Curriculum Vitae of Professor Maria de Fatima Guedes da Silva

Curriculum vitaeMaria de Fátima Costa Guedes da Silva

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 1 / 47Index2. EDUCATION ............................................................................................................................................... 33. SCIENTIFIC CARRER ................................................................................................................................. 34. POSITIONS ................................................................................................................................................. 45. TEACHING COMMITMENTS ....................................................................................................................... 5AT UNIVERSIDADE LUSÓFONA DE HUMANIDADES E TECNOLOGIAS (ULHT, LISBON) ...................... 5AT INSTITUTO SUPERIOR TÉCNICO (IST, LISBON)................................................................................ 56. MAIN RESEARCH AREAS AND METHODS .................................................................................................. 5GENERAL AREAS ...................................................................................................................................... 5SPECIFIC AREAS ....................................................................................................................................... 5TECHNIQUES ............................................................................................................................................. 67. PROJECTS .................................................................................................................................................. 68. RESERARCH TRAINING SUPERVISION ....................................................................................................... 79. PUBLICATIONS .......................................................................................................................................... 9I – CONTRIBUTIONS IN BOOKS OR IN REVIEWS ..................................................................................... 9II – RESEARCH PAPERS .......................................................................................................................... 10III RESEARCH PAPERS IN A NATIONAL (REFEREED) JOURNAL ...................................................... 27IV – PATENTS ......................................................................................................................................... 28INVITED LESSONS ................................................................................................................................... 30COMMUNICATIONS (ORAL AND POSTER) AT CONGRESSES. ................................................................ 31

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 2 / 47Abridge CVName : Maria de Fátima Costa Guedes da Silva.Nationality – PortugueseDate and Place of Birth - May 12th, 1958, Porto.Education - Chemistry (1982, FCL); Masters in Chemistry (1989, IST); D. Phil. in Chemical Engineering (1993,IST).http://cqe.ist.utl.pt/personal_pages/pages/fatima_guedes.phpPresent positions :i) Associate Professor (Universidade Lusófona de Humanidades e Tecnologias -ULHT, since 1995).ii) Researcher at the Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais,1049-001 Lisbon, PortugalContacts:E-mail : fatima.guedes@ist.utl.ptTel.: +351.218.419.207 (office); +351.218.419.235 (lab.); +351.218.417.657 (X-ray lab.)Mobile: +351.936 408 681Teaching commitments:Organic Chemistry (ULHT, since 1996); Analytical Chemistry (ULHT, since 1996); Structural Analysis (ULHT,1996-2006); Chemical Analysis (ULHT, 2005-2006); Inorganic Chemistry I and II (ULHT, 2009); GeneralChemistry (ULHT, 2011).Area of scientific activityBioinorganic, Inorganic and Analytical Chemistries; Coordination and Organometallic Chemistries. Molecularelectrochemistry. X-ray Diffraction analysis.Main research interests• Activation, by transition metal centres, of small molecules with biological, environmental,pharmacological or industrial significance (alkanes, nitriles, cyanamides, oximes, oxadiazolines,carboxamides, amidines, alkynes, phosphaalkynes, isonitriles, olefins, nitric oxide, dinitrogen, diazocompounds, azides, cyanates, dihydrogen, etc.);• Mechanistic investigation of the mechanisms of fast reactions (e.g. protonation or electron transferprocesses), mainly by digital simulation of cyclic voltammetry;• conventional and non-conventional electrochemical methods, the latter including fast cyclic voltammetryand digital simulation;• Single crystal X-ray diffraction analysis.Official appointments, membership of professional bodies, commissions, etc.:Member of the Portuguese Electrochemical Society (since 1987). Member of the Iberoamerican Society ofElectrochemistry (since its foundation, 1992). Editor of the Journal Portugaliae Electrochimica Acta (1996-2002).Member of the Directive board of the Portuguese Electrochemical Society (1996-2002). Member of the Organizingor Cientific Committees of the following symposia: NATO Advanced Research Workshop on "MolecularElectrochemistry of Inorganic, Bioinorganic and Organometallic Compounds" (Sintra, Portugal, 1992) (Director: A.Pombeiro, Co-director: J. McCleverty); 9º, 10º and 11º Meetings of the Portuguese Electrochemical Society; XVMeeting of the Iberoamerican Society of Electrochemistry, SIBAE (Évora, 2002); 12º Meetings of the PortugueseElectrochemical Society /Symposium on Molecular Electrochemistry (Academia das Ciências de Lisbon) (2003);XXV Int. Conf. Organometallic Chemistry (ICOMC2012, held in Lisbon in 2012; chairman: A. Pombeiro).Recent collaborations in research projects: “Metal-based Synthons with Pharmacological Significance” (ProjectPOCTI/QUI/43415/2001, sponsored by the POCTI programme, FCT). “Early-Late Multinuclear Metal Systems onDesign and Development of New Materials” (NATO Collaborative Linkage Grant PST. CLG. 979289). “TransitionMetal Chemistry and Catalysis in Aqueous Media” [Project MRTN-CT-2003-503864, Human Resources andMobility (HRM) Marie Curie Research Training Network (RTN)]. “Chemical Synthesis and Catalysis” (ProjectCONC-REEQ/543/2001, National Programme for Re-Equipping Science). “Catalytic Carboxylation of Alkanes”(Project POCI/QUI/58821/2004, sponsored by the POCI 2010 Programme, FCT).Reserarch training supervision: 3 Ph.D. (two awarded); 3 foreign Post-doc. fellows.Publications: 2 Chapters and 8 other contributions in books; ca. 168 research papers in International Journals; 19research papers in a national Journal; ca. 10 patents; 5 invited lectures in international Meetings; ca. 157 oral orposter communications in international congresses.Citation Report2,337 citations (142 publications found); average citations per publication = 14,46;h-index = 26 (ISI Web of Knowledge, June 5 th , 2012)

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 3 / 471. IDENTIFICATIONName : Maria de Fátima Costa Guedes da Silva.Date and Place of Birth: 12 th May, 1958.Nationality: Portuguese.Present positionsi) Associate Professor (Universidade Lusófona de Humanidades e Tecnologias -ULHT, since1995).ii) Researcher at the Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av.Rovisco Pais, 1049-001 Lisbon, PortugalOfficial addresses:Teaching: Universidade Lusófona de Humanidades e Tecnologias, Av. Campo Grande 376,1749-024 LisbonResearch: Centro de Química Estrutural, Complexo I, Instituto Superior Técnico,Av. Rovisco Pais, 1049-001 LisbonContacts:Teleph: +351-210417657 (X-ray lab)/ +351-218 419 225 (lab) or 207 (Office).E-mail: fatima.guedes@ist.utl.ptURL: http://cqe.ist.utl.pt/personal_pages/pages/fatima_guedes.php2. EDUCATIONDegree : Chemistry, University of Lisbon, 1982.Master : "Chemistry of the catalytic processes", IST, TU Lisbon, l989. Supervisor Prof. Dr. Armando J.L.Pombeiro.PhD: Chemical Engeneering, IST, TU Lisbon, 1993. Supervisor Prof. Dr. Armando J.L. Pombeiro.3. SCIENTIFIC CARRERAfter graduation the research began, free of charge, in the Electroplating field, at the Center forElectrochemistry and Kinetics, University of Lisbon, under the guidance of Prof. Isabel Pereira. In 1986she was admitted to the Master in Chemistry of Catalytic Processes (IST) and in 1987 she was awarded aMaster's scholarship by INIC. At this stage, the work was carried out under the supervision of Prof. Dr.Armando Pombeiro at the Centro de Química Estrutural (IST). Having completed the Master shecontinued her studies in the same place and with the same supervisor, under a PhD fellowship [initiallygranted by INIC, later transferred to the JNICT (CIENCIA Program) ], jointly in Line I (BioinorganicChemistry under the responsibility of Prof. Fraústo Dr. da Silva) and in Line V (Coordination Chemistryand Molecular Electrochemistry, under the responsibility of Prof. Armando Pombeiro)].During the PhD:i) She prepared the first rhenium(I) complexes containing chelating diphosphines in cis position andsynthesized a series of mono-and di-nitrile compounds with that metal center, as well as, by protonationreactions, some derived metheleneamide species.ii) She devoted to the analysis of complex spectra of nuclear magnetic resonance by using the iterativespin simulation program LAOCOON.iii) In collaboration with Prof. Christian Amatore, École Normale Superieure, in Paris, she developednon-conventional electrochemical techniques, particularly fast cyclic voltammetry and cyclicvoltammetry in steady-state conditions, and she built a potentiostat and her own ultramicroelectrodes ofgold and platinum (diameters up to 5 m).iv) She began the study of mechanisms of fast reactions by techniques of digital simulation in cyclicvoltammetry and stopped flow spectrophotometry, in collaboration with Profs. Christian Amatore andRichard A. Henderson (Univ. of Sussex), respectively.In parallel to the research work leading to the PhD degree, but regardless of this, and given the interest instudying the electrochemical behaviour of complexes with biological significance:v) Collaborated with the group of Prof. Fraústo da Silva in the investigation of the electrochemicalbehaviour of complexes of vanadium (IV), models of Amavadine.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 4 / 47vi) Collaborated in the study of the electrochemical properties of cobalt (II), nickel (II) and copper (II)complexes with Schiff bases containing indole groups, which were prepared by the group of Prof. P. Gili,University of La Laguna, Tenerife.vii) Collaborated in the study of the electrochemical properties of palladium (II) and platinum (II)complexes with Fischer type carbene ligands, in collaboration with the group of Prof. Rino. A. Michelin,University of Padua.viii) Collaborated in the study, by electrochemical techniques, of the effects of substituents oncyclopentadienyl rings in ferrocene compounds synthesized by Dr. Rudolf Herrmann, University ofMunich, which allowed the determination of p (Hammett) and *(Taft) parameters for 73 of thesesubstituents.After the PhD (1993), the research has been developed in different scientific general areas:a) Molecular electrochemistry:• Developed simulation techniques for digital cyclic voltammetry which has allowed the study ofvarious mechanisms of anodically induced fast reactions, particularly in systems of biologicalsignificance or application in organic synthesis.• Established a new type of mechanism of electrocatalises and demonstrated the occurrence of aMichaelis Menten type electrocatalytic process for the oxidation of thiols mediated by a complexof vanadium, an Amavadin model (collaboration with the group of Prof. Fraústo da Silva andProf. C. Amatore).• Established the mechanism of electron-transfer induced cis/trans isomerization i) in amonocarbonyl diphosphinic Re(I) complex which, follows a rare electrocatalytic electron transferchain process with a null global flow of current; ii) in mono- and di -nitrile Re(I) complexes witha chelating phosphines; iii) in mixed thiol-isonitrile molybdenum (II) complexes.• Established the mechanisms of electron-transfer induced deprotonations of hydride complexes ofiron (II), mono- and di-nuclear with CNH or bridged dinitrile ligands; worked on the mechanimof the electron induced conversion of CNH2/CNH/CN on a diphosphine complex of rhenium (I).• Investigated the electrochemical behaviour of several other types of complexes, sometimes withinestablished collaborations with other groups: ruthenium (II) and osmium (II) withdimethylsulphoxide and hydrazinium ligands; rhodium (I) with diketonates type ligands; platinum(0, II and IV) with cinnamonitrile, ciclofosfazene and carbene ligands; tungsten with alcenilcarbyneligands; etc. ..b) Coordination chemistry and activation of small moleculesIntroduced in the research group (1993) the synthesis of platinum complexes, an area that came to bedeveloped later. She has supervised the synthesis and reactivity, characterization and reactivity tincomplexes, of platinum and other transition metals with cyanamides, oximes, nitriles, cyanide or othernitrogenous substrates, with possible pharmacological significance.c) X-ray diffraction analysesSince 1997 has been dedicated to the structural determination, by X-ray diffraction analyses, of variousmetal complexes and organic compounds.4. POSITIONS· Member of the organizing and scientific commission of the 25 th International Conference onOrganometallic Chemistry (ICOMC) (Lisbon, 2012).· Editor of the Journal of the Portuguese Electrochemical Society, Portugaliae Electrochimica Acta(1996-2002).· Member of the Portuguese Electrochemical Society (since 1987).· Member of the Iberoamerican Electrochemical Society (since its foundation, in 1992).· Member of the Directive Board of the Portuguese Electrochemical Society (1996-2002).

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 5 / 47· Member of the organizing and scientific commissions of the following meetings: NATO AdvancedResearch Workshop on "Molecular Electrochemistry of Inorganic, Bioinorganic and OrganometallicCompounds" (Sintra Portugal, 1992); 9º, 10º and 11º Meetings of the Portuguese ElectrochemicalSociety; XV Meeting of the Iberoamerican Society of Electrochemistry, SIBAE (Évora, 2002); 12ºMeeting of the Portuguese Electrochemical Society /Symposium on Molecular Electrochemistry(Science Academy of Lisbon) (2003).5. TEACHING COMMITMENTSAT UNIVERSIDADE LUSÓFONA DE HUMANIDADES E TECNOLOGIAS (ULHT, LISBON) “Analytical Chemistry I”, 1996-2006 and “Analytical Chemistry”, since 2006. “Chemical Analysis”, 2005/06 and 2006/07. “Analytical Chemistry II” (Spectroscopic Methods), 1995-2006. “Chemistry III” (Organic Chemistry), since 1996. “Chemistry I” (General Chemistry), 1998/99 and 2007-08. “Microbial Technology”, 1995-96.AT INSTITUTO SUPERIOR TÉCNICO (IST, LISBON) "Coordination Compounds in Pharmacology” [2 years research course within the SpecificProgramme for the Development of the Portuguese Industry (PEDIP programme), I.S.T., 1991-93] . Ultramicroelectrodes in "Electrochemical Methods in Synthesis”, 1991-92 (M. Sc. course onChemical Engineering/Applied Chemistry, I.S.T.).6. MAIN RESEARCH AREAS AND METHODSGENERAL AREAS• Bioinorganic, Inorganic, Analytic, Coordination, Organometallic and Organic Chemistries.• Molecular Electrochemistry.SPECIFIC AREAS Activation of small molecules with biological, industrial or environmental interest or related ones(such as alkanes, alkynes, phosphaalkynes, isocyanides, dinitrogen, nitriles, cyanamides, nitricoxide, oximes, olefins, azides, cyanates, etc.) by transition metal centers.Crystal engineering of coordination compounds, self-assembly of polynuclear and supramolecularstructures, transition metal and organometallic chemistries. Molecular Electrochemistry of coordination and organic compounds, namely towardsapplications in electrosynthesis, electrocatalysis and in mechanistic studies, as well as in theestablishment of potential-structure relationships, and in the induction of chemical reactivity byelectron-transfer. Mechanisms of fast chemical or electrochemical reactions. Conventional molecular electrochemistry (e.g. cyclic voltammetry, controlled potentialelectrolysis). Unconventional molecular electrochemistry (use of ultramicroelectrodes in fast voltammetry, thedevelopment and use of digital simulation methods in cyclic voltammetry and their application tomechanistic studies of electrode processes involving fast reactions induced by electron-transfer,in electrocatalysis, etc.). stopped-flow spectrophotometry. mass spectrometry (including fast atom bombardment, FAB-MS) and its coupling to gaschromatography(GC-MS) .

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 6 / 47The application of digital simulation to the analysis of NMR spectra as well as NMRspectroscopy of various less-common nuclei.TECHNIQUES• High vacuum and inert atmosphere synthetical methods, and analysis of the reactional systemsand products obtained.• Multinuclear magnetic resonance.• Mass Spectrometry [fast atom bombardment (FAB) or electron impact (EI), and massspectrometry coupled to gas chromatography (GC-MS).• Stopped flow spectrophotometry (study of fast reaction kinetics).• Infrared and ultraviolet / visible spectroscopies• Chromatography (capillary columns).• Cyclic voltammetry and controlled potential electrolysis.• Digital simulation of cyclic voltammetry (application to establish mechanisms of electrodeprocesses).• Construction and use of ultramicroelectrodes (application of electrochemical techniques inunconventional, in particular fast scan cyclic voltammetry).• Structural analysis by single crystal X-ray diffraction7. PROJECTSUnder the responsability of A.J.L. Pombeiro: "Coordination Chemistry of Dinitrogen and Related Molecules" [project sponsored by INIC(1985-1992) or JNICT (1993-95)] . "Electrochemistry of Transition Metal Complexes” [project sponsored by INIC (1985-1992) orJNICT (1993-95)] . ”Activation of Small Molecules", FCT / JNICT (1996-99). "Molecular Electrochemistry of Coordination Compounds", FCT / JNICT (1996-99). “Coordination Chemistry and Molecular Electrochemistry”, Group V (Centro de QuímicaEstrutural), FCT (2000-07). “Coordination Chemistry and Molecular Electrochemistry, Synthesis and Catalysis”, Group V(Centro de Química Estrutural), FCT (since 2008). "Investigation of the Mechanisms of Proton Transfer Reactions, in Coordination Compounds, byStopped Flow Spectrophotometry" [project sponsored by the ICCTI (JNICT)/The British Councilprotocol]. Co-responsibility: Dr. R. Henderson (Nitrogen Fixation Laboratory, Norwich (1990-97). "Molecular Electrochemistry of Coordination Compounds - Application of Ultramicroelectrodes"(Project PMCT/C/CEN/339/90, sponsored by JNICT) (1990-94). "Synthesis and Mechanistic Studies in Bioinorganic Chemistry" [sponsored by the CIENCIA(Science) Program, Sub-program III - Global Support to the Scientific and Technological System,Infrastructures for Research and Development, Measure M] (1990-97) "Chemistry and Electrochemistry of Low-Valent Palladium and Platinum Complexes withUnsaturated C-N Ligands" (project sponsored jointly by INIC, JNICT and the CNR, Italy).(1991-92). "Mechanisms of the Activation of Metal-Ligand Bonds by Electrochemistry withUltramicroelectrodes. Application to the Study of Model Reactions for the Activation of SmallMolecules" (project sponsored jointly by INIC, JNICT and CNRS, France). (1992-96). "Activation and Electrochemistry of Unsaturated Small Molecules of Biological or IndustrialSignificance Nitric Oxide and Cyanamide" (Project STRDA/CEN/450/92, sponsored by theSTRIDE Program, Measure A) (1992-95).

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 7 / 47 "Activation of Unsaturated Small Molecules by Palladium or Platinum Metal Centres, a Chemicaland Electrochemical Investigation" (project sponsored jointly by JNICT and the CNR, Italy).(1993-94). “Development of Mimetic Systems of Fundamental Biological Processes with Environmental andEconomical Relevance" (Project PRAXIS/2/2.1/QUI/03/94, sponsored by the PRAXIS XXIProgramme for Scientific and Technological Research) (1994-99). "Multiple Metal-Carbon Bond Species in Selective Processes" (Project ERBCHRXCT940501,Human Capital and Mobility EC Network) (1994-97). "Chemistry and Redox Properties of Palladium or Platinum Complexes with Multiple Bonded C,N-Donor Ligands" (sponsored jointly by JNICT and the CNR, Italy). (1995-96). "Chemical and Electrochemical Investigation of Some Transition Metal-Promoted Reactions ofAlkynes, Diazoalkanes, Cyanamide and Derived Species" [sponsored jointly by ICCTI (JNICT)and the CNR, Italy]. (1997-98). “The Chemistry of Platinum Group Metals with N-Donor Ligands: Structure-Reactivity andStructure-Biological Activity Relationships”. (since 1998). "Oxidation of Saturated Hydrocarbons" (Project PRAXIS/POCTI /2/2.1/QUI/193/94, sponsoredby the PRAXIS XXI and the POCTI Programmes) (1998-2002). “Coordination and Reactivity of Organonitriles, Cyanamides and Derived Species” (sponsoredjointly by ICCTI and the CNR, Italy). (1999-2001). “Metal-based Synthons with Pharmacological Significance” (Project POCTI/QUI/43415/2001,sponsored by the POCTI programme, FCT) (2002-05). “Early-Late Multinuclear Metal Systems on Design and Development of New Materials” (NATOCollaborative Linkage Grant PST. CLG. 979289). (2003-06) “Transition Metal Chemistry and Catalysis in Aqueous Media” [Project MRTN-CT-2003-503864, Human Resources and Mobility (HRM) Marie Curie Research Training Network (RTN)](2000-07).“Single-Pot Carboxylation of Alkanes under Mild Conditions”, (Project PTDC/QUI-QUI/102150/2008) (since 2010). “GC-MS”, [Programme PO 002 (Inovation and Scientific and Technological Research), MO 003(Development of a Modern Network of R&D Institutions), Project 6811 (Consolidation ofScientific Re-equipment of S&T Institutions), sponsored by FCT, 2010-present].Under the responsability of A. Charmier: “Synthesis of New Heterocycles with Biological Activity: Reactions, by the MicrowaveActivation, of Cycloaddition of several dipoles to Transition Metals Coordinated Organonitriles”(POCI/QUI/59558/2004)8. RESERARCH TRAINING SUPERVISION3 Ph.D. (two awarded); 3 foreign Post-doc. Fellows.Doctorates:• Srinivasan Sowmianarayan Parimala, (Madras University, India) “Activation of Nitriles byElectron-Rich Metal Centres“ (SFRH/BPD/20339/2004)• Zhen Ma (Chinese academy of sciences, Fuzhou, Fujian, China) “Synthesis, Electrochemical andLuminescent Behaviours of Polyaza-Complexes” (SFRH/BPD/24691/2005)• Malgorzata Gajewska (Poland) “Syntheses and characterisation of organotin and relatedcomplexes with potential pharmacological interest” (SFRH/BPD/32522/2006)PhD Theses (Co-supervision)

