02.09.2017 Views

TÌM HIỂU VỀ CHUẨN ĐỘ ĐA AXIT - ĐA BAZƠ

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Do đó pH sẽ tính theo ion H 2 PO<br />

2 -<br />

4 theo cân bằng:<br />

W<br />

2- - -<br />

HPO<br />

4<br />

+H<br />

2O ⇌ OH +H<br />

2PO 4<br />

K<br />

a2<br />

HPO ⇌ H +PO K<br />

Áp dụng điều kiện bảo toàn proton với mức không là HPO 4<br />

2-<br />

,<br />

H 2 O ta có:<br />

2- + 3-<br />

4 4 a3<br />

[ H ] = [ OH ] + [ PO ] − [ H PO ]<br />

+ − 3 − −<br />

4 2 4<br />

2−<br />

W Ka3.[ HPO4<br />

] −1 2−<br />

⇔ h = + − Ka2. h.[ HPO4<br />

]<br />

h h<br />

⇒ W + K .[H P O ]<br />

h = 1 + K .[H ]<br />

=<br />

2 −<br />

a 3 4<br />

− 1 2 −<br />

a 2<br />

P O<br />

4<br />

3, 9 .1 0<br />

− 1 0<br />

⇒ pH = 9,41

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