturing of silicon solar cells.<br />

Main Features<br />

For cells 125 x 125 mm and 156 x 156 mm<br />

_ Output 1,500 wafers/h, 3,000 wafers/h<br />

or 4,500 wafers/h<br />

_ High uptime due to inline chamber<br />

cleaning<br />

_ Efficient raw material consumption<br />

_ Optimized for lowest cost of ownership<br />

_ Integrated automatic loading/unloading<br />

system<br />

_ Modular, highly integrated design<br />

_ Short installation and ramp-up time<br />

_ Small footprint


Thin Film Solar on Glass<br />

10<br />

THIN FILM SOLAR TECHNOLOGY<br />

Overview Thin Film Cells<br />

Thin Film<br />

Thin Film Solar Technology<br />

Thin film solar panels offer specific<br />

advantages compared to the silicon<br />

solar technology. Amongst these are the<br />

retention of efficiency during periods of<br />

weak sun intensity and an easy integration<br />

into architectural design elements.<br />

<strong>SINGULUS</strong> is the market leader for the<br />

wet-chemical cleaning for CIS and CdTe<br />

processes. New production concepts as<br />

the spray ion layer gas reaction (ILGAR ® )<br />

process expand the value-added chain<br />

in the area of thin film solar technology.<br />

The company’s target is to position itself<br />

at the forefront for the introduction of<br />

new technologies with respect to silicon<br />

as well as thin film solar technology. In<br />

addition <strong>SINGULUS</strong> will progress on the<br />

way to a system supplier in this solar<br />

segment as well.<br />

Thin Silicon Film<br />

Semiconductor<br />

Compound<br />

Based<br />

Amorphous<br />

(a-Si)<br />

Tandem<br />

(a-Si/c-Si)<br />

Thin Film<br />

(c-Si)<br />

Thin Film II-VI<br />

<strong>SINGULUS</strong> offers modern production<br />

systems for CIS/CIGS & CdTe thin film<br />

solar cells made on glass and flexible<br />

substrates:<br />

_ Chemical supply systems with<br />

automatic dosage equipment<br />

_ Systems for the deposition<br />

of cadmium-free buffer<br />

layers<br />

_ Equipment designed<br />

for spray ion layer gas<br />

reaction (ILGAR ® )<br />

processes (AACVD)<br />

_ Metal free inline glass<br />

cleaning machines<br />

_ Inline etching and<br />

coating machines<br />

CIS/CIGS<br />

CdTE


Substrate Inspection<br />

Glass Washing 1<br />

Glass Washing<br />

Interconnect and Encapsulation<br />

PVD Back Contact<br />

Substrate Inspection<br />

1<br />

CdS or. alt. Buffer Deposition<br />

TCO Etching<br />

PVD TCO<br />

Scribing P3<br />

PVD Metal Back Contact<br />

Scribing P2<br />

Scribing P1<br />

Interconnect and Encapsulation<br />

Absorber Deposition CdTe<br />

2<br />

3<br />

CdTe<br />

CIS/CIGS<br />

Scribing P3<br />

4 5<br />

Back Side Cleaning CdTe<br />

10<br />

PVD Absorber<br />

Thin Film Solar on Flexible Materials<br />

11<br />

Thin Film - CdTe Manufacturing Process<br />

CdCI2 Deposition<br />

6<br />

Activation<br />

7<br />

CdCI2 Salt Removal<br />

8<br />

9<br />

Thin Film - CIS/CIGS Manufacturing Process<br />

Selenisation/Sulphurisation<br />

2<br />

KCN Etching or.<br />

NH3 Treatment<br />

Front Contact<br />

Laser Scribing P1<br />

Negative Photoresist<br />

Developer<br />

Primary Back Contact<br />

3<br />

4<br />

Glass Washing<br />

CdS or. alt.<br />

Buffer Deposition<br />

Scribing P2<br />

<strong>SINGULUS</strong> Product<br />

Portfolio:<br />

1. VITRUM Clean<br />

2. VITRUM TCO<br />

3. TENUIS altn. ILGAR ®<br />

or IMPEDIO<br />

4. COATER CdTe<br />

5. VITRUM Etch<br />

6. VITRUM Coating<br />

7. INDO<br />

8. VITRUM Clean<br />

9. VITRUM Clean<br />

10. VITRUM Developer<br />

<strong>SINGULUS</strong><br />

Cooperation Partner<br />

<strong>SINGULUS</strong> Product<br />

Portfolio:<br />

1. VITRUM Clean<br />

2. INSE<br />

