Today - Polyurethane Association of India
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Today - Polyurethane Association of India
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d e c e m b e r 2 0 1 1<br />
p o l y u r e t h a n e s t o d a y<br />
1<br />
PU<br />
<strong>Today</strong>
PU<br />
<strong>Today</strong><br />
2 p o l y u r e t h a n e s t o d a y<br />
d e c e m b e r 2 0 1 1
Dear Readers,<br />
It has been almost 75 years since <strong>Polyurethane</strong>s was invented and this<br />
Industry has made rapid progress across many countries including<br />
<strong>India</strong>. <strong>Polyurethane</strong>s has contributed to several benefits to the society<br />
through innovations and by improving the life <strong>of</strong> consumers through<br />
various applications.<br />
The world continues to face many challenges and these can be summarized<br />
as leading to megatrends like Urbanization, Energy Conservation, Water<br />
conservation, Environmental protection and so on. These megatrends<br />
<strong>of</strong>fer significant challenges and opportunities to all industries including<br />
<strong>Polyurethane</strong>s. These challenges and opportunities can be met mainly<br />
by innovation that not only improve the life <strong>of</strong> consumers and do the<br />
same in a sustainable manner. Also there are some very unique <strong>India</strong>n<br />
opportunities that need uniquely <strong>India</strong>n innovative solutions<br />
This issue brings you the good news that such innovations continue to<br />
flourish in the polyurethanes industry even after over seven decades since<br />
the invention <strong>of</strong> polyurethanes. Some <strong>of</strong> these innovations developed<br />
outside <strong>India</strong> are finding application in <strong>India</strong> and also some unique <strong>India</strong><br />
needs are being addressed through disruptive innovation techniques.<br />
These innovations would go a long way in meeting the challenges and<br />
opportunities thrust upon us due to these megatrends.<br />
We hope that this issue does the dual job <strong>of</strong> your curiosity on some <strong>of</strong><br />
the application and also provide you with the assurance that innovation<br />
in polyurethanes is thriving despite the long history <strong>of</strong> this material.<br />
Best Regards,<br />
Anand G<br />
d e c e m b e r 2 0 1 1<br />
Committee Member’s Message<br />
p o l y u r e t h a n e s t o d a y<br />
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Editorial<br />
RIP: Mario Miranda<br />
Dev Anand<br />
Steve Jobs<br />
Bhupen Hazarika<br />
Jagjit Singh<br />
Shammi Kapoor<br />
M F Hussain<br />
We have lost such gems this past year – all ‘Innovators’ in their fields, having<br />
left behind noteworthy footprints in the sands <strong>of</strong> time.<br />
INNOVATIONS – the theme for this issue highlights the importance for this<br />
continuous process, to help keep progress and pr<strong>of</strong>its on the upward trend. A<br />
process enabled by the input <strong>of</strong> a new method / idea / product, in any field.<br />
The more radical and revolutionary innovations tend to emerge from R&D, while<br />
more incremental innovations may emerge from practice – though there are<br />
many exceptions to each <strong>of</strong> these trends. Recent years have seen considerable<br />
progress in identifying important key factors/principles or variables that affect<br />
the probability <strong>of</strong> success in innovation. The more one can master the variables<br />
and experiment, the more will one be able to create new products, processes and<br />
services that achieve what one hopes to achieve i.e. growth objectives.<br />
BUT cost reduction and re-engineering alone cannot result in growth. Economist<br />
Joseph Schumpeter, who contributed greatly to the study <strong>of</strong> innovation, argued<br />
that industries must incessantly revolutionize the economic structure from within,<br />
that is innovate with better or more effective processes and products, such as the<br />
shift from the craft shop to factory. Innovation is the key element in providing<br />
aggressive top-line growth, and for increasing bottom-line pr<strong>of</strong>its.<br />
So, in this issue, we have strived to highlight innovations across a spectrum <strong>of</strong><br />
activities in the PU arena, and hope you enjoy the read as much as we enjoyed<br />
finding enough interesting matter to fill the pages!<br />
Last but not the least, while speaking <strong>of</strong> Innovation, we cannot ignore the Master<br />
Innovator <strong>of</strong> our times, just because he belongs to a different field – who took<br />
the world by storm, by grabbing it with both hands & making it take the giant<br />
leap with him, into the next century / the next level in technology to enable<br />
comfort, convenience, and efficiency in everyday life. I talk <strong>of</strong> none other than:<br />
Steve Jobs – an ‘iConoclastic Innovator’!<br />
Do not miss our tribute to him on the Centre spread pages & the Book Review<br />
section.<br />
Sincerely,<br />
4 p o l y u r e t h a n e s t o d a y<br />
d e c e m b e r 2 0 1 1
PUBLISHED BY THE INDIAN POLYURETHANES ASSOCIATION<br />
EDITOR<br />
MRS. MEDHA BHUTA<br />
EDITORIAL TEAM<br />
MR. RAMAMURTHY - SECRETARY IPUA<br />
MR. GOVIND GUPTA - DOW<br />
MR. PRAVIN MAHAJAN - BASF<br />
MR. PRANAV MEHTA - HONEYWELL<br />
COMPILATION & SELECTION<br />
DR. MAHESH GOPALASAMUDRAM<br />
MR. G. ANAND<br />
DESIGN CONCEPT<br />
MR. MUKESH BHUTA<br />
GRAPHIC DESIGN & LAYOUT<br />
RED SKY DESIGNS<br />
PRODUCTION & EXECUTION<br />
MR. RAMAMURTHY<br />
IPUA OFFICE BEARERS<br />
CHAIRMAN<br />
MR. RAHUL GAUTAM 0120 4162 220/4162 200 rahul@sheelafoam.com<br />
VICE CHAIRMAN<br />
DR. G. MAHESH 9122 67934904 maheshgn@dow.com<br />
Mr. MUKESH BHUTA 022 2768 0303/0404 mbhuta@expandedinc.co.in<br />
TREASURER<br />
MR. GIAN JAIN 011 2724 6907/4237 6465 gcjain@karefoam.com<br />
SECRETARY GENERAL<br />
MR. K. RAMAMURTHY 044 2499 5923 admin@pu-india.org<br />
ramamurthy_k2@dataone.in<br />
IPUA EXECUTIVE COMMITTEE MEMBERS<br />
MR. JAGANNATH SARANGAPAN +9140 23704551/3 jagannath@ufoam.com<br />
MR. G. ANAND +9122 2778 7396 anand_g@huntsman.com<br />
MR. MANDAR JOSHI +9122 6791 7420 mandar.joshi@basf.com<br />
MR. DEEPAK T. MEHTA +9179 2630 4652/3/4/5 deepakmehta@tirupatifoam.com<br />
MR. M. G. BOHRA +9144 2595 2001/2 mgb@amulpolycure.com<br />
MR. H. S. KOCHAR +91120 4080000 kochar@pfeda.com<br />
MR. S. RAJESH T. BHARGAVA +912642 247160/61/62 rtbhargava@gnfc.in<br />
MR. RABINDRA JHAJHARIA +91332229 8904/2229 5496 multiwynfoams@multiwynfoams.com<br />
MR. PRANAYA PRADHAN +9731303238 pranaya.pradhan@shell.com<br />
MR. SANJAY SANGHI +91224005 9350/51/52/53/54/55sanjay.sanghi@momentive.com<br />
MR. VINOD VORA +9122 413 5141/5889 vnvora@aromaticagencies.com<br />
MR. ASHWINI K. SEHGAL +91120 4031000 aksehgal@saanglobal.com<br />
MR. ROMESH MADAN +9111 41613643/44/45 rmadan@goodiesons.com<br />
MR. ROHIT RELAN +91124 2341258 rohitgrp@ndf.vsnl.net.in<br />
MR.AJAY DURRANI +91120 3921199 ajay.durrani@bayer.com<br />
MR RAVI MUTHUKRISHNAN +9144 25942830 mravi@manalipetro.com<br />
PERMANENT INVITEE & SPECIAL ADVISOR TO THE IPUA<br />
MR G RAMACHANDRAN +91 44 24345738 indramu123@gmail.com<br />
PERMANENT INVITEE<br />
MR. SAMIR ARORA 011 26912375/26917758/26831850 samira@airtelmail.in sam@sam3.in<br />
d e c e m b e r 2 0 1 1<br />
Contents<br />
C o n t e n t s<br />
Co m m i t t e e member’s me s s age .................. 3<br />
ed i to r i a l .............................................. 4<br />
Cr e d i t s + Co n t e n t s ............................... 5<br />
in d u s t r y up d at e s ................................... 6<br />
in t e r n at i o n a l ne w s ............................... 12<br />
pr o d u C t ne w s ....................................... 16<br />
in t e r v ie w .............................................. 20<br />
te C h n iC a l up d at e s .................................. 23<br />
te C h n iC a l artiCle ................................... 24<br />
ipua ve n t u r e s ...................................... 37<br />
speCial Fe at u r e ...................................... 40<br />
en v ir o nme n t & saFe t y ........................... 45<br />
pr e v i e w s & re p o r t s ............................... 46<br />
bo o k s & pe r i o d i C a l s .............................. 49<br />
ev e n t s & tr e n d s ................................... 50<br />
p o l y u r e t h a n e s t o d a y<br />
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Industry Updates<br />
Recticel <strong>India</strong> Pvt. Ltd. <strong>of</strong>ficially inaugurated<br />
On Sunday, November 13, 2011,<br />
the new conversion plant <strong>of</strong><br />
Recticel Flexible Foams in Mumbai<br />
was <strong>of</strong>ficially inaugurated.<br />
As <strong>India</strong> is one <strong>of</strong> the fastest growing<br />
economies worldwide with a<br />
predicted average GDP growth <strong>of</strong> 6%<br />
for the next 10 to 20 years it is a huge<br />
potential industrial and consumer<br />
market. Recticel Flexible Foams will<br />
trade and convert mainly technical<br />
flexible polyurethane foams for the<br />
local market.<br />
The 6000m² plant which is located<br />
in Taloja, Navi Mumbai, close to<br />
the Nhava Shiva port <strong>of</strong> Mumbai,<br />
will be equipped with state <strong>of</strong> the<br />
art conversion machinery (cutting,<br />
pr<strong>of</strong>iling, laminating, compressing<br />
and more) to service different market<br />
segments with high technological<br />
foam solutions.<br />
While Recticel is already market<br />
leader in <strong>India</strong> for air filter foams<br />
in the automotive sector, it will also<br />
focus on other pr<strong>of</strong>itable technical<br />
segments such as acoustics.<br />
Recticel <strong>India</strong> Pvt. Ltd. currently also<br />
has a local sales <strong>of</strong>fice in Bangalore<br />
and will open up a new warehouse<br />
and converting unit in the course<br />
<strong>of</strong> 2012 to service the South <strong>India</strong>n<br />
market.<br />
The <strong>of</strong>ficial opening ceremony <strong>of</strong><br />
the Mumbai plant, which took place<br />
onsite, was attended by a large<br />
delegation <strong>of</strong> Flemish <strong>of</strong>ficials, led<br />
by the Flemish Minister President<br />
Kris Peeters and Karl Van den<br />
Bossche, Consul-General <strong>of</strong> Belgium<br />
6 p o l y u r e t h a n e s t o d a y<br />
d e c e m b e r 2 0 1 1
in Mumbai in the presence <strong>of</strong> many<br />
<strong>India</strong>n business relations.<br />
After the ribbon cutting and<br />
traditional Hindu “Pooja” inauguration<br />
ceremony, the delegation and other<br />
invitees were invited to the ro<strong>of</strong> top<br />
terrace for a reception and walking<br />
lunch buffet.<br />
Filip Goris, Regional Manager Asia<br />
and Latin America thanked all <strong>of</strong><br />
those who helped in setting up this<br />
new entity in <strong>India</strong>, and foremost<br />
the first hour employees <strong>of</strong> Recticel<br />
<strong>India</strong> Pvt. Ltd.: Abhijit Diwadkar<br />
(General Manager), Ashok Singh Sain<br />
(Business Development Manager<br />
Mumbai), Vijay Kumar (Business<br />
Development Manager Bangalore),<br />
Deepak Sawant (Finance Manager)<br />
and Aparna Munjewar (Sales Support<br />
Officer).<br />
d e c e m b e r 2 0 1 1<br />
The Flemish Minister President<br />
Peeters on his turn praised Recticel<br />
for its pioneering and proactive<br />
approach in <strong>India</strong>, setting an example<br />
Industry Updates<br />
for other Flemish companies pursuing<br />
growth opportunities.<br />
www.recticel.co.in<br />
p o l y u r e t h a n e s t o d a y<br />
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Industry Updates<br />
Honeywell Introduces New Highly Efficient,<br />
Low-Global-Warming Blowing Agent For Foam<br />
Insulation<br />
Global adoption <strong>of</strong> Solstice Liquid Blowing Agent could save the equivalent <strong>of</strong> 60 million metric<br />
tons <strong>of</strong> carbon dioxide per year<br />
MUMBAI, INDIA, NOVEMBER 4,<br />
2011 – Honeywell (NYSE: HON)<br />
has introduced a new liquid blowing<br />
agent in the company’s growing<br />
family <strong>of</strong> materials with a low-globalwarming<br />
potential (LGWP).<br />
Solstice Liquid Blowing Agent can<br />
be used in a variety <strong>of</strong> insulation<br />
applications including sprayfoam,<br />
foam insulating panels and<br />
refrigerator insulation. Use <strong>of</strong> the<br />
new material can make refrigerators<br />
up to 10 to 12 percent more energy<br />
efficient than those insulated by<br />
hydrocarbon-blown foam. Because<br />
<strong>of</strong> these energy efficiency benefits,<br />
if fully adopted globally, Solstice<br />
Liquid Blowing Agent could save<br />
approximately 60 million metric<br />
tons per year <strong>of</strong> carbon dioxide<br />
equivalent, which is comparable to<br />
eliminating carbon dioxide emissions<br />
from more than 11.8 million cars<br />
every year.*<br />
“Honeywell’s new Solstice Liquid<br />
Blowing Agent excels in the four<br />
dimensions that are most important to<br />
blowing agent users: energy efficiency<br />
performance, environmental impact,<br />
safety in use, and cost-effectiveness,”<br />
said Terrence Hahn, vice president<br />
and general manager for Honeywell<br />
Fluorine Products. “We are pleased<br />
to announce this expansion <strong>of</strong><br />
our Solstice family <strong>of</strong> low-global-<br />
8 p o l y u r e t h a n e s t o d a y<br />
warming-potential products, which<br />
is helping customers around the<br />
world lower their carbon footprint<br />
while maximizing end-product<br />
performance.”<br />
In <strong>India</strong>, Honeywell supports<br />
customers with a two-step approach<br />
when it comes to blowing agents.<br />
Appliance manufacturers can meet<br />
the Montreal Protocol regulations<br />
deman ding a phas e - out <strong>of</strong><br />
hydrochlor<strong>of</strong>luorocarbons (HCFCs)<br />
by using Honeywell´s Enovate®<br />
blowing agent, a hydr<strong>of</strong>luorocarbon<br />
(HFC) also known as 245fa blowing<br />
agent. This product can be adopted<br />
as a near drop-in replacement for<br />
HCFC 141b. It is non ozone depleting,<br />
allowing manufacturers to meet the<br />
phase-out plan for <strong>India</strong>.<br />
In a second step, starting in 2013,<br />
manufacturers can adopt Solstice<br />
Liquid Blowing Agent as needed<br />
to meet further regulation. Use <strong>of</strong><br />
Solstice Liquid Blowing Agent enables<br />
manufactuers to also meet the<br />
requirements <strong>of</strong> the <strong>India</strong>n Bureau<br />
<strong>of</strong> Energy Efficiency, a department<br />
within <strong>India</strong>´s Ministry <strong>of</strong> Power,<br />
focused on energy efficiency.<br />
Solstice Liquid Blowing Agent has<br />
an extremely short atmospheric<br />
lifetime <strong>of</strong> approximately 26 days.<br />
This gives the product its superior<br />
properties – it has an ultra-low global<br />
warming potential (GWP) <strong>of</strong> less than<br />
7 and has no impact on ozone layer<br />
depletion.<br />
Solstice Liquid Blowing Agent’s GWP is<br />
a more than 99 percent improvement<br />
over the products it can replace,<br />
including HCFC-141b (which has a<br />
GWP <strong>of</strong> 725), HFC-365mfc (which has<br />
a GWP <strong>of</strong> 794) and HFC-245fa (which<br />
has a GWP <strong>of</strong> 1,030).<br />
Because Solstice Liquid Blowing<br />
Agent is non-flammable, it does<br />
not require expensive explosionpro<strong>of</strong><br />
equipment and handling,<br />
unlike hydrocarbon alternatives. It<br />
is also a near drop-in replacement<br />
for today’s most commonly used<br />
blowing agents.<br />
Honeywell’s Solstice family <strong>of</strong><br />
products are based on hydr<strong>of</strong>luoroolefin<br />
technology and <strong>of</strong>fer similar<br />
or improved performance when<br />
compared with today’s most<br />
widely used stationary and mobile<br />
refrigerants, blowing agents and<br />
aerosol propellants. The products<br />
have dramatically reduced GWPs<br />
compared with today’s widely used<br />
fluorocarbons.<br />
For more information about<br />
Honeywell’s Solstice Liquid Blowing<br />
Agent visit www.honeywell-<br />
d e c e m b e r 2 0 1 1
solsticeLBA.com.<br />
*Source: U.S. Environmental Protection<br />
Agency greenhouse gas equivalencies<br />
calculator with inputs from Honeywell<br />
and customer Solstice Liquid Blowing<br />
Agent test results. (http://www.epa.<br />
gov/cleanenergy/energy-resources/<br />
calculator.html)<br />
Honeywell Specialty Materials is a<br />
global leader in providing customers<br />
with high-performance specialty<br />
materials, including fluorine products;<br />
specialty films and additives; advanced<br />
fibers and composites; intermediates;<br />
specialty chemicals; electronic materials<br />
and chemicals; and technologies and<br />
materials for petroleum refining.<br />
Honeywell International (www.<br />
honeywell.com) is a For tune<br />
100 diversified technology and<br />
d e c e m b e r 2 0 1 1<br />
manufacturing leader, serving<br />
customers worldwide with aerospace<br />
products and services; control<br />
technologies for buildings, homes<br />
and industry; automotive products;<br />
turbochargers; and specialty materials.<br />
Based in Morris Township, N.J.,<br />
Honeywell’s shares are traded on<br />
the New York, London, and Chicago<br />
Stock Exchanges. For more news and<br />
information on Honeywell, please visit<br />
www.honeywellnow.com.<br />
This release contains certain<br />
statements that may be deemed<br />
“forward-looking statements” within<br />
the meaning <strong>of</strong> Section 21E <strong>of</strong> the<br />
Securities Exchange Act <strong>of</strong> 1934. All<br />
