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Low-Valent Titanium Induced Carbonyl Coupling Reactions

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Table 2. Synthesis of Strained Olefins[24]<br />

Entry Substrate Product<br />

1<br />

2<br />

3<br />

4<br />

5<br />

6<br />

O<br />

O<br />

O<br />

O<br />

O<br />

O<br />

To date the synthesis of tetra-tert-butylethylene remains elusive!<br />

O<br />

Ti[<br />

Ref.<br />

26, 27<br />

31<br />

28<br />

29<br />

30<br />

32<br />

13

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