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 8 / 47Cristina Maria Pires Ferreira, “Platinum and Rhenium Compounds with Nitrogen Ligands andtheir Reactivity” (IST, 2000) .Natércia da Conceição Tomé Martins “Mechanistic Studies on the Electrocatalytic Reduction ofOrganohalides and on the Oxidation of Alcohols, Thiols and Phenols" (IST, 2004)Sónia Maria Pena Rodrigues Meireles da Cunha “Activação de Cianamidas e Diazoto por CentrosFosfínicos de Molibdénio e Tungsténio” IST, 2003, provisional thesis (deyed in June 2004).Master Theses (Co-supervision)• Isabel Luísa Ferreira Machado, "Electrochemistry of Complexes with Unsaturated N-Ligands"(IST, 1994)• Maria Estela Silva Dória, "Palladium and Platinum Complexes: Reactions with DiazoCompounds and Electrochemical Behaviour of Cyanamide Compounds" (IST, 1995)Other (Co-supervision)• Elsa Mariana P.R. Parrot Branco, "Chemistry of Platinum and Palladium Compounds withNitrogen-Ligands, specifically Cyanamide", PEDIP programme "Coordination Compounds inPharmacology" (1991-93), (2 years)• Tong Yu-Ying, “Chemistry and Electrochemistry of Complexes of Gold or other Metals withSulphur- or Nitrogen-ligands”, PEDIP programme "Coordination Compounds in Pharmacology"(1991-93)• Katarzyna Szajnowska (Wroclaw University, Poland), Erasmus programme, (1999) (2 months).• Filipa Delgado Siopa, 2004 (6,5 meses) (POCTI/QUI/43415/2001).• Tetyana Anasimova (St. Petersburg State University), PhD student (supervision: Prof. AJLPombeiro; Co-supervision: Dr. K. Luzyanin), supervisor in the course, “Advanced ExperimentalTechniques and Methodologies” of the Phd Program in Chemical Engineering of IST

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 11 / 47Complexes [ReClH(NCR)(Ph2PCH2CH2PPh2)2][BF4]. A Mechanistic Study.", J. Chem. Soc.,Chem. Commun., (1992) 1289-1291.http://dx.doi.org/10.1039/C399200012891993II.9 Rino A. Michelin, Roberta Bertani, Mirto Mozzon, Gabiella Bombieri, Franco Benetollo, M.Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Hydride to Carbene Migration atPlatinum(II). Synthesis and X-ray Structure of cis-{(PPh 3 ) 2 Pt[C(H)SCH 2 CH 2 S]}BF 4 ",Organometallics, 12 (1993) 2372-2376.http://dx.doi.org/10.1021/om00030a056II.10M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, RobertaBertani, Rino A. Michelin, Mirto Mozzon, Franco Benetollo, Gabriella Bombieri, "Reactivity of[Pt(CH 2 =CH 2 )(PPh 3 ) 2 ] Towards Ethyldiazoacetate. Synthesis and Molecular Structure of theDiethyl Fumarate Complex [Pt{trans-CH(CO 2 Et)=CH(CO 2 Et)} (PPh 3 ) 2 ] and Preparation of thenalogous Diethylmaleate Compound", Inorg. Chim. Acta, 214 (1993) 85-95.http://dx.doi.org/10.1016/S0020-1693(00)87529-5II.11 Talib Al Salih, M. Teresa Duarte, João J.R. Fraústo da Silva, Adelino M. Galvão, M. Fátima C.Guedes da Silva, Peter B. Hitchcock, David, L. Hughes, Christopher J. Pickett, Armando J.L.Pombeiro, Raymond L. Richards, "Structural and Electronic Comparison of 15- to 17-ElectronDichloro Complexes of Molybdenum and Rhenium: Electrochemical Behaviour and X-rayCrystal Structures of trans-[ReCl 2 (dppe) 2 ]A (A = Cl or BF 4 ; dppe = Ph 2 PCH 2 CH 2 PPh 2 ), trans-[ReCl 2 (dppe) 2 ] and trans-[MoCl 2 (dppe) 2 ] [NBu n 4] 2 [BF 4 ] 3 ", J. Chem. Soc., Dalton Trans., (1993),3015-3023.http://dx.doi.org/10.1039/DT9930003015II.121994II.13II.14II.151995II.16João J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, Richard A. Henderson, Armando J.L.Pombeiro, Raymond L. Richards, "Protonation of the Nitrile Ligand versus Protonation ofRhenium at cis- or trans-[ReCl(NCR)(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ] (R = Cl, F, Me or MeO). AMechanistic Study", J. Organomet. Chem., 461 (1993) 141-145.http://dx.doi.org/10.1016/0022-328X(93)83285-4M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, ChristianAmatore, Jean-Nöel Verpeaux, "Rates and Mechanism of Oxidative Two-Electron TransferInduced cis- to trans-Isomerization for the Nitrile Complex [ReCl(NC 6 H 4 Me-4)(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ]”, Organometallics, 13 (1994) 3943-3951.http://dx.doi.org/10.1021/om00022a033M. Amélia N.D.A. Lemos, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Electron-Transfer Activation of the Aminocarbyne and the Hydrogen-Isocyanide Complexes[ReCl(CNH n )(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ] [BF 4 ] n-1 (n = 2 or 1). Interconversion of Coordinated CNH2and CNH", Inorg. Chim. Acta, 226 (1994) 9-16.http://dx.doi.org/10.1016/0020-1693(94)04064-8M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "Synthesisand Redox Properties of cis-[ReCl(NCR)(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ] (R = Alkyl or Aryl), Chloro-Nitrile Complexes with a cis-Phosphinic Rhenium(I) Centre", J. Chem. Soc., Dalton Trans.,(1994) 3299-3304.http://dx.doi.org/10.1039/DT9940003299M. Fátima C. Guedes da Silva, Elsa M.P.R.P. Branco, Yu Wang, João J.R. Fraústo da Silva,Armando J.L. Pombeiro, Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Franco Benetollo,Gabriella Bombieri, "Syntheses and Properties of Cyanamide and Cyanoguanidine Complexes ofPlatinum(II). X-Ray Structure of trans-[Pt(CF 3 )(NCNEt 2 )(PPh 3 ) 2 ][BF 4 ]", J. Organomet. Chem.,490 (1995) 89-99.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 12 / 47II.17http://dx.doi.org/10.1016/0022-328X(95)05203-2Umberto Belluco, Roberta Bertani, Rino A. Michelin, Mirto Mozzon, M. Fátima C. Guedes daSilva, João J.R. Fraústo da Silva, A.J.L. Pombeiro, Wang Yu, "Reactions and ElectrochemicalBehaviour of Dithiocarbene Complexes of Platinum(II)", Inorg. Chim. Acta, 235 (1995) 397-405.http://dx.doi.org/10.1016/0020-1693(95)90082-HII.18 Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Piero Traldi, Roberta Seraglia, M. Fátima C.Guedes da Silva, Armando J.L. Pombeiro, "Highly Reactive Platinum(0) Carbene Intermediatesin the Reactions of Diazo Compounds. A Fast Atom Bombardment Mass Spectrometric Study",Organometallics, 14 (1995) 551-554.http://dx.doi.org/10.1021/om00001a0751996II.19II.20Luísa M.D.R.S. Martins, M. Fátima C. Guedes da Silva, Indalécio Marques, João J.R. Fraústo daSilva, M. Cândida N. Vaz, Armando J.L. Pombeiro, "FAB-MS Spectra of Nitrile or CyanamideComplexes with the {M(Ph2PCH2CH2PPh2)2}n+ (M = Fe or Re) Metal Sites. Application toReactions Induced in FAB Conditions", Rapid Commun. Mass Spect., 10 (1996) 447-454.http://dx.doi.org/CCC 09514198/96/040447-08P. Gili, M.G. Martin Reyes, P. Martin Zarza, Isabel L.F. Machado, M. Fátima C. Guedes da Silva,M. Amélia N.D.A. Lemos, A.J.L. Pombeiro, "Synthesis, Spectroscopic, Magnetic andElectrochemical Properties of Cu(II) and Fe(III) Complexes with the New Ligand N,N'-[1,1'-Dithiobis(phenyl)] bis(5'-Methoxysalicylaldimine)", Inorg. Chim. Acta., 244 (1996) 25-36.http://dx.doi.org/10.1016/0020-1693(95)04756-5II.21 M. Fátima C. Guedes da Silva, João J. Fraústo da Silva, Armando J.L. Pombeiro, Maria A.Pellinghelli, Antonio Tiripicchio, " Deprotonation Reactions of the Aminocarbyne Complextrans-[ReCl(CNH2)(dppe)2][BF4] (dppe = Ph2PCH2CH2PPh2). Synthesis and Properties of theCyano-Complexes trans-[Re(CN)(L)(dppe)2] (L = NCR, N2, CO or C=CHPh) and CrystalStructure of trans-[Re(CN)(NCMe)(dppe)2].PriOH", J. Chem. Soc., Dalton Trans., (1996) 2763-2772.http://dx.doi.org/10.1039/DT9960002763II.22II.23II.24M. Fátima C. Guedes da Silva, J. Armando L. da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, Christian Amatore, Jean-Nöel Verpeaux, "Evidence for a Michaelis-Menten TypeMechanism in the Electrocatalytic Oxidation of Mercaptopropionic Acid by an AmavadineModel", J. Am. Chem. Soc., 118 (1996) 7568-7573http://dx.doi.org/10.1021/ja9607042M. Gleria, R. Bertani, G. Facchin, F. Noé, Rino A. Michelin, Mirto Mozzon, Armando J.L.Pombeiro, M. Fátima C. Guedes da Silva, Isabel L.F. Machado, “Organometallic andCoordination Chemistry on Phosphazenes. III. Synthesis, Characterization, and ElectrochemicalBehavior of Transition Metal- Cinnamonitrile Cyclophosphazene Derivatives”, Journal ofInorganic and Organometallic Polymers, 6 (1996) 145-170.http://dx.doi.org/10.1007/BF01057745M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "DinitrileComplexes with a Rare cis-Diphosphine Rhenium(I) Centre: Syntheses, Properties and cis- totrans- Isomerization", J. Organomet. Chem., 526 (1996) 237-250.http://dx.doi.org/10.1016/S0022-328X(96)06566-71997II.25P. Gili, M.G. Martin Reyes, P. Martin Zarza, M. Fátima C. Guedes da Silva, Y.-Y. Tong,Armando J.L. Pombeiro, "Complexes of Mn(II) and Mn(III) with the Schiff base N-[2-(3-Ethylindole)]pyridoxaldimine. Electrochemical Study of these complexes and related Ni(II) andCu(II) and Fe(III) Complexes", Inorg. Chim. Acta., 255 (1997) 279-288.http://dx.doi.org/10.1016/S0020-1693(96)05374-1

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 13 / 47II.26 Peter B. Hitchcock, David L. Hughes, Katayoun Marjani, Armando J.L. Pombeiro, Raymond L.Richards, M. Fátima C. Guedes da Silva, “Thiolate-isocyanide Complexes of Molybdenum(II)and Tungsten (II): Crystal Structures of cis-[Mo(SC 6 H 2 Pri 3 2,4,6) 2 (CNMe) 2 ], cis-[Mo(SC 6 H 2 Pri 3 -2,4,6) 2 (CNBut) 2 ] and cis-[W(SC 6 H 2 Pri 3 -2,4,6) 2 (CNMe) 4 ], and Anodically-induced IsomerisationStudies”, J. Chem. Soc., Dalton Trans., (1997) 3725-3731.http://dx.doi.org/10.1039/a703860gII.271998II.28II.29II.30II.311999II.322000II.33II.34M. Fátima C. Guedes da Silva, Cristina M.P. Ferreira, Elsa M.P.R.P. Branco, João J.R. Fraústo daSilva, Armando J.L. Pombeiro, Rino A. Michelin, Umberto Belluco, Roberta Bertani, MirtoMozzon, Gabriella Bombieri, Franco Benetollo, Vadim Yu. Kukushkin, “Bifunctional Activationof Cyanoguanidine. Synthesis and Molecular Structure of the Azametallacycle cis-[(PPh 3 ) 2 Pt{NHC(OMe)=NC(NH 2 )=NH}][BPh 4 ]”, Inorg. Chim. Acta, 265 (1997) 267-270.http://dx.doi.org/10.1016/S0020-1693(97)05636-3Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Vadim Yu. Kukushkin, João J.R. Fraústoda Silva, Armando J.L. Pombeiro, “The First Direct Observation of the N-O- Bond Cleavage inthe Oxidative Addition of an Oxime to a Metal Centre. Synthesis and Crystal Structure of theMethyleneamide Complex trans-Re(OH)(N=CMe 2 )(Ph 2 PCH 2 CH 2 PPh 2 ) 2 HSO 4 ” J. Chem. Soc.,Dalton Trans., (1998) 325-326.http://dx.doi.org/10.1039/a707213iM. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, ChristianAmatore, Jean-Noel Verpeaux, “Electron-Transfer-Induced Geometrical Isomerization of theDinitrile Complexes cis-[Re(NCR) 2 (dppe) 2 ][BF 4 ] (R = Aryl, Alkyl): Rates, Mechanisms andLigand Effects”, Inorg. Chem., 37 (1998) 2344-3350.http://dx.doi.org/10.1021/ic971257+M. Fátima C. Guedes da Silva, Youlia A. Izotova, Armando J.L. Pombeiro, Vadim Yu.Kukushkin, “Manifestation of Redox Duality of 2-propanone oxime: Pt(II)-assisted reductionversus Pt(IV)-mediated oxidation of Me 2 C=NOH species” Inorg. Chim. Acta, 277 (1998) 83-88.http://dx.doi.org/10.1016/S0020-1693(97)06126-4M. Fátima C. Guedes da Silva, Cristina M.P. Ferreira, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, “Electron-Transfer Chain Catalysis for the cis-to-trans Isomeric Conversion of cis-[ReCl(CO)(dppe) 2 ]” J. Chem. Soc., Dalton Trans., (1998) 4139-4145.http://dx.doi.org/10.1039/a805343jSílvia S.P.R. Almeida, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, “Reactions of a Cyanosilane with an Iron(II) Centre. Synthesis and Crystal Structure ofthe Isocyanotriphenylborate complex trans-[FeH(CNBPh 3 )(dppe) 2 ] and Anodic Deprotonation ofthe Hydrogen Isocyanide (CNH) analogue”, J. Chem. Soc., Dalton Trans., (1999) 467-472.http://dx.doi.org/10.1039/a807707jM. Fátima C. Guedes da Silva, M. Amélia N.D.A. Lemos, João J.R. Fraústo da Silva, ArmandoJ.L. Pombeiro, Maria A. Pellinghelli, Antonio Tiripicchio, “Aminocarbyne and IsocyanideComplexes of rhenium. Crystal Structures of trans-[ReCl(CNR) (Ph 2 PCH 2 CH 2 PPh 2 ) 2 ] (R = H orSiMe 3 )” J. Chem. Soc., Dalton Trans., (2000) 373-380.http://dx.doi.org/10.1039/a908174gLei Zhang, M. Pilar Gamasa, José Gimeno, Rodrigo J. Carbajo, Fernando López-Ortiz, M. FátimaC. Guedes da Silva, Armando J.L. Pombeiro, “Mono and Dinuclear Alkenyl-Carbyne ComplexesBridged by Cyanide and Diisocyanide Ligands: Synthesis, Electrochemical- and 183 W-NMRstudies” Eur. J. Inorg. Chem., (2000) 341-350.http://dx.doi.org/10.1002/(SICI)1099-0682(200002)2000

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 14 / 47II.35II.36II.37II.382001II.39II.40II.41II.42II.43II.44II.45M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Silvano Geremia, Ennio Zangrando,Mario Calligaris, Andrey V. Zinchenko, Vadim Yu. Kukushkin, "Unusual Pathways for theReaction between [MCl 2 (Me 2 SO) 4 ] (M = Os, Ru) and Hydrazine dihydrochloride: deoxygenationof sulfoxides vs. coordination of hydrazinium" J. Chem. Soc. Dalton Trans., (2000) 1363-1371.http://dx.doi.org/10.1039/a908170dDmitrii A. Garnovskii, M. Fátima C. Guedes da Silva, T.B. Pakhomova, G. Wagner, M. TeresaDuarte, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, Vadim Yu. Kukushkin,“Iminoacylation. 6. Coupling of Chloro- and Amidoximes Ar(R)C=NOH(R = Cl, NH 2 ) withAcetonitrile Ligands Coordinated to Platinum(IV)” Inorg. Chim. Acta., 300-302 (2000) 499-504.http://dx.doi.org/10.1016/S0020-1693(99)00556-3Amélia Rauter, Maria Ferreira, C. Borges, Teresa Duarte, Fátima Piedade, M. Fátima C. Guedesda Silva, Helena Santos, "Construction of a Branched Chain at C-3 of a Hexopyranoside.Synthesis of Miharamycin Sugar Moiety Analogs" Carbohydrate Research, 325 (2000) 1-15.http://dx.doi.org/10.1016/S0008-6215(99)00307-9Lei Zhang, M. Pilar Gamasa, José Gimeno, M. Fátima C. Guedes da Silva, Armando J.L.Pombeiro, C. Graiff, M.Lanfranchi, Antonio Tiripicchio, “Synthesis, Characterization andElectrochemical Studies of Neutral Alkenyl-Carbyne Tunsten Complexes Bearing ChelatingBidentate and Tridentate Phosphines”, Eur. J. Inorg. Chem., (2000) 1707-1715.http://dx.doi.org/10.1002/1099-0682(200008)2000M. Fátima C. Guedes da Silva, Anna M. Trzerciak, Józef J. Ziólkowski, Armando J.L. Pombeiro,“Redox Potential, Ligand and Structural Effects in Rhodium(I) Complexes”, J. Organometal.Chem., 620 (2001) 174-181.http://dx.doi.org/10.1016/S0022-328X(00)00816-0Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, “Coordination Chemistry of CNH 2 , theSimplest Aminocarbyne”, J. Organomet. Chem, 617-618 (2001) 65-69.http://dx.doi.org/10.1016/S0022-328X(00)00641-0M. Fátima C.Guedes da Silva, Luísa M.D.R.S. Martins, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, “Redox potential-(electronic) structure relationships in 18- and 17-electron mononitrile(or monocarbonyl) diphosphine complexes of Re and Fe”, Collect. Czech. Chem. Commun., 66(2001) 139-154.http://dx.doi.org/10.1135/cccc20010139P. Sobota, K. Przybylak, J. Utko, L.B. Jerzykiewicz, A.J.L. Pombeiro, M. Fátima C. Guedes daSilva, K. Szczegot “Synthesis, Structure and Reactivity of Chiral Titanium Compounds:Procatalysts for Olefin Polymerization”, Chem. Eur.J., 7 (2001) 951-958.http://dx.doi.org/10.1002/1521-3765(20010302)7C.M.P. Ferreira, M. Fátima C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro, V.Yu.Kukushkin, R.A. Michelin “Azametallacycles from Ag(I)- or Cu(II)-Promoted CouplingReactions of Dialkylcyanamides with Oximes at Pt(II)”, Inorg. Chem., 40 (2001) 1134-1142.http://dx.doi.org/10.1021/ic000553aArmando J.L. Pombeiro, M. Fátima C. Guedes da Silva, M. Amélia N.D.A. Lemos “Electron-Transfer Induced Isomerizations of Coordination Compounds”, Coord. Chem. Rev., 219-221(2001) 53-80.http://dx.doi.org/10.1016/S0010-8545(01)00299-5Lei Zhang, M. Fátima C. Guedes da Silva, Maxim L. Kuznetsov, M. Pilar Gamasa, José Gimeno,João J.R. Fraústo da Silva, Armando J.L. Pombeiro “Synthesis and Electrochemical andTheoretical Studies of Fischer-type Alkenyl-Carbyne Tungsten Complexes[(dppe)(CO) 2 (RNC)W(CCH=CCH 2 CH 2 (CH 2 ) n CH 2 }][BF 4 ] (R = alkyl, aryl)”, Organomettalics,20 (2001) 2782-2793.http://dx.doi.org/10.1021/om001095g

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 15 / 47II.46II.47II.48Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, Rino A. Michelin “AminocarbyneComplexes Derived from Isocyanides Activated Toward Electrophilic Addition”, Coord. Chem.Rev., 218 (2001) 43-74.http://dx.doi.org/10.1016/S0010-8545(01)00357-5Rino A. Michelin, Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva “AminocarbeneComplexes Derived from Nucleophilic Addition to Isocyanides”, Coord. Chem. Rev., 218 (2001)75-112.http://dx.doi.org/10.1016/S0010-8545(01)00358-7M.N. Kopylovich, V.Yu. Kukushkin, M. Fátima C. Guedes da Silva, M. Haukka, J.J.R. Fraústoda Silva, A.J.L. Pombeiro “Conversion of Alkanenitriles to Amidines and Carboxylic AcidsMediated by a Cobalt(II)-Ketoxime System”, J. Chem. Soc., Perkin Trans. I (2001) 1569-1573.http://dx.doi.org/10.1039/b101337hII.49 Nadejha A. Bokach, Stanislav I Selivanov, Vadim Yu. Kukushkin, Matti Haukka, M. Fátima C.Guedes da Silva, Armando J.L. Pombeiro, “The First Observation and Structural Characterizationof (Formamide)Platinum(IV) Complexes”, Eur. J. Inorg. Chem., (2001) 2805-2809.http://dx.doi.org/10.1002/1099-0682(200111)20012002II.50II.51II.52II.53II.54II.552003II.56U. Belluco, F. Benetollo, R. Bertani, G. Bombieri, R.A. Michelin, M. Mozzon, A.J.L. Pombeiro,M. Fátima C. Guedes da Silva, “Stereochemical Investigation of the Addition of Primary andSecondary Aliphatic Amines to the Nitrile Complexes cis- and trans-[PtCl 2 (NCMe) 2 ]. X-rayStructures of the Amidine Complexes trans-[Pt(NH 2 Pr i ) 2 {Z-N(H)=C(NHPr i )Me}]Cl 2 .4H 2 O andtrans-[PtCl 2 (NCMe){E-N(H)=C(NMeBu t )Me}], Inorg. Chim. Acta, 330 (2002) 229-239.http://dx.doi.org/10.1016/S0020-1693(01)00803-9Umberto Belluco, Franco Benetollo, Roberta Bertani, Gabriella Bombieri, Rino A. Michelin,Mirto Mozzon, Oliviero Tonon, Armando J. L. Pombeiro, M. Fátima C. Guedes da Silva“Addition reactions of primary and secondary aliphatic amines to the benzonitrile ligands in cisandtrans-[PtCl 2 (NCPh) 2 ] complexes. X-ray structure of the amidine complex trans-[PtCl 2 {Z-N(H)=C(NHBu t )Ph} 2 ]” Inorg. Chim. Acta, 334, (2002) 437-447.http://dx.doi.org/10.1016/S0020-1693(02)00866-6S.M. P. R. M. Cunha, M. Fátima C. Guedes da Silva, A. J. L. Pombeiro, “Activation ofCyanamide by a Molybdenum(0) Diphosphinic Centre. Formation of Cyanoimide and itsReactivity with Electrophiles”, J. Chem. Soc., Dalton Trans., (2002) 1791-1799.http://dx.doi.org/10.1039/b108165aM. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, “Activationof Organonitriles Toward -Electrophilic Attack. Synthesis and Characterisation ofMethyleneamide (Azavinylidene) Complexes of Rhenium”, Inorg. Chem., 41 (2002) 219-228.http://dx.doi.org/10.1021/ic010841mC.M.P. Ferreira, M. Fátima C. Guedes da Silva, Teresa Duarte, J.J.R. Fraústo da Silva, A.J.L.Pombeiro, “Cationic Phenyl and Chloro-Platinum(II) Complexes with Cyanamides andCyanoguanidine. X-ray Structure of trans-[Pt(Ph)(NCNMe 2 )(PPh 3 ) 2 ][BPh 4 ]”, Inorg. Chim. Acta,334 (2002) 395-402.http://dx.doi.org/10.1016/S0020-1693(02)00746-6A.I.F. Venâncio, M.L. Kuznetsov, M. Fátima C. Guedes da Silva, L.M.D.R.S. Martins, J.J.R.Fraústo da Silva, A.J.L. Pombeiro, “Metal-Hydride Bond Activation and Metal-Metal Interactionin Dinuclear Iron Complexes with Linking Dinitriles: a Synthetic, Electrochemical andTheoretical Study”, Inorg. Chem., 41 (2002) 6456-6467.http://dx.doi.org/10.1021/ic025835kS.M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “Mixed Dinitrogen-Organocyanamide Complexes of Molybdenum(0) and Their Protic Conversion into Hidrazine andAmidoazavinylidene Derivatives”, Inorg. Chem., 42 (2003) 2157-2164.http://dx.doi.org/10.1021/ic026176e

