Amercoat 90HS Pearl - MSDS - AltaPaints and Coatings

Product code AT90H-23 Date of issue 22 September 2009VersionProduct name AMERCOAT 90HS PEARL GRAY RESIN86 .Accidental release measuresPersonal precautions :Environmental precautionsLarge spill :Small spill :7 .HandlingHandling and storage:No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources. Noflares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see section 8).: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains andsewers. Inform the relevant authorities if the product has caused environmental pollution(sewers, waterways, soil or air).Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Use spark-proof tools and explosion-proof equipment. Prevent entry intosewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place incontainer for disposal according to local regulations (see section 13). Dispose of via alicensed waste disposal contractor. Contaminated absorbent material may pose thesame hazard as the spilled product. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Dilute with water and mop up if water-soluble or absorb withan inert dry material and place in an appropriate waste disposal container. Dispose ofvia a licensed waste disposal contractor.Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Persons with a history of skin sensitization problems should not be employedin any process in which this product is used. Do not breathe vapor or mist. Do notswallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation.Wear appropriate respirator when ventilation is inadequate. Do not enter storage areasand confined spaces unless adequately ventilated. Keep in the original container or anapproved alternative made from a compatible material, kept tightly closed when not inuse. Store and use away from heat, sparks, open flame or any other ignition source.Use explosion-proof electrical (ventilating, lighting and material handling) equipment.Use non-sparking tools. Take precautionary measures against electrostatic discharges.Vapors are heavier than air and may spread along floors. To avoid fire or explosion,dissipate static electricity during transfer by grounding and bonding containers andequipment before transferring material. Empty containers retain product residue and canbe hazardous. Do not reuse container. If this material is part of a multiple componentsystem, read the Material Safety Data Sheet(s) for the other component or componentsbefore blending as the resulting mixture may have the hazards of all of its parts.Storage:Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see section 10) and food and drink. Eliminateall ignition sources. Separate from oxidizing materials. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination. Do not store above thefollowing temperature: 120F / 49C.United States - Canada - MexicoPage: 3/8

Product code AT90H-23 Date of issue 22 September 2009VersionProduct name AMERCOAT 90HS PEARL GRAY RESIN8 .Exposure controls/personal protection8Name Result ACGIH OSHA Ontario Mexico PPGTalc , not containing asbestiformfibresTWA 2 mg/m³ R 20 mppcf Z 2 mg/m³ RTD2 mg/m³ NotestablishedSTEL Notestablished1 f/cc Z NotestablishedNotestablishedNotestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________1-methoxy-2-propanol TWA 100 ppm Notestablished100 ppm NotestablishedNotestablishedSTEL 150 ppm Notestablished150 ppm NotestablishedNotestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________titanium dioxide TWA 10 mg/m³ 15 mg/m³ TD 10 mg/m³ TD 10 mg/m³ (asTi)NotestablishedSTEL NotestablishedNotestablishedNotestablished20 mg/m³ (asTi)Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________1,2,4-trimethylbenzene TWA 25 ppm Notestablished25 ppm 25 ppm NotestablishedSTEL NotestablishedNotestablishedNotestablished35 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm NotestablishedSTEL 150 ppm Notestablished150 ppm 150 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________Key to abbreviationsA = Acceptable Maximum PeakS = Potential skin absorptionACGIH = American Conference of Governmental Industrial Hygienists. SR = Respiratory sensitizationC = Ceiling LimitSS = Skin sensitizationF = FumeTD = Total dustIPEL = Internal Permissible Exposure LimitTLV = Threshold Limit ValueOSHA = Occupational Safety and Health Administration.TWA = Time Weighted AverageR = Respirable Z = OSHA 29CFR 1910.1200 Subpart Z - Toxic and HazardousSubstancesConsult local authorities for acceptable exposure limits.Recommended monitoringproceduresEngineering measuresHygiene measuresPersonal protectionEyesHandsGloves :: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.: Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.:Safety glasses with side shields.: Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.butyl rubberUnited States - Canada - MexicoPage: 4/8

Product code AT90H-23 Date of issue 22 September 2009VersionProduct name AMERCOAT 90HS PEARL GRAY RESIN8 .SkinExposure controls/personal protectionRespiratoryEnvironmental exposurecontrols::If workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respiratorcomplying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.89 .Physical and chemical propertiesPhysical stateFlash pointLiquid.Explosion limits : Lower: 1.2%ColorOdorpHBoiling/condensation pointMelting/freezing pointSpecific gravityVapor pressureVapor densityVolatilityOdor thresholdEvaporation rate:: Closed cup: 35.56°C (96°F):::::::::::Not available.Not available.Not available.>37.78°C (>100°F)Not available.1.52Density ( lbs / gal ) : 12.69Octanol/water partitioncoefficient% Solid. (w/w) : 75.090.99 kPa (7.4 mm Hg)Not available.43% (v/v), 24.91% (w/w)Not available.40 (butyl acetate = 1): Not available.10 .Stability and reactivityStabilityConditions to avoidMaterials to avoidHazardous decompositionproductsHazardous polymerization:::::Stable under recommended storage and handling conditions (see section 7).Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.Reactive or incompatible with the following materials:,acids,oxidizing materials,strongalkalisUnder normal conditions of storage and use, hazardous decomposition products shouldnot be produced.Under normal conditions of storage and use, hazardous polymerization will not occur.United States - Canada - MexicoPage: 5/8