3. VITRUM KCN<br />

4. TENUIS altn. ILGAR ®<br />

or IMPEDIO<br />

<strong>SINGULUS</strong><br />

Cooperation Partner


Thin Film Solar on Glass<br />

12<br />

TENUIS<br />

Wet Process Equipment for Thin Film Solar Cells on Glass<br />

1 Input Transport Unit<br />

2 Brush Off Machine<br />

3 Linear Transport System<br />

4 Process Module<br />

5 Final Rinse<br />

6 Output Transport Unit<br />

TENUIS<br />

6<br />

1<br />

With its TENUIS coating machines <strong>STANGL</strong><br />

has reached an internationally leading<br />

position in the CIS/CIGS thin film<br />

technology.<br />

Low manufacturing costs of the CIS<br />

modules can only be achieved in mass<br />

production. <strong>STANGL</strong> designs and produces<br />

high-tech systems that are used for<br />

fully-automated application of the singlesided<br />

wet chemical CdS coating.<br />

The fully-automated "dry-in/dry-out"<br />

<strong>STANGL</strong> thin film coating systems, used<br />

for single-sided wet chemical CdS coating,<br />

offer the customer a safe and reliable<br />

production capacity of up to 40/85 MW<br />

per line.<br />

2<br />

5<br />

4<br />

3<br />

4<br />

4<br />

4<br />

Main Features<br />

_ Low cost of ownership<br />

_ High throughput (cycle time 40/42 s)<br />

_ Low process temperatures<br />

_ High availability (uptime > 98 %)<br />

_ Lowest possible chemical consumption<br />

_ Single-side coating<br />

_ Easy upgrade for higher throughput<br />

_ Reproducible process results<br />

_ Automatic dosage and mixing systems<br />

_ Lowest possible DI water consumption<br />

_ Uniform spot-free glass plate drying<br />

(dry-in/dry-out)<br />

_ Waste and exhaust management<br />

system<br />

_ Networked communication supported


1 Input Transport Unit<br />

2 Process Modules<br />

3 Coarse Rinse<br />

4 Fine Rinse<br />

5 Ultra Fine Rinse<br />

6 Drying Unit<br />

7 Output Powered Roll Gears<br />

The VITRUM wet processing machine<br />

is available in different versions, e. g.<br />

cleaning, etching, brush off, CdCl2 or<br />

KCN. Thin film solar cells provide the<br />

chance to reduce manufacturing costs.<br />

This is based on the high costs of<br />

crystalline raw material and the better<br />

value chain for thin film solar cells.<br />

Besides the low cost of ownership,<br />

the main advantages of VITRUM are<br />

the exceptionally high throughput with<br />

13<br />

VITRUM<br />

Inline Wet Process Equipment for Thin Film Solar Cells on Glass<br />

VITRUM 1400<br />

1 2 4 6<br />

VITRUM 2200<br />

3 5 7<br />

1 2 3 4 5<br />

6<br />

a cycle time of only 30/60 seconds<br />

depending on glass size and process<br />

and the modular, highly integrated<br />

design. Furthermore, VITRUM offers<br />

inline systems for spraying or dipping<br />

and the standard and customer specific<br />

substrate sizes up to 2,600 mm. Moreover,<br />

high availability with an uptime of<br />

more than 98 % and the integration of<br />

automatic dosage and mixing systems<br />

are important features of <strong>STANGL</strong>'s new<br />

wet processing cleaning machine.<br />

Thin Film Solar on Glass<br />

7<br />

Main Features<br />

_ Metal free<br />

_ Low cost of ownership<br />

_ High throughput<br />

_ Inline systems<br />

_ Modular design<br />

_ High availability (uptime > 98 %)<br />

_ Standard and customer specific<br />

substrate sizes up to 2,200 mm<br />

_ Reproducible process results<br />

_ Automatic dosage and mixing systems<br />

_ Uniform spot-free glass plate drying<br />

(dry-in/dry-out)<br />

_ Waste water & exhaust treatment<br />

_ Networked communication supported


Thin Film Solar on Flexible Materials<br />

14<br />

IMPEDIO<br />

Roll-to-Roll Wet Process Equipment for Thin Film Solar Cells on Flexible Materials<br />

