Acta Mineralogica-Petrographica, Abstract Series 5, Szeged, 2006<strong>M<strong>IN</strong>ERAL</strong>OGICAL STUDY OF HYDRO<strong>THE</strong>RMAL VE<strong>IN</strong> Pb-Zn DEPOSIT POD BABOU(MALÉ KARPATY MTS., SLOVAKIA)LUPTÁKOVÁ, J. 1 , CHOVAN, M. 2 & ANDRÁŠ, P. 11 Geological Institute, Slovak Academy of Sciences, Severná 5, SK-974 01 Banská Bystrica, SlovakiaE-mail: luptak@savbb.sk2 Department of Mineralogy and Petrology, Faculty of Natural Sciences, Comenius University, Mlynská dolina G, SK-842 15Bratislava, SlovakiaThe deposit Pod Babou is situated 2.5 km SE of Pernek inthe Malé Karpaty Mts. Hydrothermal ore veins are hosted bymetamorphic rocks – gneisses, less phyllites of Palaeozoicage, that belong to Limbach formation (PUTIŠ et al., 2004)and make up the envelope of the Bratislava granitoid massif.Deposit comprises two main veins – the upper and thelower one, which were exploited at the end of 19 th century(CAMBEL, 1959). Nowadays adits are inaccessible and onlydump material is available. This small-scale deposit is interestingonly from mineralogical and metallogenetical point ofview and has no economic importance.Mineralization originated during four mineralizing events.The first, quartz-arsenopyrite (Q-Asp) stage consists ofblack quartz, arsenopyrite and pyrite. Arsenopyrite has increasedSb (up to 1.6 wt%) and rarely also Bi (up to 0.5 wt%)contents. Arsenopyrite grains show zonality under the BSEcaused by variable contents of As a S. Contents of As inpyrite vary between 0.1 and 0.9 wt%. Minerals of the firststage are cataclased and enclosed in minerals of younger Pb-Zn stage. The most abundant ore mineral of this stage issphalerite. It is also the oldest mineral of this stage, togetherwith quartz and pyrite. Sphalerite is brown coloured, with Feand Cd contents of 3.4 wt% and 0.2 wt%, respectively. Laterminerals of Pb-Zn stage fill the space between grains ofsphalerite and quartz. This association is comprised of galena,boulangerite, bournonite, tetrahedrite, stephanite, chalcopyrite,marcasite and also pyrite, sphalerite and quartz. Themost abundant features observed under reflected polarizedlight are intergrowths of galena with tetrahedrite, bournonite,and sphalerite or with boulangerite and bournonite. Otherminerals are quite scarce. Tetrahedrite is rich in Ag. Its compositiongradually proceeds from argentian tetrahedrite (9.6wt% Ag) to freibergite (30.7 wt% Ag). It is also enriched inFe (up to 5.7 wt%). Another Ag mineral is stephanite, whichis present only in small amount. However, Ag contents ingalena associating with Ag-bearing minerals do not exceed0.04 wt%. Contents of microelements in boulangerite andbournonite are only about 0.0X wt% except for Bi content,which reaches 0.3 wt%.Q-Asp and Pb-Zn stages are common for both main veins.The latest stage is different. In the case of lower vein it is thecarbonate stage, and in the case of upper vein it is the baritestage. There is no evidence about the relative age of thesetwo stages. No relationship was observed during the fieldwork.Carbonate stage is comprised of little amount of quartz,older fine-grained dolomite occurring in the vein boundariesand younger coarse-grained calcite filling vein centre.Barite stage consists of white fine-grained barite that enclosesfragments of older mineral associations. Content ofSrO in barite varies from 0.1 to 1.6 wt%. Content of otherelements is negligible.This study provides new compositional data on Pod BabouPb-Zn deposit. Moreover, previously unreported mineralspecies – boulangerite, tetrahedrite–freibergite, stephaniteand dolomite – are described.AcknowledgmentsThis work was supported by Slovak Scientific AgencyVEGA grant Nr: 1/1027/04.ReferencesCAMBEL, B. (1959): Acta Geologica et Geographica UniversitatisComenianae, 3: 338.PUTIŠ, M., HRDLIČKA, M. & UHER, P. (2004): MineraliaSlovaca, 36: 183–194.68www.sci.u-szeged.hu/asvanytan/acta.htm
