Controlled Radical Polymerization Guide - Sigma-Aldrich

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Acrylate Monomers 38 Monomer Index Acrylate Monomers For a complete list of available acrylate monomers, visit Aldrich.com/acrylic. Monofunctional Acrylate Monomers Name Structure Purity Additive Prod. No. 2-Chloroethyl acrylate Sodium acrylate Methyl acrylate Ethyl acrylate Butyl acrylate Hexyl acrylate Lauryl acrylate Octadecyl acrylate tert-Butyl acrylate Isobutyl acrylate H 2C H 2C H 2C H2C H 2C H 2C H 2C H 2C H2C 2-Ethylhexyl acrylate O H2C O Isooctyl acrylate 3,5,5-Trimethylhexyl acrylate 1H,1H,2H,2H-Perfluorodecyl acrylate 2-Hydroxyethyl acrylate Hydroxypropyl acrylate, mixture of isomers 4-Hydroxybutyl acrylate H2C H2C H 2C O 97% MEHQ, >100 ppm as inhibitor 729817-5G O Cl O 97% - 408220-25G ONa 408220-100G O OCH 3 99% monomethyl ether hydroquinone, ≤100 ppm as inhibitor M27301-5ML M27301-250ML M27301-1L M27301-2L M27301-18L O 99% MEHQ 10-20 ppm as inhibitor E9706-100ML O CH3 E9706-1L E9706-2L O ≥99% monomethyl ether hydroquinone, 234923-100ML O CH3 10-60 ppm as inhibitor 234923-1L 234923-18L O 98% hydroquinone 100 ppm as inhibitor 408905-25ML OCH2(CH2)4CH3 408905-100ML O 90%, technical grade monomethyl ether hydroquinone OCH2(CH2)10CH3 60-100 ppm as inhibitor O OCH2(CH2)16CH3 O CH3 CH3 O CH3 O H2C O CH3 CH3 O O CH 3 CH3 CH3 CH3 447315-100ML 447315-500ML 97% MEHQ 200 as inhibitor 409693-250G 409693-1KG 98% monomethyl ether hydroquinone 10-20 ppm as inhibitor ≥99% monomethyl ether hydroquinone 10-20 ppm as inhibitor 98% monomethyl ether hydroquinone ≥0.001-≤0.11% as stabilizer >90% monomethyl ether hydroquinone 75-125 ppm as inhibitor O O CH3 CH3 CH3 CH3 technical grade monomethyl ether hydroquinone 15-20 ppm as inhibitor O 97% monomethyl ether hydroquinone OCH2CH2(CF2)7CF3 100 ppm as inhibitor O H2C O OH H 2C H2C O CH3 O OH O CH3 OH O O H2C O OH 2-Carboxyethyl acrylate O O H2C O OH 2-(Dimethylamino)ethyl acrylate Isobornyl acrylate Aldrich.com H2C 96% monomethyl ether hydroquinone 200-650 ppm as inhibitor 95% hydroquinone monomethyl ether 200-650 ppm as inhibitor 90% hydroquinone 300 ppm as inhibitor monomethyl ether hydroquinone 50 ppm as inhibitor - MEHQ, 900-1100 ppm as inhibitor 327182-5ML 327182-100ML 327182-1L 436305-250ML 436305-1L 290815-25ML 290815-1L 290815-3L 290815-18L 437425-100ML 424021-25ML 474487-5ML 474487-25ML 292818-250ML 292818-1L 292818-18L 370932-1L 370932-18L 275573-25G 552348-50ML 552348-500ML O CH3 98% MEHQ, 2,000 ppm as inhibitor 330957-100ML O N CH3 330957-500ML H3C CH3 CH3 O O CH2 technical grade monomethyl ether hydroquinone 200 ppm as inhibitor TO ORDER: Contact your local Sigma-Aldrich office (see back cover) or visit Aldrich.com/matsci. 392103-100ML 392103-500ML 392103-1L
Name Structure Purity Additive Prod. No. Pentabromophenyl Br 96% - 592552-5G acrylate Br O CH2 Br O Br Pentabromobenzyl Br Br O 98% - 640263-1G acrylate Br O CH2 640263-5G Br Br Br 3-(Trimethoxysilyl)propyl O OCH3 92% BHT 100 ppm as inhibitor 475149-5ML acrylate H2C O Si OCH3 OCH3 475149-25ML Di(ethylene glycol) ethyl ether acrylate Di(ethylene glycol) 2-ethylhexyl ether acrylate H 2C H 2C Poly(ethylene glycol) methyl ether acrylate H 2C Poly(propylene glycol) acrylate O O O H 2C O O O O O O O O CH 3 O