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From Waste to Jet Fuels Novel technology in addition to ... - Bioenergi

From Waste to Jet Fuels Novel technology in addition to ... - Bioenergi

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Clear path <strong>to</strong> scaleStra<strong>in</strong>DevelopmentCSTRLabPilotPilotDemo•Bench <strong>to</strong>p•Scalable design•NZ Steel mill pilot•Pre-commercialplantReproducible & consistent data at each reac<strong>to</strong>r scale6


Our Plant <strong>in</strong> Shanghai• 400,000 liter ethanol py capacity• Reproducible results <strong>in</strong> Lab, Pilot and Demo reac<strong>to</strong>rs• BaoSteel is Ch<strong>in</strong>a’s 2 nd largest steel producer, 3 rd <strong>in</strong> theworld


Feeds<strong>to</strong>ck Flexible CommercializationIn DesignBiomassSyngasIn DesignMSWSyngas20132008 2012PilotBlueScope Steel MillBao Demo: OperationalBOF Gas50% CO, 2% H 2COREX Gas42% CO, 12% H 2LDG/COREX Mix 2BOF/COGMixGroundbreak<strong>in</strong>gFebruary 278


Accessible Feeds<strong>to</strong>ck PoolFlue GasesPet Coke~90M MTACO 2 + H 2CO + H 2COMunicipal<strong>Waste</strong>>2B MTANatural GasBiomass3300B M 3>1B MTA US Alone*2010 production data – IEA, UNEP9


Product Portfolio~1.7M bpdEthanolEthanolButanolButanediolPropanol~4 M MTA~5.5M bpdHydrocarbon<strong>Fuels</strong>~50 M MTA~51M bpd~8.5M bpd*2010 global consumption data - Harts, IEA10


Diverse Pathways <strong>to</strong> Renewable <strong>Fuels</strong>StarchesEnzymatic ConversionBiochemical ConversionEnzymatic Hydrolysis Sugars Fermentation SeparationAlcohols, ChemicalsThermochemical ConversionLign<strong>in</strong>, Cellulose,HemicelluloseFast PyrolysisGasificationLiquidBio-OilSyngasCatalytic Upgrad<strong>in</strong>gFischer TropschAlcohol SynthesisGasol<strong>in</strong>eGasol<strong>in</strong>e, Diesel, <strong>Jet</strong>AlcoholsIndustrial<strong>Waste</strong> Gases(CO, CO/H 2 )FermentationSeparationGas FermentationCatalytic ConversionGasol<strong>in</strong>e, Diesel, <strong>Jet</strong>Alcohols, ChemicalsAlgaeOil ExtractionTrans-esterificationLipid ConversionFAME, FAEENatural OilsHydrotreat<strong>in</strong>g/Hydrocrack<strong>in</strong>gDiesel, <strong>Jet</strong> (HEFA/HRJ)11


Hydrocarbon <strong>Fuels</strong> Process* Gas Feed StreamGas Reception Fermentation Recovery AlcoholChemical Synthesis Rectification Diesel <strong>Jet</strong> Gasol<strong>in</strong>eMixtureGas Feed Stream• CO from Industrial <strong>Waste</strong> Gases• Syngas from Biomass, MSW, Reformed Natural Gas or Other Sources• Partner<strong>in</strong>g for the AtJ conversion<strong>Novel</strong> Route <strong>to</strong> Drop <strong>in</strong> Hydrocarbon <strong>Fuels</strong>Key Enabler: Price and Availability of Alcohol12