statements, other than statements <strong>of</strong><br />
historical fact, that address activities,<br />
events or developments that we or<br />
our management intends, expects,<br />
projects, believes or anticipates<br />
Industry Updates<br />
will or may occur in the future are<br />
forward-looking statements. Such<br />
statements are based upon certain<br />
assumptions and assessments made<br />
by our management in light <strong>of</strong> their<br />
experience and their perception <strong>of</strong><br />
historical trends, current economic and<br />
industry conditions, expected future<br />
developments and other factors they<br />
believe to be appropriate. The forwardlooking<br />
statements included in this<br />
release are also subject to a number<br />
<strong>of</strong> material risks and uncertainties,<br />
including but not limited to economic,<br />
competitive, governmental, and<br />
technological factors affecting our<br />
operations, markets, products, services<br />
and prices. Such forward-looking<br />
statements are not guarantees <strong>of</strong><br />
future performance, and actual results,<br />
developments and business decisions<br />
may differ from those envisaged by<br />
such forward-looking statements.<br />
Huntsman’s <strong>Polyurethane</strong> division presented<br />
papers at CBRI (Central Building Research<br />
Institute) Roorkee<br />
The event<br />
The two day seminar FIRST-2011<br />
(Fire Science & Technology<br />
Research and its Implementation)<br />
is an initiative taken by the fire<br />
research division <strong>of</strong> CBRI. They want<br />
to spread awareness <strong>of</strong> research<br />
work and innovation, being carried<br />
out by academia and the industry<br />
to develop fire safe habitats. It is<br />
a first <strong>of</strong> its kind seminar where<br />
most <strong>of</strong> IIT’s and NIT’s shared their<br />
research work in this field; the<br />
industry-involved in innovation and<br />
research also supported the concept<br />
and the event was sponsored by<br />
CSIR- Government <strong>of</strong> <strong>India</strong>, L&T,<br />
C&S, Omega, Shaktiman Doors, Aska<br />
Engineering, SCD and Huntsman<br />
International <strong>India</strong> Private Limited<br />
The event was divided in 4 technical<br />
sessions and 30 technical papers<br />
were presented by various authors<br />
<strong>Polyurethane</strong> discussion in<br />
the seminar<br />
S. K. Bhattacharya, Director CBRI and<br />
Dr. S.C. Saxena Director IIT Roorkee<br />
were among the key people who<br />
kicked <strong>of</strong>f the seminar, a quick visit<br />
tour <strong>of</strong> the exhibition was followed<br />
by technical sessions<br />
The first session: Fire Retardant<br />
Materials- Modern trends in building<br />
and material was chaired by Dr.<br />
Diane Deams, Fire and building code<br />
manager Huntsman polyurethanes<br />
division. She was also the key note<br />
speaker <strong>of</strong> this session and highlighted<br />
the growing use <strong>of</strong> polyurethanes for<br />
insulation in construction in Western<br />
regions and China. Dr. Deams spoke<br />
about the evolving fire legislation in<br />
China to incorporate light weight,<br />
energy efficient and sustainable<br />
construction. She assured full support<br />
<strong>of</strong> Huntsman’s polyurethane division<br />
to the people involved in drafting the<br />
building codes in <strong>India</strong> in order to<br />
p o l y u r e t h a n e s t o d a y<br />
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upgrade them for achieving superior<br />
energy performance and fire safety<br />
<strong>of</strong> buildings<br />
The key note address was followed<br />
by Huntsman polyurethanes’ paper<br />
on Fire Performance <strong>of</strong> innovative<br />
polyurethane products in <strong>India</strong>.<br />
This paper was presented by Deepak<br />
Rathi, Business development<br />
manager- Insulation, highlighting the<br />
need <strong>of</strong> effective building insulation<br />
in <strong>India</strong> and the polyurethane<br />
products locally available to achieve<br />
this. He also shared the various test<br />
results related to fire performance <strong>of</strong><br />
INSPIRE® - PIR product developed by<br />
Huntsman’s polyurethane division<br />
Other significant papers on<br />
polyurethanes products were:<br />
l Rigid polyurethane foam as a fire<br />
retardant material- Presented by Dr.<br />
R S patil and Dr.J M Paranjpe, IIT<br />
Bombay<br />
l Flammability performance <strong>of</strong><br />
rigid PU foam manufactured using<br />
d e c e m b e r 2 0 1 1<br />
Industry Updates<br />
The Big Question: Can <strong>India</strong> clean up its image?<br />
Yahoo! <strong>India</strong> News<br />
Here’s a secret that everybody<br />
already knows: <strong>India</strong> is corrupt.<br />
Now it gets murkier. Over the past year,<br />
we have been swimming deeper into<br />
the muck. According to Transparency<br />
International’s Corruption Perception<br />
Index for 2011, <strong>India</strong> has dropped<br />
from 87 to 95. <strong>India</strong>’s image is taking<br />
a beating because <strong>of</strong> the big list <strong>of</strong><br />
corruption scandals that have rocked<br />
the nation this year.<br />
Dr. Deams spoke<br />
about the evolving fire<br />
legislation in China<br />
to incorporate light<br />
weight, energy efficient<br />
and sustainable<br />
construction. She<br />
assured full support<br />
<strong>of</strong> Huntsman’s<br />
polyurethane division<br />
to the people involved<br />
in drafting the building<br />
codes in <strong>India</strong> in order<br />
to upgrade them for<br />
achieving superior<br />
energy performance<br />
and fire safety <strong>of</strong><br />
buildings<br />
different blowing agent by Dr, Harpal<br />
Singh and Dr. S K Shrama, CBRI<br />
l Comparative fire performance<br />
evaluation <strong>of</strong> fire retardant treated<br />
rigid PU foam by cone calorimeter<br />
by Dr. Maricelin, Dr.S.R. Bhalla, Dr.<br />
S. K. Sahay, IIT Delhi<br />
l Effect <strong>of</strong> FR on generation <strong>of</strong> smoke<br />
and toxic combustion products by<br />
Dr.N K Saxena IIT Roorkee<br />
Other sessions on day one and two:<br />
Fire protec tion & life safet y<br />
technologies 9 Papers<br />
Extinguishment technologies for<br />
medium and large scale fire 4<br />
papers<br />
Mathematic al modeling and<br />
predictive methodologies 8 Papers<br />
The seminar was closed by Mr.<br />
Omprakash, from the Ministry <strong>of</strong><br />
Home affairs and chairman <strong>of</strong> the fire<br />
code revision committee BIS<br />
p o l y u r e t h a n e s t o d a y<br />
11<br />
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International News<br />
SCG-DOW Group Reaches Key<br />
Milestone toward Thailand HPPO Plant Start-up<br />
New HPPO facility ramps up to stable production levels in preparation for full capacity run<br />
scheduled for 4Q11.<br />
MIDLAND, Mich. – Oct. 4, 2011 – The<br />
Dow Chemical Company (NYSE:Dow)<br />
announced today that the SCG-Dow<br />
Group, a joint venture between Dow<br />
and SCG, has reached a key milestone<br />
for the new propylene oxide (PO)<br />
facility in Thailand by ramping the<br />
plant up to stable production levels in<br />
preparation for the full capacity run<br />
scheduled for the fourth quarter <strong>of</strong><br />
2011. The world-scale plant, located<br />
within the Asia Industrial Estates (AIE)<br />
site near Map Ta Phut, Thailand will<br />
have a name plate capacity <strong>of</strong> 390<br />
kilotons per annum (KTA) <strong>of</strong> PO via<br />
the innovative hydrogen peroxide to<br />
propylene oxide (HPPO) technology<br />
jointly developed by Dow and BASF.<br />
“The Map Ta Phut, Thailand HPPO<br />
plant cements Dow’s existing position<br />
as the global capacity leader in PO”,<br />
explained Steven English, global<br />
vice president, Dow <strong>Polyurethane</strong>s.<br />
“Not only does this large investment<br />
exemplify Dow’s commitment to the<br />
PO-based industry, we also continue<br />
to bring value by investing in the<br />
latest technology and <strong>of</strong>fering a more<br />
sustainable PO to our customers<br />
and our downstream <strong>of</strong>ferings<br />
through Dow’s other Performance<br />
and Advanced Materials businesses,<br />
such as <strong>Polyurethane</strong>s and Propylene<br />
Glycol.”<br />
According to Holger Baer, global<br />
manufacturing and technology<br />
director, PO/PG, “Within three<br />
years, this is the second world-scale<br />
plant brought on-line with the<br />
innovative Dow-BASF HPPO process.<br />
It significantly reduces wastewater<br />
and energy consumption compared<br />
12 p o l y u r e t h a n e s t o d a y<br />
to existing PO technology, and is<br />
planned to be utilized next in the<br />
Sadara Chemicals Company project<br />
between Dow and Saudi Aramco due<br />
to the clear demonstration <strong>of</strong> the<br />
advantages <strong>of</strong> this process.”<br />
“The start-up <strong>of</strong> this PO plant<br />
has completed the downstream<br />
envelope <strong>of</strong> the SCG-DOW Group joint<br />
venture cracker in Thailand which<br />
came on-stream last year”, said<br />
Cholanat Yanaranop, president,<br />
SCG Chemicals Company Limited.<br />
“With commitment between the<br />
partners, this is proved to be another<br />
successful project.”<br />
In June <strong>of</strong> 2010, Dow and BASF were<br />
honored to receive a 2010 Presidential<br />
Green Chemistry Challenge Award for<br />
the jointly developed innovative<br />
HPPO technology – recognized as<br />
a breakthrough technology that<br />
transfers sustainability principles<br />
from the research lab into the real<br />
world to enable environmentally<br />
responsible and economically viable<br />
routes to commercial chemical<br />
manufacturing. In 2009, Dow and<br />
BASF received the Institution <strong>of</strong><br />
Chemical Engineers’ Innovation and<br />
Excellence Award in Core Engineering<br />
for their jointly developed HPPO<br />
Technology – recognized as the<br />
process that best demonstrates a<br />
chemical engineering solution to<br />
improve resource efficiency, lifetime<br />
value and/or process optimization.<br />
In December 2010, Dow announced<br />
plans to build a propylene glycol (PG)<br />
plant at the Map Ta Phut, Thailand<br />
site, with a production capacity <strong>of</strong><br />
150 KTA. The PG plant is currently<br />
on-track in the design process, and<br />
will utilize this environmentally<br />
advantaged PO from the new HPPO<br />
plant. It will be the largest PG plant<br />
in the Pacific area.<br />
The AIE site also features a specialty<br />
elastomers plant, which announced<br />
start-up earlier this year; power<br />
utilities and infrastructure; and<br />
a new liquids cracker, also jointly<br />
owned by SCG and Dow. “The new<br />
integrated Thailand site serves as<br />
a strategic source point for all <strong>of</strong><br />
Asia Pacific, and demonstrates<br />
Dow’s commitment to growing<br />
our presence to serve customers<br />
in our Performance Materials and<br />
Performance Plastics businesses<br />
across the area”, said Pat Dawson,<br />
Dow Asia Pacific president.<br />
Dow to Highlight Innovations<br />
at 2011 CPI Technical<br />
Conference<br />
About Dow <strong>Polyurethane</strong>s<br />
Dow is the world’s largest producer<br />
<strong>of</strong> propylene oxide (PO), propylene<br />
glycol (PG), and polyether polyols,<br />
and is a leading producer <strong>of</strong> quality<br />
aromatic isocyanates, such as<br />
MDI and TDI. Dow’s polyurethane<br />
products enhance a broad range <strong>of</strong><br />
applications including construction,<br />
automotive, furniture, bedding,<br />
appliance, decorative molding,<br />
athletic equipment and more. The<br />
business provides key ingredients,<br />
systems and solutions for rigid, semirigid<br />
and flexible foams, adhesives,<br />
sealants, coatings, elastomers and<br />
d e c e m b e r 2 0 1 1
inders. VORANOL VORACTIV<br />
polyols exemplify Dow’s ongoing<br />
initiative to lead the industry in<br />
providing high-performance products<br />
that meet critical consumer needs.<br />
For more information, visit www.<br />
dowpolyurethanes.com, www.dowpg.<br />
com, www.dowpo.com and www.<br />
voractiv.com.<br />
About Dow<br />
Dow combines the power <strong>of</strong> science<br />
and technology with the “Human<br />
Element” to passionately innovate<br />
what is essential to human progress.<br />
The Company connects chemistry<br />
and innovation with the principles<br />
<strong>of</strong> sustainability to help address<br />
many <strong>of</strong> the world’s most challenging<br />
problems such as the need for<br />
clean water, renewable energy<br />
generation and conservation, and<br />
increasing agricultural productivity.<br />
Dow’s diversified industry-leading<br />
New Technology From Dow and Cannon Improves Energy<br />
Efficiency <strong>of</strong> Household Refrigerators by<br />
up to 10 percent<br />
d e c e m b e r 2 0 1 1<br />
portfolio <strong>of</strong> specialty chemical,<br />
advanced materials, agrosciences<br />
and plastics businesses delivers a<br />
broad range <strong>of</strong> technology-based<br />
products and solutions to customers<br />
in approximately 160 countries<br />
and in high growth sectors such as<br />
electronics, water, energy, coatings<br />
and agriculture. In 2010, Dow had<br />
annual sales <strong>of</strong> $53.7 billion and<br />
employed approximately 50,000<br />
people worldwide. The Company’s<br />
more than 5,000 products are<br />
manufactured at 188 sites in 35<br />
countries across the globe. References<br />
to “Dow” or the “Company” mean<br />
The Dow Chemical Company and<br />
its consolidated subsidiaries unless<br />
otherwise expressly noted. More<br />
information about Dow can be found<br />
at www.dow.com.<br />
About SCG<br />
SCG, established in 1913, is publicly<br />
International News<br />
listed on the Stock Exchange <strong>of</strong><br />
Thailand. SCG is one <strong>of</strong> ASEAN<br />
leading conglomerates, comprises<br />
five core businesses: chemicals,<br />
cement, paper, building materials,<br />
and distribution. Altogether, there<br />
are over 200 companies within the<br />
group, which collectively employ<br />
more than 34,000 employees, and<br />
manufacture more than 64,000<br />
products.<br />
S CG Chemic als continue s to<br />
expand its business presence into<br />
international markets, and places<br />
a strong emphasis on innovation in<br />
products/services, processes, and<br />
business models in service <strong>of</strong> its<br />
diverse and sophisticated customer<br />
base. In addition, SCG Chemicals<br />
has partnered with a number <strong>of</strong> the<br />
world’s leading chemical firms. More<br />
information about SCG can be found<br />
at www.scg.co.th.<br />
• New insulation technology decreases fill time, doubles productivity <strong>of</strong><br />
polyurethane insulation manufacturing process<br />
• Insulation technology increases energy efficiency <strong>of</strong> refrigerators and freezers<br />
by up to 10 percent<br />
Midland, Michigan – September 8,<br />
2011 – Dow <strong>Polyurethane</strong>s, a business<br />
within The Dow Chemical Company<br />
(NYSE: Dow), in cooperation with<br />
Cannon SpA, will <strong>of</strong>ficially launch<br />
PASCAL Technology on September<br />
9 at the Shanghai Summit 2011.<br />
PASCAL, a new polyurethane foam<br />
insulation technology that improves<br />
energy efficiency <strong>of</strong> refrigerators and<br />
freezers by up to 10 percent, was first<br />
featured in household refrigerators<br />
and freezers by Haier and is now<br />
commercially available to appliance<br />
manufacturers.<br />
The Shanghai Summit<br />
2011 brings together<br />
Italian and Chinese<br />
government <strong>of</strong>ficials,<br />
academic and industry<br />
leaders and media<br />
to share innovative<br />
insights on energy conservation<br />
and explore how transformational<br />
opportunities can contribute to<br />
economic growth and environmental<br />
sustainability. The summit is just one<br />
p o l y u r e t h a n e s t o d a y<br />
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<strong>of</strong> the efforts in the collaboration <strong>of</strong><br />
the Italian and Chinese governments<br />
toward making China a more<br />
sustainable country.<br />
“This summit is the perfect venue to<br />
launch PASCAL,” said Bruno Barbet,<br />
Dow <strong>Polyurethane</strong>s global appliance<br />
market leader. “China is one <strong>of</strong> the<br />
largest single-home marketplaces<br />
for refrigerators and freezers, as well<br />
as a leading global export country,<br />
and PASCAL Technology can help<br />
support the goals <strong>of</strong> making China’s<br />
industrial divisions more sustainable<br />
for the future.”<br />
Combining a proprietary polyurethane<br />
foam specifically formulated for this<br />
application, PASCAL Technology<br />
doubles the efficiency <strong>of</strong> insulation<br />
while continuing to provide thermal<br />
conductivity and adhesion—qualities<br />
that distinguish polyurethane from<br />
alternative types <strong>of</strong> insulation.<br />
Caption: When compared to standard<br />
polyurethane insulation processes,<br />
PASCAL Technology out-performs<br />
both side-by-side models and<br />
bottom freezer models by up to<br />
10%. The test results shown compare<br />
PASCAL Technology against standard<br />
polyurethane insulation using<br />
cyclopentane (CP) blowing agents.<br />
“Average Results” represent the<br />
average <strong>of</strong> all tests run on a variety<br />
<strong>of</strong> standard refrigeration models.<br />
d e c e m b e r 2 0 1 1<br />
Results vary per model, and have the<br />
potential to realize up to 10% energy<br />