CH3 CH3 O CH3 n O H n CH3 PEG Acrylate and Diacrylate Monomers ≥90%, technical grade monomethyl ether hydroquinone 1,000 ppm as inhibitor 95% monomethyl ether hydroquinone 500 ppm as inhibitor - BHT 100 ppm as inhibitor MEHQ 100 ppm as inhibitor - monomethyl ether hydroquinone 200-400 ppm as inhibitor 408298-250ML 407542-100ML 454990-250ML 454990-1L 469815-100ML 469815-500ML Name Structure Average Mn Additive (ppm) Prod. No. Poly(ethylene glycol) methyl O 2,000 MEHQ ≤3,500 as inhibitor 730270-1G ether acrylate H2C O O CH3 n (may contain) Poly(ethylene glycol) methyl ether acrylate H2C Ethylene glycol diacrylate Di(ethylene glycol) diacrylate H 2C H2C O O O O O O O O O CH3 n Tetra(ethylene glycol) O O diacrylate H2C O O O O O Poly(ethylene glycol) diacrylate Poly(ethylene glycol) diacrylate Poly(ethylene glycol) diacrylate Poly(ethylene glycol) diacrylate Poly(ethylene glycol) diacrylate Poly(ethylene glycol) diacrylate Poly(ethylene glycol) diacrylate H2C H 2C H 2C H 2C H2C H2C H2C O O O O O O O O O O O O O O O n O n O n O n O n O n O n O O O O O O O O O O CH 2 CH2 CH 2 CH 2 CH 2 CH2 CH 2 CH2 CH 2 CH 2 5,000 MEHQ ≤5,500 as inhibitor (may contain) 730289-1G 170.16 - 480797-5ML 480797-25ML 214.22 HQ 60-100 as inhibitor MEHQ 90-150 as inhibitor 302.32 HQ 100-150 as inhibitor MEHQ 150-200 as inhibitor 437433-100ML 398802-250ML 398802-1L 258 MEHQ 100 as inhibitor 475629-100ML 475629-500ML 575 MEHQ 400-600 as inhibitor 437441-100ML 437441-500ML 700 BHT 300 as inhibitor MEHQ 100 as inhibitor 1,000 MEHQ ≤1,500 as inhibitor (may contain) 2,000 MEHQ ≤1500 as inhibitor (may contain) 455008-100ML 455008-500ML 729086-1G 701971-1G 6,000 MEHQ, ≤1500 as inhibitor 701963-1G 10,000 MEHQ ≤1,500 as inhibitor (may contain) For questions, product data, or new product suggestions, contact Aldrich Materials Science at matsci@sial.com. Monomer Index 729094-1G Acrylate Monomers 39
Page 1 and 2: Controlled Radical Polymerization G
Page 3 and 4: Atom Transfer Radical Polymerizatio
Page 5 and 6: The ARGET and ICAR ATRP processes a
Page 7 and 8: Initiators for ATRP ATRP uses simpl
Page 9 and 10: ATRP: Choosing a Ligand for the Cat
Page 11 and 12: Copper(I)-mediated Living Radical P
Page 13 and 14: Typical Procedures for Polymerizing
Page 15 and 16: A wide range of monomers have been
Page 17 and 18: ARGET ATRP: Procedure for PMMA Poly
Page 19 and 20: Name Structure Description Prod. No
Page 21 and 22: A Micro Review of Reversible/Additi
Page 23 and 24: RAFT Polymerization of ′Less-Acti
Page 25 and 26: RAFT Agent to Monomer Compatibility
Page 27 and 28: In order to prepare well-defined bl
Page 29 and 30: RAFT Agents For a complete list of
Page 31 and 32: Name Structure Description Prod. No
Page 33 and 34: Block Copolymer Synthesis Using a C
Page 35 and 36: Synthesis of poly(t-butyl acrylate)
Page 37 and 38: Styrene Monomers For a complete lis
Page 39: Name Structure Purity Additive Prod
Page 43 and 44: Acrylamide Monomers For a complete
Page 45 and 46: Name Structure Purity Additive Prod
Page 47 and 48: Polyfunctional Methacrylate Monomer
Page 49 and 50: Polymer Center of Excellence Custom
Page 51 and 52: R1 Aldrich Prod. No. Structure Styr

Controlled Radical Polymerization Guide - Sigma-Aldrich

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