Acta Mineralogica-Petrographica, Abstract Series 5, Szeged, 2006GOLD <strong>IN</strong> PRE-ALP<strong>IN</strong>E <strong>M<strong>IN</strong>ERAL</strong>IZATIONS FROM ROMANIABERBELEAC, I. 1 , JUDE, R. 1 , UDUBAŞA, S. S. 1 & NUŢU, M. L. 21 Faculty of Geology and Geophysics, University of Bucharest, Bucharest, Romania2 Institute of Geodynamics of the Romanian Academy, Bucharest, RomaniaE-mail: lmnutzu@geodin.roThe territory of Romania is situated in Central-EastEurope; it is dominated by the orogenic areas of the East(ECM) and South Carpathian Mountains (SCM) and theApuseni Mountains (AM) (Fig. 1). It is a segment of the Alpine–HimalayanOrogen and the Tisza–Dacia block. Gold,with some exceptions, has been found in different fabrics andtypes of deposition in gold and gold-bearing mineralizationsrelated to Precambrian to Palaeozoic schists from these orogenicarea. Gold, gold-copper, gold-polymetallic, goldarsenicand other occurrences and deposits were formed duringthe Baikalian and Hercynian metallogenetic events inareas that are included now in the Carpathian chain. It hasbeen found in different proportions in two dominant types ofore deposits: 1) in shear-zone related gold and gold-bearingoccurrences and deposits in the AM and SCM (Fig. 2) and 2)in volcanic-hosted massive sulphide (VHMS) deposits fromEC (Fig. 3) and Dobrogea.Fig. 1: Distribution of major tectonicunits and Tertiary volcanicareas on the territory of Romania. 1:orogenic areas, 2: Carpathian flysch,3: volcanic areas, 4: post-Precambrian–Palaeozoiccover. EC:East Carpathian Chain: Os: Oaş, Gu:Gutâi, T: Tibleş, Cl: Călimani, Gu:Gurghiu and Hr: Harghita Mts.,AM: Apuseni Mts, SAM: SouthApuseni Mts: ZM: Zarand Mts,MM: Metaliferi Mts., SC: SouthCarpathian Chain, PB: PannonianBasin, TB: Transylvanian Basin,MP: Moesian Platform, EP: EuropeanPlatform, DNO: North DobrogeaOrogen.The first type of mineralization is controlled by interlayerductile shear zones with reformation and probably superimposedmineralization from dip fluid sources. It is recognisedby: 1) deep fracture; 2) brittle and brittle-ductile shear zonesbeside the deep fracture controlled the spatial locations ofore; 3) the intersections of secondary ductile shear zones withother tectonic elements are very favourable for the enrichmentof gold; 4) the ore-controlling ductile shear zones showmultistage features and a long period of evolution, the goldbearingmylonites seem to be formed in the early stage andthe gold-bearing quartz veins in the late stage. The most frequentmineral assemblages in which gold appears as commonmineral are: quartz-Au; Au-Pb-Zn(Cu); quartz-pyrite-Au (Bi)and quartz-arsenopyrite. Further, we introduce some of themost representative occurrences in which gold is present.1. Gold in auriferous quartz mineralizationsMineralizations of this type are frequently located withinPrecambrian and Palaeozoic crystalline schists of medium orlow grade of metamorphism, usually affected by migmaticand retrograde processes. Their close relation to shear zonesis characteristic. They usually form lenticular veins and nestswithin the dilatation segments of the faults. The most representativeoccurrences are hosted in Precambrian schists of theSebeş-Lotru Group (Căpăţânei, Lotru, Cibin and SemenicMts.) in the South Carpathians (SC); Precambrian schists ofthe Someş Series (Gilău Massive) and Palaeozoic schists ofthe Padeş Series (Rapolt Crystalline Island) in the ApuseniMts. (AM) The paragenesis is simple: native gold and goldassociated with pyrite, arsenopyrite and chalcopyrite inquartz gangue with minor amounts of sphalerite and galenaand occasionally Sb, Mo, Bi, Co and Ni minerals. Quartz,carbonates, sericite and chlorite represent the main gangueminerals. Hydrothermal-metamorphic genesis is consideredfor these mineralizations. As regards the source, gold is assumedto be originated both from Precambrian metabasiteand/or the deep lithospheric crustal solutions as trace elementmobilized in pre-Alpine (UDUBAŞA & HANN, 1988)and/or Alpine tectonogenesis (BERBELEAC, 1985, 1995,1997).In SC the main gold mineralizations are given in Fig. 2.14www.sci.u-szeged.hu/asvanytan/acta.htm