1 Input Web<br />

2 Process Module<br />

3 Rinsing and Drying Module<br />

4 Output Web<br />

Thin film solar cells on flexible materials<br />

are on the advance due to their potential<br />

applications regarding low weight, high<br />

flexibility and low cost of manufacturing<br />

compared to silicon based solar cells.<br />

<strong>STANGL</strong> offers roll-to-roll production<br />

systems of the type IMPEDIO for the<br />

wet-chemical coating of solar cells based<br />

on CIS/CIGS technology.<br />

IMPEDIO<br />

1<br />

Roll-to-Roll – IMPEDIO product portfolio for<br />

thin film technology on foils (metal/plastic):<br />

_ Roll-to-Roll Chemical Bath Deposition<br />

(CBD) of CdS/alternative buffer layers<br />

for CIS, CIGS, CIGSSe technologies<br />

_ Roll-to-Roll Inline-Cleaning<br />

(DI-Water, Tensides)<br />

_ Roll to Roll Inline-Etching<br />

(KCN, HCl, H3PO4)<br />

<strong>STANGL</strong> also supplies the following facillity<br />

management systems e.g. chemical supply<br />

systems, chemical mixing systems and<br />

waste water treatment.<br />

2 3 4<br />

Main Features<br />

_ Low cost of ownership<br />

_ Low process temperatures<br />

_ High availability (uptime > 98 %)<br />

_ Lowest possible chemical consumption<br />

_ Single-side coating of CdS or alt.<br />

buffer layers<br />

_ Both side etching with spray or dipping<br />

processes<br />

_ Both side cleaning with spray process<br />

_ Reproducible process results<br />

_ Automatic dosage and mixing systems<br />

_ Lowest possible DI water consumption<br />

_ Uniform spot-free foil drying<br />

(dry-in/dry-out)<br />

_ Waste and exhaust management system<br />

_ Networked communication supported


ILGAR ® R&D system<br />

Buffer Layer for CIS-Cells<br />

_ CIS/CIGS cells are normally arranged in a “Substrate configuration”<br />

_ the layer stack is deposited on a glass substrate<br />

_ the cell structure starts with sputtering of the metal back contact (Mo)<br />

Transparent front<br />

contact<br />

Window layer<br />

Absorber<br />

Back contact<br />

The standard buffer layer in a chalcopyrite<br />

thin film solar cell is made by chemical<br />

bath deposition (CBD). This is a reliable<br />

and commercially accepted method.<br />

However it also has a number of<br />

disadvantages such as: long process<br />

times, large amounts of liquid waste,<br />

critical process parameters, an inherent<br />

batch type nature and difficulties with<br />

very large substrates. As the size of the<br />

substrates used in thin film production<br />

increases and the tact time decreases<br />

there is a request for new methods with<br />

the buffer layer deposition as one example.<br />

In a collaboration between Helmholtz-<br />

Zentrum Berlin für Materi a lien und Energie<br />

(HZB), formerly the Hahn-Meitner-Institut<br />

(HMI), and <strong>SINGULUS</strong> an alternative<br />

buffer layer deposition technique is<br />

Wet chemical<br />

bath deposition<br />

„Most commonly” or<br />

In 2 S 3 − new ILGAR ®<br />

process<br />

developed for thin film solar cell fabrication.<br />

The so-called Ion-Layer-Gas-Reaction<br />

Process (ILGAR ® ) offers a new, cost<br />

efficient, chemical method to manufacture<br />

a thin homogeneous In 2S 3 layer (20 nm), as<br />

an alternative to the common CdS-buffers.<br />

The Spray-ILGAR ® deposited indium<br />

sulfide buffer layers are capable to replace<br />

the cadmium sulfide buffers used in<br />

chalcopyrite cells in order to avoid the<br />

toxic cadmium. First 30x30 mini-modules<br />

on a Pilotline Cu(In,Ga)(S,Se) 2 absorbers<br />

achieved an efficiency of 13.0 % after light<br />