Product code AT90H-23 Date of issue 22 September 2009VersionProduct name AMERCOAT 90HS PEARL GRAY RESIN811 .Toxicological informationAcute toxicityProduct/ingredient name Result Species Dose Exposurereaction product: bisphenol-A-LD50 Oral Rat >2 g/kg -(epichlorhydrin) and epoxy resin (numberaverage molecular weight 2 g/kg -solvent naphtha (petroleum), light arom. LD50 Oral Rat 8400 mg/kg -LD50 Dermal Rabbit 3.48 g/kg -1-methoxy-2-propanol LD50 Oral Rat 5.2 g/kg -LD50 Dermal Rabbit 13 g/kg -titanium dioxide LD50 Oral Rat >10 g/kg -1,2,4-trimethylbenzene LD50 Oral Rat 5 g/kg -LC50 Inhalation Rat 18000 mg/m3 4 hoursxylene LD50 Oral Rat 4.3 g/kg -LD50 Dermal Rabbit >1.7 g/kg -LC50 Inhalation Rat 5000 ppm 4 hoursVaporConclusion/Summary : Not available.Chronic toxicityConclusion/SummaryDefatting irritant?Target organsCarcinogenicityConclusion/SummaryCarcinogenicityClassification: Not available.: Not available.Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHATalc , not containing asbestiform fibres A4 3 - - - -titanium dioxide A4 2B - - - -MutagenicityConclusion/SummaryMutagenicityTeratogenicityConclusion/SummaryTeratogenicityReproductive toxicityConclusion/SummaryDevelopmental effectsFertility effects: Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ordermatitis.: Contains material which causes damage to the following organs: lungs, brain, skin,central nervous system (CNS).Contains material which may cause damage to the following organs: blood, kidneys,liver, heart, cardiovascular system, upper respiratory tract, eyes.: Contains material which may cause cancer, based on animal data. Risk of cancerdepends on duration and level of exposure.: Not available.: No known significant effects or critical hazards.: Not available.: No known significant effects or critical hazards.: Not available.: No known significant effects or critical hazards.: No known significant effects or critical hazards.United States - Canada - MexicoPage: 6/8

Product code AT90H-23 Date of issue 22 September 2009VersionProduct name AMERCOAT 90HS PEARL GRAY RESIN15 .Regulatory informationSARA 313Form R - ReportingrequirementsCanadaWHMIS (Canada)MexicoClassificationFlammability:TSCA 12(b) one-time export: No products were found.SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Talc , not containing asbestiform fibres;titanium dioxide; 1-methoxy-2-propanol; 1,2,4-trimethylbenzeneSARA 311/312 MSDS distribution - chemical inventory - hazard identification: Talc ,not containing asbestiform fibres: Immediate (acute) health hazard; titanium dioxide:Immediate (acute) health hazard; 1-methoxy-2-propanol: Fire hazard, Immediate (acute)health hazard, Delayed (chronic) health hazard; 1,2,4-trimethylbenzene: Fire hazard,Delayed (chronic) health hazardCERCLA: Hazardous substances.: No products were found.Product name CAS number Concentration: 1,2,4-trimethylbenzene 95-63-6 3 - 7Additional environmental information is contained on the Environmental Data Sheet for this product, which canbe obtained from your PPG representative.16 .Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A:Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxiceffects (Toxic).: 3 Health : 2 Reactivity : 0Other informationHazardous Material Information System (U.S.A.)Health : 2 * Flammability : 3 Physical hazards :( * ) - ChroniceffectsCaution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implementedHMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®materials may be purchased exclusively from J. J. Keller (800) 327-6868.The customer is responsible for determining the PPE code for this material.National Fire Protection Association (U.S.A.)HealthDisclaimer: 2 Flammability : 3 Instability :Date of previous issue : 7/23/2009.Organization that preparedthe MSDS: EHSIndicates information that has changed from previously issued version.The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of thisinformation is to draw attention to the health and safety aspects concerning the products supplied by PPG, and torecommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given inrespect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measuresdescribed in this data sheet or for any misuse of the products.008United States - Canada - MexicoPage: 8/8