Acta Mineralogica-Petrographica, Abstract Series 5, Szeged, 2006Fig.2: Tectonic sketch map of Southwestern Romania, with the distribution of pre-Alpine gold mineralizations related to shearzones (according to BERBELEAC, 1995, with amendments). 1: Scythian–Moesian Platform, 2: Inner Dacides, 3: Transylvanides,4: Median Dacides, 5: Outer Dacides, 6: Marginal Dacides, 7: Moldavides, 8: post-tectonic cover, 9: Neogene molasses,depressions and foredeep, 10: Laramides, 11: Neogene magmatites, 12: nappe, 13: fault. Auriferous occurrences: 14: Qz,Fe (S) ± Au, Ag, 15: Qz, Fe (S) As, Au (Bi, Pb, Ag), 16: Qz, Fe (S + Ox), Zn, (Pb, Cu, As, Au), 17: Qz, Fe (S), Cu, Au (Zn,As), 18: Qz, Fe(S), Pb, Zn, Cu, Au, As, 19: Qz, Fe (S), Pb, Zn (Cu, Au), 20: Qz, Fe (S), Pb, Zn (Au), 21: Qz, Fe (S), Pb, Zn,Cu, Au, As, 22: Qz ± Fe (S), Au, 23: Qz, Fe (S), Au, Bi, 24: Qz, Fe (S), Au, Bi, Po, (Mo), 25: Qz, Fe (S), Zn, Pb, Au (Po):Occurrences: 1: Valea Băilor, 2: Ierţii Valley-Valea Seacă, 3: Lazuri-Brusturi, 4: Ascutitu, 5: South Highiş, 6: Şoimuş Valley,7: Buceava Valley, 8: Bogatu Bătrana (Văliug), 9: Liscovul inferior (Văliug), 10: Slătinic Brook (Bozovici), 11: Sicheviţa, 12–13: Mraconia, 14: Jidoştiţa, 15: Iepii Valley (Motru Sec River), 16: Netedu Brook (Costeşti), 17: Comârnici, 18 Valea lui Stan,19: Băeşului Brook (Perişani), 20: Ţâbra-Tâncava, 21: Ghimbav Valley, 22: Brusturi Brook, 23: Arpaş Valley, 24: Dobra Valley,25: Pianu de Sus, 26: North Sebiş, 27: Cugir Valley, 28: Muncelul Mic, 29: Bobâlna, 30: Vărmaga, 31: Cioclovina, 32:Râul Mare Gallery.1.1. Valea lui StanThe gold mineralization is related to a regional N–S shearzone in Precambrian crystalline schists of the Sebeş-LotruGroup (Fig. 2). It is situated at 2 km southeast of Brezoitown, and is characterized by Au-As-Cu association. Therocks metamorphosed in amphibolite facies, underwent agreenschist retrograde metamorphism. The quartz-auriferouslenses are related to a broad (300 m) NNW–SSE and NNE–SSW fault zone. The mineral paragenesis consists of pyrite,arsenopyrite, chalcopyrite, subordinately sphalerite and galenaas main minerals and of minor amounts of pyrrhotite andmarcasite. Quartz and some carbonates are the gangue minerals.Gold as micron-size grains is frequently included in arsenopyriteand chalcopyrite, or associated with quartz(UDUBAŞA & HANN, 1988; UDUBAŞA, 2001). At thebeginning of the last century the auriferous quartz vein of thisdeposit has been exploited at four levels, within 100 mdepths. The ore grade is 11.7 g/t Au and 10.3 g/t Ag for theore richer in chalcopyrite, and 2.6 g/t Au and 5.3 g/t Ag forthe sort of ore richer in arsenopyrite. The fineness of the goldis 708–715 ‰.1.2. BozoviciIn the southeastern side of the Semenic Mts. (South Carpathians),the metamorphic rocks of the Sebeş-Lotru Grouphost the auriferous-quartz mineralization (ÎNTORSUREANUet al., 1985; BERBELEAC, 1985). It occurs along theSlătinic stream, a tributary of the Minis Valley, on the borderzone of the Bozovici Miocene sedimentary basin (Fig.2).Lenses, lenticular veins and nests of auriferous quartz arehosted in a sequence of amphibolite and amphibole schists. Alenticular vein of 200 m length and 0.2–2 m thickness wasexploited until the 1950s. Fragments of auriferous quartz maybe found in the lower conglomerate horizon of the Miocenesedimentary formation.The mineralization consists of native gold and pyrite inmassive and fissured quartz; nests of carbonates and films ofchlorite may be found occasionally. There are three varietieswww.sci.u-szeged.hu/asvanytan/acta.htm 15
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