soaking. The nature of the spray technique<br />

ensures that the ILGAR ® process is<br />

reproducible, fast, cheap and suitable<br />

for scaling up into an in-line process on<br />

large area substrates.<br />

Thin Film Solar on Flexible Materials<br />

15<br />

SOLUTUS<br />

<strong>SINGULUS</strong> New Products for Thin Film Applications<br />

Inline production system SOLUTUS<br />

Buffer Layer for CdTe-Cells<br />

_ CdTe cells are normally arranged in a “Superstrate configuration”<br />

_ the layer stack is deposited on a glass substrate<br />

_ the cell structure starts with sputtering of the front contact (TCO)<br />

Transparent front contact<br />

Buffer layer<br />

Absorber<br />

Primary back contact<br />

Secondary back contact<br />

Wet chemical<br />

bath deposition<br />

„Most commonly” or<br />

In 2 S 3 − new ILGAR ®<br />

process<br />

Main Features<br />

_ AACVD atmospheric process (aerosol<br />

assisted chemical vapor deposition)<br />

_ No vacuum required<br />

_ Quasi-dry process<br />

_ In 2S 3-deposition technique<br />

_ Cadmium free<br />

_ High efficiency cells produced with<br />

potential for further improvement<br />

(certified efficiency of 14.7% measured<br />

at ISE Freiburg)<br />

_ Machine cycle 60 s<br />

_ Continuous substrate flow under the<br />

aerosol area<br />

_ Design for variable size of production<br />

substrates:<br />

substrate width up to 1,200 mm (Larger<br />

substrate size can be processed on<br />

request!)<br />

_ Inline, fast production speeds<br />

_ Flexible method: bilayers and mixed<br />

compositions possible


Headquarters<br />

<strong>SINGULUS</strong> TECHNOLOGIES <strong>AG</strong><br />

Hanauer Landstrasse 103<br />

D - 63796 Kahl, Germany<br />

Tel. +49 6188 440-0<br />

Fax +49 6188 440-110<br />

sales@singulus.de<br />

www.singulus.de<br />

Affiliated Companies<br />

China<br />

<strong>SINGULUS</strong> MANUFACTURING<br />

GUANGZHOU LTD.<br />

Tel. +86 20 34518-830<br />

frank@singulus.com.cn<br />

France<br />

<strong>SINGULUS</strong> TECHNOLOGIES<br />

France S.A.R.L.<br />

Tel. +33 3 893111-29<br />

singulus@club-internet.fr<br />

Great Britain<br />

<strong>SINGULUS</strong> TECHNOLOGIES UK LTD.<br />

Tel. +44 1793 7842-00<br />

brian.walsh@singulusuk.com<br />

<strong>SINGULUS</strong> <strong>STANGL</strong> SOLAR GmbH<br />

Fraunhofer Strasse 9<br />

D - 82256 Fürstenfeldbruck, Germany<br />

Tel. +49 8141 3600-0<br />

Fax +49 8141 3600-100<br />

stangl@singulus.de<br />

www.stangl.de<br />

Italy<br />

<strong>SINGULUS</strong> TECHNOLOGIES ITALIA S.r.l.<br />

Tel. +39 071 79303-12<br />

info@singulus.it<br />

Latin America<br />

<strong>SINGULUS</strong> TECHNOLOGIES<br />

Latin America Ltda.<br />

Tel. +55 1121 6524-10<br />

rodolfo.mignone@singulus.com.br<br />

Netherlands<br />

<strong>SINGULUS</strong> MASTERING B.V.<br />

Tel. +31 407 5014-00<br />

info@singulus.nl<br />

Singapore<br />

<strong>SINGULUS</strong> TECHNOLOGIES<br />

ASIA PACIFIC PTE LTD.<br />

Tel. +65 674 119-12<br />

singulus@singnet.com.sg<br />

Spain<br />

<strong>SINGULUS</strong> TECHNOLOGIES IBERICA S.L.<br />

Tel. +34 936 7500-25<br />

singulus@singulusib.com<br />

Taiwan<br />

<strong>SINGULUS</strong> TECHNOLOGIES<br />

ASIA PACIFIC PTE LTD.<br />

TAIWAN REPRESENTATIVES OFFICE<br />

Tel. +886 2 274833-66<br />

sales@singulus.com.tw<br />

United States and Canada<br />

<strong>SINGULUS</strong> TECHNOLOGIES INC.<br />

Tel. +1 860 68380-00<br />

sales@singulus.com<br />

08/2010 – MetaCom Printed in Germany - Technical alterations reserved

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