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 16 / 47II.57II.58II.59II.602004II.61II.62II.63II.642005II.65II.66II.67D.A. Garnovskii, M. Fátima C. Guedes da Silva, M.N. Kopylovich, A.D. Garnovskii, J.J.R.Fraústo da Silva, A.J.L. Pombeiro, “Electrochemical Synthesis of Adducts of 2-Aminopyridineor Methanol in Metal Chelates of a N,N,N-Tridentate Schiff Base Ligand. X-ray CrystalStructures of the Ni(II) and Zn(II) Derivatives”, Polyhedron, 22(10) (2003) 1335-1340.http://dx.doi.org/10.1016/S0277-5387(03)00104-9C.M.P. Ferreira, M. Fátima C. Guedes da Silva, R.A. Michelin, V.Yu. Kukushkin, J.J.R. Fraústoda Silva, A.J.L. Pombeiro, “2-Amino-2-oxazoline and Trialkylisourea Pt(II) Complexes Derivedfrom Organocyanamides”, Dalton Trans., (2003) 3751-3756.http://dx.doi.org/10.1039/b306690hS.S.P.R. Almeida, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “Electrochemical Behaviourof trans-[FeH(CN)(dppe) 2 ] Adducts”, Collect. Czech. Chem. Commun., 68 (2003) 1663-1676.http://dx.doi.org/10.1135/cccc20031663S.S.P.R. Almeida, M. Fátima C. Guedes da Silva, L.B. Jerzykiewicz, P. Sobota, A.J.L. Pombeiro,“Cyanide as a versatile Lewis Base Ligand at a Dinitrogen-binding Iron(II) centre: Mono- andHeteronuclear Adducts”, Inorg. Chim. Acta, 356 (2003) 259-266.http://dx.doi.org/10.1016/S0020-1693(03)00249-4Q. Li, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “Diorganotin(IV) Derivatives ofSubstituted Benzohydroxamic Acids with High Antitumor Acivity”, Chem. Eur. J., 10 (2004)1456-1462.http://dx.doi.org/10.1002/chem.200305266A.M. Trzeciak, B. Borak, Z. Ciunik, J.J. Ziólkowski, M. Fátima C. Guedes da Silva, A.J.L.Pombeiro, “Structure, Electrochemistry and Hydroformylation Catalytic Activity of thebis(pyrazolylborato)rhodium(I) Complexes [RhBp(CO)P] [P = P(NC 4 H 4 ) 3 , PPh 3 , PCy 3 ,P(C 6 H 4 OMe-4) 3 ”, Eur. J. Inorg. Chem., (2004) 1411-1419.http://dx.doi.org/10.1002/ejic.200300517E. Reisner, V.B. Arion, M. Fátima C. Guedes da Silva, R. Lichtenecker, A. Eichinger, B.K.Keppler, V. Yu. Kukushkin, A.J.L. Pombeiro, “Tuning of Redox Potentials for the Design ofRuthenium Anticancer Drugs — an Electrochemical Study of [trans-RuCl 4 L(DMSO)] - and[trans-RuCl 4 L 2 ] - Complexes, where L = Imidazole, 1,2,4-Triazole, Indazole”, Inorg. Chem., 43(2004) 7083-7093.http://dx.doi.org/10.1021/ic049479cQ. Li, M. Fátima C. Guedes da Silva, Z. Jinghua, A.J.L. Pombeiro, “Diorganotin(IV) Derivativesof Arylhydroxamic Acids. Synthesis, Properties and Antitumor Activity”, J. Organometal.Chem., 689 (2004) 4584-4591.http://dx.doi.org/10.1016/j.jorganchem.2004.08.025E.C.B. Alegria, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “Synthesesand Properties of Re(III) Complexes Derived from Hydrotris(1- pyrazolyl)methanes: MolecularStructure of [ReCl 2 (HCpz 3 )(PPh 3 )][BF 4 ]”, J. Organometal. Chem., 690(8), (2005) 1947-1958.http://dx.doi.org/10.1016/j.jorganchem.2004.11.005A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, M. Haukka, M. Fátima C. Guedes da Silva,A.J.L. Pombeiro, “Multinuclear Copper Triethanolamine Complexes as Selective Catalysts for thePeroxidative Oxidation of Alkanes under Mild Conditions”, Angew. Chem., Int. Ed. 44 (2005)4345–4349 and Angew. Chem., 2005, 117, 1119-1123.http://dx.doi.org/10.1002/anie.200500585A.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, Armando J. L. Pombeiro “Preparationand Crystal Structures of Benzoylhydrazido- and -diazenidorhenium Complexes with N,O-Ligands and Their Catalytic Activity Towards Peroxidative Oxidation of Cycloalkane” Eur. J.Inorg. Chem. (2005) 2071–2080.http://dx.doi.org/10.1002/ejic.200400991

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 17 / 47II.682006II.69II.70II.71II.722007II.73II.74II.75II.76II.77II.78A.I.F. Venâncio, M. Fátima C. Guedes da Silva, L.M.D.R.S. Martins, João J.R. Fraústo da Silva,Armando J.L. Pombeiro “Allenylidene Iron(II) Complexes and Their Deprotonation, NucleophilicAddition Reactions, and Cathodic Protonation toward Alkynyl Derivatives: A Chemical andElectrochemical Study“ Organometallics, 24 (2005) 4654-4665.http://dx.doi.org/10.1021/om050408aA.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, E.Yu. Karabach, M. Haukka, M. FátimaC.Guedes da Silva, Armando J. L. Pombeiro “Mild Peroxidative Oxidation of CyclohexaneCatalyzed by Mono-, Di-, Tri-, Tetra- and Polynuclear Copper Triethanolamine Complexes”Advanced Synthesis & Catalysis, Volume 348, 1-2 (2006) 159 – 174.http://dx.doi.org/10.1002/adsc.200505216N.A. Bokach, M.Haukka, P.Hirva, M. Fátima C. Guedes da Silva, V.Yu. Kukushkin,ArmandoJ.L. Pombeiro “Photoinduced synthesis and electrochemical properties of newruthenium(mono)bipyridine dialkylcyanamide and propiononitrile complexes” J. Organomet.Chem. 691 (2006) 2368–2377.http://dx.doi.org/10.1016/j.jorganchem.2005.12.064Y.Yu. Karabach, A.M. Kirillov, M. Fátima C. Guedes da Silva, M.N. Kopylovich, A.J.L.Pombeiro “An Aqua-soluble Copper(II)-sodium 2D Coordination on Polymer with IntercalatedInfinite Chains of Decameric Water Clusters”, Crystal Growth & Design, 6(10), (2006) 2200-2203.http://dx.doi.org/10.1021/cg060310eA.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, J.J.R. Fraústo da Silva,A.J.L.Pombeiro “A Picolinate-N2 Complex of Rhenium, the first Dinitrogen Complex Bearing aCarboxylate or a N,O-Ligand”, J. Organomet. Chem. 691 (2006) 4153–4158.http://dx.doi.org/10.1016/j.jorganchem.2006.06.015A.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “Synthesis,Characterization and Redox Behaviour of Mono- and Dicarbonyl Phosphane Rhenium(I)Complexes Bearing N-, N,N- and N,O-Type Ligands”, Eur. J. Inorg. Chem. (2007) 1556-1565.http://dx.doi.org/10.1002/ejic.200601026M.V. Kirillova, M. Fátima C. Guedes da Silva, A.M. Kirillov, J.J.R. Fraústo da Silva, A.J.L.Pombeiro “3D Hydrogen Bonded Heteroneclear Co II , Ni II , Cu II and Zn II Aqua Complexes Derivedfrom Dipicolonic Acid”, Inorg. Chim Acta. 360 (2007) 506–512.http://dx.doi.org/10.1016/j.ica.2006.07.087J. Lasri, M.A.Januário Charmier, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, "Directsynthesis of (imine)platinum(II) complexes by iminoacylation of ketoximes with activatedorganonitrile ligands", Dalton Trans., (2007) 5062-5067.http://dx.doi.org/10.1039/b611341aA.M. Kirillov, P. Smolénski, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “The First CopperComplexes Bearing the 1,3,5-Triaza-phosphaadamantane (PTA) Ligand” Eur. J. Inorg. Chem.(2007) 2686–2692.http://dx.doi.org/10.1002/ejic.200601152J. Lasri, M.A.Januário Charmier, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro, “MixedUnsymmetric Oxadiazoline and/or Imine Platinum(II) Complexes”, Dalton Trans., (2007) 3259-3266.http://dx.doi.org/10.1039/b704329eM.T.A.R.S. da Costa, M.F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro,“Reactions of Bis(phenyldiazenido)rhenium Complex [ReBr 2 (NNPh) 2 (PPh 3 ) 2 ]Br with CarbonMonoxide and Alk-1-ynes”, Collect Czech. Chem. Commun., 72 (2007) 599-608.http://dx.doi.org/10.1135/cccc20070599

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 18 / 47II.79II.80II.81S. Mukhopadhyay, J. Lasri, M.A.J. Charmier, M.F.C. Guedes da Silva, A.J.L. Pombeiro,“Microwave Synthesis of Mono- and Bis-Tetrazolato Complexes via 1, 3-Dipolar Cycloadditionof Organonitriles with Platinum(II)-bound Azides”, Dalton Trans., (2007) 5297-5304.http://dx.doi.org/10.1039/b709959bS. Bolaño, J. Bravo, J.A. Castro-Fojo, M.M. Rodríguez-Rocha, M.F.C. Guedes da Silva, A.J.L.Pombeiro, L. Gonsalvi, M. Peruzzini, “Synthesis, Reactivity, X-ray Crystal Structures andElectrochemical Behaviour of Water-Soluble [Tris(pyrazolyl)borato] ruthenium(II) Complexes of1,3,5-triaza-7-phosphaadamantane (PTA)”, Eur. J. Inorg. Chem., 35 (2007) 5523-5532.(highlighted as one of the most accessed articles in December 2007).http://dx.doi.org/10.1002/ejic.200700672S. Mukhopadhyay, J. Lasri, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J.L. Pombeiro, “trans-Bis[5(4-fluorophenyl)tetrazolato]bis(triphenylphosphine)platinum(II)”, Acta Crys. E63, (2007)m2656.http://dx.doi.org/10.1107/S1600536807047617II.82 Alexander M. Kirillov, Piotr Smolenski, M. Fátima C. Guedes da Silva and Armando J. L.Pombeiro, “1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.1]decane 7-oxide triiodide”Acta Crys. E64 (2007) o496–o497.http://dx.doi.org/10.1107/S1600536808001426II.832008II.83T.F.S Silva, L.M.D.R. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Bis[tris(1-pyrazolyl)methane-kappa N-3,N ',N '']copper(II) dichloride methanol disolvate” Acta Cryst., E63(2007) M1979-U1707http://dx.doi.org/10.1107/S1600536807024671A.M. Kirillov, Y.Y. Karabach, M. Haukka, M.F.C. Guedes da Silva, J. Sanchiz, M.N.Kopylovich, A.J.L. Pombeiro, “Self-assembled Copper(II) Coordination Polymers Derived fromAminopolyalcohols and Benzenepolycarboxylates: Structural and Magnetic Properties”, Inorg.Chem., 47 (2008) 162-175.http://dx.doi.org/10.1021/ic701669xII.84 M.V. Kirillova, A.M. Kirillov, M.F.C. Guedes da Silva, M.N. Kopylovich, J.J.R. Fraústo daSilva, A.J.L. Pombeiro, “3D Hydrogen Bonded Metal-Organic Frameworks Constructed from[M(H 2 O) 6 ][M’(dipicolinate) 2 ].mH 2 O (M/M’ = Zn/Ni or Ni/Ni). Identification of IntercalatedAcyclic (H 2 O) 6 /(H 2 O) 10 Clusters”, Inorg. Chim. Acta, 361 (2008) 1728-1737.http://dx.doi.org/10.1016/j.ica.2006.12.016II.85 M.V. Kirillova, M.L. Kuznetsov, J.A.L. Silva, M.Fátima C. Guedes da Silva, J.J.R. Fraústo daSilva, A. J.L. Pombeiro, “Amavadin and Other Vanadium Complexes as Remarkable EfficientCatalysts for the Single-Pot Conversion of Ethane into Propionic and Acetic Acids”, Chem. Eur.J., 14 (2008) 1828-1842.http://dx.doi.org/10.1002/chem.200700980II.86 Piotr Smolenski, Alexander M. Kirillov, M. Fátima C. Guedes da Silva and Armando J. L.Pombeiro,“1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.13,7]decaneTetrafluoroborate”, Acta Cryst. (2008) E64, o556.http://dx.doi.org/10.1107/S1600536808003401II.87 Alexander M. Kirillov, Piotr Smolenski, M. Fátima C. Guedes da Silva, Maximilian N.Kopylovich and Armando J. L. Pombeiro “Three-dimensional hydrogen-bonded supramolecularassembly in tetrakis(1,3,5-triaza-7-phosphaadamantane)copper(I) chloride hexahydrate” ActaCryst. E64 (2008) m603–m604.http://dx.doi.org/10.1107/S1600536808008179II.88 Ricardo R. Fernandes, Alexander M. Kirillov, M. Fátima C. Guedes da Silva, Zhen Ma, José A.L. da Silva, João J. R. Fraústo da Silva, Armando J. L. Pombeiro “An Infinite Two-DimensionalHybrid Water-Chloride Network, Self-Assembled in a Hydrophobic Terpyridine Iron(II) Matrix”Crys. Grow. & Design 8 (2008) 782–785.http://dx.doi.org/10.1021/cg7010315

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 19 / 47II.89II.90II.91II.92II.93Paolo Sgarbossa, M. Fátima C. Guedes da Silva, Alessandro Scarso, Rino A. Michelin, ArmandoJ.L. Pombeiro “Lewis acidity of platinum(II)-based Baeyer–Villiger catalysts: Na electrochemicalapproach” Inorg. Chim. Acta, 2008, 361, 3247- 3253.http://dx.doi.org/10.1016/j.ica.2007.10.050P. Smolenski, C. Dinoi, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Synthesis of the Watersoluble[Rh(Tpms)(CO)(PTA)] Compound, the First Transition Metal Complex Bearing the 1,3,5-triaza-7-phosphaadamantane (PTA) and the Tris(1-pyrazolyl)methane sulfonate (Tpms) Ligands”, J.Organometal. Chem., 693 (2008) 2338-2344.http://dx.doi.org/10.1016/j.jorganchem.2008.04.008J. Lasri , M.F.C. Guedes da Silva, M.A. Charmier, A.J.L. Pombeiro “Optically Active MixedUnsymmetric Imine Platinum(II) Complexes. Utilization of the Liberated Imines to FurtherSyntheses of Mixed Imine-Diazadiene Complexes and of E-cyanoalkanes”, Eur. J. Inorg. Chem.,(2008) 3668-3677.http://dx.doi.org/10.1002/ejic.200800343J. Lasri, M.N. Kopylovich, M.F.C. Guedes da Silva, M.A. Charmier, A.J.L. Pombeiro , “Metal-Free and PdII-Promoted [2+3] Cycloadditions of a Cyclic Nitrone to Phthalonitriles: Syntheses ofOxadiazolines as well as Phthalamide-PdII and Dihydropyrrolyl-iminoisoindolinone-PdIIComplexes with High Catalytic Activity in Suzuki-Miyaura Cross-Coupling Reactions”, Chem.Eur. J., 14(30), (2008) 9312-9322.http://dx.doi.org/10.1002/chem.200800510Marina V. Kirillova, Alexander M. Kirillov, M. Fátima C. Guedes da Silva, Armando J.L.Pombeiro “Self-assembled Two-dimensional Water-soluble Dipicolinate-Cu/Na CoordinationPolymer: Structural Features and Catalytic Activity for the Mild Peroxidative Oxidation ofCycloalkanes in Acid-free Medium”, Eur. J. Inorg. Chem., (2008) 3423–3427.http://dx.doi.org/10.1002/ejic.200800355II.94 P. Smoleński, S. Mukhopadhyay, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J.L. Pombeiro ,“New Water-soluble Azido- and Derived Tetrazolato-platinum(II) Complexes with 1,3,5-Triaza-7-phosphaadamantane (PTA). Easy Metal-mediated Synthesis and Isolation, from AqueousMedium, of 5-Substituted Tetrazoles”, Dalton Trans., (2008) 6546 - 6555.http://dx.doi.org/10.1039/b808156eII.95 S. Mukhopadhyay, J. Lasri, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J.L. Pombeiro“Activation of C-CN bond of Propionitrile: an Alternative Route to the Syntheses of 5-substituted-1H-Tetrazoles and Dicyano-Platinum(II) Species”, Polyhedron, 27(13), (2008) 2883-2888.http://dx.doi.org/10.1016/j.poly.2008.06.031II.96II.97S. Mukhopadhyay, B.G. Mukhopadhyay, M.F.C. Guedes da Silva, J. Lasri, M. A. J. Charmier,A.J.L. Pombeiro, “PtII-Promoted [2+3] Cycloaddition of Azide to Cyanopyridines: ConvenientTool toward Heterometallic Structures” , Inorg. Chem., 47 (2008) 11334-11341.http://dx.doi.org/10.1021/ic8014223R. Wanke, P. Smolenski, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro, “Cu(I)Complexes Bearing the New Sterically Demanding and Coordination Flexible Tris(3-phenyl-1-pyrazolyl)methanesulfonate Ligand and the Water-Soluble Phosphine 1,3,5-Triaza-7-phosphaadamantane or Related Ligands”, Inorg.Chem., 47 (2008) 10158-10168.http://dx.doi.org/10.1021/ic801254b2009II.98 Ł. Jaremko, A.M. Kirillov, P. Smoleński, T. Lis, M.F.C. Guedes da Silva, A.J.L. Pombeiro ,“Synthesis, Characterization and Molecular Structures of the Hybrid Organic-Inorganic Salts ofN-alkyl-1,3,5-triaza-7-phosphaadamantane (alkyl = methyl, ethyl) andTetra(isothiocyanato)cobalt(II) “, Inorg. Chim. Acta, 362 (2009) 1645-1649.http://dx.doi.org/10.1016/j.ica.2008.07.016

