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Towards a Platform for Widespread Embedded Intelligence - ERCIM

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50<br />

Articles in this Section<br />

50 Nanotechnology<br />

Single Molecule Switch and<br />

Memory Element<br />

by Emanuel Lörtscher and Heike<br />

Riel, IBM Zurich Research Lab,<br />

Switzerland<br />

52 Mobile Hybrid Wireless Networks<br />

HyMN: A Self-Organizing System<br />

<strong>for</strong> Interest-based Data<br />

Distribution in Mobile Hybrid<br />

Wireless Networks<br />

by Steffen Rothkugel, Matthias R.<br />

Brust and Adrian Andronache,<br />

University of Luxembourg<br />

53 Visualization<br />

Visualization of Colour<br />

In<strong>for</strong>mation on Highly Detailed 3D<br />

Models<br />

by Matteo Dellepiane and Marco<br />

Callieri, ISTI-CNR, Italy<br />

55 Databases<br />

Modular Access to Large Socio-<br />

Economic Databases - the Sedo<br />

Project in Luxembourg<br />

by Uwe Warner, Centre d'Etude de<br />

Population, de Pauvreté et de<br />

Politiques Socio-Economiques, and<br />

Thomas Tamisier and Fernand Feltz<br />

Centre de Recherche Public -<br />

Gabriel Lippmann, Luxembourg<br />

56 Digital Libraries<br />

BELIEF: Bringing Europe's<br />

Electronic Infrastructures to<br />

Expanding Frontiers<br />

by Federico Biagini, Pasquale<br />

Pagano and Franco Zoppi, ISTI-<br />

CNR, Italy<br />

58 Electromagnetic Radiation<br />

Cell Phone Danger<br />

by Martin Röösli, Unversity of Bern,<br />

and Harry Rudin, Consultant,<br />

Switzerland<br />

60 Satellite Communication Services<br />

SAFE: Satellites <strong>for</strong> Epidemiology<br />

and Health Early Warning<br />

by Catherine Chronaki, ICS-FORTH<br />

and Laurent Braak,<br />

61 Satellite Devices<br />

Planck Mission 70 GHz Receivers<br />

by Jussi Varis, MilliLab-Millimetre<br />

Wave Laboratory of Finland<br />

62 Detector Technology<br />

Data Acquisition in Scientific<br />

Applications<br />

by Rob Halsall, CCLC, UK<br />

63 Security<br />

Network Anomaly Detection by<br />

Means of Machine Learning<br />

by Roland Kwitt, Salzburg Research<br />

GmbH, Austria<br />

64 Web 2.0 and Novel Interaction<br />

From Solitary Podcasting<br />

to Ambient Pondcasting<br />

by Emmanuel Frécon and Pär<br />

Hansson, SICS<br />

<strong>ERCIM</strong> News No. 67, October 2006<br />

R&D AND TECHNOLOGY TRANSFER<br />

Nanotechnology<br />

Single-Molecule Switch and Memory Element<br />

by Emanuel Lörtscher and Heike Riel<br />

Scientists at the IBM Zurich Research Laboratory have demonstrated how a single<br />

molecule can be switched between two distinct conductive states, which allows<br />

it to store data. As published in SMALL, these experiments show that certain<br />

types of molecules reveal intrinsic molecular functionalities that are comparable<br />

to devices used in today's semiconductor technology. This finding is a result<br />

coming from IBM's Research Labs' ef<strong>for</strong>t to explore and develop novel<br />

technologies <strong>for</strong> beyond the CMOS (Complementary Metal Oxide Semi-conductor)<br />

era.<br />

In the August 4 issue of SMALL 1 , we<br />

report on a single-molecule switch and<br />

memory element. Using a sophisticated<br />

mechanical method, we were able to<br />

establish electrical contact with an individual<br />

molecule to demonstrate<br />

reversible and controllable switching<br />

between two distinct conductive states.<br />

This investigation is part of our work to<br />

explore and characterize molecules to<br />

become possible building blocks <strong>for</strong><br />

future memory and logic applications.<br />

With dimensions of a single molecule on<br />

the order of one nanometer (one millionth<br />

of a millimeter), molecular electronics<br />

redefines the ultimate limit of<br />

miniaturization far beyond that of<br />

today's silicon-based technology.<br />

The results show that these molecules<br />

exhibit properties that can be utilized to<br />

per<strong>for</strong>m the same logic operations as<br />

used in today's in<strong>for</strong>mation technology.<br />

Namely, by applying voltage pulses to<br />

the molecule, it can be controllably<br />

switched between two distinct 'on' and<br />

'off' states. These correspond to the '0'<br />

and '1' states on which data storage is<br />

based. Moreover, both conductive states<br />

are stable and enable non-destructive<br />

read-out of the bit state - a prerequisite<br />

<strong>for</strong> nonvolatile memory operation -<br />

which we demonstrated by per<strong>for</strong>ming<br />

repeated write-read-erase-read cycles.<br />

With this single-molecule memory element,<br />

we have documented more than<br />

500 switching cycles and switching<br />

times in the microsecond range.<br />

Crucial <strong>for</strong> investigating the inherent<br />

properties of molecules is the ability to<br />

deal with them individually. To do this,<br />

we extended a method called the<br />

mechanically controllable break-junc-<br />

tion (MCBJ). With this technique, a<br />

metallic bridge on an insulating substrate<br />

is carefully stretched by mechanical<br />

bending. Ultimately the bridge breaks,<br />

creating two separate electrodes that<br />

possess atomic-sized tips. The gap<br />

between the electrodes can be controlled<br />

with picometer (one thousandth of a<br />

nanometer) accuracy due to the very<br />

high transmission ratio of the bending<br />

mechanism. In a next step, a solution of<br />

the organic molecules is deposited on top<br />

of the electrodes. As the junction closes,<br />

a molecule capable of chemically<br />

bonding to both metallic electrodes can<br />

bridge the gap. In this way, an individual<br />

molecule is 'caught' between the electrodes,<br />

and measurements can be per<strong>for</strong>med.<br />

The molecules investigated are specially<br />

designed organic molecules measuring<br />

only about 1.5 nanometers in length,<br />

approximately one hundredth of a stateof-the-art<br />

CMOS element. The molecule<br />

was designed and synthesized by<br />

Professor James M. Tour and co-workers<br />

at Rice University, Houston, USA.<br />

The main advantage of exploiting transport<br />

capabilities at the molecular scale is<br />

that the fundamental building blocks are<br />

much smaller than today's CMOS elements.<br />

Furthermore, chemical synthesis<br />

produces completely identical<br />

molecules, which, in principle, are<br />

building blocks with no variability. This<br />

allows us to avoid a known problem that<br />

CMOS devices face as they are scaled to<br />

ever smaller dimensions. In addition, we<br />

hope to discover possibly novel, yet<br />

unknown properties that silicon and<br />

related materials do not have.<br />

1 (E. Lörtscher, J. W. Ciszek, J. Tour, and H. Riel, "Reversible and Controllable Switching of a Single-Molecule Junction",<br />

Small, Volume 2, Issue 8-9 , pp. 973-977, 4 August 2006)

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