efficiency improvement based on<br />
a variety <strong>of</strong> influencing factors<br />
as advantages <strong>of</strong> the Technology<br />
continue to be understood.<br />
PASCAL is just one <strong>of</strong> the innovative<br />
s olutions spurre d by Dow ’s<br />
commitment to addressing the<br />
world’s most critical challenges,<br />
including the need to conserve<br />
energy.<br />
“Governments are setting more<br />
stringent mandatory minimum<br />
Energy targets, and consumers<br />
worldwide are demanding energy<br />
efficient appliances,” said Barbet.<br />
“With PASCAL, manufacturers may<br />
deliver on this demand, while also<br />
increasing energy efficiency and<br />
output during manufacturing.”<br />
PASCAL Technology incorporates<br />
v a c u u m<br />
equipment from<br />
Cannon SpA, during<br />
the insulation<br />
process to bypass<br />
the deficiencies<br />
o f s t a n d a r d<br />
insulation. The<br />
vacuum, paired<br />
with a hydrocarbon<br />
blowing agent,<br />
allows PA S C AL<br />
polyurethane foam<br />
to fit into the small<br />
spaces traditional insulation might<br />
miss, especially in modern designs,<br />
and also mold to the contours <strong>of</strong> the<br />
appliance, reducing the amount <strong>of</strong><br />
energy lost during consumer use. The<br />
resulting system can also decrease<br />
the insulation reactivity time from<br />
a standard <strong>of</strong> about five to three<br />
minutes.<br />
For more information, please visit<br />
www.dowpascal.com.<br />
International News<br />
About Dow <strong>Polyurethane</strong>s<br />
Dow is the world’s largest producer<br />
<strong>of</strong> propylene oxide (PO), propylene<br />
glycol (PG), and polyether polyols,<br />
and is a leading producer <strong>of</strong> quality<br />
aromatic isocyanates, such as<br />
MDI and TDI. Dow’s polyurethane<br />
products enhance a broad range <strong>of</strong><br />
applications including construction,<br />
automotive, furniture, bedding,<br />
appliance, decorative molding,<br />
athletic equipment and more. The<br />
business provides key ingredients,<br />
systems and solutions for rigid, semirigid<br />
and flexible foams, adhesives,<br />
sealants, coatings, elastomers and<br />
binders. VORANOL VORACTIV<br />
polyols exemplify Dow’s ongoing<br />
initiative to lead the industry in<br />
providing high-performance products<br />
that meet critical consumer needs.<br />
For more information, visit www.<br />
dowpolyurethanes.com, www.dowpg.<br />
com, www.dowpo.com and www.<br />
voractiv.com.<br />
About Dow<br />
Dow combines the power <strong>of</strong> science and<br />
technology with the “Human Element” to<br />
passionately innovate what is essential to<br />
human progress. The Company connects<br />
chemistry and innovation with the principles<br />
<strong>of</strong> sustainability to help address many <strong>of</strong> the<br />
world’s most challenging problems such as<br />
the need for clean water, renewable energy<br />
generation and conservation, and increasing<br />
agricultural productivity. Dow’s diversified<br />
industry-leading portfolio <strong>of</strong> specialty<br />
chemical, advanced materials, agrosciences<br />
and plastics businesses delivers a broad<br />
range <strong>of</strong> technology-based products and<br />
solutions to customers in approximately 160<br />
countries and in high growth sectors such<br />
as electronics, water, energy, coatings and<br />
agriculture. In 2010, Dow had annual sales<br />
<strong>of</strong> $53.7 billion and employed approximately<br />
50,000 people worldwide. The Company’s<br />
more than 5,000 products are manufactured<br />
at 188 sites in 35 countries across the globe.<br />
References to “Dow” or the “Company”<br />
mean The Dow Chemical Company and its<br />
consolidated subsidiaries unless otherwise<br />
expressly noted. More information about<br />
Dow can be found at www.dow.com.<br />
p o l y u r e t h a n e s t o d a y<br />
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Product News<br />
Honeywell Fluorine Products in <strong>India</strong><br />
Overview<br />
Honeywell’s Fluorine Products<br />
business is a leader in the<br />
manufacture and supply <strong>of</strong> zero<br />
non-ozone-depleting refrigerants<br />
used by top air-conditioning and<br />
refrigeration makers worldwide, as<br />
well as blowing agents for energyefficient<br />
foam insulation, and<br />
hydr<strong>of</strong>luoric acid and precursors for<br />
nuclear fuel. The business pioneered<br />
the development <strong>of</strong> fluorocarbons<br />
used in environmentally safer<br />
refrigerants, foam blowing agents<br />
and aerosols and solvents. It is a<br />
leading producer <strong>of</strong> fluorocarbons<br />
used to replace ozone-depleting CFCs<br />
(chlor<strong>of</strong>luorocarbons) and HCFCs<br />
(hydrochlor<strong>of</strong>luorocarbons).<br />
Continuing its commitment towards<br />
more secure, safer and more<br />
energy-efficient homes and <strong>of</strong>fices,<br />
Honeywell works towards helping<br />
the world responding to its energy<br />
and environmental challenges.<br />
In 2008, Honeywell introduced<br />
the first product in its Low Global<br />
Warming Potential (LGWP) portfolio,<br />
based on hydr<strong>of</strong>luoroolefin (HFO)<br />
technology. <strong>Today</strong>, Honeywell is a<br />
pioneer in developing LGWP blowing<br />
agent technology for polyurethane<br />
and extruded polystyrene foams<br />
insulation; advanced energy-efficient<br />
refrigerants for refrigeration and air<br />
conditioning, and organic rankine<br />
cycle waste heat recovery systems;<br />
and propellants for aerosol and<br />
solvent applications.<br />
<strong>India</strong>, as a part <strong>of</strong> Article V countries <strong>of</strong><br />
Montreal Protocol on Substances That<br />
Deplete the Ozone Layer, is working<br />
16 p o l y u r e t h a n e s t o d a y<br />
toward phasing out HCFC 141b and<br />
R22 from 2013 onwards. The transition<br />
from HCFCs to environmentally<br />
friendlier alternatives is <strong>of</strong> particular<br />
significance since the country aims to<br />
not only phase out ozone depleting<br />
HCFC’s but also significantly improve<br />
the energy efficiency <strong>of</strong> domestic<br />
appliances over the next 2-3 years.<br />
Fluorine Products <strong>of</strong>fers:<br />
• F or p olyurethane foam:<br />
Honeywell Enovate blowing<br />
agent and Honeywell Solstice<br />
Liquid Blowing Agent<br />
• For extruded polystyrene foam<br />
and one-component foam:<br />
Honeywell Solstice Gas Blowing<br />
Agent<br />
• For refrigerants: Genetron®<br />
410A<br />
Meeting the Montreal Protocol<br />
regulations for HCFC phase-out,<br />
Enovate 245fa has No Ozone<br />
Depletion Potential and provides<br />
efficiencies similar to HCFC 141b<br />
blowing agent. It is non-toxic, noncorrosive,<br />
non-flammable and <strong>of</strong>fers<br />
8 to 10 percent more energy efficiency<br />
than any hydrocarbon blowing agent.<br />
Converting to Enovate 245fa incurs<br />
no significant cost or changes to the<br />
existing HCFC 141b or hydrocarbonbased<br />
foaming equipment setup.<br />
Honeywell has also developed and<br />
recently launched Solstice Liquid<br />
Blowing Agent (LBA). Solstice LBA<br />
excels in the four dimensions that<br />
are most critical to blowing agent<br />
customers: Performance, Cost-<br />
Effectiveness, Environment and<br />
Safety. This fourth generation blowing<br />
agent has been developed to have a<br />
significantly lower global-warming<br />
potential (GWP) while improving<br />
energy efficiency performance.<br />
The energy efficiency benefits <strong>of</strong><br />
Honeywell Solstice Liquid Blowing<br />
Agent, combined with its low global<br />
warming potential and safety in<br />
use, make it the right choice as a<br />
replacement for HCFC-141b, as well<br />
as hydrocarbons, for manufacture<br />
<strong>of</strong> polyurethane foam.<br />
Honeywell Specialty Materials is a<br />
leading international supplier and<br />
licensor <strong>of</strong> process technology,<br />
catalysts, adsorbents, process plants,<br />
and consulting services to the<br />
petroleum refining, petrochemical,<br />
and gas processing industries. It is<br />
a global leader in developing and<br />
manufacturing high-purity, highquality<br />
performance chemicals and<br />
materials, pharmaceutical packaging,<br />
and construction materials. Our<br />
technologies reduce emissions, stop<br />
bullets, enable the production <strong>of</strong><br />
green diesel and green gasoline,<br />
increase oil refinery capacity,<br />
speed drug discovery, and protect<br />
medicines.<br />
Honeywell is a Fortune 100 company<br />
that invents and manufactures<br />
technologies to address tough<br />
challenges linked to global macro<br />
trends such as safety, security, and<br />
energy. With approximately 122,000<br />
employees worldwide, including<br />
more than 19,000 engineers and<br />
scientists, Honeywell stands for<br />
an unrelenting focus on quality,<br />
delivery, value, and technology in<br />
everything we make and do.<br />
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Product News<br />
You’re all screwed: Assange’s message to iPhone,<br />
BB, Gmail users<br />
December 03, 2011<br />
Daily Mirror<br />
London Wiki Leaks founder Julian<br />
Assange has warned Smartphone<br />
and email users: “ You’re all<br />
screwed”.<br />
The whistle-blowing website has<br />
released details <strong>of</strong> companies it says<br />
are selling information obtained by<br />
monitoring people’s mobile phones<br />
and computers. According to Assange,<br />
more than 150 organizations around<br />
the world have the ability to use<br />
phones as tracking devices as well<br />
as intercept messages and listen to<br />
calls.<br />
Those companies then sell the<br />
wholesale information, <strong>of</strong>ten the<br />
telecommunications data <strong>of</strong> “entire<br />
populations”.<br />
He told a press conference at City<br />
University in London that the<br />
publication <strong>of</strong> the “Spy Files” is a<br />
“mass attack on this mass surveillance<br />
industry”.<br />
The 40-year-old asked the audience<br />
<strong>of</strong> students and press: “Who here<br />
has an iPhone? Who here has a<br />
BlackBerry? Who here uses Gmail?<br />
“Well, you’re all screwed.<br />
“The reality is, intelligence contractors<br />
are selling right now to countries<br />
across the world mass surveillance<br />
systems for all those products.”<br />
Assange said this interception,<br />
although lawful, is leading towards<br />
Sleep Innovations Introduces Gel Infused Memory Foam<br />
a “totalitarian surveillance state”.<br />
Wiki Leaks is releasing 287 documents<br />
today, in conjunction with website<br />
spyfiles.org. Assange said the US, UK,<br />
Australia, South Africa and Canada are<br />
all developing the “spying systems”,<br />
and the information is being sold to<br />
“dictators and democracies alike”.<br />
He said: “<strong>Today</strong> we release over<br />
287 files documenting the reality <strong>of</strong><br />
the international mass surveillance<br />
industry – which now sells equipment<br />
to dictators and democracies<br />
alike in order to intercept entire<br />
populations.”<br />
The Australian national said the<br />
surveillance industry has grown<br />
over the last 10 years from “covert,<br />
secretive and small” to one involving<br />
160 companies and 25 countries.<br />
Sleep Innovations Announces Revolutionary New<br />
Technology Proven to Help Consumers Sleep Better<br />
Gel-Infused Memor y Foam<br />
Provides Maximum Pressure-<br />
Point Relief, Improved Airflow and<br />
Reduces Heat for Better Quality<br />
Sleep<br />
WEST LONG BRANCH, N.J., Sept. 14<br />
/PRNewswire/ -- Sleep Innovations,<br />
a market leader in designing and<br />
manufacturing advanced foam<br />
comfort solutions, announced today<br />
a revolutionary new product that<br />
takes memory foam to the next<br />
level. The company’s first-<strong>of</strong>-its-kind<br />
p o l y u r e t h a n e s t o d a y<br />
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gel-infused memory foam provides<br />
the traditional comfort <strong>of</strong> memory<br />
foam with the additional benefits<br />
<strong>of</strong> increased support and improved<br />
airflow.<br />
Sleep Innovations is launching the<br />
patent-pending new technology<br />
in response to consumers’ need<br />
for a quality sleep experience. The<br />
gel-infused memory foam provides<br />
the ultimate solution, combining<br />
comfort, support, pressure relief<br />
and improved airflow. To create gelmemory<br />
foam, gel beads are infused<br />
into traditional memory foam. These<br />
gel beads add a layer <strong>of</strong> support<br />
within the foam, gathering together<br />
at pressure points to deliver the<br />
maximum support a person needs,<br />
exactly where it’s needed.<br />
With nearly thirty-five percent <strong>of</strong><br />
Americans not getting the quality<br />
sleep they need, the revolutionary<br />
gel-infused memory foam technology<br />
addresses one <strong>of</strong> the main reasons<br />
people are sleep deprived – poor<br />
quality sleep products. When<br />
d e c e m b e r 2 0 1 1<br />
developing products on which people<br />
spend one-third <strong>of</strong> their lives, Sleep<br />
Innovations believes it is critical to<br />
deliver a sleep solution, proven to<br />
addresses those consumer needs.<br />
Sleep Innovations’ new gel-infused<br />
memory foam technology is launching<br />
as the company expands its current<br />
<strong>of</strong>ferings to include comfort solutions<br />
for every moment in life beyond<br />
sleep. “Its advantages include better<br />
air flow for a cooler night’s sleep,<br />
more balanced support resulting<br />
in less cradling, optimal pressure<br />
point relief for improved circulation<br />
and better spinal alignment. Sleep<br />
Innovations’ new gel-infused<br />
memory foam technology <strong>of</strong>fers<br />
the perfect balance between the<br />
comfort <strong>of</strong> traditional memory foam<br />
and the support <strong>of</strong> gel,” said Mike<br />
Loomis, Vice President <strong>of</strong> Business<br />
and Product Development at Sleep<br />
Innovations<br />
Sleep Innovations is working to<br />
continuously improve existing<br />
memory foam products as well<br />
Product News<br />
as develop the next generation <strong>of</strong><br />
comfort foam solutions using this<br />
new gel-infused memory foam<br />
technology.<br />
The new gel memory foam products<br />
are currently available at leading<br />
retailers throughout the U.S. and<br />
Canada.<br />
For additional information, or to<br />
see additional retailers where the<br />
product will be available, visit www.<br />
sleepinnovations.com.<br />
About Sleep Innovations<br />
Sleep Innovations is the leader in<br />
consumer-driven foam products,<br />
proven to deliver comfort, relaxation<br />
and rejuvenation. The company<br />
designs and manufactures advanced,<br />
memory foam products, including<br />
pillows, mattress toppers and<br />
mattresses. Through extensive<br />
clinical testing, Sleep Innovations has<br />
found that its foam solutions help to<br />
improve the quality <strong>of</strong> its consumers’<br />
lives through better sleep.<br />
p o l y u r e t h a n e s t o d a y<br />
19<br />
PU<br />
<strong>Today</strong>
PU<br />
<strong>Today</strong><br />
Interview<br />
PAUL SANDERS<br />
Honeywell Solstice LBA will be more<br />
cost-effective than other solutions to meet<br />
ever-increasing energy standards globally<br />
l The energy efficiency benefits <strong>of</strong><br />
Solstice Liquid Blowing Agent (LBA),<br />
combined with its low global warming<br />
potential and safety in use, make it<br />
the right choice as a replacement<br />
for HCFC-141b, hydrocarbons, HFC-<br />
365mfc, and HFC-245fa for use as a<br />
foam insulation blowing agent.<br />
l Refrigerators using un-optimized<br />
Solstice LBA formulations have<br />
been demonstrated to be up to<br />
10-12% better than cyclopentane<br />
formulations. We expect even more<br />
as formulations are fine-tuned.<br />
l With a global warming potential<br />
(GWP) <strong>of</strong> less than 7, its widespread<br />
adoption could save about 60 million<br />
metric tons per year <strong>of</strong> CO2 equivalent,<br />
comparable to eliminating carbon<br />
dioxide emissions from more than<br />
11.8 million cars every year. (Source:<br />
GHG Equivalencies Calculator: http://<br />
www.epa.gov/cleanenergy/energy-<br />
20 p o l y u r e t h a n e s t o d a y<br />
Paul Sanders is the Commercial Director for the Fluorines<br />
business in Europe, Middle East Africa and <strong>India</strong> (EMEAI)<br />
I. He joined Honeywell in 2006 and has had several<br />
Marketing and Commercial roles for the Fluorines<br />
business in EMEAI. Paul has worked in Sales, Marketing,<br />
Asset Management and Plant Management roles for 20<br />
years in the chemical industry, previously at Rhodia and<br />
Albright & Wilson prior to joining Honeywell.<br />
Paul Sanders holds a Bachelor <strong>of</strong> Science (with special<br />
honours) in Chemistry from University Sheffield, UK.<br />
resources/calculator.html)<br />
PU TODAY: What is Solstice TM<br />
LBA?<br />
Mr. PAUL SANDERS: Honeywell<br />
Solstice LBA is the latest technological<br />
advance with a GWP <strong>of</strong> less than<br />
7. It can be used in refrigerator/<br />
freezer insulation, insulated metal<br />
panels, spray foam insulation and<br />
other applications. It is a promising<br />
replacement for foam insulation<br />
blowing agents currently in use, with<br />
the potential to make contributions<br />
to reductions in global warming.<br />
PU TODAY: How Solstice<br />
LBA is compared with (other<br />
alternatives) hydrocarbon and<br />
HCFC 141b blowing agents?<br />