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 20 / 47II.99 Konstantin V. Luzyanin, M. Fátima C. Guedes da Silva, Vadim Yu. Kukushkin, ArmandoJ.L.Pombeiro, “First example of an imine addition to coordinated isonitrile” Inorganica ChimicaActa, 362 (3), (2009) 833-838.http://dx.doi.org/10.1016/j.ica.2008.02.026II.100 J. Lasri, M.F.C. Guedes da Silva, M.N. Kopylovich, S. Mukhopadhyay, M.A.J. Charmier, A.J.L.Pombeiro, “Pd II -Promoted [2+3] Cycloadditions of Pyrrolin N-oxide to Organonitriles.Application of ( 4 -1,2,4-oxadiazoline)-Pd II Complexes in the Suzuki-Miyaura Reaction”, DaltonTrans., (2009) 2210-2216.http://dx.doi.org/10.1039/b813996bII.101 M.N. Kopylovich, J. Lasri, M.F.C. Guedes da Silva, A.J.L. Pombeiro , “Single-pot TemplateTransformations of Cyanopyridines on a PdII Centre: Syntheses of Ketoimine and 2,4-Dipyridyl-1,3,5-Triazapentadiene Palladium(II) Complexes and Their Catalytic Activity for Microwaveassisted Suzuki-Miyaura and Heck Cross-Coupling Reactions in Solid Phase”, Dalton Trans.,(2009) 3074-3084. Highlighted as a “hot article”.http://dx.doi.org/10.1039/b820680eII.102 P. Smolenski, L. Benisvy, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “Syntheses and CrystalStructures of the First Zinc Complex with 1,3,5-Triaza-7-phosphaadamantane (PTA),[ZnCl 2 (PTA) 2 ], and of the Hybrid Organic-Inorganic Salts of N-Methyl-1,3,5-triaza-7-phosphaadamantane with Tetrahalozinc [PTA-Me] 2 [ZnI 2 X 2 ] (X = I, Cl)” Eur. J. Inorg. Chem.(2009) 1181–1186.http://dx.doi.org/10.1002/ejic.200801023II.103 Zhen Ma, Yanpeng Xing, Mei Yang, Miao Hua, Baoqing Liu, M. Fátima C. Guedes da Silva,A.J.L. Pombeiro, “The double-helicate terpyridine silver(I) compound [Ag 2 L 2 ](SO 3 CF 3 ) 2 (L = 4’-phenyl-terpyridine) as a building block for di- and mononuclear complexes”, Inorg. Chim. Acta,(2009) 2921-2926.http://dx.doi.org/10.1016/j.ica.2009.01.018II.104 A.M.Kirillov, P. Smolenski, L. Benisvy, M.F.C. Guedes da Silva, A.J.L. Pombeiro “UnprecedentMetal-Free C(sp3)-C(sp3) Bond Cleavage: Switching from N-Alkyl- to N-Methyl- 1,3,5-triaza-7-phosphaadamantane” Organometallics 28 (2009) 1683-1687.http://dx.doi.org/10.1021/om801026aII.105 K.V. Luzyanin, A.G. Tshovrebov, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro,V.Yu.Kukushkin “Metal-mediated [2+3] Cycloaddition of Nitrones to Palladium-bound Isonitriles”Chem. Eur. J., 15 (24), (2009) 5969 – 5978.http://dx.doi.org/10.1002/chem.200802623II.106 N.C.T. Martins, M.F.C. Guedes da Silva, R.Wanke, Armando J.L. Pombeiro, “ElectrocatalyticReduction of Organohalides Mediated by the Dihalo-Molybdenum Phosphinic Complexes trans-[MoX 2 (Ph 2 PCH 2 CH 2 PPh 2 ) 2 ] (X = I, Br) – A Mechanistic Study by Cyclic Voltammetry DigitalSimulation”, Dalton Trans.,(2009) 4772–4777.http://dx.doi.org/10.1039/b811393aII.107 M. Gajewska, K.V. Luzyanin, M.F.C. Guedes da Silva, Q. Li, Jingrong Cui, A.J.L. Pombeiro,“Cyclic Trinuclear Diorganotin(IV)-Complexes – the First Tin Compounds BearingOximehydroxamate Ligands: Synthesis, Structural Characterization and High in vitroCytotoxicity” Eur.J.Inorg.Chem., (2009) 3765-3769.http://dx.doi.org/10.1002/ejic.200900388II.108 B.G. Mukhopadhyay, S. Mukhopadhyay, M.F.C. Guedes da Silva, M.A.J. Charmier, A.J. L.Pombeiro, “Synthesis of mono- and bis-tetrazolato complexes of Ni(II), Pt(II) and Cu(II) via 1,3-dipolar cycloadditions of 2-cyanopyridines with metal ligated azides inN,N,Oaminoiminophenolato complexes”, Dalton Trans., (2009) 4778–4785.http://dx.doi.org/10.1039/b902007aII.109 S.M.P.R.M. Cunha, M.F.C. Guedes da Silva, J.J. R. Fraústo da Silva, A.J.L. Pombeiro,“Cyanoimide-Bridged, Bi- and Trinuclear, Heterometallic Complexes with na NCN–Mo–NCNPhosphinic Core” Eur. J. Inorg. Chem., (2009) 3966-3971.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 21 / 47http://dx.doi.org/10.1002/ejic.200900398II.110 A.M. Kirillov, P. Smoleński, Z. Ma, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro“Copper(I) Iodide Complexes derived from N-alkyl-1,3,5-Triaza-7-phosphaadamantanes:Synthesis, Crystal Structures, Photoluminescence and Identification of the Unprecedented{Cu 3 I 5 } 2– Cluster”, Organometallics, 28 (2009) 6425-6431.http://dx.doi:10.1021/om900591qII.111 L. Benisvy, R. Wanke, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “Towards the Functionalisationof the Methine Carbon of a Sterically Hindered Tris(pyrazolyl)methane: Is a Radical PathwayEnvisageable? Synthesis and structure of Tetrakis(3,5-dimethylpyrazolyl)methane”, Tetrahedron,2009, Volume 65( 45), (2009) 9218-9223.http://dx.doi.org/10.1016/j.tet.2009.09.006II.112 T.F.S. Silva, G.S. Mishra, M.F. Guedes da Silva, R. Wanke, L.M.D.R.S. Martins, A.J.L.Pombeiro, “CuII Complexes Bearing the 2,2,2-tris(1-pyrazolyl)ethanol or 2,2,2-tris(1-pyrazolyl)ethyl methanesulfonate Scorpionates. X-Ray Structural Characterization andApplication in the Mild Catalytic Peroxidative Oxidation of Cyclohexane”, Dalton Trans., (2009)9207–9215.http://dx.doi.org/10.1039/b911990fII.113 K.V. Luzyanin, A.G. Tskhovrebov, M.C.Maia, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro,V.Yu. Kukushkin, "Novel Metal-Mediated (M = Pt, Pd) Coupling between Isonitriles andBenzophenone Hydrazone as a Route to Aminocarbene Complexes Exhibiting High CatalyticActivity (M = Pd) in the Suzuki–Miyaura Reaction" Organometallics, 28(22), (2009) 6559–6566.http://dx.DOI.org/10.1021/om900682vII.114 J. Lasri, M. F.C. Guedes da Silva, M.N. Kopylovich, B.Ghosh Mukhopadhyay, A.J. L. Pombeiro“Platinum(II)-Promoted [2+3] Cycloaddition of Azide with 4-Cyanobenzaldehyde, a Schiff BaseDerivative or Dicyanobenzenes To Give Formyl-, Amino(imino)- or Cyano-FunctionalizedTetrazolato Complexes” Eur. J. Inorg. Chem. (2009) 5541-5549.http://dx.DOI.org/10.1002/ejic.2009008582010II.114 A.M. Kirillov, E.C.B.A. Alegria, M. F.C. Guedes da Silva, L.M.D.R.S. Martins, C. Sousa, A.J.L.Pombeiro. “Synthesis, characterization and redox behaviour of benzoyldiazenido-3 andoxorhenium complexes bearing N,N- and S,S-type ligands” Inorg. Chim. Acta, 363 (2010) 1269-1274.http://dx.doi.org/10.1016/j.ica.2009.08.030II.115 T.F.S. Silva, K.V. Luzyanin, M.V. Kirillova, M. Fátima Guedes da Silva, L.M. D. R. S. Martins,A.J. L. Pombeiro “Novel Scorpionate and Pyrazole Dioxovanadium Complexes, Catalysts forCarboxylation and Peroxidative Oxidation of Alkanes” Advanced Synthesis & Catalysis,Volume 352, 1 (2010) 171-187.http://dx.doi.org/10.1002/adsc.200900660II.116 K.T. Mahmudov, M.N. Kopylovich, M.F.C. Guedes da Silva, P.J. Figiel, Y. Yu. Karabach, A.J L.Pombeiro, “New copper(II) dimer with 3-(2-hydroxy-4-nitro-phenylhydrazo)pentane-2,4-dioneand its catalytic activity in cyclohexane and benzyl alcohol oxidations”, J. Mol. Cat. A:Chem.,Volume 318, 1-2, (2010) 44-50.http://dx.doi.org/10.1016/j.molcata.2009.11.006II.117 Z. Ma, Y. Cao, Q. Li , M. F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro,“Synthesis, Characterization, Solid-state Photo-luminescence and Anti-tumor Activity of Zinc(II)4’-phenyl-terpyridine Compounds”, J. Inorg. Biochem., 104(7), (2010) 704-11.http://dx.doi.org/10.1016/j.jinorgbio.2010.03.002II.118 C. Dinoi, M.F.C. Guedes da Silva, .E.C.B.A. Alegria, P. Smoleński, L.M.D.R.S. Martins, R. Poli,A.J L. Pombeiro*, “Molybdenum Complexes Bearing the Tris(1-pyrazolyl)methanesulfonateLigand: Synthesis, Characterization and Electrochemical Behaviour”, Eur. J. Inorg. Chem., 16(2010) 2415-2424.http://dx.doi.org/10.1002/ejic.201000018

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 22 / 47II.119 P. J. Figiel, M.N. Kopylovich, J. Lasri, M.F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L.Pombeiro, “ Solvent-free Microwave-assisted Peroxidative Oxidation of Secondary Alcohols tothe Corresponding Ketones Catalyzed by Copper(II) 2,4-alkoxy-1,3,5-triazapentadienatoComplexes”, Chem. Commun., 46 (2010) 2766-2768.http://dx.doi.org/10.1039/b922738eII.120 R. Wanke, M.F.C. Guedes da Silva, S. Lancianesi,T.F.S. Silva, L.M.D.R.S. Martins, C. Pettinari,A.J.L. Pombeiro “Synthesis and Coordination Chemistry of a New N 4 -Polydentate Class ofPyridyl-Functionalized Scorpionate Ligands: Complexes of Fe II , Zn II , Ni II , V IV , Pd II and Use forHeterobimetallic Systems” Inorg.Chem., 49 (2010) 7941-7952.http://dx.doi.org/10.1021/ic100966uII.121 P.J. Figiel, A. M. Kirillov, M. F. C. Guedes da Silva, J. Lasri, A. J. L. Pombeiro “Self-assembleddicopper(II) diethanolaminate cores for mild aerobic and peroxidative oxidation of alcohols”Dalton Trans., 39 (2010) 9879–9888.http://dx.doi.org/10.1039/c0dt00472cII.122 A.M. Kirillov, J.A. S. Coelho, M.V. Kirillova, M. F. C. Guedes da Silva, D.S. Nesterov, K.R.Gruenwald, M. Haukka, A.J.L. Pombeiro “Bringing an “Old” Biological Buffer to CoordinationChemistry: New 1D and 3D Coordination Polymers with [Cu4(Hbes)4] Cores for MildHydrocarboxylation of Alkanes” Inorg. Chem. 49 (2010) 6390–6392.http://dx.doi.org/10.1021/ic1007999II.123 Y. Y. Karabach, M. F.C. Guedes da Silva, M. N. Kopylovich, B. Gil-Hernandez, J. Sanchiz, A.M. Kirillov, A. J. L. Pombeiro “Self-Assembled 3D Heterometallic CuII/FeII CoordinationPolymers with Octahedral Net Skeletons: Structural Features, Molecular Magnetism, Thermal andOxidation Catalytic Properties” Inorg. Chem., 2010, 49, 11096-11105http://dx.doi.org/10.1021/ic101668fII.124 A. Lis, M.F.C. Guedes da Silva, A. M. Kirillov, P. Smolenski, A. J. L. Pombeiro “Design ofSilver(I)-PTA Coordination Polymers through Controlled N,P-Coordination of 1,3,5-Triaza-7-phosphaadamantane (PTA) with Arylcarboxylates” Crystal Growth & Design, 2010, 10, 5244-5253.http://dx.doi.org/10.1021/cg101058x2011II.125 M.N. Kopylovich, J. Lasri, M.F.C. Guedes da Silva, A.J. L. Pombeiro, “Pd II -Promoted Single-PotTemplate Transformations of Benzonitriles, Cyanoguanidine and Sodium Dicyanamide with theFormation of Symmetrical and Asymmetrical (1,3,5-Triazapentadienate)palladium(II) ComplexesEur. J. Inorg. Chem. 2011, 377–383 .http://dx.doi.org/10.1002/ejic.201000898II.126 T.F.S. Silva, M.F.C. Guedes da Silva, G.S. Mishra, L.M.D.R.S. Martins, A.J.L. Pombeiro,“Synthesis and structural characterization of iron complexes with 2,2,2-tris(1-pyrazolyl)ethanolligands: Application in the peroxidative oxidation of cyclohexane under mild conditions”J.Organomet. Chem. 2011, 696, 1310-1318.http://dx.doi.org/10.1016/j.jorganchem.2010.12.036II.127 M.N. Kopylovich, T.C..O. MacLeod, K.T. Mahmudov, M.F.C. Guedes da Silva, A.J.L. Pombeiro“Zinc(II) ortho-Hydroxyphenylhydrazo-β-diketonate Complexes and their Catalytic Abilitytowards Diastereoselective Nitroaldol (Henry) Reaction” Dalton Trans., 2011, 40, 5352-5361.http://dx.doi.org/10.1039/C0DT01457EII.128 M.N. Kopylovich, K.T. Mahmudov, M.F.C. Guedes da Silva, P.J. Figiel, Y.Yu. Karabach, M.L.Kuznetsov, K.V. Luzyanin, A.J. L. Pombeiro, “Ortho-hydroxyphenylhydrazo-β-diketones:tautomery, coordination ability and catalytic activity of their copper(II) complexes towardoxidation of cyclohexane and benzylic alcohols”, Inorganic Chemistry, 2011, 50¸918-931.http://dx.doi.org/10.1021/ic101516kII.129 M.N. Kopylovich, K.T. Mahmudov, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, M.L.Kuznetsov, T.F.S. Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro “Trends in properties of para-

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 23 / 47substituted 3-(phenylhydrazo)pentane-2,4-diones” J. Phys. Org. Chem. 2010, Published online inWiley Online Library: 2010; 24, 2010, 764 – 773. http://dx.doi.org/10.1002/poc.1824II.130 K.T. Mahmudov, M.N. Kopylovich, K.V. Luzyanin, A. Mizar, M.F.C. Guedes da Silva, V.André, A.J.L. Pombeiro, “Structural and thermal properties of three cyano-substitutedazoderivatives of β-diketones” J. Mol. Struct. 2011, Volume 992, Nº 1-3, 19 Abril 2011, 72-76.http://dx.doi.org/10.1016/j.molstruc.2011.02.045II.131 A.G. Tskhovrebov, K. V. Luzyanin, F. M. Dolgushin, M.Yu. Antipin, M. Fátima C. Guedes daSilva, A. J. L. Pombeiro, V.Yu. Kukushkin “Novel Reactivity Mode of Metal Diaminocarbenes:Pd II -Mediated Coupling between ADCs and Isonitriles Leading to Binuclear Carbene Species”Organometallics, 30, 2011, 3362–3370. Publication Date (Web): May 26, 2011.http://dx.doi.org/10.1021/om20025744II.132 L. Benisvy, R. Wanke, M.F.C. Guedes da Silva, A.J.L. Pombeiro “A Dianionic Dinickel(II)Complex and Its Oxidised Phenoxyl Radical States” Eur. J. Inorg. Chem. 2011, 21912796 (online18-05-2011). http://dx.doi.org/10.1002/ejic.201100232II.133 R.R. Fernandes, J. Lasri, M. Fátima C. Guedes da Silva, J.A da Silva, J.J.R. Fraústo da Silva,A.J. L. Pombeiro “Mild Alkane C H and O H Oxidations Catalysed by Mixed N,S Copper, Ironand Vanadium Systems” Applied Catalysis A: General, Volume 402, Issues 1-2, 2011, 110-120.http://dx.doi.org/10.1016/j.apcata.2011.05.035II.134 R.R. Fernandes, J. Lasri, M.F.C. Guedes da Silva, A.M.F. Palavra, J.A.L. da Silva, J.J.R. Fraústoda Silv, A.J. L. Pombeiro , “Oxadiazoline and ketoimine Pd(II) complexes as highly efficientcatalysts for Suzuki-Miyaura cross-coupling reactions in supercritical CO 2 ” Adv. Synth. Catal.2011, 353, 1153 – 1160http://dx.doi.org/10.1002/adsc.201000909II.135 R.R. Fernandes, J. Lasri, A.M. Kirillov, M. Fátima C. Guedes da Silva, J.A.L. da Silva, J.J.R.Fraústo da Silva, A. Pombeiro “New Fe(II) and Cu(II) complexes bearing azathia macrocycles:catalyst precursors for mild peroxidative oxidation of cyclohexane and 1-phenylethanol” Eur. J.Inorg. Chem. (on-line 26 JUL 2011), 2011, 3781–3790.http://dx.doi.org/10.1002/ejic.201100460II.136 A. M. Kirillov, S. Wieczorek, A. Lis, M. F. C. Guedes da Silva, M. Florek,J. Król, Z.Staroniewicz, P. Smoleński, A. J. L. Pombeiro, “1,3,5-triaza-7-phosphaadamantane-7-oxide(PTA=O): new diamondoid building block for design of 3D metal-organic frameworks” CrystalGrowth & Design, 2011, 11, 2711–2716. http://dx.doi.org/cg200571yII.137 Xianmei Shang, Xianggao Meng, Elisabete C.B.A. Alegria, Qingshan Li, M. Fátima C. Guedes daSilva, Maxim L. Kuznetsov, Armando J.L. Pombeiro "Syntheses, molecular structures,electrochemical behavior, theoretical study and antitumor activities of organotin(IV) complexescontaining 1-(4-chlorophenyl)-1-cyclopentanecarboxylato ligands" Inorg. Chem., 2011, 50, 8158-8167. Publication Date (Web): July 27, 2011.http://dx.doi.org/ic200635gII.138 R. Wanke, L. Benisvy, Maxim L. Kuznetsov, M. Fátima C. Guedes da Silva and Prof. Armando J.L. Pombeiro “Persistent Hydrogen-Bonded and Non-Hydrogen-Bonded Phenoxyl Radicals”Chemistry - A European Journal 17(42), 2011, 11882–11892.http://dx.doi.org/10.1002/chem.201101509II.139 J. Lasri, M. J. F. Rodríguez, M. Fátima C. Guedes da Silva, P. Smoleński, M. N. Kopylovich, J.J.R. Fraústo da Silva, A.J.L. Pombeiro “Microwave Synthesis of Bis(tetrazolato)-Pd II Complexeswith PPh 3 and Water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA). The First Example of C-CN Bond Cleavage of Propionitrile by a Pd II Centre” J. Organomet.Chem., 2011, 696, 3513-3520.http://dx.doi.org/10.1016/j.jorganchem.2011.07.047II.140 R.R. Fernandes, J. Lasri, M. Fátima C. Guedes da Silva, J.A. L. da Silva, J.J.R. Fraústo da Silva,A.J.L. Pombeiro “Bis- and tris-pyridyl amino and imino thioether Cu and Fe complexes. Thermaland microwave-assisted peroxidative oxidations of 1-phenylethanol and cyclohexane in the

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 24 / 47presence of various N-based additives” Journal of Molecular Catalysis A: Chemical, 2011, 351,100-111. Available online 1 October 2011. http://dx.doi.org/10.1016/j.molcata.2011.09.022II.141 C. Pettinari, F. Marchetti, G. Lupidi, L. Quassinti, M. Bramucci, D. Petrelli, Luca A. Vitali, M.Fátima C. Guedes da Silva, L. M. D. R. S. Martins, P. Smoleński, A. J. L. Pombeiro “Synthesis,Antimicrobial and Antiproliferative Activity of Novel Silver(I) Tris(pyrazolyl) methanesulfonateand 1,3,5-Triaza-7- phosphadamantane Complexes” Inorg. Chem. 2011, 50 (21), 11173–11183.http://dx.doi.org/10.1021/ic201714cII.142 Piotr Smoleński, Alexander M. Kirillov, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro“Transformations of the Vaska-type complex trans-[RhCl(CO)(PTA)2] (PTA = 1,3,5-triaza-7-phosphaadamantane) during stepwise addition of HCl: Synthesis, characterization and crystalstructure of trans-[RhCl 2 (PTA)(PTAH)]” Inorg. Chim. Acta, 2011, 378, 342-346.http://dx.doi.org/10.1016/j.ica.2011.09.002II.143 A. M. Kirillov, S. W. Wieczorek, M. Fátima C. Guedes da Silva, J. Sokolnicki, P. Smolenski, A.J. L. Pombeiro “Crystal engineering with 1,3,5-triaza-7-phosphaadamantane (PTA): first PTAdriven3D metal-organic frameworks. CrystEngComm, 2011, 13, 6329-6333.http://dx.doi.org/10.1039/c1ce05612cII.144 S. H. Mehdi, R. Hashim, R. M. Ghalib, M. Fátima C. Guedes da Silva, O. Sulaiman, S. Z.Rahman d, V. Murugaiyah, M. M. Marimuth “Synthesis, characterization, antimicrobial andenzymatic activity of 4b,9b-dihydroxy-7,8-dihydro-4bH-indeno[1,2-b]benzofuran-9,10(6H,9bH)-dione” J. Mol. Struct., 2011, 1006, 318-323. Available online 21 September 2011http://dx.doi.org/10.1016/j.molstruc.2011.09.026II.145 F. Marchetti, C. Pettinari, R. Pettinari, A. Cerquetella, L.M. D. R. S. Martins, M. Fátima C.Guedes da Silva, T.F.S. Silva, A.J. L. Pombeiro “Ru(II) arene complexes bearingtris(pyrazolyl)methanesulfonate capping ligands. Electrochemistry, spectroscopic and X-raystructural characterization” Organomettalics, 2011, 30, 6180-6188 Publication Date (Web):October 24, 2011.http://dx.doi.org/10.1021/om200713vII.146 M.N. Kopylovich, K.T. Mahmudov, M. Fátima C. Guedes da Silva, A. M. Kirillov, A. J. L.Pombeiro “Unusual shift of a nitro group in a phenylhydrazo--diketone” Dalton Trans. 2011, 40,12472-12478. First published on the web 13 Oct 2011.http://dx.doi.org/10.1039/C1DT11209KII.147 A.M. Kirillov, M.V. Kirillova, L.S. Shul’pina, P.J. Figiel, K.R. Gruenwald, M. Fátima C. Guedesda Silva, M. Haukka, A..L. Pombeiro, G.B. Shul’pin, “Mild oxidative functionalization of alkanesand alcohols catalyzed by new mono- and dicopper(II) aminopolyalcoholates” J. Mol. Catal. A-Chem., 2011, 350, 26-34.http://dx.doi.org/10.1016/j.molcata.2011.08.028II.148 R. R. Fernandes, J. Lasri, M. Fátima C. Guedes da Silva, J.A.L. da Silva, J.J.R. Fraústo da Silva,A.J.L. Pombeiro, “Bis- and tris-pyridyl amino and imino thioether Cu and Fe complexes. Thermaland microwave-assisted peroxidative oxidations of 1-phenylethanol and cyclohexane in thepresence of various N-based additives”, J. Mol. Cat.: A Chem., 2011, 351, 100-111.http://dx.doi.org/10.1016/j.molcata.2011.09.0222012II.149 M.N. Kopylovich, Y.Yu. Karabach, M. Fátima C. Guedes da Silva, P.J. Figiel, J. Lasri, A.J.L.Pombeiro “Alkoxy-1,3,5-Triazapentadien(e/ato) Copper(II) Complexes: Template Formation andApplications for Preparation of Pyrimidines and as Catalysts for Oxidation of Alcohols toCarbonyl Products” Chemistry – A European Journal, 2012, 18, 899-914.http://dx.doi.org/10.1002/chem.201101688II.150 J. Lasri, S. Gupta, M. Fátima C. Guedes da Silva, A. J. L. Pombeiro “Copper(II)-mediated in-situhydrolyses of pyrroline N-oxide and benzonitrile leading to a mixed ligand complex” Inorg.Chem. Commun, 2012,18, 72-69.http://dx.doi.org/10.1016/j.inoche.2012.01.012

