Abstract book - Prof. Per Jensen, Ph.D. - Bergische Universität ...

Poster session, D32 79High Resolution Fourier Transform Spectrum of PHD 2in the Region of 1550 - 1800 cm -1O. N. Ulenikov 1,2 , E. S. Bekhtereva 1,2 , Yu. V. Krivchikova 2 ,V. A. Zamotaeva 2 , and H. Bürger 3Ulenikov O.N.Bekhtereva E.S.Krivchikova Yu.V.Zamotaeva V.A.Burger H.1 Physical Chemistry Laboratory, ETH-Zürich, CH-8093, Zürich, Switzerland; 2 TomskState University, Physics Department, 634050, Tomsk, Russia; 3 Anorganische Chemie,FB C, Universität, 42097 Wuppertal, GermanyFor the first time the infrared spectrum of the PHD 2 molecule has been measured in theregion of 1550 - 1800 cm -1 on a Fourier transform spectrometer (Wuppertal, Germany) witha resolution of 0.0027 cm −1 and analyzed. Assigned transitions have been used in a fitprocedure with effective Hamiltonian which takes into account resonance interactionsbetween three closely located vibrational bands, states v 2 , v 5 , and v 3 +v 4 . Results of analysisare discussed.