WSA Adhesive - Duro Dyne

Page 1 of 5WSAMATERIAL SAFETY DATA SHEETDURO DYNE CANADA INC.5030 Francois-CussonLachine, Quebec H8T 1B3Phone: (514) 422-9760Fax: (514) 636-0328, (888) DURODYNEEmergency Telephone Numbers:MEDICAL: 860-571-5100 (24 hours)TRANSPORT: CHEMTREC: 800-424-9300 (24 hours)CHEMTREC International: 703-527-3887 (call collect)CREATION DATE: JUNE 26, 1990REVISION DATE: FEBRUARY 14, 2013SECTION 01:WSA CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NUMBER: 407082 (FORMER NUMBER: N40366A)PRODUCT NAME: WSA (DORUS PL 7082)IDH NUMBER: 1218406DURO DYNE PRODUCT NUMBER & NAME: #5035 WSA-1, #5036 WSA-5, #5037 WSA-44 OR 55 (DRUM)MANUFACTURER:Henkel Canada Corporation (Formerly Nacan Products Limited)2515 Meadowpine BoulevardMississauga, Ontario L5N 6C3 CanadaTelephone: 905-814-6511Emergency Telephone Numbers:MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608(toll free) or 1-303-592-1711TRANSPORT: CHEMTREC: 1-800-424-9300 (24 hours)CHEMTREC International: 703-527-3887 (call collect)SECTION 02:WSA HAZARDS IDENTIFICATIONEMERGENCY OVERVIEW:WHMIS hazard class: D.2.BPhysical state: LiquidColor: GrayOdor: PungentCAUTION: MAY CAUSE EYE AND SKIN ITTITATION ON PROLONGED OR REPEATED CONTACT.RELEVANT ROUTES OF EXPOSURE: Skin, Eyes, InhalationPotential health EffectsEYE CONTACT: May cause slight irritation to eyes on contact.SKIN CONTACT: Prolonged and/or repeated skin contact may result in mild irritation or redness.INHALATION: Inhalation of vapors or mists of the product may be irritating to the respiratory system.INGESTION: May cause gastrointestinal tract irritation if swallowed. Not expected under normal conditionsof use.See Section 11 for additional toxicological information

Page 2 of 5SECTION 03:WSA COMPOSITION / INFORMATION ON INGREDIENTSHazardous Components CAS Number %Propane-1,2-diol 57-55-6 1-5SECTION 04:WSA FIRST-AID MEASURESEYE CONTACT: If irritation develops, flush eyes immediately with large amounts of water. If irritationpersists, seek medical attention or advice.SKIN CONTACT: Wash skin with soap and water. If symptoms develop and persist, get medical attention.INHALATION: Move to fresh air. If breathing is difficult, give oxygen. If symptoms develop and persist, getmedical attention.INGESTION: Rinse out mouth, drink 1-2 glasses of water, do NOT induce vomiting. If symptoms developand persist, get medical attention. DO NOT attempt to give anything by mouth to a drowsy or unconsciousperson.SECTION 05:WSA FIREFIGHTING MEASURESAUTOIGNITION: Not availableFLASH POINT: > 100.00 °C (>212 °F) Closed CupEXTINGUISHING MEDIA: Use extinguishing measures appropriate to local circumstances and thesurrounding environment. Water spray or fog, CO2, Dry chemical; Foam;SPECIAL FIREFIGHTING PROCEDURES: Fire fighters should wear full-face, self-contained breathingapparatus and impervious protective clothing. Fire fighters should avoid inhaling any combustion products.UNUSUAL FIRE OR EXPLOSIVE HAZARDS: This is an aqueous mixture which will not burn. Ifevaporated to dryness, the solid residue may pose a moderate fire hazard. Closed containers may rupture(due to build up of pressure) when exposed to extreme heat.FIRE AND EXPLOSION HAZARDS: This is a water-based product and presents no particular fire orexplosion hazard.HAZARDOUS COMBUSTION PRODUCTS: Upon decomposition, this product emits Carbon monoxide,carbon dioxide and/or molecular weight hydrocarbons.FLAMMABLE/EXPLOSIVE LIMITS - LOWER: Not applicableFLAMMABLE/EXPLOSIVE LIMITS - UPPER: Not applicableSECTION 06:WSA ACCIDENTAL RELEASE MEASURESUse personal protection recommended in Section 8, isolate the hazard area and deny entry tounnecessary and unprotected personnel.ENVIRONMENTAL PRECAUTIONS: No special environmental precautions required. Do not allowmaterial to contaminate ground water system.CLEAN-UP METHODS: Take up with liquid-absorbing material (sand). Wash spillage site thoroughly withsoap and water or detergent solution. Dispose of according to Federal, State and local governmentalregulations.