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 25 / 47II.151 A. Mizar, M. Fátima C. Guedes da Silva, M.N. Kopylovich, S. Mukherjee, K.T. Mahmudov,A.J.L. Pombeiro “Water-Soluble Copper(II) Complexes with a Sulfonic-FunctionalizedArylhydrazone of β-Diketone and Their Application in Peroxidative Allylic Oxidation ofCyclohexene” Eur. J. Inorg. Chem. 2012, 2305–2313. http://dx.doi.org/10.1002/ejic.201101361II.152 R.S. Chay, K.V. Luzyanin, V.Yu. Kukushkin, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro“Novel Palladium–Aminocarbene Species Derived from Metal-Mediated Coupling of Isonitrilesand 1,3-Diiminoisoindoline: Synthesis and Catalytic Application in Suzuki–Miyaura Cross-Coupling” Organometallics, 2012, 31 (6), 2379–2387http://dx.doi.org/10.1021/om300020jII.153 C. Di Nicola, F. Garau, M. Gazzano, M. Fátima C. Guedes da Silva, A. Lanza, M. Monari, F.Nestola, L. Pandolfo, C. Pettinari, A.J.L. Pombeiro “New Coordination Polymers and PorousSupramolecular Metal Organic Network Based on the Trinuclear Triangular SBU [Cu 3 (μ 3 -OH)(μpz)3 ] 2+ and 4,4’-Bipyridine. 1” Cristal Growth & Design, 12, 2012, 2890−2901.http://dx.doi.org/10.1021/cg300080a (listed as one of the 10 most read articles of CC&D in2012).II.154 B.G.M. Rocha, R. Wanke, M. Fátima C. Guedes da Silva, K.V. Luzyanin, L.M.D.R.S. Martins, P.Smolénski, A.J.L. Pombeiro, “Reactivity of bulky tris(phenylpyrazolyl)methanesulfonatecopper(I) complexes towards small unsaturated molecules”, J. Organomet. Chem., 714, 2012, 47-52. http://dx.doi.org/10.1016/j.jorganchem.2012.03.022II.155 E.C.B.A. Alegria, M.Fátima C. Guedes da Silva, M.L. Kuznetov, S.M.P.R.M. Cunha, L.M.D.R.S.Martins, A.J.L. Pombeiro a “Acylated Cyanoimido-Complexes trans-[Mo(NCN){NCNC(O)R}(dppe) 2 ]Cl and their Reactions with Electrophiles: Chemical, Electrochemical and TheoreticalStudy” Dalton Trans., 2012, 41,13876-13890.http://dx.doi.org/10.1039/C2DT30867CII.156 M.N. Kopylovich, M.J. Gajewska, K.T. Mahmudov, M.V. Kirillova, P.J. Figiel, M. Fátima C.Guedes da Silva,B.Gil-Hernández, J.Sanchiz, A.J.L. Pombeiro, "Copper(II) complexes of 3-(2-hydroxy-4-carboxyphenyl-hydrazone)pentane-2,4-dione as effective catalysts for the acid-freeperoxidative alkane and aerobic benzyl alcohol oxidations" New Journal of Chemistry, 2012, 36,1646-1654. http://dx.doi.org/10.1039/C2NJ40210FII.157 K.T. Mahmudov, M. Fátima C. Guedes da Silva, M. Glucini, M. Renzi, K.C.P. Gabriel, M.N.Kopylovich, M. Sutradhar, F. Marchetti, C. Pettinari, S. Zamponi, A.J.L. Pombeiro “Watersolubleheterometallic copper(II)-sodium complex comprising arylhydrazone of barbituric acid asa ligand” Inorg. Chem. Commun., 32, 2012,172-189.http://dx.doi.org/10.1016/j.inoche.2012.06.008II.158 M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “Redox Potential Parameterization inCoordination Compounds with Polydentate Scorpionate and Benzene Ligands” ElectrochimicaActa, 2012, 82, 478-483. http://dx.doi.org/10.1016/j.electacta.2012.05.006II.159 K.T. Mahmudov, M. Fátima C. Guedes da Silva, M. Glucini, M. Renzi, K.C.P. Gabriel, M.N.Kopylovich, M. Sutradhar, F. Marchetti, C. Pettinari, S. Zamponi, A.J.L. Pombeiro*, “Watersolubleheterometallic copper(II)-sodium complex comprising arylhydrazone of barbituric acid asa ligand”, Inorg. Chem. Commun., 2012, 22, 187-189.http://dx.doi.org/10.1016/j.inoche.2012.06.008II.160 T.C.O. Mac Leod, M.N. Kopylovich, M. Fátima C. Guedes da Silva, K.T. Mahmudov, A.J.L.Pombeiro, “Copper(II) complexes of arylhydrazones of -diketones immobilized on Zn-Allayered double hydroxides as effective recyclable catalysts for peroxidative oxidation of alkanes”,Appl.Cat. A: Gen., 2012, 439, 15-23. http://dx.doi.org/10.1016/j.apcata.2012.06.032II.161 J. Lasri, G. Gajewski M. Fátima C. Guedes da Silva, M.L. Kuznetsov, R.R Fernandes, A.J.L.Pombeiro, “Solvent-Dependent Reactivities of Acyclic Nitrones with β-Diketones: Catalyst-freeSyntheses of Endiones and Enones”, Tetrahedron, 2012, 35, 7019-7027.http://dx.doi.org/10.1016/j.tet.2012.06.086II.162 A. Kirillov, M. Filipowicz, M. Fátima C. Guedes da Silva, J. Kłak, P. Smoleński, A.J.L.Pombeiro, “Unprecedented Mixed-Valence Cu(I)/Cu(II) Complex Derived from N-Methyl-1,3,5-

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 26 / 47triaza-7-phosphaadamantane: Synthesis, Structural Features and Magnetic Properties”Organometallics, 31 (22), 7921–7925. http://dx.doi.org/10.1021/om3005564II.163 X. Shang, E.C.B.A. Alegria, M. F. C. Guedes da Silva, M. L. Kuznetsov, Q. Li, A. J.L.Pombeiro,* "Redox-Active Cytotoxic Diorganotin(IV) Cycloalkylhydroxamate Complexes withDifferent Ring Sizes: Reduction Behaviour and Theoretical Interpretation", J. Inorg. Biochem.,2012, 117, 147-156.http://dx.doi.org/10.1016/j.jinorgbio.2012.08.019II.164 J. Lasri, M. Kuznetsov, M. F. C. Guedes da Silva, A. J. L. Pombeiro, "Pt II -mediated imine–nitrilecoupling leading to symmetrical (1,3,5,7,9-pentaazanona-1,3,6,8-tetraenato)Pt(II) complexescontaining the incorporated 1,3-diiminoisoindoline moiety", Inorg. Chem., 2012, 51 10774-10786. http://dx.doi.org/10.1021/ic301176bII.165 T. F. S. Silva, L. M. D. R. S. Martins, M. F. C. Guedes da Silva, A. R. Fernandes, A. Silva, P. M.Borralho, S. Santos, C.M. P. Rodrigues, A. J. L. Pombeiro, “Cobalt complexes bearingscorpionate ligands: synthesis, characterization, cytotoxicity and DNA cleavage”, Dalton Trans.,2012, 41, 12888-12897 (article featured online on Global Medical Discovery [ISSN 1929-8536])http://dx.doi.org/10.1039/c2dt11577hII.166 M. Sutradhar, M. Kirillova, M. F. C. Guedes da Silva, L. Martins, A.J.L. Pombeiro, “AHexanuclear Mixed-valence Oxovanadium(IV,V) Complex as a Highly Efficient AlkaneOxidation Catalyst”, Inorg. Chem., 2012, 51 (21), 11229–11231.http://dx.doi.org/10.1021/ic30170622013II.167 M.N. Kopylovich, A. Mizar, M.F.C. Guedes da Silva, T.C.O. Mac Leod, K.T. Mahmudov, A.J. L.Pombeiro, “ Template Syntheses of Copper(II) Complexes from Arylhydrazones of Malononitrileand their Catalytic Activity towards Alcohol Oxidations and Nitroaldol Reaction. Hydrogen BondAssisted Ligand Liberation and E/Z Isomerisation”, Chem.-Eur.J., 2013, 19, 588-600.http://dx.doi.org/10.1002/chem.201203254II.168 T.F.S. Silva, T.C.O. Mac Leod, L. M. D. R. S. Martins, M. F. C. Guedes da Silva, M. A.Schiavon, A. J.L. Pombeiro, “Pyrazole or tris(pyrazolyl)ethanol oxo-vanadium(IV) complexes ashomogeneous or supported catalysts for oxidation of cyclohexane under mild conditions” J. MolCat.:A Chem. 2013, 367, 52–60. http://dx.doi.org/10.1016/j.molcata.2012.10.024II.169 M.N. Kopylovich, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, M.L. Kuznetsov, K.T.Mahmudov, A.J.L. Pombeiro, “Synthesis, structure and electrochemical behaviour of Na, MgII,MnII, ZnII, CdII and NiII complexes of 3-(2-carboxyphenylhydrazone)pentane-2,4-dione”Polyhedron, 2013, 50, 374-382. http://dx.doi.org/10.1016/j.poly.2012.11.030II.170 M. Fátima C. Guedes da Silva, A.J. L. Pombeiro “XXV International Conference onOrganometallic Chemistry”, Platinum Metals Rev., 2013, 57, (1), 17–31.http://dx.doi.org/10.1595/147106713X659127II.171 X. Shang, T.F.S. Silva, L.M.D.R.S. Martins, Q. Li, M.F.C. Guedes da Silva, M.L. Kuznetsov,A.J.L. Pombeiro “Synthesis, characterization, electrochemical behavior and in vitro proteintyrosine kinase inhibitory activity of the cymene-halogenobenzohydroxamato [Ru(η 6 -cymene)(bha)Cl] complexes” J. Organomet. Chem. in press.http://dx.doi.org/10.1016/j.jorganchem.2012.12.013II.172 M. Sutradhar, M.F.C. Guedes da Silva, D.S. Nesterov, J. Jezierska, A.J.L. Pombeiro “1Dcoordination polymer with octahedral and square-planar nickel(II) centres” Inorganic ChemistryCommunications, 2013, 29, 82-84. http://dx.doi.org/10.1016/j.inoche.2012.12.008II.173 M. Sutradhar, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Synthesis and chemical reactivity ofan Fe(III) metallacrown-6 towards N-donor Lewis bases”, Inorg. Chem. Commun., 2013, 30, 42.-45. http://dx.doi.org/10.1016/j.inoche.2013.01.017

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 27 / 47III RESEARCH PAPERS IN A NATIONAL (REFEREED) JOURNALIII.1III.2III.3III.4III.5III.6III.7III.8III.9M. Isabel S. Pereira, M. Fátima C. Guedes da Silva, M. José B.V. Melo, Fernanda M. A. daCosta, "Estudo Comparativo da Electrocristalização do SnS em Eléctrodos de Amálgama eEstanho Sólido", Port. Electroch. Acta, 3 (1985) 21-34.M. Fátima C. Guedes da Silva, Armando J. L. Pombeiro, "Redox Properties of the NitrileComplexes trans-[ReCl(NCR)(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ]", Port. Electroch. Acta, 7 (1989) 95-100.M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Anodic Deprotonation ofMethyleneamido to Nitrile Ligands at a Rhenium Centre", Port. Electroch. Acta, 9 (1991) 189-194.M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "AnodicallyInduced cis to trans Isomerization of the Nitile Complexes cis-[ReCl(NCR)(dppe) 2 ]", Port.Electroch. Acta, 11 (1993) 93-97.Yu-Ying Tong, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, P. Martin-Zarga, G. Martin, P. Gili, "Redox Properties of some Tryptamine-DerivedSalicylaldimines and of their Tetra-Coordinate Cobalt(II), Nickel(II) or Copper(II) Complexes",Port. Electroch. Acta, 11 (1993) 87-92.Elsa M.P.R.P. Branco, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Roberta Bertani,Rino A. Michelin, Mirto Mozzon, "Redox Properties of Hydride Complexes of Pt(II) with aMetal-Carbon Single Bond", Port. Electroch. Acta, 11 (1993) 81-86.M. Estela S. Dória, Elsa M.P.R. Branco, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro,Rino A. Michelin, Roberta Bertani, Mirto Mozzon, "Redox Properties of Some Cyanamide-Derived Complexes of Palladium(II) or Platinum(II)", Port. Electroch. Acta, 13 (1995) 325-328.M. Fátima C. Guedes da Silva, J. Armando L. da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, Christian Amatore, Jean-Nöel Verpeaux, "Searching for the Mechanism of theElectrocatalytic Oxidation of Mercaptopropionic Acid by an Amavadine model", Port. Electroch.Acta, 13 (1995) 315-318.M. Fátima C. Guedes da Silva, "Activation of Complexes by Electron-Transfer Processes",Portugaliæ Electrochimica Acta, 14 (1996) 41-43.III.10 Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro,“Electrochemical Behaviour of adducts of trans-Mo(NCN) 2 (dppe) 2 with some transition metalLewis acids”, Port. Electroch. Acta, (1996) 177-181.III.11 M. Fátima C. Guedes da Silva, Isabel L.F. Machado, Armando J.L. Pombeiro, R. Bertani, G.Facchin, M. Gleria, R.A. Michelin, M. Mozzon, F. Noé, “Electrochemical Behavior of Pt-Cinnamonitrile Cyclophosphazene Complexes”, Port. Electroch. Acta, 14 (1996) 183-187.III.12 Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Piotr Sobota,“Electrochemical Study of Some Vanadium Complexes”, Port. Electroch. Acta, (1996) 157-161.III.13 Fernando S.C.L. Conde, Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Armando J.L.Pombeiro, Rino A. Michelin, Christian Amatore, “ Electrochemical Behaviour of PlatinumComplexes with Ligating Unsaturated Carbon Species”, Port. Electroch. Acta, 15 (1997) 263-268.III.14 Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “ComparativeElectrochemical Behaviour of Protonated Derivatives of trans-[Mo(NCEt)(NCN)(dppe) 2 ] + ” Port.Electroch. Acta, 15 (1997) 269-273.III.15 M. Fátima C. Guedes da Silva, Katayoun Marjami, Armando J.L. Pombeiro, Raymond L.Richards, “Anodically-Induced Isomerization of cis-[Mo(SC 6 H 2 Pr i 3-2,4,6) 2 (CNBu t ) 4 ]. AMechanistic Study” Port. Electroch. Acta, 15 (1997) 275-280.III.16 Sónia M.P.R.M. da Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "RedoxProperties of the Nitrogen-Cyanamide Complexes trans-[Mo(N 2 )(NCNR 2 ) (dppe) 2 ]” Port.Electroch. Acta, 17 (1999), 221-224.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 28 / 47III.17 Natércia C. T. Martins, M. Fátima C. Guedes da Silva , J.Armando L. da Silva, João J. R. Fraústoda Silva, Carlos Paliteiro, Armando J.L. Pombeiro “Electrocatalytic Oxidation of Pyrogallol by anAmavadin Model”, Port. Electroch. Acta, 19 (2001) 367-370.III.18 Silvia S.P.R. Almeida, João J.R. Fraústo da Silva and Armando J.L. Pombeiro “Estimate ofElectrochemical Ligand Parameters in Iron(II) Adducts of [FeH(CN)(dppe) 2 ]”, Port. Electroch.Acta, 19 (2001) 371-376.III.19 E.C.B.A. Alegria, S.M.P.R.M. Cunha, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.Pombeiro, “Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe) 2 ]Cl (R = Et or Ph) and trans-[Mo(NCN)Cl(dppe) 2 ][BF 4 ]”,Portugaliae Electrochimica Acta, 2004, 22, 19-23.IV – PATENTSIV.1 Q.Li, A.J.L. Pombeiro, M. Fátima C. Guedes da Silva, H. Lingge, “Diorgano-tin Derivatives ofAryl-hydroxamic Acids Having Anti-tumor Activity”, PT 102826 (priority date: 2002/08/07;award date: 2004/08/23).IV.2 A.J.L. Pombeiro, A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, M. Haukka, M. Fátima C.Guedes da Silva, “New Di-, Tri-, Tetra- and Poly-nuclear Copper Complexes, and Their Use asCatalysts for the Peroxidative Oxidation of Cyclohexane”. PT 103225 (priority date:2005/01/19; award date: 2006/03/20).IV.3 A.J.L. Pombeiro, J. Lasri, M. Kopylovich, M. Fátima C. Guedes da Silva, R.R. Fernandes,M.A.C. Januário, “New Palladium Complexes with Bis(pyrrolidinyledene)phthalamides and Dihydropyrrolyliminoisoindolinones,and their Application as Catalysts in Suzuki-MiyauraCoupling Reactions”, PT 104187 (priority date: 2008/09/25; award date: 2009/07/23).IV.4 A.J.L. Pombeiro, J. Lasri, M. Kopylovich, M. Fátima C. Guedes da Silva, S. Mukhopadhyay,R.R. Fernandes, M.A.J. Charmier, “New Palladium Complexes with Bicyclic Ligands ofHydropyrol-Oxadiazole Type, and Their Application as Catalysts in Microwave-assistedSuzuki-Miyaura Coupling Reactions”, PT 104199 (priority date: 2008/09/30; award date:2009/08/11).IV.5 A.J.L. Pombeiro, M. Gajewska, K.V. Luzyanin, M. Fátima C. Guedes da Silva, Q. Li, “NewCyclic Trinuclear Tin Complexes with Antitumor Activity bearing the Oxime-HydroxamateType Ligand N,2-di-hydroxi-5-(1-hidroxyiminoethyl)benzamide”, PT 104676 (priority date:2009/07/20; award date: 2010/02/08).IV.6 A.J.L. Pombeiro, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, G.S. Mishra, T.F.S. Silva,R. Wanke, “Copper(II) Complexes with Hydrophilic C-functionalized Scorpionate Ligands andTheir Application as Catalysts for thye Peroxidative Oxidation of Cyclohexane underEnvironmentally Tolerable Conditions, in Particular in Aqueous Medium”, PT 104713 (prioritydate: 2009/08/09; award date: 2010/09/13).IV.7 A.M. Kirillov, P. Smoleński, Z. Ma, M. Fátima C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro,“Copper Complexes Bearing Iodo and Aminophosphine Ligands, Their Preparative Method andUse as Photoluminescent Materials, PT 104799 (priority date: 2009/10/20; award date:2010/10/26).IV.8A. J.L. Pombeiro, P.J. Figiel, M. Kopylovich, J. Lasri, M. Fátima C. Guedes da Silva, J. J.R.Fraústo da Silva, L. M.D.R.S. Martins, T. F.S. Silva, “Copper(II) Complex with 2,4-ethoxy-1,3,5-triazapentadienide Ligands and its Application, and of the 2,4-methoxy Analogue, asCatalysts for the Peroxidative Oxidation, Assisted by Microwaves and without Addition ofSolvent, of Secondary Alcohols to Ketones”, PT 104884 (priority date: 2009/12/15; award date:2011/10/26).IV.9 A.J.L. Pombeiro, L.M.D.R.S. Martins, T.F.S. Silva, M. Fátima C. Guedes da Silva, K. V.Luzyanin, M. V. Kirillova, “Oxocomplexes of Vanadium(IV-V) with Scorpionate or PyrazolLigands and Their Application as Catalysts for the Peroxidative Oxidation of Cycloalkanes and

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 29 / 47IV.10the Carboxylation of Gaseous Alkanes”, PT 104887 (priority date: 2009/12/15; award date:2011/09/06).A.J.L. Pombeiro, R.R. Fernandes, J. Lasri, A.M.F. Palavra, M. Fátima C. Guedes da Silva,J.A.L. Silva, J.J.R. Fraústo da Silva, “Palladium (II) Complexes with Oxadiazoline andKetoimine Ligands as Catalysts of Suzuki-Miyaura Reactions in Supercritical Carbon DioxideMedium”, PT 105634 (priority date: 2011/04/19; award date: 2011/04/19).

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 30 / 47INVITED LESSONS1 M. Fátima C. Guedes da Silva, "Activation of Complexes by Electron-Transfer Processes", VIIIEncontro da Sociedade Portuguesa de Electroquímica, Covilhã, 1996, 1. (invited lecture).2 M. Fátima C. Guedes da Silva “Reacções Induzidas por Transferência Electrónica” SIBAE 2002,XV Congresso da Sociedade Ibero-Americana de Electroquímica, Évora, Portugal, 2002, 5030-KN (invited keynote lecture).3 M. Fátima C. Guedes da Silva, "Mechanisms of Selected Electron-Transfer Induced Processes inCoordination Chemistry", X Iberic Meeting of Electrochemistry, XIV Congresso da SociedadePortuguesa de Electroquímica, 2007, Coimbra, Portugal, PL3, p5 (invited lecture).4 M. Fátima C. Guedes da Silva, “Chemical and Structural Studies of Complexes with N- and O-Ligands”, International Conference on Organometallic and Coordination Chemistry, NizhnyNovgorod, Rússia, Setembro, 2008, S9 (invited keynote lecture).5 M. Fátima C. Guedes da Silva, “Metal Coordination Structures and Hydrogen Bond Effects”International workshop on Materials for Catalysis and Energy, National Taiwan University of S& T, Taipei, Taiwan, February, 2009 (invited lecture)..