Mr. PAUL SANDERS: The energy<br />
efficiency benefits <strong>of</strong> Solstice LBA,<br />
combined with its low environmental<br />
impact and non-flammability, make<br />
it the right choice as a replacement<br />
for hydrocarbons, HFCs and HCFCs<br />
for use as a foam insulation blowing<br />
agent.<br />
Solstice LBA per forms better<br />
than hydrocarbons in refrigerator<br />
applications by delivering:<br />
l Better low-temperature efficiency<br />
that saves energy costs<br />
l Lower capital costs by avoiding<br />
e xpensive flammabilit y risk<br />
mitigation equipment and preventive<br />
maintenance<br />
l Similar performance for spray and<br />
panel foam<br />
l Lower end-<strong>of</strong>-life management<br />
costs<br />
While S olstice LBA provides<br />
excellent insulation performance<br />
to polyurethane foam, it’s distinctly<br />
dif ferent from hydrocarbon<br />
d e c e m b e r 2 0 1 1
lowing agents in flammability<br />
characterization. Solstice LBA<br />
shipment, storage, handling and<br />
processing do not require flammability<br />
risk mitigation. Flammable blowing<br />
agents, such as cyclopentane, require<br />
flammability risk mitigation, which<br />
can add significant capital costs.<br />
PU TODAY: Is it a drop in<br />
replacement for HCFC 141b?<br />
What are the changes required<br />
in process equipments?<br />
Mr. PAUL SANDERS: Solstice LBA is<br />
a low cost energy efficient alternative<br />
to HCFC 141b, minimal equipment<br />
modifications may be needed as<br />
the temperature and pressure <strong>of</strong> the<br />
products differ. Please contact us to<br />
set up a time to review your current<br />
operation.<br />
PU TODAY: What are the safety<br />
precautions required while<br />
processing & transporting<br />
polyol blended with Solstice<br />
L B A a n d re c o m m e n d e d<br />
storage conditions? What is<br />
the typical shelf-life <strong>of</strong> the<br />
polyol pre-blended under<br />
the recommended storage<br />
conditions?<br />
Mr. PAUL SANDERS: While Solstice<br />
LBA provides excellent insulation<br />
performance to polyurethane<br />
foam, it’s distinctly different from<br />
hydrocarbon blowing agents in<br />
flammability characterization.<br />
Solstice LBA shipment, storage,<br />
handling and processing do not<br />
require flammability risk mitigation.<br />
Flammable blowing agents, such as<br />
cyclopentane, require flammability<br />
risk mitigation, which can add<br />
significant capital costs.<br />
Solstice LBA is non-flammable by<br />
ASTM E-861 test method and has no<br />
d e c e m b e r 2 0 1 1<br />
Honeywell Solstice LBA<br />
is the latest<br />
technological advance<br />
with a GWP <strong>of</strong> less<br />
than 7. It can be used<br />
in refrigerator/freezer<br />
insulation, insulated<br />
metal panels, spray<br />
foam insulation and<br />
other applications.<br />
limitation on hazards classification.<br />
The flammability characteristics<br />
and VOC mitigation required<br />
with other blowing agents (such<br />
as hydrocarbons) make them less<br />
desirable as replacements for existing<br />
blowing agents.<br />
PU TODAY: Is it a cost effective<br />
alternative?<br />
Mr. PAUL SANDERS: Honeywell<br />
Solstice LBA will be more cost-effective<br />
than other solutions to meet ever-<br />
increasing energy standards globally.<br />
A near drop-in replacement for liquid<br />
HCFC, HFC, hydrocarbons and other<br />
non-fluorocarbon blowing agents. It<br />
is liquid at room temperature and<br />
can be used in most existing foam<br />
equipment, regardless <strong>of</strong> current<br />
blowing agent used, with little or no<br />
modification.<br />
It does not require costly hydrocarbon<br />
storage and handling or mitigation<br />
equipment. Replacing existing<br />
blowing agents with Solstice LBA<br />
eliminates the need for large capital<br />
conversion costs.<br />
PU TODAY: When Solstice TM<br />
Interview<br />
LBA will be commercially<br />
available in <strong>India</strong>?<br />
Mr. PAUL SANDERS: In <strong>India</strong>,<br />
Honeywell supports customers<br />
with a two-step approach when<br />
it comes to blowing agents.<br />
Appliance manufacturers can meet<br />
the Montreal Protocol regulations<br />
deman ding a phas e - out <strong>of</strong><br />
hydrochlor<strong>of</strong>luorocarbons (HCFCs) by<br />
using Honeywell’s Enovate® blowing<br />
agent, a hydr<strong>of</strong>luorocarbon also<br />
known as HFC-245fa . This product<br />
can be adopted as a near dropin<br />
replacement for HCFC-141b. It<br />
is non-ozone depleting, allowing<br />
manufacturers to meet the phase-out<br />
plan for <strong>India</strong> and has been available<br />
and used globally since 2003.<br />
In a second step, starting in 2013,<br />
manufacturers can adopt Solstice<br />
LBA as needed to meet any future<br />
environmental needs concerning<br />
GWP or Climate Change and/or to<br />
further improve energy efficiency.<br />
Use <strong>of</strong> Solstice LBA enables appliance<br />
manufactuers to effectively meet<br />
the Energy standard requirements<br />
<strong>of</strong> the <strong>India</strong>n Bureau <strong>of</strong> Energy<br />
Efficiency, a department within<br />
<strong>India</strong>´s Ministry <strong>of</strong> Power, focused on<br />
energy efficiency.<br />
Disclaimer:<br />
The information provided herein are<br />
believed to be accurate and reliable,<br />
but are presented without guarantee or<br />
warranty <strong>of</strong> any kind, express or implied.<br />
User assumes all risk and liability for use<br />
<strong>of</strong> the information and results obtained.<br />
Statements or suggestions concerning<br />
possible use <strong>of</strong> materials and processes are<br />
made without representation or warranty<br />
that any such recommendations to infringe<br />
any patent. The user should not assume that<br />
all safety measures are indicated herein, or<br />
that other measures may not be required.<br />
p o l y u r e t h a n e s t o d a y<br />
21<br />
PU<br />
<strong>Today</strong>
PU<br />
<strong>Today</strong><br />
22 p o l y u r e t h a n e s t o d a y<br />
d e c e m b e r 2 0 1 1
RAMPF at Plast<strong>India</strong> 2012<br />
“Material and machine technology” from a<br />
single source<br />
Grafenberg, Zimmern, November<br />
30, 2011 – In hall 13 on stand<br />
12 F7 visitors to Plast<strong>India</strong> 2012 will<br />
have the opportunity to see both the<br />
material and machine technology <strong>of</strong><br />
RAMPF from a single source. RAMPF<br />
Dosiertechnik will provide a live<br />
demonstration <strong>of</strong> the contour-precise<br />
application <strong>of</strong> a two-component<br />
system based on polyurethane <strong>of</strong><br />
the product range RAKU-PUR® on<br />
the DC-CNC low-pressure mixing and<br />
dispensing system.<br />
The company has specialized in<br />
the development, production and<br />
sale <strong>of</strong> polyure-thane, silicone and<br />
epoxy resin systems since 1980. Its<br />
product portfolio includes liquid<br />
and thixotropic sealing systems,<br />
electro casting resins, edge and filter<br />
casting resins and two-component<br />
adhesives. RAMPF Giessharze <strong>of</strong>fers<br />
solutions for all key industries around<br />
the globe.<br />
The compact DC-CNC dispensing cell<br />
is the optimum solution for the 2D<br />
or 3D ap-plication <strong>of</strong> casting, sealing<br />
and adhesive systems. The basic setup<br />
<strong>of</strong> the fully en-closed DC-CNC is<br />
equipped with an integrated control<br />
cabinet and a 2-component material<br />
conditioning system. Further features<br />
include the Siemens Sinumerik<br />
modular control system and<br />
integrated process control for<br />
continuous monitoring <strong>of</strong> pressure,<br />
fill level and speed. The mixing and<br />
dispensing system can optionally be<br />
equipped with a high-pressure rinse<br />
agent recycling system, high-pressure<br />
d e c e m b e r 2 0 1 1<br />
water rinsing or various items <strong>of</strong><br />
automation equipment depending<br />
on the application in question.<br />
With more than 2,200 system<br />
solutions on the market worldwide,<br />
RAMPF Dosiertechnik from Zimmern<br />
o.R., Germany, is one <strong>of</strong> the leading<br />
manufacturers <strong>of</strong> low-pressure<br />
mixing and dispensing systems and<br />
serves customers in the automo-tive,<br />
electrical, household appliance and<br />
filter industries. With a global service<br />
net-work and numerous branches<br />
in France, Spain, Eastern Europe,<br />
the United States, China, Korea and<br />
<strong>India</strong>, the company has a strong<br />
international presence.<br />
www.rampf-dosiertechnik.de<br />
With 2,200 system solutions on the market<br />
worldwide, RAMPF Dosiertechnik from<br />
Zimmern o.R., Germany, is one <strong>of</strong> the<br />
leading manufacturers <strong>of</strong> low-pressure<br />
mixing and dispensing systems. As a supplier<br />
<strong>of</strong> innovative systems for processing one-,<br />
two- and multi-component reaction resin<br />
systems, RAMPF Dosiertechnik serves<br />
customers in the automotive, electrical,<br />
household appliance and filter industries.<br />
Particular asset <strong>of</strong> the company, which is<br />
part <strong>of</strong> the international RAMPF Group since<br />
2003, is its broad-ranging product portfolio.<br />
This stretches from simple manual systems<br />
all the way through to fully automated<br />
production plants. RAMPF Dosiertechnik<br />
has carved out a name for itself on an<br />
international stage. With a global service<br />
network and numerous branches in France,<br />
Spain, East-ern Europe, the United States,<br />
China and Korea, the company has a strong<br />
international presence.<br />
www.rampf-giessharze.de<br />
RAMPF Giessharze GmbH & Co. KG,<br />
the nucleus <strong>of</strong> the RAMPF Group, is<br />
Technical Updates<br />
Abb.1: The working axle, material<br />
preparation and the dispensing technique<br />
<strong>of</strong> the DC-CNC is a com-pact unit.<br />
headquartered in Grafenberg, Germany.<br />
The company has specialized in the<br />
development, production and sale <strong>of</strong> polyurethane<br />
silicone, and epoxy resin systems<br />
since 1980. Its product portfolio includes<br />
liquid and thixo-tropic sealing systems,<br />
electro and engineering casting resins, edge<br />
and filter casting resins and two-component<br />
adhesives. RAMPF Giessharze <strong>of</strong>fers solutions<br />
for all key industries around the globe.<br />
POLYURETHANE FOAM<br />
MANUFACTURERS/IMPORTERS:<br />
We <strong>of</strong>fer TDI 80/20 and Polyether<br />
Polyol different grades for your direct<br />
import from our overseas suppliers.<br />
Please Contact:<br />
Global Impex Corporation<br />
# 4 Leela Nilayam, Road # 3,<br />
Tank Pakkadi, Sahar, Mumbai 400 099<br />
Telefax: 022-2822 8113<br />
Cell: 099876 37385<br />
E-mail: epgloimpex@ sify.com<br />
p o l y u r e t h a n e s t o d a y<br />
23<br />
PU<br />
<strong>Today</strong>
PU<br />
<strong>Today</strong><br />
Technical Article<br />
Cannon V.A.I.: Vacuum-Assisted Injection<br />
Technology for Refrigerators Production,<br />
Providing Cost-Effective Eco-design and Superior<br />
Energy Savings<br />
PIERO CORRADI<br />
Cannon Group<br />
Via Resistenza, 12<br />
Peschiera Borromeo (Milano) Italy<br />
Abstract<br />
Cannon announces the first<br />
industrial mass production <strong>of</strong><br />
domestic refrigerators manufactured<br />
with the new Cannon V.A.I. technology,<br />
a vacuum-assisted injection method<br />
specifically developed for the<br />
production <strong>of</strong> white cold appliances.<br />
An injection method introduced in<br />
1998 - applying vacuum into the mold<br />
cavity where insulated sandwich<br />
panels are manufactured with the<br />
discontinuous production process -<br />
the vacuum-assisted injection has<br />
now successfully been applied to<br />
the geometrically complex design <strong>of</strong><br />
domestic refrigerators.<br />
Prior to the foaming operation,<br />
a controlled degree <strong>of</strong> vacuum is<br />
applied into the jig where the empty<br />
refrigerator cabinet is positioned..<br />
The reduced pressure applied into<br />
the cavity during the injection and<br />
the expansion <strong>of</strong> the foam facilitates<br />
the filling <strong>of</strong> the cabinet, providing<br />
substantial benefits:<br />
l optimized distribution <strong>of</strong> foam<br />
density throughout the entire<br />
cabinet.<br />
l the polymerization time per<br />
foaming station has been cut nearly<br />
in half due to the possibility <strong>of</strong> using<br />
high reactivity formulations providing<br />
24 p o l y u r e t h a n e s t o d a y<br />
MAX TAVERNA<br />
Cannon Group<br />
Via Resistenza, 12<br />
Peschiera Borromeo (Milano) Italy<br />
a significantly higher productivity.<br />
l reduced plant’s floor space in half<br />
when using the new “twin” foaming<br />
fixture - the RotoJig – specifically<br />
conceived for this technology.<br />
A partnership with Dow allowed for<br />
the development <strong>of</strong> PASCAL , an<br />
innovative technological solution that<br />
draws new frontiers in the production<br />
<strong>of</strong> refrigerators. The new <strong>Polyurethane</strong><br />
chemistry, specifically developed<br />
for this application, reduces the<br />
foam thermal conductivity to a new<br />
reference level, while maintaining the<br />
density at least within the industry<br />
state-<strong>of</strong>-the-art levels and allowing<br />
for a shorter polymerization time.<br />
Several patents have been applied by<br />
the two companies in their respective<br />
fields <strong>of</strong> activity.<br />
In order to produce a refrigerator<br />
characterized by the same thermal<br />
conductivity in all its components,<br />
the vacuum-assisted injection<br />
technology has been extended to<br />
the door’s production method: the<br />
well known “Drum” Unit – a rotating<br />
multiple-mold manufacturing tool<br />
originally patented by Cannon in the<br />
early 1980’s – has been redesigned<br />
applying the vacuum capability,<br />
obtaining the same advantages<br />
described for the cabinets.<br />
The presentation <strong>of</strong> this Paper will<br />
be illustrated by a video, featuring<br />
the vacuum-assisted injection system<br />
during the validation phase, and<br />
by the updated results <strong>of</strong> the first<br />
industrial plant in operation at<br />
HAIER, the major global appliances<br />
producer based in P.R. <strong>of</strong> China.<br />
Initial Developments<br />
An innovative method for foaming<br />
sandwich insulation panels using<br />
vacuum during the injection phase was<br />
jointly developed – back in 1998 – by<br />
MISA (an Italian panel manufacturer),<br />
Manni (a polymerization press<br />
manufacturer), Cannon (the foaming<br />
machine producer) and Dow Italia<br />
(the supplier <strong>of</strong> the <strong>Polyurethane</strong><br />
chemicals). Its functioning concept<br />
relied on the controlled application<br />
<strong>of</strong> vacuum into the polymerization<br />
cavity <strong>of</strong> the press, maintaining a<br />
constant level <strong>of</strong> negative pressure<br />
within the polymerization cavity<br />
during the entire injection and foam<br />
expansion’s time (Picture 1). High<br />
productivity (more than 300 large<br />
Picture 1 – Manufacture <strong>of</strong> sandwich panels<br />
with V.A.I. (Vacuum Assisted Injection)<br />
technology<br />
d e c e m b e r 2 0 1 1
panels per shift), enhanced panel<br />
quality, savings in raw materials<br />
and labor cost, and a very clean<br />
workplace characterized this new<br />
process (Picture 2). Blowing agents<br />
with a wider range <strong>of</strong> boiling points<br />
could be used and, very remarkable,<br />
Picture 2 – Demolding time greatly reduced<br />
due to the effect <strong>of</strong> vacuum during foam<br />
injection<br />
polyisocyanurate foam could be easily<br />
processed with the new injection<br />
technique. The resulting panels were<br />
filled with a foam characterized by an<br />
almost perfect distribution <strong>of</strong> density<br />
across the entire length (thus avoiding<br />
overweight, a widely used practice to<br />
guarantee a minimum safe density in<br />
the most remote corners <strong>of</strong> the panel)<br />
and by very high values <strong>of</strong> adhesion<br />
between foam and metal facings<br />
(deriving from the very low level <strong>of</strong><br />
water required in the formulation to<br />
provide expansion, a practice which<br />
avoids the production in the foam<br />
<strong>of</strong> undesired Urea crystals that spoil<br />
adhesion properties).<br />
The Vacuum Effect<br />
As shown in Picture 3, the Pressure<br />
vs. Time graph shows the build-up<br />
<strong>of</strong> pressure in the polymerization<br />
cavity. The practice shows that safe<br />
demolding (when a panel can be<br />
demolded without the risk <strong>of</strong> swelling)<br />
can be performed at a residual<br />
pressure <strong>of</strong> approx. 200 mbar. The<br />
upper curve refers to a conventional<br />
d e c e m b e r 2 0 1 1<br />
Picture 3 – Demolding time shortens because<br />
<strong>of</strong> reduced pressure build-up in the mold<br />
Picture<br />
PUR formulation, and the demolding<br />
time can be reached after 1800 s<br />
for a given thickness. The lower<br />
curve, referring to a vacuum-assisted<br />
injection system, shows that the<br />
application <strong>of</strong> 500 mBar <strong>of</strong> vacuum<br />
in the polymerization cavity allows to<br />
fill it faster and with a lower residual<br />
pressure. This means that the moment<br />
for safe demolding can be reached<br />
earlier, approximately at 360 s.<br />
A faster demolding that occurs<br />