Page 3 of 5SECTION 07:WSA HANDLING AND STORAGEHANDLING: Avoid extreme temperatures. Protect from freezing. This material should not be spilled,discharged, or flushed into sewers or public waterways. Product contains low level organic volatiles whichcould accumulate in the unvented headspace of drums or bulk storage vessels. Open drums in wellventilated area. Avoid breathing vapors. Do not wear contact lenses.STORAGE: For safe storage, store between 1 °C (33.8 °F) and 37 °C (98.6 °F). Below temperature limitthe product will be irreversibly damaged and no longer usable. Above temperature limit the productproperties change.For information on product shelf life, please review labels on container or check Technical Data Sheet.SECTION 08:WSA EXPOSURE CONTROLS / PERSONAL PROTECTIONEmployers should complete an assessment of all workplaces to determine the need for, andselection of, proper exposure controls and protective equipment for each task performed.Hazardous Components ACGIH TLV OSHA PEL AIHA WEEL OTHERPropane-1,2-diol None None10 mg/m3 TWAAerosolNoneENGINEERING CONTROLS: Handle in accordance with good industrial hygiene and safety practice.Normal ventilation expected to be adequate.RESPIRATORY PROTECTION: Under normal conditions, respirator is not normally required. If ventilationis not sufficient to effectively prevent buildup of vapors/mist/fume/dust, appropriate NIOSH/MSHArespiratory protection must be provided.EYE/FACE PROTECTION: Wear safety glasses with side shields. Do not wear contact lenses.SKIN PROTECTION: Use of protective coveralls and long sleeves is recommended.SECTION 09:WSA PHYSICAL AND CHEMICAL PROPERTIESPURE SUBSTANCE OR MIXTURE: MixturePHYSICAL FORM: LiquidCOLOUR: GrayODOUR: PungentODOUR THRESHOLD: Not availablepH: 4.5 – 6.0VAPOR PRESSURE: 17.5000000 MM HG (20.0 °C (68°F))BOILING POINT/RANGE: > 100 °C (> 212 °F)MELTING POINT/RANGE: 0.0 °C (32°F) (Freezing point)SPECIFIC GRAVITY (WATER=1): 1.18VAPOR DENSITY: > 1.0000 (Air = 1)FLASH POINT: > 100.00 °C (> 212°F) Closed CupAUTOIGNITION TEMPERATURE: Not applicableEVAPORATION RATE: 1.00 (Water = 1)SOLUBILITY IN WATER: MisciblePARTITION COEFFICIENT (n-octanol/water): Not determinedVOC CONTENT: < 3.0% (by weight)

Page 4 of 5SECTION 10:WSA STABILITY AND REACTIVITYSTABILITY: StableHAZARDOUS REACTIONS: Will not occur.HAZARDOUS DECOMPOSITION PRODUCTS: Upon decomposition, this product emits carbonmonoxide, carbon dioxide and/or low molecular weight hydrocarbons.INCOMPATIBLE MATERIALS: This product may react with strong oxidizing agents.CONDITIONS TO AVOID: Freezing. Product may be unstable if frozen.SECTION 11:WSA TOXICOLOGICAL INFORMATIONToxicologically synergistic products: Not availableRefer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, ReproductiveToxicity, Teratogenicity and Mutagenicity.Hazardous ComponentsNTPCarcinogenIARCCarcinogenOSHACarcinogen(SpecificallyRegulated)ACGIHCarcinogenPropane-1,2-diol No No No NoHazardous Components LD50s and LC50s Health Effects/Target OrgansPropane-1,2-diolOral LD50 (rabbit) = 18 g/kgOral LD50 (RAT) = 30 g/kgIrritantSECTION 12:WSA ECOLOGICAL INFORMATIONECOLOGICAL INFORMATION: No data available.SECTION 13:WSA DISPOSAL CONSIDERATIONSInformation provided is for unused product only.RECOMMENDED METHOD OF DISPOSAL: Follow all local, state, federal and provincial regulations fordisposal. This product is not a RCRA hazardous waste when discarded. Processing, use, orcontamination of this product may change the hazard classification and waste management options.SECTION 14:WSA TRANSPORTATION INFORMATIONCANADA TRANSPORTATION OF DANGEROUS GOODS – GROUNDProper Shipping Name: Not regulatedHazard class or division: NoneIdentification number: NonePacking group: NoneINTERNATIONAL AIR TRANSPORTATION (ICAO/IATA)Proper Shipping Name: Not regulatedHazard class or division: NoneIdentification number: NonePacking group: None

Page 5 of 5SECTION 14:WSA TRANSPORTATION INFORMATION - CONTINUEDWATER TRANSPORATION (IMO/IMDG)Proper Shipping Name: Not regulatedHazard class or division: NoneIdentification number: NonePacking group: NoneSECTION 15:WSA REGULATORY INFORMATIONCanada Regulatory InformationCEPA DSL/NDSL STATUS: Contains one or more components listed on the Non-Domestic SubstancesList. All other components are listed on or exempt from listing on the Domestic Substances List.Components listed on the NDSL must be tracked by all Canadian Importers of Record as required byEnvironment Canada. They may be imported into Canada in limited quantities. Please contact RegulatoryAffairs for additional details.United States Regulatory InformationTSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the ToxicSubstances Control Act Inventory.SECTION 16:WSA OTHER INFORMATIONThis material safety data sheet contains changes from the previous version in sections: Reviewed MSDS.Reissued with new date.This product has been classified in accordance with the hazard criteria of the Controlled ProductsRegulation (CPR), and the MSDS contains all the information required by the CPR.Prepared by: Jennifer Altman, Sr. Regulatory Affairs SpecialistWSA ADDITIONAL INFORMATION** The information given and the recommendations made herein apply to our product(s) alone andare not combined with other product(s). Such are based on our research and on data from otherreliable sources and are believed to be accurate. No guarantee of accuracy is made. It is thepurchaser's responsibility before using any product to verify this data under their own operatingconditions and to determine whether the product is suitable for their purposes. **WSA TECHNICAL CONTACTFOR INFORMATION CONTACT:M.S.D.S. Co-OrdinatorDuro Dyne Canada Inc(514) 422-9760