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 31 / 47COMMUNICATIONS (ORAL AND POSTER) AT CONGRESSES.19831 M. Isabel S. Pereira, M. Fátima C. Guedes da Silva, Fernanda M.A. da Costa, "Electrodeposiçãodo Sulfureto de Estanho(II) em Amálgama de Estanho", IV Reunião Internacional deElectroquímica, Braga, 1983, C31.4.2 M. Isabel S. Pereira, M. Fátima C. Guedes da Silva, Fernanda M.A. da Costa, "ElectrochemicalPhase Formation on Tin Amalgam in Sulphide Solutions", 34 th ISE Meeting, Erlangen,Alemanha, 1983.19883 Talib Al-Salih, C.J. Pickett, M. Emília R. Silva, M. Fátima C. Guedes da Silva, Armando J.L.Pombeiro, "Carbon-Halogen Bond Cleavage at Electrochemically Generated Molybdenum(I)Sites", XXVI International Conference on Coordination Chemistry, Porto, 1988, MS-1, P8.19894 M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Redox Properties of the NitrileComplexes trans-[ReCl(NCR)(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ]", IV Encontro da Sociedade Portuguesa deElectroquímica, Estoril, Portugal, 1989, A6.5 M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Redox Potential-Structure Relationshipsat Nitrile Complexes with the Metal Centre {Re(Ph 2 PCH 2 CH 2 PPh 2 ) 2 } +" , Journéesd'Electrochimie, Montpellier, França, 1989, A 3-21.6 Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, David Hughes, Raymond L. Richards,"Preparation and Properties of the Nitrile Complexes trans-[ReCl(NCR)(dppe) 2 ] (R=alkyl oraryl)", International Conference on the Chemistry of the Early Transition Metals, The RoyalSociety of Chemistry, University of Sussex, 1989 (ver I.3).19907 João J.R. Fraústo da Silva, Armando J.L. Pombeiro, J. Armando L. Silva, M. Fátima C.Guedes daSilva, "Electrochemical Behaviour of the 'Amavadine' Model [V(HIDA) 2 ] 2- in Non-AqueousMedia", Italian-Portuguese-Spanish Meeting in Inorganic Chemistry, Gandia, Espanha, 1990,B20, 240.8 Roberta Bertani, Tânia J. Castilho, Rino Michelin, Mirto Mozzon, Armando J.L. Pombeiro, M.Fátima C. Guedes da Silva, "Redox Properties of Carbene Complexes of Palladium(II) andPlatinum(II)" J. Heyrovsky Centennial Congress on Polarography, Praga, 1990.19919 M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Adrian Hills, David L. Hughes,Raymond L. Richards, "Syntheses and Molecular Structure of the Dinitrile-and Difluoro-Rhenium Complex trans-[Re(NCC 6 H 4 Me-4) 2 (dppe) 2 ][ReF 2 (dppe) 2 ][BF 4 ] 2 ", 12º Encontro daSociedade Portuguesa de Química, Coimbra, 1991, 36210 M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Anodic Deprotonation of Methyleneamidoto Nitrile Ligands at a Rhenium Centre", V Encontro da Sociedade Portuguesa deElectroquímica e I Reunião Ibérica de Electroquímica, Aveiro, 1991, 108 (presented byM.F.C.G.S.).11 M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Electrochemically-InducedDehydrogenation of the Hydride-Nitrile Complexes [ReClH(NCR)(dppe) 2 ][BF 4 ]", Journnéesd'Electrochimie, Brest, França, 1991, Ca4.3.12 M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Raymond L.Richards, "Synthesis of theHydride-Nitrile-Complexes [ReClH(NCR)(dppe) 2 ][BF 4 ]", International Conference on InorganicChemistry, Univ. Sussex, Brighton, 1991.199213 M. Teresa Duarte, João J.R. Fraústo da Silva, Adelino M. Galvão, M. Fátima C. Guedes da Silva,Armando J.L. Pombeiro, "Synthesis and Crystal Structure of trans-[ReCl 2 (dppe) 2 ][BF 4 ]", 13ºEncontro da Sociedade Portuguesa de Química, Lisbon, 1992, PI10.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 32 / 4714 M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Rino A. Michelin, Mirto Mozzon,"Conversion of Ethyldiazoacetate into Diethylfumarate at a Pt Centre; Synthesis of [Pt( 2 -EtO 2 CCH=CHCO 2 Et)(PPh 3 ) 2 ]", Italian-Portuguese-Spanish Meeting, Algarve, 1992, OM44(presented by M.F.C.G.S.).15 Tânia J. Castilho, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Roberta Bertani, MirtoMozzon, Rino A. Michelin "Electrochemical Behaviour of Aminooxy-, Dioxy- andDiaminocarbene Complexes of Palladium(II) and Platinum(II)", NATO ARW, Sintra, 1992, P14.16 João J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, José Armando L. da Silva, Armando J.L. Pombeiro, "Redox Properties of the Amavadine Models [V(HIDA) 2 ] 2- and [V(HIDPA) 2 ] 2- andtheir Electroinduced Reactivity towards Activated-Thiols and -Phenols", NATO ARW,Sintra, 1992, P19.17 M. Fátima C. Guedes da Silva, João J. R. Fraústo da Silva, Armando J.L. Pombeiro, ChristianAmatore, Jean-Nöel Verpeaux, "Mechanism of the Electroactivation of the Metal-Hydride Bondin [ReClH(NCR)(Ph 2 PCH 2 CH 2 PPh 2 ) 2 ][BF 4 ]", NATO ARW, Sintra, 1992, P24.18 M. Fátima C. G. Silva, M. Teresa Duarte, Adelino M. Galvão, João J. R. Fraústo da Silva,Armando J.L. Pombeiro, "Synthesis and Structural Characterization of cis-[Re(NCC 6 H 4 Me-4) 2 (Ph 2 PCH 2 CH 2 PPh 2 ) 2 ][BF 4 ]", I.C.C.C., Lausanne, 1992, P550.19 João J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, J. Armando L. da Silva, Armando J.L.Pombeiro, "Redox Properties of Amavadine Models [V(HIDA) 2 ] 2- and [V(HIDPA) 2 ] 2- , Mediatorsfor the Electrocatalytic Oxidation of some Thiols and Phenols", EUROBIC I, Newcastle, 1992,P84.20 Rino A. Michelin, Mirto Mozzon, Roberta Bertani, Armando J.L. Pombeiro, M. Fátima C.Guedes da Silva, "Chemical and Electrochemical Behaviour of Hydrido-Carbene Complexes ofPt(II)", I Congresso Gruppo Interdivisionaly Chimica Organometallica, CO.G.I.C.O.'92,Camerino, 1992, 20.21 Elsa M.P.R.P. Branco, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, Roberta Bertani,Rino Michelin, Mirto Mozzon, "Redox Properties of Hydride Complexes of Pt(II) with a Metal-Carbon Single Bond", VI Encontro da Sociedade Portuguesa de Electroquímica, Vila Real, 1992,44.22 Yu-Ying Tong, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, P. Martin-Zarga, G. Martin, P. Gili, "Redox Properties of some Tryptamine-DerivedSalicylaldimines and of their Tetra-Coordinate Cobalt(II), Nickel(II) or Copper(II) Complexes",VI Encontro da Sociedade Portuguesa de Electroquímica, Vila Real, 1992, 46 (presented byY.Y.T.).23 M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "AnodicallyInduced cis to trans Isomerization of the Nitrile Complexes [ReCl(NCR)(dppe) 2 ]", VI Encontroda Sociedade Portuguesa de Electroquímica, Vila Real, 1992, 48 (presented by M.F.C.G.S.).199324 M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, ChristianAmatore, J.-N. Verpeaux, "Electrochemical Mechanistic Study of the Isomerization of the NitrileComplex [ReCl(NCC 6 H 4 F-4)(dppe) 2 ]", 12 th Summer School on Coordination Chemistry,Karpacz, Polónia, 1993, P20, 72.25 M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, "Synthesisand Characterization of the cis Isomers of the Nitrile Complexes [ReCl(NCR)(dppe) 2 ]", Latin-American Inorganic Chemistry Meeting, Santiago de Compostela, 1993, LAICM1220P, 115.26 Elsa M.P.R.P. Branco, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, Rino Michelin, Roberta Bertani, Mirto Mozzon, Paola Berin, "Cyanamide Complexesof Palladium and Platinum", Latin-American Inorganic Chemistry Meeting, Santiago deCompostela, 1993, LAICM1218P, 104.27 Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Roberta Seraglia, M. Fátima C. Guedes daSilva, Armando J.L. Pombeiro, "Highly Reactive Platinum(0) Intermediates; a Fast AtomBombardment-Mass Spectrometry Study", XXI Congresso Nazionale di Chimica Inorganica,

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 33 / 47Villasimius, Cagliari, 29 Septembre-01 Octobre (1993) 419; 1 st Journal of OrganometallicConference on Applied Organometallic Chemistry, Munchen, Germany, Nov. 4-5, (1993) 7;Sintesi e Metodologie Speciali in Chimica Inorganica (Applicazioni a Composti e MaterialiInnovativi), Bressanone, Itália, 1993, p.58.199428 Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Roberta Seraglia, M. Fátima C. Guedes daSilva, Armando J.L. Pombeiro, "Highly Reactive Platinum(0) Carbene Intermediates in theReactions of Diazo Compounds. A Fast Atom Bombardment Mass Spectrometric Study", XVI Int.Conf. Organomet. Chem., Univ. Sussex, 1994, P.42.29 Franco Benetollo, Roberta Bertani, Gabriela Bombieri, Elsa M.P.R.P. Branco, M. Estela S. Dória,M. Fátima C. Guedes da Silva, Rino A. Michelin, Mirto Mozzon, Armando J.L. Pombeiro, YuWang, "Synthesis and Properties of Cyanamide and Cyanoguanidine Complexes of Platinum(II).X-Ray Structure of trans-[Pt(CF 3 )(NCNEt 2 )(PPh 3 ) 2 ][BF 4 ]." XVI Int. Conf. Organomet. Chem.,Univ. Sussex, 1994, P.211.30 Roberta Bertani, Giacomo Facchin, M. Gleria, M. Fátima C. Guedes da Silva, Isabel L.F.Machado, Rino Michelin, Armando J.L. Pombeiro, "Redox Properties of Platinum Complexeswith Cinnamonitrile Substituted Phosphazenes", 45 th Annual Meeting of the International Societyof Electrochemistry, Porto, 1994, IV-6.31 M. Fátima C. Guedes da Silva, M. Amélia N.D.A. Lemos, Armando J.L. Pombeiro, "Electron-Transfer Activation of the Aminocarbyne Complex trans-[ReCl(CNH 2 )(dppe) 2 ] [BF 4 ]", 45 thAnnual Meeting of the International Society of Electrochemistry, Porto, 1994, IV-31.199532 Adelino M. Galvão, Elena Levi, Armando J.L. Pombeiro, M. Fátima C. Guedes da Silva, J.Armando da Silva, João J.R. Fraústo da Silva, "Modelos da Amavadina - Estudos com oComplexo de Crómio(III) com HIDA", 2ª Conferência de Química Inorgânica, SociedadePortuguesa de Química, Monte Real, 1995, CP 22, 91.33 M. Fátima C. Guedes da Silva, José Armando L. Silva, João J. R. Fraústo da Silva, Armando J.L.Pombeiro, "Oxidação Electrocatalítica de Tióis por Complexos de Vanádio, modelos daAmavadina", 2º Encontro da Divisão de Catálise, Sociedade Portuguesa de Química, Lisbon,1995, 47-48.34 M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro, M. AngelaPellinghelli, Antonio Tiripicchio, "Binding of Isocyanides to an Electron-Rich Rhenium(I)Centre. X-Ray Molecular Structures of the Complexes trans-[ReCl(CNR)(dppe) 2 ] (R = H orSiMe 3 )", 24 th IUPAC Conference on Solution Chemistry, Lisbon, 1995, PH04, 192.35 M. Estela S. Dória, Elsa M.P.R.P. Branco, Maria de Fátima C. Guedes da Silva, Armando J.L.Pombeiro, Rino A. Michelin, Roberta Bertani, Mirto Mozzon, "Redox Properties of SomeCyanamide-Derived Complexes of Palladium(II) and Platinum(II)", VII Encontro da SociedadePortuguesa de Electroquímica, III Encontro Ibérico de Electroquímica, Algarve, 1995, B7, 67.36 M. Fátima C. Guedes da Silva, J. Armando L. da Silva, João J. R. Fraústo da Silva, Armando J.L.Pombeiro, Christian Amatore, Jean-Nöel Verpeaux, "Searching for the Mechanism of theElectrocatalytic Oxidation of Mercaptopropionic Acid by an Amavadin Model", VII Encontro daSociedade Portuguesa de Electroquímica, III Encontro Ibérico de Electroquímica, Algarve, 1995,B4, 59.37 M. Fátima C. Guedes da Silva, Luísa M.D.R.S. Martins, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, "FAB-MS Spectra of Nitrile or Cyanamide Complexes with the{M(Ph 2 PCH 2 CH 2 PPh 2 ) 2 } n+ (M = Fe or Re) Metal Sites. Applications to the Reactions Induced inFAB Conditions", 2º Encontro de Espectrometria de Massa, Lisbon, 1995, P15, 85.199638 M. Fátima C. Guedes da Silva, João J. Fraústo da Silva, Armando J.L. Pombeiro, Maria A.Pellinghelli, Antonio Tiripicchio, " Deprotonation Reactions of the Aminocarbyne Complex

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 34 / 47trans-[ReCl(CNH 2 )(dppe) 2 ][BF 4 ] (dppe = Ph 2 PCH 2 CH 2 PPh 2 ) to Form Cyano-Complexes withSmall Unsaturated Ligands. X- Ray Molecular Structure of trans-[Re(CN)(NCMe)(dppe) 2 ].C 3 H 8 O", 13 th Summer School on Coordination Chemistry, Wroclaw -Polónia, 1996, P30. 88.39 M. Fátima C. Guedes da Silva, Cristina M.P. Ferreira, Elsa M.P.R.P. Branco, Armando J.L.Pombeiro, Rino Michelin, Gabriella Bombieri, Franco Benetollo, " Synthesis and MolecularStructure of the Cyanoguanidine-Derived Azametallacycle Complex cis-[(PPh 3 ) 2 Pt{NH-C(OMe)=NC(NH 2 )=NH}][BPh 4 ]" 13 th Summer School on Coordination Chemistry, Wroclaw,Polónia, 1996, P22, 80.40 Cristina M.P. Ferreira, Annette Limberg, M. Fátima C. Guedes da Silva, Mohamed F. Meidine,Armando J. L. Pombeiro, Piotr Sobota, “Electrochemical Study of Some Vanadium Complexes”,VIII Encontro da Sociedade Portuguesa de Electroquímica, Covilhã, 25-28 Setembro 1996, 26.41 Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, ElectrochemicalBehaviour of Adducts of trans-Mo(NCN) 2 (dppe) 2 with Some Transition Metal Lewis Acids”,VIII Encontro da Sociedade Portuguesa de Electroquímica, Covilhã, 1996, 33.42 M. Fátima C. Guedes da Silva, Isabel L.F. Machado, Armando J.L. Pombeiro, M. Gleria, R.Bertani, G. Facchin, F. Noé, R.A. Michelin, M. Mozzon, “Electrochemical behavior of Pt-Cinnamonitrile Cyclophosphazene Complexes”, VIII Encontro da Sociedade Portuguesa deElectroquímica, Covilhã, 1996, B9, 34.199743 M. Fátima C. Guedes da Silva, M. Fernanda N.N. Carvalho, M Amélia N.D.A. Lemos, ArmandoJ.L. Pombeiro, “Binding and Reactivity of Cyanide, Isocyanide and Aminocarbyne, CNH x (x = 0- 2), at a Single Transition Metal Centre”, 16 th Conference on Coordination Chemistry,Smolenice, Eslovaquia, 1997, p. 61.44 Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Indalécio Marques, João J.R. Fraústo daSilva, M. Cândida Vaz, Armando J.L. Pombeiro, “Fast-Atom Bombardment (FAB) Mass Spectraof the CyanoimidoComplexe trans-Mo(NCN) 2 (Ph 2 CH 2 CH 2 PPh 2 ) 2 and some derivatives”, 3ºEncontro Nacional de Espectrometria de Massa, Lisbon, 1997, p.56-57.45 Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Indalécio Marques, João J.R. Fraústo daSilva, M. Cândida Vaz, Armando J.L. Pombeiro, “Fast-Atom Bombardment (FAB) Mass Spectraof Some Platinum Complexes. Unusually Intense Molecular Ion Peaks in AzametallacycleComplexes”, 3º Encontro Nacional de Espectrometria de Massa, Lisbon, 1997, p.59-60.46 Rino A. Michelin, Mirto Mozzon, Roberta Bertani, Cristina M.P. Ferreira, M. Fátima C. Guedesda Silva, Armando J.L. Pombeiro, “N-Heterocycles and Azametallacycles from reactions ofNitriles and Cyanoguanidine Promoted by Platinum(II)”, XXV Congresso di Chimica Inorganica,Alessandria, 1997, C12.47 Lei Zhang, M.P. Gamasa, J. Gimeno, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro,“Synthesis and Electrochemical Studies of Cyanide and Diisocyanide Bridged Fischer TypeDinuclear Bis(Alkenyl-Carbyne) Tungsten Complexes”, International School of OrganometallicChemistry, Camerino, 1997, p.115-116.48 M. Fátima C. Guedes da Silva, Karayoun Marjani, Armando J.L. Pombeiro, R.L. Richards,“Anodically-Induced Isomerisation of cis-Mo(SC 6 H 2 Pr i 3-2,4,6) 2 (CNBu t ) 4 A MechanisticStudy.” IX Encontro da Sociedade Portuguesa de Electroquímica, Braga, 1997, p. 51-52.49 Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “ComparativeElectrochemical Study of Protonated Derivatives of trans-Mo(NCN) 2 (Ph 2 CH 2 CH 2 PPh 2 ) 2 andtrans-Mo(NCNEt)(NCN)(Ph 2 CH 2 CH 2 PPh 2 ) 2 + ”, IX Encontro da Sociedade Portuguesa deElectroquímica, Braga, 1997, p. 49-50.50 Fernando S.C.L. Conde, Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Armando J.L.Pombeiro, Rino A. Michelin, Christian Amatore, “Electrochemical Behaviour of Platinum(II)Complexes with Ligating Unsaturated Carbon Species”, IX Encontro da Sociedade Portuguesa deElectroquímica, Braga, 1997, p. 47-48.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 35 / 4751 Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Vadim Yu. Kukuskin, Armando J.L.Pombeiro, “Oxidative addition of Oxime to a Metal Centre, a Novel Route for MethyleneamideLigands. Synthesis and Crystal Structures of trans-Re(OH)(N=CMe 2 )(Ph 2 PCH 2 CH 2 PPh 2 ) 2 HSO 4 .” 2 nd International Conference on Progress inInorganic and Organometallic Chemistry, Polanica Zdrój-Poland, 1997, p. 73.52 Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, “Electrophilic Additions to Cyanoimide (NCN) Ligands, Crystal Structure of trans-Mo(NCNEt)(NCN)(Ph 2 CH 2 CH 2 PPh 2 ) 2 BF 4 .” 2 nd International Conference on Progress inInorganic and Organometallic Chemistry, Polanica Zdrój-Poland, 1997, p. 72.53 Cristina M.M. Matoso, J. Armando L. Silva, J.J.R. Fraústo da Silva, M. Fátima C. Guedes daSilva, Armando J.L. Pombeiro, “A Possible Role for Amavadine in some Amanita Fungi – AUnique Case in Biology”, The Fifth Chemical Congress of North America, Cancún, QuintanaRoo, México, 1997, 02-845.54 Cristina M.M. Matoso, João J.R. Fraústo da Silva, M. Fátima C. Guedes da Silva, J. Armando L.Silva, Nádia S.S. Viaro, “Reacções dos N-Amino e N-Hidroxi Derivados do Ácidoiminodicarboxílico e seus complexos”, XI Encontro Galego-Português de Química, Férrol, 1997,1.02-75.199855 Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, V.Yu. Kukushkin, Armando J.L.Pombeiro, “Methyleneamide Complexes of Re Derived from Oximes”, XXXIII InternationalConference on Coordination Chemistry, Florence, Itália, 1998, p. 468.56 M. Fátima C. Guedes da Silva, C.M.P. Ferreira, Armando J.L. Pombeiro, “Isomeric Conversionof cis-ReCl(CO)(Ph 2 CH 2 CH 2 PPh 2 ) 2 via an Electron-Transfer Chain Catalytic Mechanism”, PostICCC Satellite Meeting. Electrochemistry: Long- and Short-Lived Intermediates in Coordinationand Organometallic Compounds, Siena, Itália, 1998, p. 48-49.57 Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “MechanisticStudy of the Cathodically Induced Dehydrogenation of Hydrogen Cyanamide at trans-Mo(NCNH)(NCN) (Ph 2 CH 2 CH 2 PPh 2 ) 2 + ”, Post ICCC Satellite Meeting. Electrochemistry:Long- and Short-Lived Intermediates in Coordination and Organometallic Compounds, Siena,Itália, 1998, p. 46-47.199958 Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, Vadim Yu. Kukushkin, Rino A. Michelin,Armando J.L. Pombeiro, “Síntese e Caracterização de Complexos Neutros de Pt(II) comLigandos do Tipo Imino Éter e Oxazolina. Estrutura Molecular do Complexo cis-[PtCl 2 {N=C(OCH 2 CH 2 )NEt 2 } 2 ]. “IV Conferência de Química Inorgânica, Peniche, Portugal, O4,1999, p. 29-30.59 Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, “Síntese, Caracterização e Reactividade dos primeiros Complexos Mistos de Diazoto eCianamidas trans-[Mo(N 2 )(NCNR 2 ) (Ph 2 PCH 2 CH 2 PPh2) 2 ]. Estrutura Molecular de Cianamidastrans-[Mo(N 2 )(NCNEt 2 ) (Ph 2 PCH 2 CH 2 PPh2) 2 ]. “IV Conferência de Química Inorgânica,Peniche, Portugal, 1999, P2, p. 61-62.60 M. Fátima C. Guedes da Silva, Sílvia S.P.R. Almeida, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, “Anodic Deprotonation of the Hydrogen Isocyanide Complex trans-[FeH(CNH)(dppe) 2 ].” V Encontro Ibérico de Electroquímica, X Encontro da SociedadePortuguesa de Electroquímica”, Évora, Portugal, 1999, p. 79-80.61 Sónia, M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “RedoxProperties of the Dinitrogen-Cyanamide Complexes trans-[Mo(N 2 )(NCNR 2 )(Ph 2 PCH 2 CH 2 PPh2) 2 ] and some derivatives.” V Encontro Ibérico de Electroquímica, X Encontroda Sociedade Portuguesa de Electroquímica”, Évora, Portugal, 1999, p. 91-92.62 M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, A.V. Zinchenko, Vadim Yu. Kukushkin,“Electrochemical Study of Ruthenium and Osmium Complexes with S-Coordinated Me 2 S and