without any loss <strong>of</strong> mechanical<br />
properties: in fact the structure <strong>of</strong> the<br />
foam results much finer (due to the<br />
fast-reacting formulation that can be<br />
employed) and more homogeneous<br />
in density across the entire panel due<br />
to the lower effort that the expanding<br />
mass must spend to reach the remote<br />
corners <strong>of</strong> the cavity (Picture 4).<br />
Picture 4 – Initial development with vacuum<br />
assisted molding gave promising results<br />
The minimum density at which<br />
the cavity is fully filled with foam<br />
decreases as the pressure is reduced.<br />
Working at 0.7 bar in the mold, the<br />
minimum filling density lowers by<br />
Technical Article<br />
25%. (It has to be said that this huge<br />
savings cannot be fully exploited in<br />
practical terms <strong>of</strong> thermal insulation,<br />
since the mechanical properties <strong>of</strong><br />
foam are also directly linked with its<br />
final molded density.) What can be<br />
concluded at this respect is that the<br />
applied vacuum helps the foam flowproperties,<br />
and the minimum filling<br />
density is significantly reduced.<br />
New Ideas Are Born<br />
It goes without saying that the<br />
successful use <strong>of</strong> vacuum-assisted<br />
injection immediately stimulated<br />
the idea to extend this technology<br />
to other application fields, beginning<br />
with the production <strong>of</strong> refrigerators<br />
and freezers. The technical problems<br />
– and the deriving advantages –<br />
were common among the two<br />
industries, but basic differences<br />
were to be found in the geometry <strong>of</strong><br />
their respective final products. While<br />
it proved sufficiently easy to apply<br />
vacuum in the regular polymerization<br />
cavity <strong>of</strong> a sandwich panel and to<br />
obtain a perfect result, the complex<br />
geometry <strong>of</strong> a refrigerator’s cabinet<br />
immediately showed that much more<br />
engineering work was demanded to<br />
guarantee the same performance in<br />
a fridge: a 3D part with a complex<br />
inner core, “the plug” (Picture 5).<br />
Several metal parts must be moved<br />
hundreds <strong>of</strong> times per shift, in order<br />
to lock the refrigerator cabinet into<br />
its foaming position. Various sizes <strong>of</strong><br />
cabinets must be feasible in the same<br />
Picture 5 – A combi refrigerator shows the<br />
difficult geometry, difficult to be filled with<br />
conventional foam and vacuum<br />
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foaming station, thus requiring an<br />
almost automatic adjustment <strong>of</strong> the<br />
jig’s walls, to be performed quickly.<br />
The foaming concept had to be rethought,<br />
as well as the design <strong>of</strong> the<br />
required tool.<br />
The same approach had to be followed<br />
for the chemical side, for the very good<br />
reason that a major change in foaming<br />
technology would not be adopted by<br />
the appliance manufacturers if the<br />
obtained savings were not more than<br />
substantial in terms <strong>of</strong> foam’s lambda<br />
value, demolding time and molded<br />
density. Here, too, a major amount<br />
<strong>of</strong> R&D work was demanded to the<br />
chemical specialists.<br />
The V.A.I. Project<br />
Cannon approached this project<br />
– named V.A.I. (Vacuum Assisted<br />
Injection) – using the human, financial<br />
and technical resources available<br />
in their two Divisions involved in<br />
refrigerators manufacturing: Cannon<br />
Afros for the metering and mixing<br />
equipment, and Cannon Crios for the<br />
cabinet’s polymerization and handling<br />
solutions. A team <strong>of</strong> specialists<br />
identified a number <strong>of</strong> technical<br />
problems, and soon started to suggest<br />
various hypothetically viable solutions,<br />
to be ground tested in Cannon R&D<br />
laboratories. The development work<br />
took several months.<br />
After a number <strong>of</strong> unsuccessful<br />
attempts with available formulations<br />
modified on purpose, a new,<br />
dedicated chemistry was developed<br />
by Dow. Cannon in the meantime<br />
designed the first industrial solution<br />
for the production jig.<br />
The V.A.I. Jig construction<br />
The new jig has the same functionality<br />
and movements <strong>of</strong> a standard jig but<br />
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its lateral sides, the upper plate<br />
which holds the plug and the top and<br />
bottom walls are fitted with special<br />
seals that, when the jig is locked,<br />
provide an airtight cavity (Picture 6).<br />
The vacuum is applied through the<br />
upper plate. The main difference<br />
Picture 6 – The Cannon V.A.I. foaming jig<br />
with a standard polymerization jig<br />
is the use <strong>of</strong> a sliding plate, called<br />
pallet, where the back wall <strong>of</strong> the<br />
fridge rests. This pallet is sliding in<br />
and out from the jig for the cabinet’s<br />
loading and unloading operations.<br />
It is not recirculated around the<br />
plant and thus can be permanently<br />
connected to a hot water circuit for a<br />
very efficient thermostatization.<br />
The V.A.I. module:<br />
Productivity/investment<br />
optimization<br />
An industrial foaming plant based<br />
on V.A.I. jig is typically composed <strong>of</strong><br />
eight jigs placed side-by-side, each <strong>of</strong><br />
them served by one loading and one<br />
unloading conveyor (Picture 7). The<br />
two automatic devices travel above<br />
these conveyors: the loader picks the<br />
empty, warm cabinet coming from<br />
Picture 7 – A typical foaming plant with<br />
eight Cannon V.A.I. foaming jigs<br />
the pre-heating oven (on the far right<br />
<strong>of</strong> the plant) and carries it towards<br />
the jig that has produced the latest<br />
cured cabinet. The unloader picks it<br />
from the pallet where it is carried,<br />
and moves to the left <strong>of</strong> the plant to<br />
the discharge area. In the meantime<br />
the loader moves right over the pallet<br />
and unloads on it the empty cabinet,<br />
which immediately is brought in<br />
the waiting jig. The cycle starts, as<br />
described before. Productivity <strong>of</strong><br />
this configuration can be up to two<br />
cabinets per minute.<br />
V.A.I. – Main Advantages<br />
Several innovative features provide a<br />
number <strong>of</strong> interesting advantages:<br />
l Faster demolding time, up to 50%<br />
less than with conventional foams<br />
l The system is suitable for difficult<br />
cabinet geometries: even the<br />
combined use <strong>of</strong> VIP (Vacuum<br />
Insulated Panels) is possible, since<br />
the foam filling operation is much<br />
easier than with a slow, conventional<br />
formulation.<br />
l k-factor values <strong>of</strong> the foamed<br />
refrigerators are very low, due to the<br />
finer cell structure and the very even<br />
distribution <strong>of</strong> densities across the<br />
entire cabinet.<br />
The Rotojig Development<br />
In order to reduce the service time<br />
to get full advantage <strong>of</strong> this new<br />
fast curing formulation, Cannon<br />
developed a new solution for the<br />
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polymerization jig, by designing a<br />
rotating jig holding two fixtures fitted<br />
on the opposite sides <strong>of</strong> a common<br />
platform. In this way the foot print<br />
<strong>of</strong> the plant can be halved, also<br />
reducing the travelling time <strong>of</strong> the<br />
mixhead overhead carrier and the<br />
cabinet’s loading and unloading<br />
carts.<br />
The concept derives from a wellproven<br />
Cannon solution, the RotoPlug<br />
system. Patented by Cannon Crios<br />
in the early 1980’s, the RotoPlug<br />
polymerization jig hosts two male<br />
plugs mounted on the opposite sides<br />
<strong>of</strong> a rotating platform. While the<br />
lower plug is in the polymerization<br />
phase, the upper plug stands on the<br />
upper side, where adjustment and<br />
maintenance work can be executed<br />
without interrupting the production<br />
cycle.<br />
An evolution <strong>of</strong> the RotoPlug, the<br />
new RotoJig was designed and built<br />
for the VAI project. In this version,<br />
at the end <strong>of</strong> the foam-filling phase<br />
the entire jig - not only the male<br />
plug - is rotated (Picture 8). Curing<br />
occurs in the upper station while<br />
loading, unloading, foam injection<br />
Picture 8 – The Cannon RotoJig features two<br />
foaming jigs rotating on a common platform.<br />
Injection <strong>of</strong> chemicals, under vacuum, occurs<br />
in the bottom position, foam curing in the<br />
upper one.<br />
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and cavity filling occurs in the lower<br />
one (Picture 9).<br />
Picture 9 – A RotoJig during the validation<br />
phase, at Cannon Afros R&D laboratory in<br />
Italy<br />
The foaming cycle <strong>of</strong> a RotoJig station<br />
can be described as follows:<br />
l The large metal plate where the<br />
back <strong>of</strong> the fridge will rest (the pallet)<br />
fully slides out from the RotoJig to a<br />
nearby handling station. An empty<br />
cabinet, arriving from a pre-heating<br />
oven, is laid on the pallet, which reenters<br />
in the foaming station.<br />
l Once it is in position, the pallet with<br />
the cabinet is lifted towards the male<br />
plug, the four lateral mold’s walls are<br />
closed on the cabinet and the entire<br />
jig is locked. The cabinet is now held<br />
in position on its six sides, and all the<br />
foamed seals mounted to keep the<br />
vacuum in the jig are compressed<br />
by the walls.<br />
l The mixing head, which is mounted<br />
on a sliding support, is introduced in<br />
front <strong>of</strong> the injection hole, positioned<br />
in the refrigerator’s compressor<br />
cavity.<br />
l Vacuum is applied throughout the<br />
entire cavity containing the empty<br />
cabinet. In a few seconds most <strong>of</strong><br />
the contained air is extracted and<br />
the vacuum level reaches the desired<br />
value (around 300 mbar).<br />
Technical Article<br />
l The foam injection starts: metered<br />
by a high-pressure two-component<br />
dosing unit, the chemicals are mixed<br />
within the mixing head that works<br />
with an output rate at approximately<br />
1.5-2 kg/s. The desired amount <strong>of</strong><br />
foam – that for a large 2 m high<br />
Combi freezer&fridge model can<br />
reach 9 kg <strong>of</strong> weight – is injected<br />
in 4 to 6 seconds in the cabinet’s<br />
empty cavity, between the external<br />
metal sheet and the internal plastic<br />
liner. The vacuum level is maintained<br />
constant during the entire injection<br />
and foam-filling operation, so that<br />
the expansion <strong>of</strong> the foam can be<br />
helped by the vacuum in the very<br />
same way from the first to the last<br />
moment <strong>of</strong> this delicate phase.<br />
l Helped by this favorable condition,<br />
the foam rapidly fills the complex<br />
cavity and is distributed evenly in<br />
the most remote corners and thinner<br />
parts <strong>of</strong> the cabinet’s walls.<br />
l At the end <strong>of</strong> this phase the vacuum<br />
is no longer required and the cabinet,<br />
held between the male plug and<br />
the lateral walls, is moved with a<br />
180° platform’s rotation from the<br />
lower position <strong>of</strong> the station to the<br />
upper one; it will rest there for the<br />
remaining cycle time.<br />
l When the foam ends its curing phase,<br />
becoming firm and dimensionally<br />
stable, then another 180° rotation<br />
<strong>of</strong> the platform brings it back to the<br />
lower level: here, in the meantime,<br />
another cabinet was loaded, foamed<br />
and waited to “go up” for the curing<br />
phase. One 180° rotation <strong>of</strong> the<br />
platform does the two jobs at the<br />
same time: it sends up a foamed<br />
cabinet for curing, and brings down<br />
a cured cabinet for extraction in a<br />
masked time.<br />
l The pallet holding the cured<br />
cabinet is automatically extracted<br />
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from the RotoJig and goes to the<br />
nearby handling station: here the<br />
ready cabinet is automatically<br />
removed, an empty cabinet is laid<br />
on the pallet, which re-enters in<br />
the foaming station for the next<br />
injection cycle.<br />
When using a RotoJig plant instead <strong>of</strong><br />
a single V.A.I. jig further advantages<br />
are immediately understandable:<br />
with two curing stations working<br />
with one shifting injection head or<br />
two fixed injection heads.<br />
l Factory floor space is cut by 50% for<br />
the same daily product output.<br />
l Cycle time is further reduced due to<br />
shorter travelling paths <strong>of</strong> the mixing<br />
head carrier and loading/unloading<br />
carts<br />
Cabinet Performances<br />
Refrigerator cabinets produced with the<br />
PASCAL Technology are characterized<br />
by the lowest levels <strong>of</strong> k-factor value<br />
among all the <strong>Polyurethane</strong>-insulated<br />
fridges made with single injection<br />
technology. Thermal transmission<br />
coefficients <strong>of</strong> 18.0 – 18.5 mW m °K<br />
(at 10 °C) have been measured after<br />
evaluation trials run on commercial<br />
refrigerators foamed with the PASCAL<br />
Technology by a major refrigerator’s<br />
manufacturer.<br />
The first industrial products made<br />
with this technology can be sold within<br />
the A++++ Energy Conservation<br />
Class and an Energy Consumption<br />
Value <strong>of</strong> 0.19 kWh per day by HAIER<br />
in China (Picture 10).<br />
Since 2006 Cannon has filed four<br />
international patents related to<br />
this process – two <strong>of</strong> them are<br />
published.<br />
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Picture 10 – The first industrially-produced<br />
refrigerators made with the V.A.I. – PASCAL<br />
technology by HAIER<br />
Doors<br />
In order to produce a refrigerator<br />
characterized by the same thermal<br />
conductivity in all its components,<br />
the new vacuum-assisted injection<br />
technology has been extended to<br />
the door’s production method: the<br />
well known “Drum” Unit – a rotating<br />
multiple-mold manufacturing tool<br />
originally patented by Cannon in the<br />
early 1980’s – has been redesigned<br />
applying the vacuum capability,<br />
obtaining the same advantages<br />
described for the cabinets (Picture<br />
11). A four-mold version has been<br />
designed, able to manufacture one<br />
large door or two small ones every<br />
50 s.<br />
Picture 11 – A Cannon Drum-4 Unit for the<br />
production <strong>of</strong> refrigerator’s doors using the<br />
V.A.I. – PASCAL technology<br />
Technical Article<br />
The Drum unit’s functional sequence<br />
can be described as follows:<br />
l At the end <strong>of</strong> a polymerization<br />
phase the mold opening device<br />
opens the lower part <strong>of</strong> the mold<br />
standing in vertical position.<br />
l The lower mold half is tilted by 45°<br />
towards the operator.<br />
l The operator – standing in front <strong>of</strong><br />
one <strong>of</strong> the four molds, opened for<br />
the service operations – extracts a<br />
filled door from its polymerization<br />
cavity and fits one empty door shell<br />
in the mold.<br />
l The conveyor is rotated by 90° and<br />
the mold is automatically closed in<br />
its horizontal position.<br />
l The mixing head is inserted in the<br />
injection hole, vacuum is applied<br />
into this empty mold, the injection<br />
<strong>of</strong> chemicals starts, the mold is filled<br />
in very few seconds.<br />
l The Drum can be rotated again<br />
by 90°. The filled mold enters in the<br />
polymerization area that covers two<br />
<strong>of</strong> the four positions <strong>of</strong> the Drum and<br />
a sequence like the one described<br />
above is performed.<br />
Dow – Pascal<br />
Within the Dow-Cannon partnership<br />
agreement, Dow has been working<br />
on the chemistry side for an indepth<br />
PU system re-design aiming<br />
at developing new solutions able<br />
to capture the maximum PU foam<br />
performance advantages while<br />
using the vacuum-assisted injection<br />
technology, irrespective to the<br />
blowing agent employed.<br />
This fundamental R&D work has led<br />
to the development <strong>of</strong> a completely<br />
new series <strong>of</strong> PU systems that are<br />
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the core <strong>of</strong> the Dow Pascal TM<br />
technology which, in essence,<br />
combine the application <strong>of</strong> lower inmold<br />
pressure to achieve maximum<br />
PU foam insulation and process<br />
performance.<br />
Lower in-mold pressure results in:<br />
l Easier flow due to the resulting<br />
lower cavity’s back-pressure<br />
l Better demolding time due to the<br />
lower foam pressure in-mold at the<br />
time <strong>of</strong> demolding the units (Picture<br />
3)<br />
Improved flow gives options for<br />
improving foam k-factor hence<br />
cabinet’s energy consumption using<br />
fast reactive PU foam systems without<br />
penalties on density and demolding<br />
as it happens with the conventional<br />
foaming process. As known, PU foam<br />
k-factor is the sum <strong>of</strong> three main<br />
contributions:<br />
k-f PU foam = k gas + k solid +<br />
k radiative<br />
Fast reactive systems are known to<br />
give very uniform and finer cell size<br />
showing improved foam k-factor as<br />
a consequence <strong>of</strong>:<br />
l Optimized cell gas composition<br />
(best balance <strong>of</strong> CO2 and physical<br />
Blowing Agent) enhancing the k gas<br />
contribution<br />
l Finer cell size enhancing the k radiative<br />