Acta Mineralogica-Petrographica, Abstract Series 5, Szeged, 2006CROSS-CHECK<strong>IN</strong>G OF AERIAL IMAGES AND RESULTS OF LOCAL SAMPL<strong>IN</strong>G OFGYÖNGYÖSOROSZI FLOTATION TAIL<strong>IN</strong>G IMPOUNDMENT, NORTH-EASTERNHUNGARYMÁDAI, V.Department of Mineralogy and Petrology, University of Miskolc, H-3515 Miskolc-Egyetemváros, HungaryE-mail: askcesar@gold.uni-miskolc.huPyrite-containing ore mining wastes may seriously damagetheir surrounding environment. The phenomenon is theso-called Acid Rock Drainage (ARD) or Acid Mine Drainage(AMD). Oxidation of iron sulphides produces low pHsolutionsand Fe(III) ions. The process is extremely complex,and heavily influenced by vital functions of sulphide oxidizingbacteria. Products of the oxidation among others are gypsum,jarosite, goethite, hematite, and lepidocrocite. Usinghyperspectral or multispectral remote sensing methods,anomalies of these secondary mineral phases can be plotted(VIJDEA et al., 2004).In this study hyperspectral aerial photography of the flotationtailing impoundment (KARDEVÁN et al., 2003) andresults of local sampling were cross-checked. In the aerialpicture, goethite and jarosite anomalies could be seen. In mylocal sampling programme nearly 100 samples were gatheredfrom the surface of the tailing impoundment covering thewhole area. Samples were analyzed by an HZG-3 powderdiffractometer and a MOM Derivatograph C equipment.The thickness of the vegetation, the roughness of the surfaceand the presence of mineral component enrichments mayinfluence the quality of the reflected beam, which determinesthe detectable mineral phases in the aerial picture.Samples, collected from any part of the tailing impoundment,were rich in jarosite. Nevertheless, on the aerial photography,jarosite anomaly on the surface of the older andheavily oxidized parts of the tailing impoundment covered byricher vegetation cannot be seen. The samples, collected fromthese areas, were rich in jarosite as well, but other mineralcomponent enrichment could not be detected which shouldcover the reflected beam component of the jarosite in the nearinfra red and visible range of the spectrum. Surface roughnesswas the same all over the impoundment. The differencesbetween the results of the two methods might be explained bythe high sensitivity of the hyperspectral method to the thicknessof the vegetation.It might be concluded, that the results obtained by the twomethods are comparable only on the non-vegetated areas.Data of remote sensing give valuable information about themineral phases, but detailed and accurate sampling on thespot is indispensable.ReferencesKARDEVÁN, P., VEKERDY, Z., RÓTH, L. SOMMER, S.,KEMPER, TH., JORDÁN, GY., TAMÁS J.,PECHMANN, I., KOVÁCS, E., HARGITAI, H.,LÁSZLÓ, F. (2003): In: HABERMEYER, M., MÜLLE,A., & HOLZWARTH, S. (eds.): Proceedings of the 3 rdEARSeL workshop on imaging spectroscopy, Herrsching,Germany, 13–16 May 2003, 324–332.VIJDEA, A., SOMMER, S. & MEHL, W. (2004):PECOM<strong>IN</strong>ES, Inventory, Regulations and EnvironmentalImpact of Toxic Mining Wastes in Pre-Accession Countries,A Report of the JRC Enlargement Project. 4–32.www.sci.u-szeged.hu/asvanytan/acta.htm 69
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