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 36 / 47Me 2 SO Ligands.” V Encontro Ibérico de Electroquímica, X Encontro da Sociedade Portuguesade Electroquímica”, Évora, Portugal, 1999, p. 109-110.63 Natércia C.T. Martins, M. Fátima C. Guedes da Silva, Sónia M.P.R.M. Cunha, Carlos Paliteiro,Christopher J. Pickett, Armando J.L. Pombeiro, "Mechanistic Investigation of the ElectrocatalyticReduction of Organoiodides by trans-[MoI 2 (dppe) 2 ]", 14 th Summer School on CoordinationChemistry, Polanica-Zdrój, Polónia, 1999, P82, p. 144.64 Cristina M.P. Ferreira, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, Vadim Yu Kukushkin, "Azametallacylces from Coupling Reactions ofDialkylcyanamides with Oximes Promoted by Pt(II)", 14 th Summer School on CoordinationChemistry, Polanica-Zdrój, Polónia, 1999, P85, p. 147.65 Sónia M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L.Pombeiro, "Reactions of Cyanoimide (NCN) at a Mo Centre", 14 th Summer School onCoordination Chemistry, Polanica-Zdrój, Polónia, 1999, P86, p. 148.66 M. Fátima C. Guedes da Silva, Lei Zhang, João J.R. Fraústo da Silva, Armando J.L. Pombeiro,"Anodically-Induced C-H and N-H Bond Cleavage at Isocyanide, Alkenylcarbyne or HydrazibeComplexes", Organometallics and Catalysis, 14-16 Julho, 1999, University of Rennes, França, p.34.67 Lei Zhang, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, "Mo or W Complexes with4e- or 2e-donor Alkenylalkyne Ligands", Organometallics and Catalysis, 14-16 Julho, 1999,University of Rennes, França, p. 61.200068 Natércia C.T. Martins, M. Fátima C. Guedes da Silva, Sónia M.P.R. Cunha, C. Paliteiro, C.J.Pickett, Armando J.L. Pombeiro, “Study of the Kinetics of the Electrocatalytic Reduction ofOrganic Halides by trans-[MoX 2 (dppe) 2 ] (X = I, Br)”, 34 th Internat. Conference on CoordinationChemistry, 2000, Edinburg, P0065.69 M. Fátima C. Guedes da Silva, Anna M. Trzeciak, Józef Ziólkowski, Armando J.L. Pombeiro,"Electrochemical Parameterisation of Square Planar Rhodium(I/II) Redox Couples", Metal-Containing Molecules: 1 st Chianti Electrochemistry Meeting, Siena, Itália, 2000,57.70 Ana I.F. Venâncio, Luisa M.D.R.S. Martins, M. Fátima C. Guedes da Silva, João J.R. Fraústo daSilva, Armando J.L. Pombeiro, "Electrochemical Behaviour of Dinitrile Iron(II)-HydrideComplexes", Metal-Containing Molecules: 1 st Chianti Electrochemistry Meeting, Siena, Itália,2000, 71.71 M. Fátima C. Guedes da Silva, João J.R. Fraústo da Silva, Armando J.L. Pombeiro,“Azavinylidene Complexes of Rhenium”, 3 rd Internat. Conference on Progress in Inorganic andOrganometallic Chemistry (PIOC), 2000, Polanica Zdrój, Polónia, P56, p. 100.200172 Sílvia S.P.R. Almeida, J.J.R. Fraústo da Silva, Armando J.L. Pombeiro, “Estimate ofElectrochemical Ligand Parameters in Iron(II) Adducts of [FeH(CN)(dppe) 2 ]”, VI EncontroIbérico de Electroquímica/XI Encontro da Sociedade Portuguesa de Electroquímica, Porto,Portugal, 2001, P-B1,73 Natércia C. T. Martins, M. Fátima C. Guedes da Silva , J. Armando L. da Silva, João J. R. Fraústoda Silva, Carlos Paliteiro, Armando J.L. Pombeiro, “Electrocatalytic Oxidation of Pyrogallol byan Amavadin Model”, VI Encontro Ibérico de Electroquímica/XI Encontro da SociedadePortuguesa de Electroquímica, Porto, Portugal, 2001, P-B3.74 Natércia C.T. Martins, P.J. Figiel, M. Fátima C. Guedes da Silva, Józef Ziólkowski, ArmandoJ.L. Pombeiro, “Searching for the mechanism of the Electrocatalytic Oxidation of Cyclohexanolby N-Hydroxyphthalimide”, 6 th FIGIPS (France, Itália, Greece, Israel, Portugal and Espanha)Meeting in Inorganic Chemistry (European Mediterranean Conference in Inorganic Chemistry),Barcelona, Espanha, 2001, PA.058, p. 170.75 Maximilian N. Kopylovich, Vadim Yu. Kukushkin, M. Fátima C. Guedes da Silva, Matti Haukka,João J.R. Fraústo da Silva, Armando J.L. Pombeiro “Conversion of Alkyl Nitriles to Amidines

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 37 / 47and Carboxylic Acids Catalyzed by a Cobalt(II)-Ketoxime System” 4 th International School onMolecular Catalysis, Poznań Dymaczewo, Polónia, 2001, IIA-P5, p.79.76 M. Fátima C. Guedes da Silva, J.J.R. Fraústo da Silva, Armando J.L. Pombeiro “Activation ofOrganonitriles Towards B-Electrophilic Addition”, 3 rd International School of OrganometallicChemistry, Univ. Camerino, Itália, 2001, p.81.77 Qingshan Li, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro “Diorgano- and Dichloro-Tin(IV) Complexes of ArylHydroxamic Acids, Their Antitumor Activity in vitro and MolecularStructures”, 3 rd International School of Organometallic Chemistry, Univ. Camerino, Itália, 2001,p.136.200278 Natércia C.T. Martins, P.J. Figiel, M. Fátima C. Guedes da Silva, Józef Ziólkowski, ArmandoJ.L. Pombeiro “Digital Simulation of the Electrocatalytic Oxidation of Secondary Alcohols by N-Hydroxyphthalimide”, 2 nd Chianti Electrochemistry Meeting, Siena, Itália, Julho 2002, p.69.79 Sílvia S.P.R Almeida, M. Fátima C. Guedes da Silva, Armando J.L. Pombeiro, “ComportamentoElectroquímico de Alguns Aductos de trans-[FeH(CN)(dppe) 2 ]”, SIBAE 2002, XV Congresso daSociedade Ibero-Americana de Electroquímica, Évora, Portugal, 2002, 5255P.80 Natércia C.T. Martins, P.J. Figiel, M. Fátima C. Guedes da Silva, Józef Ziólkowski, ArmandoJ.L. Pombeiro “Mechanistic Investigation of the Electrocatalytic Oxidation of Alcohols by N-Hydroxyphthalimide”, 53 rd Annual Meeting of the International Society of Electrochemistry,Alemanha, 2002, p.355.200381 E.C.B. Alegria, L.M.D.R.S. Martins, T.F.S. Silva, M. Fátima C. Guedes da Silva, A.J.L.Pombeiro*, “Unexpected Complex Double Salt with Poly(pyrazolyl)borate Iron(III). CrystalStructure of [Fe(HB(pz) 3 ][FeCl 4 ] {HB(pz) 3 = hidrotris(1-pyrazolyl)borate}”, FIGIPS Meeting inInorganic Chemistry, Lisboa, 2003, P148.82 S.S.P.R. Almeida, M. Fátima C. Guedes da Silva, L.B. Jerzykiewicz, P. Sobota, A.J.L. Pombeiro,“Synthesis and Characterization of some Heteronuclear Complexes of Iron(II)”, FIGIPS Meetingin Inorganic Chemistry, Lisboa, Portugal, 2003, P151.83 A.I.F. Venâncio, M. Fátima C. Guedes da Silva, L.M.D.R.S. Martins, A.J.L. Pombeiro,“Reactions of the Allenylidene Complex trans-[FeBr(=C=C=CPh 2 )(dppe) 2 ][BPh 4 ] withNucleophilic Agents”, FIGIPS Meeting in Inorganic Chemistry, Lisboa, Portugal, 2003, P403.84 E.C.B. Alegria, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, S.M.P.R.M. Cunha, J.J.R.Fraústo da Silva, A.J.L. Pombeiro, “Reactions of Cyanamide at a N 2 – Binding MolybdenumCenter. Formation of Cyanoimide Species”, SMWC - II Santa Maria Workshop on Chemistry,Devoted to Bioinorganic Chemistry, Havana, Cuba, 2003, P1.85 A.J.L. Pombeiro, M. Fátima C. Guedes da Silva “Bond and Structure Activation by AnodicElectron-Transfer: Metal-Hydrogen Bond Cleavage and cis/trans Isomerization in CoordinationCompounds”, New Trends in Molecular Electrochemistry and XII Meeting of The PortugueseElectrochemical Society, Academia das Ciências de Lisboa, Portugal, 2003, PL9, 10.86 E.C.B. Alegria, S.M.P.R.M. Cunha, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.Pombeiro, “Electrochemical Behaviour of the Cyanoimide-Type Complexes trans-[Mo(NCN){NCNC(O)R}(dppe) 2 ]Cl and trans--[Mo(NCN)Cl(dppe) 2 ][BF 4 ]”, New Trends inMolecular Electrochemistry and XII Meeting of The Portuguese Electrochemical Society,Academia das Ciências de Lisboa, Portugal, 2003, P.ME11, 88.87 N.A. Bokach, M. Haukka, V.Yu. Kukushkin, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro,“Electrochemical Investigation of Rithenium-Bipyridine-Cyanamide Complexes” New Trends inMolecular Electrochemistry and XII Meeting of The Portuguese Electrochemical Society,Academia das Ciências de Lisboa, Portugal, 2003, P.ME13, 90.200488 L.M.D.R.S. Martins, T.F.S. Silva, S.M.P.R.M. Cunha, E.C.B. Alegria, M. Fátima C. Guedes daSilva, A.J.L. Pombeiro “Reactions of Cyanamide and Derived Cyanoimide at a Molybdenum

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 38 / 47Diphosphinic Centre”, Inorganic Reactions Mechanisms Meeting 2003, Athens, Greece, 2004,P44.89 E.C.B. Alegria, S.M.P.R.M. Cunha, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.Pombeiro “Isomerização Geométrica Induzida por Transferência Electrónica de Complexos transde Molibdénio e Cianoimida”, XV Congresso da Sociedade Ibero-Americana de Electroquímica,SIBAE 2004, 2004, C027.90 E.C.B. Alegria, L.M.D.R.S. Martins, M.F.C.G. da Silva, A.J.L. Pombeiro, “Cleavage of a C(sp 3 )-N Bond in Hydrotris(pyrazolyl)methane Promoted by a Re- Benzoylhydrazido Complex”, IIIEuchem Conference on Nitrogen Ligands in Organometallic Chemistry and HomogeneousCatalysis, Camerino, Itália, 2004, P2.91 E. Reisner, V.B. Arion, M. Fátima C. Guedes da Silva, M.A. Jakupec, B.K. Keppler, V. Yu.Kukushkin, A.J.L. Pombeiro, “Electrochemical Aspects for the Design of Ruthenium AnticancerDrugs – Redox Behaviour, Digital Simulations and Correlations with in vitro AntiproliferativeActivity”, 3 rd Chianti Electrochemistry Meeting on Metal-containing Molecules, Certosa diPontignano, Siena, Itália, 2004, p. 35.92 L.M.D.R.S. Martins, E. Alegria, S.M.P.R.M. Cunha, M. Fátima C. Guedes da Silva, A.J.L.Pombeiro, “Alkylation of Cyanoimido at a N 2 -binding Molybdenum Centre”, XXXVI thInternational Conference on Coordination Chemistry, Mérida, Mexico, 2004, P1.106, p. 468.200593 A.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “Rhenium Benzoylhydrazido and Diazenido Complexes with N,O-Ligands and their application in the CatalyticPeroxidative Oxidation of Cycloalkanes” 20 th International Conference on Coordination andBioinorganic Chemistry, Smolenice, Slovakia, 2005, p.56.94 Y.Yu. Karabach, A.M. Kirillov, M.N. Kopylovich, M. Fátima C. Guedes da Silva, M. Haukka,A.J.L. Pombeiro “New Self-Assembled Copper 1D and 2D-Coordination Polymers as Catalystsfor Biphasic Peroxidative Oxidation of Cyclohexane under mild Conditions”, Current and FutureTrends in Polymeric Meterials, Prague, República Checa, 2005, PC23.95 K.V. Luzyanin, M.F. C. Guedes da Silva, V. Yu. Kukushikin, A.J.L. Pombeiro “Platinum-Mediated Coupling of Some HON-Nucleophiles and Nitriles: Synthetic and ElectrochemicalStudies”, VIII Iberic Meeting of Electrochemistry/XII Meeting of the Portuguese ElectrochemicalSociety, Covilhã, Portugal, 2005, PB.2, pp97-98.200696 A.M. Kirilov, M.N. Kopylovich, M.V. Kirillova, Y. Yu. Karabach, M. Haukka, M. Fátima C.Guedes da Silva and A.J.L. Pombeiro, “New Water-soluble Multinuclear Copper TriethanolamineComplexes as Efficient Catalysts for Mild Peroxidative Oxidation of Alkanes in AqueousBiphasic Liquid Medium”, Green Chemistry: a Solution for the World (Andalusia meets EuropeII, 2 nd Workshop of COST D29/0009/03 Working Group and AQUACHEM Midterm ReviewMeeting and Workshop), Almeria, Espanha, 2006, C-3, pp. 7-8.97 Y. Yu. Karabach, M. Fátima C. Guedes da Silva, M. Haukka, A.M. Kirillov, M.N. Kopylovich,A.J.L. Pombeiro, “New 1D and 2D Water-soluble Cu(II) Polymers Derived from PyromelliticAcid”, Green Chemistry: a Solution for the World (Andalusia meets Europe II, 2 nd Workshop ofCOST D29/0009/03 Working Group and AQUACHEM Midterm Review Meeting andWorkshop), Almeria, Espanha, 2006, C-30, p. 44.98 M.V. Kirillova, M. Fátima C. Guedes da Silva, A.M. Kirillov, J.J.R. Fraústo da Silva, A.J.L.Pombeiro, “Self-assembly Synthesis and Characterization of New Heterodinuclear AquaComplexes of the type [M(H 2 O) 5 M’(dipic) 2 ] (M,M’ = Co 2+ , Ni 2+ , Cu 2+ , Zn 2+ ) Derived fromDipicolinic Acid in Water Solution”, Green Chemistry: a Solution for the World (Andalusiameets Europe II, 2 nd Workshop of COST D29/0009/03 Working Group and AQUACHEMMidterm Review Meeting and Workshop), Almeria, Espanha, 2006, P-2, p. 50.99 M.F.C.Guedes da Silva, Maximilian Kuznetsov, A.J.L. Pombeiro “Azavinylidene Complexes ofRhenium: Electrochemical Behaviour and Theoretical Study”, 4 th Chianti Meeting on InorganicElectrochemistry, Siena, Itália, Julho 2006, p. 63.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 39 / 47100 A.M. Kirillov, M. Haukka, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “New Mono- nadDicarbonyl Phosphine Rhenium(I) Complexes Bearing Aromatic N-, N, N- and N,O_HeterocyclicLigands” XXII International Conference on Organometallic Chemistry, Zaragoza, Espanha, 2006,P199, p. 387.101 Y. Yu. Karabach, A.M. Kirillov, M. Fátima C. Guedes da Silva, M.N. Kopylovich, A.J.L.Pombeiro “Catalytic Activity of na Aqua-Soluble Copper(II)-Sodium Two-DimensionalCoordination Polymer in the Peroxidqative Oxidation of Cyclohexane” Experiment & Theory inTransition Metal Chemistry: a Meeting Point, Bellaterra, Espanha, 2006, p.45.102 S.M. Sbovota, A.J.L. Pombeiro, M. Fátima C. Guedes da Silova, R.A. Michelin “Water SolubleOrganonitrile Platinum(II) Complexes” Experiment & Theory in Transition Metal Chemistry: aMeeting Point, Bellaterra, Espanha, 2006, p.47.103 M. Fátima C. Guedes da Silva, M.Kuznetsov, A.J.L. Pombeiro “Azavinylidine Complexes ofRhenium: Electrochemical Behaviour and Theoretical Study, 4 th Chianti Meeting on InorganicElectrochemistry, Siena, Itália, 2006, p.63.2007104 A.M. Kirillov, M.N. Kopylovich, M.V. Kirillova, M. Haukka, M.F.C. Guedes da Silva, A.J.L.Pombeiro, “Mild Peroxidative Oxidation of Alkanes Catalyzed by Multinuclear Cooper(II)Triethanolaminate Complexes”, 3 rd International Conference on Green and SustainableChemistry (GSC-3 Symposium), Delft, The Netherlands, 2007, P108, p. 108.105 M.N. Kopylovich, Ya. Yu. Karabach, A.M. Kirillov, M. Haukka, M.F.C.G. da Silva, A.J.L.Pombeiro, “From Solution to Solid Phase: Synthesis of New Copper(II) ContainingCoordination Polymers with Diverse Architectures”. XVI International Conference on ChemicalThermodynamics in Russia (RCCT 2007) / X International Conference on the Problems ofSolvation and Complex Formation in Solutions, Suzdal, Russia, 2007, 5/S – 560-561.106 Y. Yu. Karabach, A.M. Kirilllov, M. Haukka, M.F.C. Guedes da Silva, M.N. Kopylovich,A.J.L. Pombeiro, “New Copper(II) Containing Coordination Polymers with DiverseArchitectures”, 9 th FIGIPAS Meeting in Inorganic Chemistry, Vienna, Austria, 2007, PO-76.107 Y. Yu. Karabach, A.M. Kirilllov, M.F.C. Guedes da Silva, M. Haukka, M.N. Kopylovich,A.J.L. Pombeiro “Synthesis and Characterization of Copper(II)-Aminopolyalcohol-Benzenepolycarboxylate Coordination Polymers” AQUACHEM – Transition Metal Chemistryand Catalysis in Aqueous Media; 3 rd Annual Meeting, Debrecen, Hungary, 2007, P3.108 A.M. Kirilllov, P. Smolenski, M.F.C. Guedes da Silva, M. Haukka, M.N. Kopylovich, A.J.L.Pombeiro “The First Copper Complexes Bearing the 1,3,5-triaza-7-phosphaadamantane (tpa)Ligand” AQUACHEM – Transition Metal Chemistry and Catalysis in Aqueous Media; 3 rdAnnual Meeting, Debrecen, Hungary, 2007, P4.2008109 J. Lasri, M.A.J. Charmier, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “Mixed UnsymmetricalOxadiazoline and/or Imino Platinum(II) Complexes”, IX th Netherlands’ Catalysis and ChemistryConference, Noordwijkerhout, The Netherlands, 2008, P71, p.223.110 A. Furtado, C. Travassos, A.M. Kirillov, M.F.C. Guedes da Silva, L.M.D.R.S. Martins,E.C.B.A. Alegria, A.J.L. Pombeiro, “Benzoyldiazenido-Re(III) or Oxo-Re(V) ComplexesBearing N,N- and N,O-type Ligands”, XXI Portuguese Chemical Society National Meeting,Porto, 2008, CP 210, p.274.111 A.J.L.Pombeiro, M.V.Kirillova, A.M.Kirillov, M.L.Kuznetsov, J.A.L.Silva, A. Palavra,M.F.C.Guedes da Silva, J.J.R. Fraústo da Silva, “Highly Efficient Single-pot Carboxylation ofAlkanes to Carboxylic Acids Catalysed by Group 5-7 Metal Catalysts” XXIII InternationalConference on Organometallic Chemistry (ICOMC), Rennes, France, 2008, OC29.112 R.R. Fernandes, A.M. Kirillov, M.F.C. Guedes da Silva, Z. Ma, J.A.L. Silva, J.J.R. Fraústo daSilva, A.J.L. Pombeiro, “Infinite Two-Dimensional Hybrid Water-Chloride Netwrok Self-Assembled in a Hydrophobic Terpyridine Iron(II) Matrix”, XXIII International Conference onOrganometallic Chemistry (ICOMC), Rennes, France, 2008, P352.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 41 / 47125 T.F.S. Silva, G.S. Mishra, M.F. Guedes da Silva, R. Wanke, L.M.D.R.S. Martins, A.J.L.Pombeiro,”Water-soluble Cu(II) Complexes Bearing the 2,2,2-Tris(1-pyrazolyl)ethanol or2,2,2-Tris(1-pyrazolyl)ethylmethanesulfonate. X-ray Structural Characterization andApplication in the Mild Catalytic Peroxidative Oxidation of Cyclohexane”, XII RegionalSeminar of PhD Students on Organometallic and Coordination Chemistry, Szklarska Poreba,Poland, 2009, OP18.126 R.R. Fernandes, J.A.L. da Silva, M.F.C. Guedes da Silva, J.J.R. Fraústo da Silva, A.J.L.Pombeiro, “Bioinspired Oxidations Catalysed by Non-Heme Fe, Cu and V Metal Centres”, XIIRegional Seminar of PhD Students on Organometallic and Coordination Chemistry, SzklarskaPoreba, Poland, 2009, OP24.127 K. V. Luzyanin, A. G. Tskhovrebov, M. F. C. Guedes da Silva, M. Haukka, V. Yu. Kukushkin,A. J. L. Pombeiro, “Metal-mediated [2+3] Cycloaddition of Nitrones to Palladium-boundIsonitriles”, 8 th Inorganic Chemistry Conference, Curia, Portugal, 2009, p. 124.128 M. Gajewska, K.V. Luzyanin, M.F.C. Guedes da Silva, Q. Li, J. Cui, A.J.L. Pombeiro,“Synthesis, Characterization and Biological Activity of Diorganotin(IV) Complexes withOximehydroxamate Ligands”, VII International Congress of Young Chemists (YoungChem2009), Warsaw, Poland, 2009, P07, p.66.129 P. J. Figiel, M.N. Kopylovich, J. Lasri, M.F.C. Guedes da Silva, A.J.L. Pombeiro, “GreenProtocols for the Oxidation of Alcohols Catalysed by Copper(II) 1,3,5-TriazapentadienatoComplexes”, 10 th European Meeting on Environmental Chemistry (EMEC), Limoges, France,2009, ID:147, p.87.2010130 E.C.B.A. Alegria, M.F.C. Guedes da Silva, M.L. Kuznetov, L.M.D.R.S. Martins, C. SousaA.J.L. Pombeiro “Electrochemical, Termodynamic and Kinetic Studies of the AcylatedCyanoimido-Complexes trans- Mo(NCN){NCNC(O)R}(dppe) 2 Cl” XII Iberic Meeting ofElectrochemistry & XVI Meeting of the Portuguese Electrochemical Society, I.S.E.L., 8–11,September, 2010, Lisbon, Portugal. (Oral)131 R.R. Fernandes, J. Lasri, M.F.C. Guedes da Silva, A.M.F. Palavra, J.A.L. da Silva, A.J.L.Pombeiro, “Oxadiazoline and ketoimine Pd(II) complexes as highly efficient catalysts forSuzuki-Miyaura cross-couplings in scCO 2 ” Green Solvents Conference, Berchtesgaden(Germany), 10-13 October 2010. Book of Abstract: P37. (Oral)132 M. Gajewska, K.V. Luzyanin, K.T. Mahmudov, M.N. Kopylovich, M.F.C. Guedes da Silva, Q.Li, J. Cui, A.J.L. Pombeiro “Synthesis, characterization and biological activity ofdiorganotin(IV) complexes with polyfunctional ligands” XXIV International Conference onOrganometallic Chemistry, July, 2010, Taipei, PS2-164.133 L.M.D.R.S. Martins, T.F.S. Silva, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Greenercyclohexane partial oxidation: use of Co scorpionate catalysts” XVI Encontro Luso-Galego deQuímica, Aveiro-Portugal, November 10 th -12 th , 2010, Book of Abstracts CT4. (Oral)134 B.G.M. Rocha, R. Wanke, M.F.C. Guedes da Silva, L.M.D.R.S Martins. A.J.L. Pombeiro“Synthesis and coordination chemistry of the sterically hindered scorpionate ligand Li[Tpms Ph ]towards Ni II , Zn II and Cu II metal centres” 2PYCheM, P. Y. C. M., Ed Aveiro, Portugal 2010.(Oral)135 E.C.B.A. Alegria, X. Shang, X. Meng, Q. Li, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Redoxproperties of antitumor active organotin(IV) complexes containing 1-(4-chlorophenyl)-1-cyclopentanecarboxylato ligands” XII Iberian Meeting of Electrochemistry & XVI Meeting ofthe Portuguese Electrochemical Society, I.S.E.L., 8–11, September, 2010, Lisbon, Portugal.136 M.F.C. Guedes da Silva, A.M. Kirillov, P. Smoleński, Ł. Jaremko, M. Haukka, Z. Ma, A.J.L.Pombeiro “Copper compounds bearing 1,3,5-triaza-7-phosphaadamantane (PTA) and derivedligands: synthesis, structural features and applications” 24 th International Conference onOrganometallic Chemistry (ICOMC), July 18-23, 2010, Taipei, Taiwan. PS2-052.137 M.N. Kopylovich, K.T. Mahmudov, M.F.C. Guedes da Silva, L.M.D.R.S. Martins, M.L.Kuznetsov, T.F.S. Silva, J.J.R. Fraústo da Silva, A.J.L. Pombeiro “Electrochemical behaviour of

