Learning Guide for Chapter 24 - Carboxylic Acid derivatives
Learning Guide for Chapter 24 - Carboxylic Acid derivatives
Learning Guide for Chapter 24 - Carboxylic Acid derivatives
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LG Ch <strong>24</strong> p 8Esters - C=O at 1735 cm -1C-O at 1000-1300 cm -1-1Amides - C=O at 1650 cmN-H 3200-3400 cm -1 (2 <strong>for</strong> primary, 1 <strong>for</strong> secondary, none <strong>for</strong> tertiary)NH 2 scissor sometimes overlaps C=ONitriles - triple bond at 2260-2200 cm -1NMR - protons on C's next to C=O's are around 2.0-2.5 ppm <strong>for</strong> all functional groupsprotons on C's next to O's are between 3-4 ppm in alcohols, ethers, and estersprotons on C's next to N's are between 2.5 and 3.0 <strong>for</strong> amines and amidesamide H's are variable, but usually appear between 5-8 ppm and exchange w/D 2 OH's on C=O's are about 9-11 ppm <strong>for</strong> aldehydes, 8 ppm <strong>for</strong> <strong>for</strong>mic acid <strong>derivatives</strong>OOH 3 C C NONHOH NH 2