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Statement of Basis Vigor Shipyards Inc. - Puget Sound Clean Air ...

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<strong>Statement</strong> <strong>of</strong> <strong>Basis</strong> for<strong>Vigor</strong> <strong>Shipyards</strong>, <strong>Inc</strong>.Administrative Amendment: June 13, 2011 Page 13 <strong>of</strong> 315. 2.8 Requirement I.A.10<strong>Puget</strong> <strong>Sound</strong> <strong>Clean</strong> <strong>Air</strong> Agency Regulation I, Section 9.10 specifies that HCl emissionsshall not exceed 100 ppm (dry) corrected to 7% O 2 for combustion sources. Since ToddPacific <strong>Shipyards</strong> burns only pipeline grade natural gas and distillate fuel oil and theother processes do not use chlorine in a form likely to emit HCl, it is incapable <strong>of</strong>violating this standard while complying with the other requirements in the permit.Refer to the “Conversion Factors for Concentration” table in Section 2 <strong>of</strong> ReferenceMethod 19 to compute value for C d . Note that this factor is equal to molecular weight <strong>of</strong>the pollutant divided by 10 6 , and then divided by 385.3 ft 3 per mole. The conversionfactor for HCl is 36.4610 -6 /385.3 ft 3 = 9.46310 -8 lb/dscf-ppmdv. One part per million<strong>of</strong> HCl is equivalent to 9.46310 -8 lb HCL per dry standard cubic foot <strong>of</strong> stack gas.Residual oil:EquationEquation 1According to AP-42, Section 1.3:• Burning 1,000 gallons <strong>of</strong> No. 6 “residual” oil produces 0.347 pound <strong>of</strong>chloride. Assume all <strong>of</strong> the chloride is emitted in the form <strong>of</strong> hydrogenchloride.• There are 150 MMBtu/10 3 gallons <strong>of</strong> No. 6 oil.Equation converts the emission factor for chloride in Table 1.3-11 frompounds <strong>of</strong> HCl per 1,000 gallons <strong>of</strong> oil burned to pounds per million Btu.3lb10 gallbE 0.347 0.3470.00231310 gal 150 MMBtu MMBtuAccording to Table 19.1 <strong>of</strong> EPA Reference Method 19:• Burning a million Btu <strong>of</strong> oil produces 9,190 dry standard cubic feet <strong>of</strong>stack gas.• One part per million HCl is equivalent to 9.46310 -8 pound <strong>of</strong> HydrogenChloride per dry standard cubic foot.Equation 1 is derived from Equation 19-1 from EPA Reference Method 19,which may be used to calculate parts per million HCl, corrected to 7% O 2 ,from HCL emissions in lb/MMBtu.Cd E20 .9%O2( dry)20.9 7 20.9Fd 0.00231lbMMBtu8MMBtudscf ppmdv20.9dscf lb9,1909.4610Therefore, based on the AP-42 emission factor for HCl (expressed aschloride) from new residual oil, the concentration <strong>of</strong> HCl in the boilerexhaust will be less than 2% <strong>of</strong> the regulatory limit <strong>of</strong> 100 ppmdv,corrected to 7% O 2 , 1.77ppmdv

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