Controlled Radical Polymerization Guide - Sigma-Aldrich

Methacrylate Monomers
42
Monomer Index
Methacrylate Monomers
For a complete list of available methacrylate monomers, visit Aldrich.com/acrylic.
Monofunctional Methacrylate Monomers
Name Structure Purity Additive Prod. No.
Glycidyl methacrylate
Pentafluorophenyl methacrylate
Solketal methacrylate
Bis(2-methacryloyl)oxyethyl disulfide
1,1,1-Trifluoro-2-(trifluoromethyl)-2hydroxy-4-methyl-5-pentyl
methacrylate
CH3
O
H2C
O
O ≥97.0%, GC hydrochinone monomethylether
H2C O
~0.01% (w/v) as stabilizer
CH3 O
O
H2C O
CH3 F
F
F
F
F
779342-100ML
779342-500ML
95% MEHQ 1,500 ppm as inhibitor 741108-5G
741108-1G
O - 4-tert-Butylcatechol ~280 ppm
H2C O O
as inhibitor
CH3
O
CH3
CH3 S S
CH3 H3C HO
O
H2C
O
O
CF3
O
CF3
CH3
CH2
- hydroquinone, ≤6,000 ppm
as stabilizer
740950-5ML
740950-25ML
735094-5G
>97% - 733695-1G
733695-5G
2-[(1′,1′,1′-Trifluoro-2′-(trifluoromethyl)-
HO CF3
>97% - 733660-1G
2′-hydroxy)propyl]-3-norbornyl
methacrylate O
CF3
733660-5G
O
CH2
CH3
2-(Diisopropylamino)ethyl
methacrylate H2C
Methacrylic acid N-hydroxysuccinimide
ester
TEMPO methacrylate
O
O
CH3
H3C
CH3
N CH3
CH3
O
O
H2C N
O
CH3 O
97% monomethyl ether hydroquinone
~100 ppm as inhibitor
730971-25G
98% - 730300-1G
730300-5G
O 98% - 730297-1G
O
CH2 CH3
H3C H3C N
O
CH3 CH3
2-Methacryloyloxyethyl phosphoryl-
O O CH3 97% 4-methylphenol ≤100 ppm as
choline H2C O
CH3 O P O
O
N CH3 CH3
inhibitor
Triethylene glycol methyl ether
methacrylate
2-N-Morpholinoethyl methacrylate
Methacryloyl chloride
Sodium methacrylate
Aldrich.com
730114-5G
CH3 95% MEHQ, >1,000 ppm 729841-25G
H2C O
O
O
OCH3 O
N
O
O
O 95% MEHQ ppm as inhibitor 729833-25G
CH3
O
H2C
Cl
CH3 CH 2
O
H2C ONa
CH3
TO ORDER: Contact your local Sigma-Aldrich office (see back cover) or visit Aldrich.com/matsci.
97% monomethyl ether hydroquinone,
~200 ppm as stabilizer
523216-100ML
523216-1L
99% - 408212-50G
408212-250G