contribution (Pictures 12 and 13)<br />
In this case, the finer foam cell<br />
size well explains the k-factor<br />
improvement according to the Booth<br />
equation [1].<br />
S ome <strong>of</strong> the main PU foam<br />
characteristics <strong>of</strong> the new Pascal TM<br />
technology system compared to<br />
standard K and Low K C-Pentane<br />
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Picture 12 – Picture from Standard K foam,<br />
cell size 270 – 300 micron<br />
Picture 13 – Picture from Pascal TM foam, cell<br />
size 150 – 180 micron<br />
blown systems now in the market<br />
are summarized in the following<br />
table (average data measured from<br />
a foamed Combi-Bottom freezer<br />
European cabinet design, 178 x 60<br />
x 60 cm):<br />
Reference PU System Standard Low Pascal TM<br />
k-factor C-p k-factor C-p TM System<br />
System reactivity (sec) 40 38 20<br />
Applied density (kg/m3) Reference +3% Reference<br />
Foam k-factor at 10°C (mW/m.K) 20.5 19.7 18.5<br />
Average cell size (micron) 270 - 300 240 – 270 150 - 180<br />
Demolding time (min) 5 5 2.5<br />
Haier<br />
The first industrial plant for the<br />
application <strong>of</strong> the PASCAL Technology<br />
was designed for HAIER, the world<br />
leader in the manufacture <strong>of</strong><br />
refrigerators and a major player<br />
in the entire appliance industry.<br />
Confronted with the need to <strong>of</strong>fer an<br />
extremely efficient refrigerator model<br />
within their wide catalogue, HAIER<br />
decided to invest in a completely new<br />
concept <strong>of</strong> a foaming plant to achieve<br />
their goal. DOW and Cannon jointly<br />
discussed the technical options<br />
with HAIER, and defined the most<br />
appropriate solution for a fastdemolding<br />
foaming plant.<br />
Sixteen VAI jigs, in two rows <strong>of</strong> eight<br />
jigs each, are fed by two high pressure<br />
metering units through four mixing<br />
heads mounted on traverse carriers<br />
(Picture 14). One loading and one<br />
unloading aerial carts handle each<br />
row <strong>of</strong> eight jigs. Vacuum to the jigs<br />
Picture 14 – The first industrial plant using<br />
the V.A.I. – PASCAL technology is in<br />
production at Haier, P.R. <strong>of</strong> China<br />
is provided by two separate vacuum<br />
pumps with accumulators. If needed,<br />
the vacuum pumps can be switched<br />
between the two rows <strong>of</strong> jigs to<br />
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ensure uninterrupted service to the<br />
entire plant. Also the two metering<br />
units are fully interchangeable, should<br />
one <strong>of</strong> them be stopped.<br />
Due to the fast demolding properties<br />
<strong>of</strong> the PASCAL Technology, HAIER<br />
achieved for this first plant a<br />
production capacity <strong>of</strong> one unit every<br />
15 seconds. The thermal insulation<br />
performance <strong>of</strong> these models is<br />
rated A++++ and the new line <strong>of</strong><br />
refrigerators, launched at the World<br />
Appliance Expo in Shanghai on March<br />
16, 2011 – is getting a very positive<br />
response from the consumers. The<br />
PASCAL Technology used for this<br />
refrigerator contributes for 5% to the<br />
energy savings.<br />
A very positive environmental impact<br />
already oriented a wide number <strong>of</strong><br />
Chinese consumers towards this model<br />
<strong>of</strong> refrigerator for their home.<br />
The emissions deriving from the use<br />
<strong>of</strong> this white appliance are calculated<br />
d e c e m b e r 2 0 1 1<br />
to be reduced by an average <strong>of</strong> 8 kg <strong>of</strong><br />
CO 2 -equivalent per every year <strong>of</strong> use<br />
<strong>of</strong> the refrigerator.<br />
Conclusions<br />
The vacuum-assisted injection<br />
has been successfully applied to<br />
the complex design <strong>of</strong> domestic<br />
refrigerators. A partnership between<br />
Cannon and Dow allowed for the<br />
development <strong>of</strong> PASCAL, we believe<br />
it is an innovative technological<br />
solution that draws new frontiers in<br />
the production <strong>of</strong> refrigerators.<br />
The reduced pressure applied into<br />
the cavity during the injection and<br />
the expansion <strong>of</strong> the foam facilitates<br />
the filling <strong>of</strong> the cabinet, providing<br />
substantial benefits:<br />
l optimized distribution <strong>of</strong> foam<br />
density throughout the entire<br />
cabinet.<br />
l the polymerization time per foaming<br />
station has been cut nearly in half<br />
due to the possibility <strong>of</strong> using high<br />
reactivity formulations providing a<br />
significantly higher productivity.<br />
l reduced plant’s floor space in half<br />
when using the new “twin” foaming<br />
fixture - the RotoJig – specifically<br />
conceived for this technology.<br />
The new <strong>Polyurethane</strong> formulation,<br />
specifically developed for this<br />
application, reduces the foam thermal<br />
conductivity to a new reference level,<br />
while maintaining the density at list<br />
within the industry state <strong>of</strong> the art<br />
levels and allowing for a shorter<br />
polymerization time.<br />
p o l y u r e t h a n e s t o d a y<br />
References<br />
1. H. Kramer, V. Parenti, “Novel rigid<br />
polyurethane formulations <strong>of</strong>fering<br />
combined high energy efficiency and<br />
fast productivity for outstanding<br />
performance in the domestic appliance<br />
industry”, Proceeding the 2007 CPI<br />
Conference, Orlando USA.<br />
Vydro®: Smart Water Management Substrate Set<br />
to Transform Green Ro<strong>of</strong> & Vertical Walls Market<br />
Skygardens are a growing phenomenon.<br />
In towns and cities around the world,<br />
a quiet architectural revolution is<br />
occurring. At first glance the changes<br />
might not be noticeable, particularly<br />
from street level, but look closely<br />
at the skyline or out <strong>of</strong> a high-rise<br />
window and the transformation might<br />
become more apparent.<br />
Slowly but surely, green ro<strong>of</strong>s and<br />
skyrise gardens are being added to<br />
public and private buildings in a<br />
quantum shift in the s<strong>of</strong>t landscaping<br />
<strong>of</strong> our metropolitan areas.<br />
Driven by the need to respond to<br />
climate change, many government<br />
authorities are now actively<br />
encouraging architects and<br />
construction companies to make<br />
green or ‘living’ ro<strong>of</strong>s a standard<br />
design feature in new buildings.<br />
As part <strong>of</strong> a wider drive on sustainability,<br />
building certification programs such<br />
as BREAM [1] and LEED (Leadership in<br />
Energy and Environmental Design)<br />
now acknowledge the importance<br />
<strong>of</strong> green ro<strong>of</strong>s. As such, many<br />
Technical Article<br />
construction-related credit systems,<br />
grants and other financial incentives<br />
are being put in place to encourage<br />
adoption and new ro<strong>of</strong>ing-related<br />
legislation is also coming into force.<br />
In 2010, in a bid to become the world’s<br />
first carbon neutral city, Copenhagen<br />
introduced a mandatory green ro<strong>of</strong><br />
policy. Legally, all new buildings in<br />
the Danish capital with a ro<strong>of</strong> pitch<br />
<strong>of</strong> less than 30 degrees now have<br />
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to feature some sort <strong>of</strong> green or soil<br />
element. [2] The city <strong>of</strong> Toronto has<br />
also introduced similar by-laws and<br />
other major urban centers are sure<br />
to follow suit.<br />
Widely regarded as an effective tool<br />
in the creation <strong>of</strong> sustainable, low<br />
carbon developments, green ro<strong>of</strong>s<br />
have an array <strong>of</strong> public and private<br />
benefits. When developed correctly<br />
they can:<br />
Assist with water management:<br />
By retaining rainwater for plant<br />
consumption, run <strong>of</strong>f is minimized<br />
reducing the risk <strong>of</strong> localized<br />
flooding.<br />
Improve a building’s insulating<br />
envelope: Adding an extra layer<br />
<strong>of</strong> insulation in the form <strong>of</strong> a green<br />
ro<strong>of</strong> can boost energy efficiency and<br />
reduce heating and cooling costs by<br />
up to 5%.<br />
Reduce the impact <strong>of</strong> urbanization:<br />
Plants improve urban air quality by<br />
filtering out polluting particles that<br />
can create smog. According to US<br />
industry association, Green Ro<strong>of</strong>s For<br />
Healthy Cities; “One square meter <strong>of</strong><br />
grass ro<strong>of</strong> can remove up to 2.0kg<br />
<strong>of</strong> airborne particles every year,<br />
depending on foliage type.” [3]<br />
Decrease the Urban Heat Island<br />
Effect (UHIE): Cities can be up to<br />
10 degrees hotter than rural areas<br />
because <strong>of</strong> the widespread use <strong>of</strong><br />
heat absorbing materials like concrete<br />
and asphalt. Adding more foliage<br />
into metropolitan areas reduces this<br />
problem.<br />
Improve biodiversity: Green ro<strong>of</strong>s<br />
provide a safe refuge for native insect,<br />
bird and animal species that<br />
might otherwise struggle to thrive<br />
amid a mass <strong>of</strong> concrete, glass and<br />
asphalt.<br />
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Counter urban sprawl: Green ro<strong>of</strong>s<br />
can help create a more aesthetically<br />
pleasing built environment. A<br />
sanctuary away from the hustle and<br />
bustle <strong>of</strong> metropolitan life they are<br />
more visually appealing and can serve<br />
as a relaxing outdoor space for the<br />
people that live, work or regularly<br />
visit a building. They can also reduce<br />
noise pollution by dampening sound<br />
and decreasing the number <strong>of</strong> hard<br />
surfaces available for sound to reflect<br />
<strong>of</strong>f.<br />
Reduce building maintenance<br />
costs: Green ro<strong>of</strong>s can dramatically<br />
increase a ro<strong>of</strong>’s life expectancy by<br />
shielding it from inclement weather.<br />
To realize all <strong>of</strong> these associated<br />
benefits, it is vital that the correct<br />
decisions are made when planning a<br />
green ro<strong>of</strong>. Until recently, the main<br />
materials available to specifiers<br />
were lava stone or heavy bulky<br />
substrates. While effective, these<br />
solutions can prove prohibitive<br />
when it comes to weight, ease <strong>of</strong><br />
installation and sustainability. <strong>Today</strong>,<br />
a new generation <strong>of</strong> lightweight,<br />
intelligent materials is emerging<br />
that have the ability to improve the<br />
construction, maintenance and longterm<br />
performance <strong>of</strong> green ro<strong>of</strong>s.<br />
The construction <strong>of</strong> green ro<strong>of</strong>s,<br />
skyrise gardens and vertical walls<br />
that enhance the sustainability <strong>of</strong> new<br />
buildings or properties undergoing<br />
renovation is now much easier<br />
thanks to an innovative growing<br />
substrate developed by Huntsman<br />
<strong>Polyurethane</strong>s.<br />
VYDRO® substrate is a unique<br />
hydrophilic material unlike any other<br />
currently available. Capable <strong>of</strong> storing<br />
up to 30 times its own weight in water,<br />
and retaining large amounts for a long<br />
period <strong>of</strong> time, this breakthrough<br />
smart water management solution is<br />
Technical Article<br />
a highly effective planting medium for<br />
intensive, extensive green ro<strong>of</strong>s and<br />
vertical walls.<br />
VYDRO® substrate works by locking<br />
in exactly the right balance <strong>of</strong> air and<br />
water needed to optimize successful<br />
plant development. Plant roots can<br />
easily penetrate the inert, PH-neutral<br />
open structured foam enabling rapid<br />
growth and improved crop yields:<br />
third party trials have shown that<br />
plants cultivated using VYDRO®<br />
substrate can generate 5% higher<br />
yields than those produced using<br />
conventional growing methods.<br />
VYDRO® water retention chart<br />
Proven to function where other<br />
materials fail, VYDRO® substrate<br />
enables the creation <strong>of</strong> green ro<strong>of</strong>s in<br />
locations where they were previously<br />
ruled out. In the case <strong>of</strong> vertical walls,<br />
VYDRO® substrate makes it possible<br />
to significantly reduce the costs (up<br />
to 50%) <strong>of</strong> the metal frame structure<br />
needed to sustain the vertical wall<br />
itself. With the ability to rehydrate<br />
over multiple growing cycles and a<br />
water buffering capacity <strong>of</strong> 60%, it can<br />
be used in hot, dry climates. And with<br />
weight savings <strong>of</strong> up to 70% on <strong>of</strong>fer<br />
compared to standard greenro<strong>of</strong>s<br />
systems. It can dramatically simplify<br />
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the installation <strong>of</strong> ‘living’ ro<strong>of</strong>s,<br />
particularly on properties where<br />
weight and structural strength are<br />
a critical factor, for example, in<br />
retr<strong>of</strong>itting older buildings. A one<br />
meter cubed area <strong>of</strong> VYDRO® substrate<br />
weighs just 30 kg. The same area <strong>of</strong><br />
lava stone weighs approximately<br />
1500 kg.<br />
VYDRO® living ro<strong>of</strong>s installed to<br />
date have reduced the weight <strong>of</strong> the<br />
standard substrate down virtually<br />
to zero. In fact, by using a “smart”<br />
solution, comprising a layer <strong>of</strong> VYDRO®<br />
substrate and a sedum carpet on top,<br />
it is possible to achieve a total weight<br />
<strong>of</strong> 40 kg/m2, including 30 l/m2 <strong>of</strong><br />
water retention.<br />
The standard VYDRO® build-up<br />
Weight 50-60 kg/m2 / slope <strong>of</strong> min.<br />
three degrees (Fully saturated)<br />
Super lightweight VYDRO® build-up<br />
a Total weight <strong>of</strong> 40 kg/m2, including<br />
30 l/m2 <strong>of</strong> water retention<br />
a Reduces installation cost.<br />
VYDRO® vertical walls, as mentioned,<br />
can help to drastically reduce total<br />
system weight, and ensure that the<br />
walls remain wet for longer periods<br />
than conventional substrates. In the<br />
VYDRO® vertical walls installed so far,<br />
it has been proven that the weight<br />
reduction achieved, had a strong<br />
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impact on the total installation cost<br />
(up to 40% cheaper, due the to lighter<br />
metal frame structure), <strong>of</strong>fering the<br />
same visual effect <strong>of</strong> the finished work<br />
as a standard vertical wall.<br />
VYDRO® build-up for light and<br />
efficient vertical walls<br />
a Total weight reduction<br />
a Installation cost up to 40%<br />
cheaper.<br />
Switching to VYDRO® substrate as<br />
a replacement green ro<strong>of</strong> substrate<br />
brings numerous other benefits.<br />
With superior insulating properties<br />
VYDRO® substrate can improve<br />
a building’s envelope, helping to<br />
minimize temperature loss, reduce<br />
energy consumption levels and cut<br />
heating and cooling costs by up to 5%.<br />
It can also:<br />
• Reduce the risk <strong>of</strong> flooding by<br />
minimizing rainwater run <strong>of</strong>f and<br />
retaining it for plant growth<br />
• Improve air quality: Green ro<strong>of</strong>s<br />
act as filters absorbing polluting<br />
particles that cause smog<br />
• Reduce noise pollution: Vegetation<br />
in cities dampens sound reflection<br />
<strong>of</strong>f hard surfaces<br />
• Minimize the Urban Heat Island<br />
Effect (UHIE): Cities are generally<br />
hotter than rural areas because<br />
<strong>of</strong> the widespread use <strong>of</strong> heat<br />
absorbing materials like concrete<br />
and asphalt. Adding more foliage<br />
into metropolitan areas in the form<br />
<strong>of</strong> green ro<strong>of</strong>s can help mitigate this<br />
problem<br />
• Improve biodiversity: Green ro<strong>of</strong>s<br />
provide a safe refuge for insects,<br />
birds and wildlife<br />
• Save time and money: VYDRO®<br />
substrate is inherently light and can<br />
be compressed, vacuum packed and<br />
shaped to ease transportation and<br />
installation logistics.<br />
Huntsman has a strong network <strong>of</strong><br />
VYDRO® substrate ro<strong>of</strong>ing partners in<br />
place across Europe and interest in the<br />
product is growing with a global list <strong>of</strong><br />
high-pr<strong>of</strong>ile reference sites.<br />
As well as transforming green<br />
ro<strong>of</strong>ing projects in the sustainable<br />
building sector, VYDRO® substrate<br />
is also expected to prove popular in<br />
agricultural initiatives. Its excellent<br />
water retention properties will enable<br />
growers to save money on irrigation<br />
costs, reduce water consumption and<br />
lessen their overall environmental<br />
impact. VYDRO® substrate can also be<br />
used in the manufacture <strong>of</strong> flowerpots<br />
and landscaping and sports projects.<br />
Conclusion<br />
VYDRO® substrate has been created by<br />
Huntsman <strong>Polyurethane</strong>s in response to<br />
some <strong>of</strong> the world’s major environmental<br />
concerns; water scarcity, climate change<br />
and increased urbanization.<br />
Finding new ways to tackle climate change<br />
and manage water in an intelligent way<br />
is vital, particularly in urban areas<br />
where populations are increasing and<br />
urbanization is having a stark impact on<br />
the environment. Getting more vegetation<br />
into cities and reducing the use <strong>of</strong> hard<br />
