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From landfill to the tomato plant – purified biogas powers ... - Eco-Tec

From landfill to the tomato plant – purified biogas powers ... - Eco-Tec

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Te Ca Fe c at s h e u n in r o elPo o g y i n Sp <strong>to</strong> t l i g h t<strong>From</strong> <strong>landfill</strong> <strong>to</strong> <strong>the</strong> <strong>to</strong>ma<strong>to</strong><strong>plant</strong> – <strong>purified</strong> <strong>biogas</strong> <strong>powers</strong>greenhouse operationThe Board of Waste Management for<strong>the</strong> Mauricie region of Quebec, Canada,known as RGMRM, needed a gasscrubber <strong>to</strong> remove <strong>the</strong> highly corrosivelevels of hydrogen sulfide (H 2S) at itsmunicipal <strong>landfill</strong>.The aim was <strong>to</strong> purify <strong>the</strong> <strong>landfill</strong> gasfor a greenhouse on site, which also isRGMRM’s cus<strong>to</strong>mer. The gas was <strong>to</strong> beconverted in<strong>to</strong> a usable source of heatfor <strong>the</strong> greenhouse, especially during <strong>the</strong>winter months, and in<strong>to</strong> a source of CO 2<strong>to</strong> enrich <strong>the</strong> hydroponic <strong>to</strong>ma<strong>to</strong>es grown<strong>the</strong>re. In turn, <strong>the</strong> renewable source ofcarbon dioxide, present in <strong>the</strong> <strong>biogas</strong>,would eliminate <strong>the</strong> costs associated withhaving <strong>to</strong> purchase and maintain CO 2for<strong>the</strong> operation.In 2009, RGMRM found a solutionthrough an <strong>Eco</strong>-<strong>Tec</strong> Inc. system knownas BgPur, which uses a patented, highefficiency gas-liquid contacting process,allowing H 2S <strong>to</strong> be absorbed and <strong>the</strong> gas<strong>purified</strong> for reuse in power generation,cogeneration and heating applications.Today, <strong>the</strong> BgPur system continues <strong>to</strong> successfully removemore than 99 percent of hydrogen sulfide from <strong>the</strong> gasat RGMRM’s <strong>landfill</strong>, for reuse in its internal processes.Located among <strong>the</strong> Laurentian Mountains, RGMRM is <strong>the</strong>board of management of waste for <strong>the</strong> Mauricie region ofQuebec, Canada, which has a population of approximately300,000 people. The public body was formed through anamalgamation ofseveral municipalitiesentrusting it <strong>to</strong>manage <strong>the</strong> region’swaste. RGMRM’smission includesrespect for <strong>the</strong>environment, soundmanagementprinciples and a focuson innovation.Figure 1. The washed solid crystalline sulfurproduced by BgPur is pure sulfur, which canbe used as an agricultural supplement andresold as a valuable commodity by <strong>the</strong> client.It was RGMRM’sfirst partnership withfellow Canadianmanufacturer, <strong>Eco</strong>-Contributed by <strong>Eco</strong>-<strong>Tec</strong>Figure 2. An RGMRM installation<strong>Tec</strong> Inc., located in Pickering, Ontario. <strong>Eco</strong>-<strong>Tec</strong>’s in-houseResearch and Development facility has been building industrialpurification solutions since 1970, and has installed more than1,500 systems in more than 55 countries.RequirementsRGMRM needed a <strong>landfill</strong> gas scrubber that would removeH 2S and allow <strong>the</strong> gas <strong>to</strong> be used as a source of heat andCO 2for a 540,000 sq. ft. greenhouse on site. The volume ofsaturated <strong>landfill</strong> gas extracted from <strong>the</strong> wells is 3,085 Nm 3 /hour, at a maximum temperature of 40°C and with an H 2Sconcentration of 50 ppmv.The greenhouse specified that <strong>the</strong> gas needs <strong>to</strong> beprovided <strong>to</strong> <strong>the</strong>m with an H 2S concentration of less than 1ppmv and dried <strong>to</strong> a maximum dew point temperature of 3°C.SolutionThe BgPur system was designed for <strong>the</strong> client <strong>to</strong> handle<strong>the</strong> complete flow through two single contac<strong>to</strong>rs <strong>to</strong> remove <strong>the</strong>H 2S down <strong>to</strong> <strong>the</strong> required level. The <strong>purified</strong> gas is compressed(<strong>to</strong> 1 barg) and <strong>the</strong>n chilled <strong>to</strong> meet <strong>the</strong> greenhouse’srequirements.10 Biomass Products & <strong>Tec</strong>hnologyJune 2011


Te c h n o l oCa g y sSp e in o tPo lTe i g i n h x tThis specific BgPur configuration – which features twocontac<strong>to</strong>r tanks ra<strong>the</strong>r than one – was installed for RGMRMbecause of <strong>the</strong> large volume of gas coming from <strong>the</strong> <strong>landfill</strong>(3,085 Nm 3 /hour). Each contac<strong>to</strong>r can handle about 1,500Nm 3 /hour.The overall system eliminated <strong>the</strong> need for 9 million m 3 /year of natural gas and, as a result, reduced Greenhouse Gas(GHG) emissions by approximately 135,000 <strong>to</strong>ns of CO 2for<strong>the</strong> client. The H 2S in <strong>the</strong> treated gas is less than 1ppmv, andgenerally below <strong>the</strong> detection limit of 0.2 ppmv more than <strong>the</strong>entire inlet concentration range.SystemThe H 2S scrubber system is designed with a patentedmass transfer technology that allows <strong>the</strong> H 2S <strong>to</strong> be absorbedin<strong>to</strong> solution where <strong>the</strong> chemistry converts it in<strong>to</strong> elementalsulfur. The system takes advantage of <strong>the</strong> oxygen present in<strong>landfill</strong> gas, which regenerates <strong>the</strong> absorption chemistry at<strong>the</strong> same time. The elemental sulfur floats <strong>to</strong> <strong>the</strong> surface as afroth/foam where it overflows in<strong>to</strong> a slurry thickening section.The slurry is pumped <strong>to</strong> a filter press which removes <strong>the</strong> solidsulfur and returns <strong>the</strong> filtrate back <strong>to</strong> <strong>the</strong> contac<strong>to</strong>r for a fullyclosed-loop process.The filter press provides a 60-65 w/w sulfur cake, whichis greater than 99 percent sulfur. The washed solid crystallinesulfur produced by BgPur is pure sulfur, which can be usedas an agricultural supplement that can be resold as a valuablecommodity by <strong>the</strong> client.For RGMRM, <strong>the</strong> system also delivers a simple designand operation with no packed columns, allowing continuousreliable operation without any column <strong>to</strong> plug, foul or foam;and no labor formedia cleaningor replacement.The systemarrived fac<strong>to</strong>ryconstructedwith a compactdesign, whichprovides a smallfootprint, shortdelivery and lowinstalled costs.The au<strong>to</strong>matedcontrol systemdetects response<strong>to</strong> changes ingas flow-rate orH 2S compositionand suppliesau<strong>to</strong>maticreagent addition.As well,Figure 3. Single contac<strong>to</strong>r schematic<strong>the</strong>re’s no wasteresulting from <strong>the</strong>operation, onlyenvironmentally acceptable solid sulfur cake, which means noadditional waste treatment equipment or operating costs areneeded; and no disposal of potentially hazardous media. CFor more information, visit www.eco-tec.comJune 2011www.GoBiomass.com11

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