$4m DOE award: A Hybrid CatalyticRoute <strong>to</strong> <strong>Fuels</strong> from Biomass SyngasProject Objectives:Develop a cost-effective hybrid conversion <strong>technology</strong> for catalytic upgrad<strong>in</strong>g of biomassderivedsyngas <strong>to</strong> jet fuel and chemicals <strong>to</strong> meet the price, quality and environmentalrequirements of the aviation <strong>in</strong>dustry.WoodS<strong>to</strong>verSwitchgrassGasification& SyngasCondition<strong>in</strong>gFermentation& AlcoholRecoveryIntegrationEOH2,3BDOCatalysisCatalysisGasol<strong>in</strong>e<strong>Jet</strong> FuelDieselButadieneMEKSystem Integration, Optimization and AnalysisImprove Economics and Process Susta<strong>in</strong>ability13


Susta<strong>in</strong>able Alternative <strong>Jet</strong> Fuelfrom Biomass and <strong>Waste</strong> GasesProject Team:Swedish Biofuels, ABAlcohol-<strong>to</strong>-<strong>Jet</strong> ConversionIntegrated Process DesignU.S. DOTVolpe Na onalTransporta on CenterLanzaTech, Inc.Batelle Pacific NorthwestDivision (PNWD)Alcohol ProductionIntegrated Process DesignProject ManagementMichigan TechnologicalUniversityLife Cycle AssessmentsSteer<strong>in</strong>g TeamAFRLAlaska Airl<strong>in</strong>esATABoe<strong>in</strong>gNASAPratt & WhitneyValeroImperium RenewablesProject Objectives:• Optimize ATJ fuel process,us<strong>in</strong>g steel mill off gases andlign<strong>in</strong>• Produce 100+ gallons of fullysyntheticalternative jet fuel forcertification test<strong>in</strong>g• Develop prelim<strong>in</strong>ary design, TEAand LCA for commercial-scalefacility• Assess feeds<strong>to</strong>ck availability andpotential commercial sitesTechno-economic AnalysesFeeds<strong>to</strong>ck Availability StudySite Evaluation14


LT-SB SPK Sample PropertiesPropertyASTMTest MethodASTMD7566LT-SBSampleTotal Aromatics, volume % D1319 < 25 0.6Freeze po<strong>in</strong>t, °C D5972 < -40 < -77Flash po<strong>in</strong>t, °C D93 > 38 54Density at 15°C, kg/L D4052 0.751 - 0.770 0.762Heat of combustion, MJ/kg D4809 > 42.8 43.5Hydrocarbon Type AnalysisAromatics, volume % D6379 < 0.5 < 0.2Aromatics, mass % D2425 < 0.5 < 0.3Cycloparaff<strong>in</strong>s, mass % D2425 < 15 8Paraff<strong>in</strong>s D2425 report 91API Gravity at 60 o F D1298 52 - 57 54.2Olef<strong>in</strong>s, % volume D1319 report 1.0Key Properties Confirmed15


Commercialization of Aviation FuelImperial College of LondonTeam Work is Key <strong>to</strong> Success1616


SUSTAINABILITY FRAMEWORKEU Regula<strong>to</strong>ry Framework is the Start<strong>in</strong>g Po<strong>in</strong>t<strong>to</strong> Improve Economics for Renewables MarketEU EmissionTrad<strong>in</strong>g Scheme• 2005: power generation, oil ref<strong>in</strong>ery, steel,cement and lime, pulp, board andpaper sec<strong>to</strong>rs• 2012: Aviation• 2013: Ammonia• Susta<strong>in</strong>abilitycriteria differper sec<strong>to</strong>rEU RenewableEnergy DirectiveEU FuelQuality DirectiveLanzaTech• 10% of all transport fuels from renewablesources <strong>in</strong> 2020– Most MS apply only <strong>to</strong> road transport• Fuel Producers & Suppliers (Traders)• Reduction of the greenhouse gas <strong>in</strong>tensityof liquid fuels by at least 6% by 31December 2020 (part of EU RED)• Fuel Suppliers• Partner of EC Biofuels Flight path aim <strong>to</strong> produce and consume 2 mln<strong>to</strong>n py <strong>in</strong> 2020 <strong>in</strong> aviation <strong>in</strong>dustry• GHG sav<strong>in</strong>gs atleast 35% (50%2017 / 60% 2018)• No conversion ofland with highcarbon s<strong>to</strong>ck• No raw materialfrom land withhigh biodiversityvalueNew ILUCproposal17