landscaping materials, is now a priority<br />
for many countries and installing green<br />
ro<strong>of</strong>s is an effective way to achieve this.<br />
With government legislation, financial<br />
incentives and new buildings standards<br />
encouraging the adoption <strong>of</strong> green ro<strong>of</strong>s,<br />
the sector is buoyant. What better time<br />
to launch VYDRO® substrate – a product<br />
that makes it far easier to create green<br />
ro<strong>of</strong>s and vertical walls, and helps embed<br />
smart water management capabilities<br />
into horticultural applications, bringing<br />
sustainability benefits to people and the<br />
planet.<br />
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Report: IPUA & Honeywell’s Seminar on<br />
Next Generation Blowing Agents for<br />
<strong>Polyurethane</strong> Foam<br />
Mumbai, November 4, 2011<br />
Honeywell Specialty Materials,<br />
in association with <strong>India</strong>n<br />
<strong>Polyurethane</strong> <strong>Association</strong> (IPUA)<br />
organized a conference for the <strong>India</strong>n<br />
<strong>Polyurethane</strong> Industry in Mumbai,<br />
<strong>India</strong> on 04th November, 2011.<br />
Titled ‘Next Generation Blowing<br />
Agents for <strong>Polyurethane</strong> Foam’<br />
the conference witnessed the<br />
participation <strong>of</strong> Honeywell Fluorine<br />
Products team led by Mr. Paul<br />
Sanders, Managing Director, Fluorine<br />
Products, EMEAI, Mr. Sanjeev Rastogi,<br />
Global Business Director, Honeywell<br />
– Foams and Mr. David Williams,<br />
Technical Director, Blowing Agents<br />
along with Mr. Mukesh Bhuta, Vice<br />
-Chairman, IPUA.<br />
The event also marked the launch<br />
<strong>of</strong> Honeywell’s new Solstice Liquid<br />
Blowing Agent by Paul Sanders and<br />
Sanjeev Rastogi in <strong>India</strong>. Speaking<br />
on the launch, Paul Sanders, said,<br />
“With Solstice Liquid Blowing Agent,<br />
we are pleased to announce the<br />
expansion <strong>of</strong> our family <strong>of</strong> lowglobal-warming-potential<br />
products,<br />
which are helping our customers<br />
around the world lower their carbon<br />
footprint while maximizing endproduct<br />
performance.”<br />
Delivering the key-note address,<br />
Mr. Mukesh Bhuta spoke about<br />
the current transition scenario and<br />
challenges for ozone depleting HCFC<br />
blowing agents in <strong>India</strong>. Speaking on<br />
the conference, he said, “The event<br />
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IPUA Ventures<br />
Mr. Paul Sanders, Managing Director, Honeywell Fluorine Products - EMEAI<br />
IPUA Vice Chairman Mr. Mukesh Bhuta<br />
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eceived an excellent participation<br />
especially from Mumbai and near<br />
by regions. IPUA and Honeywell<br />
will take this forward and conduct<br />
more such conferences across the<br />
country to meet our industry peers<br />
and educate them about these latest<br />
product developments.” Regarding<br />
the launch <strong>of</strong> Solstice Liquid Blowing<br />
agent from Honeywell Fluorine<br />
Products, Mr. Bhuta said, “ Looking<br />
at the information shared on Solstice<br />
Liquid Blowing Agent, it seems to be<br />
a very promising product with great<br />
potential to be a drop in solution to<br />
HCFCs and hydrocarbons and with<br />
improved product performance”.<br />
Technical papers presented at the<br />
conference by Honeywell’s David<br />
Williams and Ben Lu highlighted the<br />
Blowing Agent’s four dimensional<br />
excellence <strong>of</strong>fered through its<br />
energy efficiency performance,<br />
environmental impact, safety in use,<br />
and cost-effectiveness.<br />
The event was well attended by<br />
the <strong>India</strong>n Poyurethane Industry<br />
including leading system houses,<br />
PU panel manufacturers, domestic<br />
and commercial refrigerator<br />
manufacturers and spray foam<br />
companies.<br />
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Polyols for improved HR slabstock foams<br />
K.Pickin, Corporate Business Development Manager, PCC SE<br />
High resilience (HR) foams have<br />
been utilized by the furnishings<br />
and mattress manufacturing industry<br />
for decades, with several polyurethane<br />
raw material suppliers <strong>of</strong>fering<br />
various solutions. The key property<br />
driving the adoption <strong>of</strong> these types <strong>of</strong><br />
flexible foams compared to standard<br />
foams is superior comfort at the<br />
same foam density. However, despite<br />
their long history, wide adoption<br />
and the expertise <strong>of</strong> competent<br />
foam manufacturers these HR foams<br />
types have not been fully optimized<br />
in terms <strong>of</strong>, for instance, yield and<br />
physical properties.<br />
Introduction<br />
In recent years there has been<br />
a significant increase in the<br />
manufacture <strong>of</strong> HR foams in Europe<br />
and, as expected, HR foams are now<br />
attracting the attention <strong>of</strong> many foam<br />
manufacturers in North America and<br />
Asia. Foam manufacturers in <strong>India</strong><br />
who are seeking to expand their<br />
foam range into superior comfort,<br />
high quality applications will find<br />
this development particularly<br />
interesting. In discussion with<br />
customers, especially in relation to<br />
future developments, PCC Rokita, a<br />
subsidiary <strong>of</strong> PCC SE headquartered<br />
in Duisburg, Germany, was made<br />
aware <strong>of</strong> the potential improvements<br />
that customers would like achieve<br />
with their HR foams.<br />
Thus improved HR foam technology<br />
became a key element in PCC<br />
Rokita’s emerging product expansion<br />
strategy.<br />
With this knowledge the research and<br />
40 p o l y u r e t h a n e s t o d a y<br />
development experts then set about<br />
developing new materials to enable<br />
the production <strong>of</strong> a range <strong>of</strong> superior<br />
HR foams featuring:<br />
• High comfort factor<br />
• Excellent durability<br />
• Class leading shape retention<br />
• Low odour<br />
• Wide density/hardness range<br />
• High yield<br />
Rokopol iPol – a case history<br />
In addition to the usual in-depth<br />
technical expertise and production<br />
know-how <strong>of</strong> different high resilience<br />
foam technologies, to improve the<br />
final foam and in turn mattress<br />
comfort properties, a study was<br />
undertaken to provide a genuine<br />
understanding <strong>of</strong> the needs <strong>of</strong> the<br />
whole supply change. In this case<br />
study, within the section <strong>of</strong> the supply<br />
chain involving polyols producer to<br />
end user there are essentially four<br />
key levels:<br />
1. Polyols producer<br />
2. Foam manufacturer<br />
3. Mattress manufacturer<br />
4. Retailer/End user<br />
Traditionally the supply chain<br />
is viewed as a flow <strong>of</strong> materials<br />
going, in this case, from polyols<br />
supplier to foam manufacturer<br />
to mattress producer to end user.<br />
Information usually follows in the<br />
same direction. However adding a<br />
flow <strong>of</strong> information in the reverse<br />
direction from end user to mattress<br />
producer to foam manufacturer to<br />
polyols producer gives an insight in<br />
to the needs throughout the supply<br />
chain. With this valuable information<br />
it is possible to target exactly what<br />
should be improved to meet the<br />
needs <strong>of</strong> each level in the chain<br />
and ultimately add value for every<br />
member <strong>of</strong> that chain.<br />
The supply chain needs analysis for<br />
Rokopol iPol is illustrated below:<br />
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In this illustration the material flow<br />
is shown in the top section from left<br />
to right but the information flow<br />
informing what needs to be improved<br />
is from right to left as shown in the<br />
middle section. There are <strong>of</strong> course<br />
some overarching considerations<br />
such as statutory compliance which<br />
is indicated in the arrow headed text<br />
box. Clearly not every articulated<br />
need is listed here. It is important to<br />
note that information doesn’t have<br />
to be passed along in sequence;<br />
it can be very helpful to highlight<br />
needs directly to the company in<br />
the supply chain that can actually<br />
<strong>of</strong>fer a solution. Yes, talking to<br />
customers’ customers can be a source<br />
<strong>of</strong> friction but careful explanation <strong>of</strong><br />
the benefits <strong>of</strong> finding value-adding<br />
solutions throughout the supply<br />
chain was found to minimize any<br />
sensitivity.<br />
Needs examples range from the very<br />
specific “we want to reduce cold<br />
flow” (foam manufacturer), “we don’t<br />
want mattress cores snapping in two<br />
during transport/handling” (mattress<br />
producer) to generic “we would like<br />
more comfort” (user). Interpreting the<br />
causes <strong>of</strong> these weaknesses or sources<br />
<strong>of</strong> improvement and providing<br />
subsequent solutions brings tangible<br />
benefits to the relevant section <strong>of</strong> the<br />
supply chain.<br />
This solutions engineering involved<br />
the following series <strong>of</strong> activities<br />
leading to new polyol for HR foams.<br />
Benchmark existing HR<br />
technologies<br />
i<br />
Screen potential HR technologies<br />
for development<br />
i<br />
Select key improvements<br />
(determined from supply chain<br />
needs analysis)<br />
i<br />
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Develop candidate polyols<br />
i<br />
Develop effective foam<br />
formulations<br />
i<br />
Trials at foam manufacturers<br />
i<br />
Verification at mattress producer<br />
The overall aim was met:<br />
To <strong>of</strong>fer a polyol which enables foam<br />
manufacturers to produce a wide<br />
range <strong>of</strong> high yield, cost effective,<br />
durable high comfort foams.<br />
Easy processing<br />
Foam manufacturers highlighted the<br />
need for easy, fault free processing<br />
which in turn has a significant impact<br />
on end–<strong>of</strong>-line prime foam yield.<br />
They also needed to be able to provide<br />
consistent foams (e.g. minimise top/<br />
bottom variation) with a wide density<br />
and hardness range. By utilising<br />
extensive technical service knowhow<br />
to develop suitable practical<br />
foam formulations and working with<br />
leading foam manufacturers the<br />
following was achieved:<br />
• Easy Processing on trough<br />
or reciprocating head type,<br />
high or low pressure foam<br />
manufacturing machinery.<br />
• Wide Processing Window.<br />
• Simple Foam Formulations<br />
minimizing capital investment<br />
• Wide Density and Hardness<br />
range<br />
• High Yield with good Block<br />
Shape (no cold flow)<br />
• Excellent Density and Hardness<br />
Distribution<br />
Fire safety test compliance<br />
Depending on the geographic location<br />
and local regulatory or purchaser<br />
specified test criteria various fire test<br />
Special Feature<br />
standards must be complied with.<br />
Rokopol iPol technology <strong>of</strong>fers cost<br />
effective compliance by utilising low<br />
levels <strong>of</strong> halogenated fire retardants<br />
and /or melamine. Compliance<br />
examples:<br />
• FMVSS 302 (no flame retardant<br />
additive depending on foam<br />
density)<br />
• California 117 A and D (small<br />
amount <strong>of</strong> flame retardant<br />
additive)<br />
• Crib 5 BS 5852 part 2 (limited<br />
addition <strong>of</strong> flame retardant<br />
additive or without melamine)<br />
• B2 to EN ISO 11925-2 (limited<br />
addition <strong>of</strong> flame retardant<br />
additive or without melamine)<br />
Example formulation and physical<br />
properties <strong>of</strong> a CMHR type foam produced<br />
on a low pressure Maxfoam machine:<br />
Rokopol iPol M 90phr<br />
Rokopol M6000 10phr<br />
TDI Index 99<br />
Total water 2.53phr<br />
DEOA 1.02phr<br />
Antiblaze WR30 LV 15phr<br />
+ standard HR additives,<br />
NO melamine<br />
Density 41kg/<br />
m3<br />
CLD 40% 3.0kPa<br />
Tensile strength 130kPa<br />
Elongation 103%<br />
Compression set 5.5%<br />
22h/50%/70degC<br />
Sag factor 3.3<br />
Resilience (ball rebound) 65%<br />
BS5852 part 2 crib 5 Pass<br />
Data courtesy <strong>of</strong> CT Formpolster<br />
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Rokopol iPol typical<br />
properties<br />
Appearance homogeneous<br />
white liquid<br />
Hydroxyl value 50 mg KOH/g<br />
Water content max. 0.1%(m/m)<br />
Acid Value max. 0.1<br />
mgKOH/g<br />
Viscosity at 25 o C 3,000 mPas<br />
Density at 25 o C 1.047<br />
Low odour<br />
An issue reported by foam and<br />
mattress manufacturers alike is that<br />
<strong>of</strong> foam odour. Prevention is the<br />
key here. By elimination <strong>of</strong> odour<br />
creating components such as styrene,<br />
acrylonitrile, DBTDL catalyst and<br />
polymerisation initiator and with<br />
correct choice <strong>of</strong> ancillary chemicals<br />
at the foam manufacturing stage low<br />
odour foams were achieved.<br />
As an example, residual VOC (Volatile<br />
Organic Compound) tests carried out<br />
to LGA standard on a Rokopol iPol<br />
based foam <strong>of</strong> 60 kg/m3 density<br />
showed the following results:<br />
Total Emmissions 60 kg/m3 foam<br />
After 3 days 95 ppm<br />
After 7 days 25ppm<br />
As a comparison, typical levels<br />
for a similar styrene/acrylonitrile<br />
copolymer polyol foam are:<br />
220ppmm after 3days and 100ppm<br />
after 7days.<br />
Physical properties<br />
It is clear that all HR foams must meet<br />
customer specifications. However<br />
foam “touch” has an important part<br />
to play in conveying high quality<br />
d e c e m b e r 2 0 1 1<br />
and perceived comfort. Foam<br />
manufacturers and users frequently<br />
describe this touch as “latex- like”.<br />
In terms <strong>of</strong> measurable physical<br />
properties two items are generally<br />
considered to be associated with<br />
this feature:<br />
Resilience (ball rebound) and Sag<br />
Factor (extracted from stress/strain<br />
hysteresis data) where numerical<br />
values <strong>of</strong> >60% and >3 respectively<br />
are considered to be good results.<br />
Rokopol iPol derived HR foams<br />
are notable for their latex-like feel<br />
with externally verified foam tests<br />
showing up to almost 70% resilience<br />
and Sag Factors exceeding 3.3.<br />
Examples <strong>of</strong> externally independently<br />
measured physical properties for<br />
typical HR foams are given below:<br />
Property summary<br />
Throughout the supply chain<br />
performance targets were met or<br />
Special Feature<br />
exceeded. Each <strong>of</strong> the highlighted<br />
features below represents a value<br />
adding benefit for members <strong>of</strong><br />
the supply chain <strong>of</strong>ten creating<br />
important selling points for their<br />
direct customers.<br />
• Easy processing<br />
• High yield<br />
• Very High Resilience – up to 70%<br />
DIN 5357(Type A)<br />
• Latex-Like Comfort, Sag factor<br />
typically 3.3<br />
• First-Rate Compression Set<br />
• Excellent Flex Fatigue Properties<br />
• Superior Latex-Like Touch<br />
• Low Odour foams<br />
• Cost effective Fire Test Compliance<br />
Property Foam A Foam B Foam C Test Method Units<br />
Density 38.5 35 58 DIN EN ISO 845 kg/m3<br />
CLD 40% 2.5 2.72 4.1 EN ISO 3386-1 kPa<br />
Tensile Strength 108 123 103 EN ISO 1798 kPa<br />
Elongation to Break 110 116 93 EN ISO 1798 %<br />
Resilience 69 66 69 DIN 5357 (Type A) %<br />
Compression Set 3.4 3.7 2.2 DIN EN ISO1856 %<br />
(70 o C, 22hr, 50%)<br />
Flex Fatigue CLD Loss 18 24 n/a DIN EN ISO 3385 %<br />
Flex Fatigue Height Loss 1.5 2.8 n/a DIN EN ISO 3385 %<br />
p o l y u r e t h a n e s t o d a y<br />
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d e c e m b e r 2 0 1 1<br />
Environment & Safety<br />
China may agree to binding CO2 cuts - envoy<br />
By Stian Reklev | Reuters<br />
DURBAN (Reuters) - China gave<br />
U.N. climate talks a lift on Friday<br />
by confirming it may sign up to a<br />
legally binding deal to cut emissions<br />
<strong>of</strong> heat-trapping gases, a move<br />
that could help rescue talks about<br />
the future <strong>of</strong> the Kyoto Protocol,<br />
observers said.<br />
Delegates from more than 190<br />
nations are in the coastal city <strong>of</strong><br />
Durban to try to break a four-year<br />
deadlock to secure a new global deal<br />
that will bind countries to cut and<br />
slow down growth in emissions <strong>of</strong> six<br />
main greenhouse gases.<br />
“We do not rule out the possibility <strong>of</strong><br />
legally binding. It is possible for us,<br />
but it depends on the negotiations,”<br />
Su Wei, China’s lead negotiator, said<br />
- speaking in English - at a media<br />
briefing on the sidelines <strong>of</strong> the twoweek<br />
talks in South Africa.<br />
The EU has said it will sign up to a<br />
second round <strong>of</strong> targets under the<br />
1997 Kyoto Protocol, but only if all<br />
big emitters agree legally binding<br />
cuts that will start in 2020.<br />
So far, China, <strong>India</strong> and the United<br />
States, the world’s top three emitters,<br />
are not bound by Kyoto and have<br />
refused to commit to legal targets,<br />
raising the prospect that no country<br />
will have targets to cut emissions<br />
after 2012.<br />
“Since the EU is the only group <strong>of</strong><br />
parties that is ready to consider a<br />
second commitment period (under<br />
Kyoto) we are ready and willing to<br />
engage constructively with the EU,”<br />
said Su.<br />
Li Yan, a campaigner with Greenpeace<br />
China said, “China is trying to find a<br />