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 42 / 47para-substituted 3-(phenylhydrazo)pentane-2,4-diones” XII Iberic Meeting of Electrochemistry& XVI Meeting of the Portuguese Electrochemical Society, September 8–11, 2010, ISEL -Lisboa, p. 99.138 M.F.C. Guedes da Silva, K.V. Luzyanin, M.L. Kuznetsov, A.G. Tskhovrebov, V.Yu.Kukushkin, A.J.L. Pombeiro “Heterocarbene-palladium(II) complexes upon [2 + 3] metalmediatedcycloaddition of nitrones to isonitriles” 24 th International Conference onOrganometallic Chemistry, July 18th–23rd, 2010, Taipei, Taiwan. PS1-056.139 K.V. Luzyanin, A.G. Tskhovrebov, M. Haukka, M.F.C. Guedes da Silva, A.J.L. Pombeiro,V.Yu. Kukushkin “A route to novel palladocarbenes based on [2 + 3] cycloaddition of nitronesto palladium-bound isonitriles” Development of new pharmaceuticals and biologically activespecies based on naturally occurred compounds. ChemWasteChem – Chemistry and fulltransformation of wood biomass, June 14 th –18 th , 2010, St. Petersburg, Russia. p.349.140 K.V. Luzyanin, A.G. Tskhovrebov, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro,V.Yu. Kukushkin “First example of the metal-mediated [2+3] cycloaddition of nitrones topalladium-bound isonitriles” National Favorsky Conference on Organic Chemistry, March23rd–26th, 2010, St. Petersburg, Russia.141 L.M.D.R.S. Martins, T.F.S. Silva, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Coordinationchemistry of the C-scorpionate 2,2,2-tris(1-pyrazolyl)ethylmethanesulfonate towards the firstrow transition metals” 3 rd EuCheMS Chemistry Congress, Nürnberg-Germany, August 29 th -September 2 nd , 2010, poster VIIb.061, p.94.142 D.S. Nesterov, M.F.C. Guedes da Silva, J. Jezierska, A.J.L. Pombeiro “Polynuclear selfassembledCu 4 , Cu 6 and Cu 8 complexes with aminoalcohols” 3 rd EuCheMS Chemistry Congress,Nurnberg, Germany, 2010.143 T.F.S. Silva, K.V. Luzyanin, M.V. Kirillova, M.F.C. Guedes da Silva, L.M.D.R.S. Martins,A.J.L. Pombeiro “Dioxovanadium complexes with scorpionate or pyrazole ligands as catalystsfor the carboxylation of alkanes” V7 – 7 th International Vanadium Symposium, Toyama-Japan,October 6 th -9 th , 2010. p.27.144 T.F.S. Silva, T.C.O. Mac Leod, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro“Vanadium-pyrazole or -tris(pyrazolyl)ethanol complexes immobilized on apoly(dimethylsiloxane) membrane as supported catalysts for oxidation of cyclohexane” V7 – 7 thInternational Vanadium Symposium, Toyama-Japan, October 6 th -9 th , 2010. p.28.145 T.F.S. Silva, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro “Electrochemicalbehaviour of cobalt towards tris(1-pyrazolyl)methanesulfonate, 2,2,2-tris(1-pyrazolyl)ethanol ortris(3-phenylpyrazolyl)methane complexes” XII Iberian Meeting of Electrochemistry & XVIMeeting of the Portuguese Electrochemical Society, Lisbon-Portugal, September 9 th -11 th , 2010.PE 06.146 T.F.S. Silva, K.V. Luzyanin, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro“Electrochemical behaviour of the novel scorpionate and pyrazole dioxovanadium complexes”XII Iberian Meeting of Electrochemistry & XVI Meeting of the Portuguese ElectrochemicalSociety, Lisbon-Portugal, September 9 th -11 th , 2010. PE 08.147 T.F.S. Silva, K.V. Luzyanin, L.M.D.R.S. Martins, M.F.C. Guedes da Silva, A.J.L. Pombeiro“New functionalized C-scorpionate cobalt complexes” 3 rd EuCheMS Chemistry Congress,Nürnberg-Germany, August 29 th -September 2 nd , 2010, poster VIIb.081. P.94.148 A.J.L. Pombeiro, T.F.S. Silva, K.V. Luzyanin, L.M.D.R.S. Martins, M.F.C. Guedes da Silva,“Cyclohexane Functionalization to Cyclohexanol and Cyclohexanone Catalysed by Hydro-Soluble Scorpionate Complexes” ICOMC - 24 th International Conference on OrganometallicChemistry, Taipei - Taiwan, July 18 th -23 rd , 2010. PS1-163.149 P. Smoleński, A. Lis, M.F.C. Guedes da Silva, A.M. Kirillov, A.J.L. Pombeiro “Design ofsilver(I)-PTA and copper(I)-PTA coordination polymers through controlled N,P-coordination of1,3,5-triaza-7-phosphaadamantane (PTA) with various heterocycle ligands” XVII InternationalWinter School on Coordination Chemistry, December 6-10, 2010, Karpacz, Poland. P-31.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 43 / 47150 P. Smoleński, A.M. Kirillov, Z. Ma, M.F.C. Guedes da Silva, M. Haukka, A.J.L. Pombeiro“Synthesis, crystal structures and photoluminescence of new copper(I) iodide complexesderived from N-alkyl-1,3,5-triaza-7-phosphaadamantanes” Excited States of TransitionElements and Workshop on Luminescence, September 4-9, 2010, Wroclaw-Piechowice, Poland.151 K.V. Luzyanin, M.L. Kuznetsov, A.G. Tskhovrebov, M.F.C. Guedes da Silva, A.J.L. Pombeiro,V.Yu. Kukushkin “Heterocarbene-palladium(II) complexes upon [2 + 3] metal-mediatedcycloaddition of nitrones to isonitriles” 24 th International Conference on OrganometallicChemistry, July 18 th –23 rd , 2010, Taipei, Taiwan. PS1–056.2011152 B.G.M. Rocha, K.V. Luzyanin, R. Wanke, M.F.C.G. Silva, L.M.D.R.S. Martins, A.J.L.Pombeiro, “Bulky Tris(phenylpyrazolyl)methanesulfonate Copper Complexes with UnsaturatedMolecules”, 8 th International School of Organometallic Chemistry, Camerino, Italy, August 27-31 st , 2011, p49.153 E.C.B. Alegria, T. F. S. Silva, M. Fátima Guedes da Silva, L.M. D. R.S. Martins, A.J. L.Pombeiro, “V, Re, Fe, Co, Ni, Cu and Zn complexes bearing 2,2,2-tris(1-pyrazolyl)ethylmethanesulfonate scorpionates. Application as catalysts for the Baeyer-Villiger oxidation ofketones under mild conditions” 5 th EuCheMS Conference on Nitrogen Ligands in CoordinationChemistry, Metal-Organic Chemistry, Bioinorganic Chemistry, Materials and Catalysis,Granada – Spain, 4 – 8 Setembro 2011.154 L.M.D.R.S. Martins, T.F.S. Silva, M.F.C.G. Silva, A.R. Fernandes, A. Silva, P.M. Borralho, S.Santos, C.M.P. Rodrigues, A.J.L. Pombeiro, “Cobalt Complexes Bearing Scorpionate Ligands:Synthesis, Characterization and Applications as Catalysts for the Peroxidative Oxidation ofCyclohexane and as in vitro Tumor-Inhibitors”, 5th EuCheMS Conference on Nitrogen Ligandsin Coordination Chemistry, Metal-Organic Chemistry, Bioinorganic Chemistry, Materials andCatalysis, Granada, Spain, 2011, P88, p. 184.155 L.M.D.R.S. Martins, M. Fátima Guedes da Silva, T.F.S. Silva, C. Pettinari, F. Marchetti, A.Cerquetella, A..L. Pombeiro “ELECTROCHEMICAL BEHAVIOUR OF C-SCORPIONATERUTHENIUM(II) COMPOUNDS” XXXII Reunión del Grupo de Electroquímica de la RealSociedada Española de Química – XIII Encontro Ibérico de Electroquímica, Murcia - Spain, 7 –9 Setembro 2011.156 X. Shang, E.C.B.A. Alegria, M.Fátima C. Guedes da Silva, M.L. Kuznetsov, X. Meng, Q. Li,A.J.L. Pombeiro “Electrochemical behavior, theoretical study and antitumor activity oforganotin(IV) complexes bearing cyclopentanecarboxylato ligands” 62 nd Annual Meeting of theInternational Society of Electrochemistry, Niigata - Japan, 11 – 16 Setembro 2011 (oralpresentation by MFCGS)157 P. Smoleński, A. M. Kirillov, A. Lis, Ł. Jaremko, M. F. C. Guedes da Silva, A. J. L. Pombeiro.“Engineering coordination and supramolecular metal-organic networks by aqueous mediumselfassembly using 1,3,5-triaza-7-phosphaadamantane (PTA) with copper(I) and silver(I) salts”XXIII International Conference on Coordination and Bioinorganic Chemistry, June 5-10, 2011,Smolenice, Slovakia.2012158 E.C.B.A. Alegria, X.i Shang,M. Fatima C. Guedes da Silva, M.L. Kuznetsov, Q. Li, A.J.L.Pombeiro “ REDOX PROPERTIES OF ORGANOTIN(IV) CYCLOALKYLHYDROXAMATECOMPLEXES WITH DIFFERENT RING SIZES: ANTI-TUMOR ACTIVITY ANDREDUCTION POTENTIAL” XIV Iberian Meeting of Electrochemistry & XVII Meeting of thePortuguese Electrochemical Society, 11 - 14 of April, 2012, Funchal, Madeira Island,PORTUGAL.159 M. Fátima C. Guedes da Silva, M. Gajewska, X. Shang, K.V. Luzyanin, Q. Li, J. Cui, A.J.L.Pombeiro “Diorganotin(IV) Complexes Bearing Hydroxamate- or Carboxylate-typeLigands:Structural and Biological Characterization XXV International Conference onOrganometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (S2. 6;invited Satellite Communication presented by MFCGS).

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 44 / 47160 T. B. Anisimova, K.V. Luzyanin, M. Fátima C. Guedes da Silva, V. Yu. Kukushkin, A.J.L.Pombeiro “Addition of the Amino Acid Esters to PdII-Complexed Isonitriles Leading to theChiral Aminocarbene Complexes” XXV International Conference on Organometallic Chemistry(XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (F2.9; poster with flash presented byTBA).161 A.C. Silva, D.V. Luís, S. Santos, P.M. Borralho, C.M. Rodrigues, G. Cabral, P. Videira, A.S.Rodrigues, M.Gajewska, M. Fátima C. Guedes da Silva, C. Monteiro, A.J.L. Pombeiro,Alexandra R. Fernandes “BIOLOGICAL CHARACTERIZATION OFANTIPROLIFERATIVE POTENCIAL OF A CYCLIC TRINUCLEAR ORGANOTIN(IV)COMPLEX” XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7Septembre 2012 Lisbon, Portugal (F3.27; poster with flash presented by ACS).162 A.V.M. Nunes, E.C.B.A. Alegria, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.Pombeiro “New Trinuclear Mixed-Valence Cobalt(II)/(III) Complex Derived fromArylhydrazone of Dimedone” XXV International Conference on Organometallic Chemistry(XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.21; poster presented by AVMN).163 Z.Ma, W. Lu, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “A Novel Palladium CompoundAssembled by PdCl2 and a Functionalized Cryptand” XXV International Conference onOrganometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.50;poster presented by ZM).164 B.G.M. Rocha, E.A. Valishina, M. Fátima C. Guedes da Silva, V. Yu. Kukushkin, A.J.L.Pombeiro, K. V. Luzyanin, “New platinum-(acyclic aminocarbene) complexes derived from themetal-mediated addition of hydrazones to isocyanides”XXV International Conference onOrganometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.61;poster presented by BGMR).165 O.V. Nesterova, M. Fátima C. Guedes da Silva, D.S. Nesterov, M.V. Kirillova, A.J.L.Pombeiro, “Synthesis, Structure and Catalytic Activity of Novel Fe(III), Mn(III) and Cu(II)Schiff Base Complexes” XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.84; poster presented by OVN).166 A. Mizar, M.F.C. Guedes da Silva, M. N. Kopylovich, S. Mukherjee, K. T. Mahmudov, A.J.L.Pombeiro “Water-Soluble Copper(II) Complexes with a Sulfonic-Functionalized Arylhydrazoneof -Diketone and Their Application in Peroxidative Allylic Oxidation” XXV InternationalConference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon,Portugal (PA.100; poster presented by AM).167 T.C.O. Mac Leod, M.N. Kopylovich, M.F.C. Guedes Da Silva, K.T. Mahmudov, A.J.L.Pombeiro “Copper(II) Complexes of Arylhydrazones of -Diketones Immobilized on LayeredDouble Hydroxides as Catalysts for Oxidation of Alkanes” XXV International Conference onOrganometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.119;poster presented by TCOML).168 T.F.S. Silva, T.C.O. Mac Leod, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.Pombeiro “Oxo-Vanadium(IV) Complexes as Catalysts for Oxidation of Cyclohexane:Homogeneous or Supported Systems” XXV International Conference on OrganometallicChemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.136; poster presented byTFSS).169 P. Smolenski, A. Kirillov, S. Wieczorek, M.F.C. Guedes da Silva, Z. Ma, A.J.L. Pombeiro“Coordination Engeenering with 1,3,5-Triaza-7-phosphaadamantane (PTA) Towards UnusualMetal-Organic Networks” XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.164; poster presented by PS).170 S.W. Wieczorek, A. Kirillov, M. Fátima C. Guedes da Silva, P. Smolenski, A.J.L. Pombeiro“First Three-Dimensional Metal-Organic Frameworks Driven by 1,3,5-Triaza-7-phosphaadamantane” XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.172; poster presented by SWW).

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 45 / 47171 T.F.S. Silva, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, B. J. Hwang, M.L. Kuznetsov,A.J.L. Pombeiro “Cobalt Complexes Bearing C-Scorpionate or Pyrazole Ligands as Catalystsfor the Peroxidative Oxidation of Cyclohexane. EXAFS and Teorectical Studies” XXVInternational Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012Lisbon, Portugal (PA.267; poster presented by TFSS).172 B.G.M. Rocha, T. C. O. Mac Leod, L.M.D.R.S. Martins, M. Fátima C. Guedes da Silva, A.J.L.Pombeiro “Nitroaldol Reaction Studies of NiII, ZnII and CuII Complexes Bearing a StericallyHindered Scorpionate Ligand (TPMSph - “ XXV International Conference on OrganometallicChemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PA.315; poster presented byBGMR).173 Z. Ma, F. Mai, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “A Novel CompoundAssembled by a Double-Helicate Terpyridine Silver(I) Compound and a FunctionalizedTetrapyridyl Cyclam” XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PB.5; poster presented by ZM).174 M. Sutradhar, M. V. Kirillova, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro “A Novel MixedValence Hexanuclear Oxovanadium(IV,V) Complex Acts as Highly Efficient Catalyst inAlkane Oxidation” XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PB.122; poster presented by MS).175 K.T. Mahmudov, M. Gajewska, M. Fátima C. Guedes da Silva,M.N. Kopylovich, A.J.L. Pombeiro “ISOMORPHOUS HYBRID ORGANOTIN(IV)-NITRATECLUSTERS” XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PB.197; poster presented by KTM).176 K.T. Mahmudov, A.J.L. Pombeiro, M.J. Gajewska, M. Fátima C. Guedes da Silva,A.M. Maharramov, I.N. Aliyeva, M.N. Kopylovich, “COMPOSITE OLIGOMERCONSTRUCTED FROM TRI- AND TETRANUCLEAR BUTYLTIN(IV) OXOCLUSTERS”XXV International Conference on Organometallic Chemistry (XXV-ICOMC), 2-7 Septembre2012 Lisbon, Portugal (PB.258; poster presented by KTM).177 J.F. Silva, A.C. Silva, D.V. Luís, S. Santos, P.M. Borralho, C.M. Rodrigues, G. Cabral, P.Videira, A.S. Rodrigues, J. Lasri, A. Charmier, M. Fátima C. Guedes da Silva, A.J.L. Pombeiro,Alexandra R. Fernandes “Characterization of the Antiproliferative Potential and BiologicalTargets of a New Platinum Complex” XXV International Conference on OrganometallicChemistry (XXV-ICOMC), 2-7 Septembre 2012 Lisbon, Portugal (PB.293; poster presented byJFS).178 T.B. Anisimova, M.F.C. Guedes Da Silva, A.J.L. Pombeiro, V.Yu. Kukushkin, K.V. Luzyanin,“NOVEL CHIRAL AMINOCARBENE COMPLEXES DERIVED FROM THE COUPLINGOF AMINO ACID ESTERS WITH ISONITRILES”, International Conference Catalysis inOrganic Synthesis - ICCOS-2012, September 15-20, 2012, Moscow. P15. (poster presented byTBA).179 M. Fátima C. Guedes da Silva, K.T. Mahmudov, M.N. Kopylovich,A.J.L. Pombeiro “Discrimination of Metal-Organic Architectures Bearing an Arylhydrazone of-Diketone” Post-conference Symposium “Frontiers of Organometallic Chemistry” Septembre, Saint-Petersburg, Russia (poster presented by MFCGS).180 A. Silva, D. Luís, S. Santos, T. Silva, M.F.C. Guedes da Silva, L. Martins, A.J.L. Pombeiro, P.Borralho, C.M. Rodrigues, G. Cabral, P. Videira, C. Monteiro 7 , A.R. Fernandes “Biologicalcharacterization of the antiproliferative potential of Co(II) and Tin(IV) coordinationcompounds” SantoriniConference Biologie Prospective – Systems Biology and PersonalizedHealth Science and Translation, 30 Sept – 2 Oct 2012, Santorini, Greece.

Curriculum VitaeMaria de Fátima Costa Guedes da Silva 46 / 47V- OTHER WORKSV.1 M. Fátima C. Guedes da Silva, “Síntese e Electroquímica de Complexos Nitrílicos de Rénio(I)",Tese de Mestrado, IST, 1989.V.2 M. Fátima C. Guedes da Silva, "Química e Electroquímica Molecular de Complexos Derivadosda Activação de Nitrilos, Metilenoamidas e Diazoalcanos", Tese de Doutoramento, IST, 1993.V.3 M. Fátima C. Guedes da Silva, "Book Review: Inorganic Syntheses, Volume 29", InorganicaChimica Acta, 206 (1993) 237.V.4 M. Fátima C. Guedes da Silva, “Voltametría Cíclica – Aplicações ao Estudo de Mecanismos deReacções Induzidas por Transferência Electrónica” Química, 70 (1998) 21-26.2636 citations (158 publications found); average citations per publication = 16.685;h-index = 27 (ISI Web of Knowledge, February 18 th , 2013)Published Items in Each YearCitations in Each YearThe latest 20 years are displayed.Results found: 158Sum of the Times Cited : 2636Sum of Times Cited without self-citation : 1976Citing Article : 1373Citing Articles without self-citations : 1245Average Citations per Item : 16.685h-index : 27