gCO 2 e/MJA new source for renewable fuelsLanzaTech fits <strong>in</strong> European regulations:• Our Proprietary microbe falls under Article2(e) – ‘biodegradable fraction of <strong>in</strong>dustrialwaste’ *• Meets required GHG emission reductions• No <strong>in</strong>volvement <strong>in</strong> food value cha<strong>in</strong>• No ILUC or LUC120100806040Life Cycle GHG Emission9045Life Cycle Assessment collaborations:• Michigan Technological University• Ts<strong>in</strong>ghua University• Roundtable on Susta<strong>in</strong>able Biofuels200ConventionalGasol<strong>in</strong>eLanzaTech e<strong>to</strong>hGHG footpr<strong>in</strong>t is 50% of the footpr<strong>in</strong><strong>to</strong>f produc<strong>in</strong>g petroleum fuelsUnlike many types of traditional biomass –LanzaTech expands the renewables poolwithout impact on land or food.* Article 2(e) DIRECTIVE 2009/28/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL18


LanzaTech Global Partnerships19


Creat<strong>in</strong>g Value through DiversificationIndustry Partners/Projects End User/MarketsSteelOil/Natural GasCoalBiomassChemicals20


2012 & 2013 Global Recognition2012TiE50 has named LanzaTech as one of the <strong>to</strong>pEnergy/CleanTech <strong>technology</strong> start upcompanies for 2012. TiE50 is TiE Silicon Valley’spremier annual awards program keenlycontested by thousands of <strong>technology</strong> startupsworldwide.MIT <strong>technology</strong> reviewLanzaTech was named by TechnologyReview <strong>to</strong> the 2012 TR50, the thirdannual list of the world’s most<strong>in</strong>novative <strong>technology</strong> companiesLanzaTech has been named asone of 10 New Energy Pioneersat the fifth annual Bloomberg NewEnergy F<strong>in</strong>ance Summit. Thisaward recognizes LanzaTech as aworld-leader <strong>in</strong> energy <strong>in</strong>novation.Richard Pearse Award for InnovationExcellence <strong>in</strong> the NZ Aviation Industry LanzaTech has won the RichardPearse Award for InnovationExcellence <strong>in</strong> the NZ AviationIndustry.2013LanzaTech has been selected as a World EconomicForum Technology Pioneer 2013. Recognition is forcompanies <strong>in</strong>volved <strong>in</strong> the design, development anddeployment of new technologies and hold promise ofsignificantly impact<strong>in</strong>g the way bus<strong>in</strong>ess and societyoperates.Recognized as Thought Leader <strong>in</strong> Sec<strong>to</strong>r21


Summary• To meet grow<strong>in</strong>g energy demand & stabilize atmospheric CO 2 levels, there is aneed <strong>to</strong> diversify fuel pool through multiple pathways• Emerg<strong>in</strong>g technologies and cont<strong>in</strong>uous <strong>in</strong>novation will support reach<strong>in</strong>gEurope’s renewable energy goals• LanzaTech fits <strong>in</strong> current regulations and is removed from the food for fueldiscussion• The LanzaTech process captures non-food, waste carbon<strong>to</strong> produce low cost alcohols, thereby challeng<strong>in</strong>g traditional conceptions ofwaste and energy sources• Alcohols produced via the LanzaTech process are an excellent substrate forconversion <strong>to</strong> drop-<strong>in</strong> hydrocarbon fuels• Commercial alcohol production rates on raw <strong>in</strong>dustrial waste gases has beendemonstrated at scale• Compell<strong>in</strong>g volumes of waste gases world wide have potential <strong>to</strong> makesignificant impact on the fuel pool22

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