middle ground, especially with<br />
Europe, which would need to<br />
reconcile with China’s priorities for<br />
the conference, which are a second<br />
commitment period <strong>of</strong> the Kyoto<br />
Protocol and operationalisation <strong>of</strong><br />
the Green Climate Fund.”<br />
China wants negotiations to kick<br />
start a fund that would contribute<br />
to raising $100 billion a year by 2020<br />
to help the poorest nations adapt<br />
to climate change and cut their<br />
emissions.<br />
Traction<br />
Time is running out to reach<br />
agreement on a deal for meaningful<br />
cuts in the emissions blamed for<br />
worsening storms and raising sea<br />
levels to a point that would wipe out<br />
several small island states, experts<br />
said.<br />
Earlier in the day, senior EU negotiator,<br />
Tomasz Chruszczow, said the bloc’s<br />
plan to have a deal in place by 2015<br />
and entering into force in 2020 was<br />
“getting traction”.<br />
China has previously said it supported<br />
legal targets for others, but not for<br />
itself.<br />
The talks end on December 9 and<br />
South Africa’s President Jacob Zuma<br />
signalled the host is looking for a<br />
deal that puts more <strong>of</strong> an onus on<br />
rich nations to cut greenhouses gases<br />
than the developing nations most<br />
harmed by rising temperatures.<br />
Canada and Russia have bluntly<br />
So far, China, <strong>India</strong><br />
and the United States,<br />
the world’s top three<br />
emitters, are not bound<br />
by Kyoto and have<br />
refused to commit to<br />
legal targets, raising<br />
the prospect that no<br />
country will have<br />
targets to cut emissions<br />
after 2012.<br />
refused to sign another target under<br />
Kyoto, while Japan on Friday asked<br />
for a fresh look on a new treaty that<br />
encompasses all major emitters.<br />
Negotiators said the outline <strong>of</strong> the<br />
EU plan <strong>of</strong>fers a political cushion for<br />
many countries by setting 2015 as a<br />
deadline for a new deal, which would<br />
be implemented by 2020.<br />
Meanwhile, negotiators from small<br />
island states most at risk <strong>of</strong> rising<br />
sea levels want a new deal to start<br />
in 2013, although observers say this<br />
is highly unlikely to happen.<br />
Envoys could say they made<br />
progress in Durban by agreeing to<br />
an encompassing agreement, leaving<br />
the details <strong>of</strong> how the deal would<br />
work to a later date.<br />
(Additional reporting by Michael<br />
Szabo and Jon Herskovitz; Writing<br />
by Andrew Allan; Editing by Louise<br />
Ireland)<br />
p o l y u r e t h a n e s t o d a y<br />
45<br />
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PU<br />
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Previews & Reports<br />
Leading International Exhibition<br />
& Conference Celebrates 75 Years <strong>of</strong> Global<br />
<strong>Polyurethane</strong>s Industry<br />
UTECH Europe Exhibition and Conference, 17-19 April 2012, MECC, Maastricht, The Netherlands<br />
29 November 2011 – 75 years<br />
after Pr<strong>of</strong>. Otto Bayer’s initial patent<br />
marking the advent <strong>of</strong> polyurethanes<br />
chemistry in 1937, the organisers <strong>of</strong><br />
UTECH Europe 2012 taking place<br />
in Maastricht, The Netherlands 17-<br />
19 April, have announced the full<br />
speaker programme for the threeday<br />
conference and confirmed that<br />
the accompanying exhibition will<br />
be the biggest ever staged. Anyone<br />
wishing to book a place at the<br />
conference or register for the freeto-attend<br />
exhibition can now do so<br />
online at www.utecheurope.eu<br />
Often described as the hidden<br />
polymer, polyurethanes are ever<br />
more widely used throughout<br />
manufacturing and construction<br />
industries today. Applications are as<br />
diverse as automotive, aerospace,<br />
building and construction, furniture<br />
and bedding, electrical and electrotechnical,<br />
footwear and textiles,<br />
mining and <strong>of</strong>fshore, pipes and<br />
pipelines, refrigeration and insulation<br />
as well as specialist surgical and<br />
medical.<br />
The UTECH Europe 2012 exhibition<br />
and conference <strong>of</strong>fers materials<br />
specialists from across all these<br />
industries the perfect opportunity<br />
to see global advancements in<br />
polyurethane technology including<br />
all the latest products and machines.<br />
Among more than 100 exhibitors<br />
are industry leaders Bayer, BASF,<br />
Huntsman, BorsodChem, Wanhua,<br />
Shell, Repsol, Baule, Dow, Silcart<br />
and Evonik as well as systems<br />
houses, technical consultancies, and<br />
46 p o l y u r e t h a n e s t o d a y<br />
test laboratories.<br />
“Interest from exhibitors has been<br />
so strong that we have just had to<br />
extend the exhibition space to cater<br />
for increased demand and this too<br />
is selling fast,” said Sue Rothwell,<br />
Business Development Director at<br />
Crain Communications, organisers <strong>of</strong><br />
UTECH Europe. “This is set to be our<br />
most successful event ever.”<br />
Opening the UTECH Europe threeday<br />
conference will be a keynote<br />
presentation from Ding Jiansheng,<br />
Chairman <strong>of</strong> Yantai Wanhua<br />
<strong>Polyurethane</strong>s Co Ltd, China, leading<br />
into a Plenary Session focused on<br />
celebrating the 75th Anniversary<br />
<strong>of</strong> the invention <strong>of</strong> polyurethanes<br />
chemistry. Six further presentations<br />
look back over the history <strong>of</strong> the<br />
industry and assess its prospects for<br />
the future. Experts will discuss the<br />
development <strong>of</strong> the key raw materials<br />
and processing equipment used to<br />
make these versatile materials.<br />
In the afternoon <strong>of</strong> the first day two<br />
papers look at the development<br />
<strong>of</strong> and prospects for the global<br />
markets amid the current turmoil<br />
in the world’s leading economies,<br />
including a special report on the<br />
development <strong>of</strong> the polyurethanes<br />
industry in Indonesia. This is followed<br />
by an Innovations session, with eight<br />
papers detailing recent work from the<br />
world’s leading suppliers. The parallel<br />
session in the afternoon comprises 10<br />
papers looking at the latest advances<br />
in “Green” chemistry, raw materials<br />
based on renewable resources.<br />
The main technical conference<br />
continues through to 19 April, in a<br />
series <strong>of</strong> half-day sessions focused<br />
on the key technical developments<br />
in the use <strong>of</strong> polyurethanes to<br />
make rigid and flexible foams, and<br />
CASE products (coatings, adhesives,<br />
sealants and elastomers), with a<br />
separate session on the final day<br />
discussing more scientific approaches<br />
to the production <strong>of</strong> PU-based<br />
products.<br />
In addition to the technical<br />
programme, there will be separate<br />
sessions created by ISOPA (the<br />
European Diisocyanate and Polyols<br />
Producers <strong>Association</strong>) and the<br />
Polyurea Development <strong>Association</strong><br />
Europe. The first <strong>of</strong> these, in the<br />
afternoon <strong>of</strong> the second day <strong>of</strong> the<br />
conference, will address key safety,<br />
health and environmental issues<br />
including an overview <strong>of</strong> the latest<br />
life-cycle analysis work on rigid<br />
PU foams and details <strong>of</strong> the latest<br />
US legislation, Chemical Action<br />
Plans, and their likely impact on the<br />
industry.<br />
“In the 75th Year <strong>of</strong> <strong>Polyurethane</strong>,<br />
which is also the 25th anniversary<br />
<strong>of</strong> ISOPA, the visibility <strong>of</strong> this ‘hidden’<br />
polymer still has to be increased,”<br />
said Dr. Frank Wolfram, ISOPA’s<br />
Secretary General. “ISOPA will have<br />
a strong presence at UTECH Europe<br />
2012 and we look forward to seeing<br />
everyone in Maastricht.”<br />
“Our keynote speaker will be the<br />
ISOPA president Steven English<br />
and the ISOPA stand will convey<br />
d e c e m b e r 2 0 1 1
two key messages, which are both<br />
part <strong>of</strong> the special ISOPA session,”<br />
Wolfram continued. “These are<br />
the launch <strong>of</strong> our new Product<br />
Stewardship program Walk the<br />
Talk 2nd generation focusing on<br />
the requirements <strong>of</strong> REACH and an<br />
update <strong>of</strong> the new <strong>Polyurethane</strong><br />
Passive House Project in Brussels,<br />
which positions <strong>Polyurethane</strong> as the<br />
high performing and sustainable<br />
insulation material contributing to<br />
reduce Europe’s CO² emissions.”<br />
In the second special session,<br />
on the morning <strong>of</strong> the final day<br />
d e c e m b e r 2 0 1 1<br />
<strong>of</strong> the conference, 19 April, the<br />
latest commercial and technical<br />
developments relating to the fastgrowing<br />
polyureas market will be<br />
discussed.<br />
Last time the event was held in<br />
2009 visitors came from more<br />
than 85 dif ferent countrie s<br />
worldwide. In 2012, thousands are<br />
expected to travel to Maastricht<br />
for all the latest information on<br />
polyurethane technology from<br />
isocyanates, polyester polyols,<br />
polyether polyols, formulated<br />
systems and ancillary chemicals, as<br />
p u t o d a y a d v e r t i s e m e n t ta r i f f<br />
Previews & Reports<br />
Advertisement 1 Issue 2 Issues 4 Issues<br />
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Each Additional Page Rs 4000 (USD 100)<br />
well as surfactants, catalysts and<br />
flame retardants. Manufacturing<br />
technology innovations unveiled at<br />
the exhibition will include the latest<br />
cutting equipment and machinery<br />
for making flexible foams, rigid<br />
foams, elastomers, reaction injection<br />
moulding and test equipment.<br />
Anyone wishing to attend the<br />
paid-for UTECH Europe conference<br />
and the free-to-attend exhibition<br />
can now register online at www.<br />
utecheurope.eu A wealth <strong>of</strong> travel and<br />
accommodation information is also<br />
available on the event website.<br />
Service Tax is applicable at the rate <strong>of</strong> 10.30% as per Government rules. The Inside Front & Back Covers And Back Cover<br />
are already booked for the next four issues.<br />
Technical Details <strong>of</strong> the Ad<br />
Bleed Size: 8.5 In X 11 In (21.59 Cm W X 27.94 In H) (Letter Size)<br />
Print Area: 7 in x 9.24 in (17.8 cm W x 29.50 cm H)<br />
YOU HAVE TO SEND THE MATTER IN A PDF FILE OR EPS OR TIFF FORMATS<br />
ALL MATTER TO BE SENT TO<br />
Ramamurthy K<br />
Secretary<br />
INDIAN POLYURETHANE ASSOCIATION<br />
Flat 7, III Floor, Shakti Mahal, New 24, Old 41, First Main Road, CIT Colony,<br />
Mylapore, CHENNAI 600 004. Tel/Fax: 044 2499 5923, H/P: 94440 55923<br />
Email: ramamurthy_k2@dataone.in admin@pu-india.org ramapu42@gmail.com<br />
p o l y u r e t h a n e s t o d a y<br />
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48 p o l y u r e t h a n e s t o d a y<br />
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Book Description<br />
Publication Date: September 20, 2010<br />
A “Think Different” Approach to<br />
Innovation Based on The Seven Guiding<br />
Principles <strong>of</strong> Apple CEO Steve Jobs<br />
In his acclaimed bestseller The<br />
Presentation Secrets <strong>of</strong> Steve Jobs<br />
author Carmine Gallo laid out a simple<br />
step-by-step program <strong>of</strong> powerful tools<br />
and proven techniques inspired by Steve<br />
Jobs’s legendary presentations. Now, he<br />
shares the Apple CEO’s most famous,<br />
most original, and most effective<br />
strategies for sparking true creativity<br />
and real innovation in any workplace.<br />
The Innovation Secrets Of<br />
Steve Jobs<br />
“Steve Jobs has reinvented music<br />
distribution, the mobile telephone,<br />
and book publishing. You might want<br />
to take a look at how someone creates<br />
multi-billion dollar ideas, and turns<br />
them into multi-billion dollar products<br />
that everyone loves and admires. This<br />
book is not an option. Buy it now, bank<br />
it tomorrow.”<br />
– Jeffrey Gitomer, author <strong>of</strong> The Little<br />
Red Book <strong>of</strong> Selling<br />
“In The Innovation Secrets <strong>of</strong> Steve Jobs,<br />
Carmine Gallo captures the true mindset<br />
<strong>of</strong> Jobs and Apple. This book is not just<br />
for the techie and marketing crowd,<br />
although they will gain valuable insight<br />
that can be applied to their worlds. It is<br />
also for anyone who loves technology<br />
and wants to understand how to create<br />
simple devices that are easy to use and<br />
can impact our lives.”<br />
– Tim Bajarin, president, Creative<br />
Strategies, Inc.<br />
“An inspiring roadmap for anyone<br />
who wants to live a life <strong>of</strong> passion and<br />
purpose.”<br />
d e c e m b e r 2 0 1 1<br />
– Tony Hsieh, author <strong>of</strong> Delivering<br />
Happiness and CEO <strong>of</strong> Zappos.com,<br />
Inc.<br />
“Apple changed the world with the Mac<br />
and hasn’t stopped innovating since.<br />
Carmine Gallo reveals the secrets and<br />
gives you the tools to unleash your<br />
inner Steve.”<br />
– Marc Beni<strong>of</strong>f, chairman and CEO<br />
<strong>of</strong> salesforce.com and author <strong>of</strong> the<br />
national bestseller Behind the Cloud<br />
Learn how to RETHINK your business,<br />
REINVENT your produc ts, and<br />
REVITALIZE your vision <strong>of</strong> success the<br />
Steve Jobs way.<br />
When it comes to innovation, Apple CEO<br />
Steve Jobs is legendary. His company<br />
slogan “Think Different” is more than<br />
a marketing tool. It’s a way <strong>of</strong> life a<br />
powerful, positive, game changing<br />
approach to innovation that anyone can<br />
apply to any field <strong>of</strong> endeavor.<br />
These are the Seven Principles <strong>of</strong><br />
Innovation, inspired by the master<br />
himself:<br />
1. Do What You Love.<br />
Think differently about your<br />
career.<br />
2. Put a Dent in the Universe.<br />
Think differently about your<br />
vision.<br />
3. Kick Start Your Brain.<br />
Think differently about how you<br />
think.<br />
4. Sell Dreams, Not Products.<br />
Think differently about your<br />
customers.<br />
Books & Periodicals<br />
5. Say No to 1,000 Things.<br />
Think differently about design.<br />
6. C r e a t e I n s a n e l y G r e a t<br />
Experiences.<br />
Think differently about your brand<br />
experience.<br />
7. Master the Message.<br />
Think differently about your<br />
story.<br />
By following Steve Jobs’s visionary<br />
example, you’ll discover exciting new<br />
ways to unlock your creative potential<br />
and to foster an environment that<br />
encourages innovation and allows<br />
it to flourish. You’ll learn how to<br />
match and beat the most powerful<br />
competitors, develop the most<br />
revolutionary products, attract the<br />
most loyal customers, and thrive in<br />
the most challenging times. Bestselling<br />
business journalist Carmine Gallo has<br />
interviewed hundreds <strong>of</strong> successful<br />
pr<strong>of</strong>essionals-from CEOs, managers, and<br />
entrepreneurs to teachers, consultants,<br />
and stay at home moms to get to the core<br />
<strong>of</strong> Steve Jobs’s innovative philosophies.<br />
These are the simple, meaningful, and<br />
attainable principles that drive us all to<br />
“Think Different.”<br />
The Innovation Secrets <strong>of</strong> Steve Jobs<br />
<strong>of</strong>fers precious guidance as it presents<br />
key principles that allowed Steve Jobs to<br />
constantly, brilliantly innovate.<br />
p o l y u r e t h a n e s t o d a y<br />
49<br />
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PU<br />
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Events & Trends<br />
30 Jan - 02 Feb 2012<br />
Sprayfoam Convention & Expo<br />
2012<br />
Spray <strong>Polyurethane</strong> Foam<br />
Alliance<br />
Dallas<br />
01 - 06 Feb 2012<br />
Plastindia 2012<br />
Plastindia Foundatio<br />
New Delhi<br />
07 - 08 Mar 2012<br />
26th IKV International Plastics<br />
Technology<br />
kv Aachen<br />
ColloquiumI<br />
22 - 21 Mar 2012<br />
Plastics In Automotive<br />
Engineering 2012<br />
Vdi Wissensforum Gmbh<br />
Mannheim<br />
26 - 29 Mar 2012<br />
PDA National Conference 2012<br />
Polyurea Development<br />
<strong>Association</strong><br />
Orlando<br />
01 - 05 Apr 2012<br />
NPE 2012<br />
Spi - Society Of The Plastics<br />
Industry<br />
Orlando<br />
50 p o l y u r e t h a n e s t o d a y<br />
Events Calendar<br />
INTERNATIONAL<br />
01 - 05 Apr 2012<br />
Antec 2012<br />
Society Of Plastics Engineers<br />
Orlando<br />
15 - 17 Apr 2012<br />
Adhesive And Sealant Spring<br />
Convention<br />
The Adhesive And Sealant<br />
Council, Inc<br />
Denver<br />
16 - 17 Apr 2012<br />
3rd International Confernce On<br />
Flame Retardants<br />
Sino - German Plastic<br />
Technology Ser...<br />
Shanghai<br />
17 - 19 Apr 2012<br />
Utech Europe 2012<br />
Crain Communications<br />
Maastricht Netherlands<br />
18- 21 April 2012<br />
Chinaplas 2012<br />
Adsale Exhibition Services Ltd<br />
Shanghai<br />
07 - 10 May 2012<br />
American Coatings Show And<br />
Conference 2012<br />
Vincentz Network Gmbh & Co.<br />
Kg<br />
<strong>India</strong>napolis<br />
08 - 12 May 2012<br />
Plast 2012<br />
Fiera Milano International S.P.A.<br />
Milano<br />
14 - 17 May 2012<br />
Plastivision Arabia<br />
Expo Centre Sharjah<br />
Sharjah<br />
16 – 21 Sept 2012<br />
World Adhesive Conference<br />
Feica<br />
Paris<br />
16-23 Oct 2013<br />
K 2013<br />
Messe Düsseldorf Gmbh<br />
Dusseldorf<br />
08 - 14 May 2014<br />
Interpack<br />
Messe Düsseldorf Gmbh<br />
Dusseldorf<br />
d e c e m b e r 2 0 1 1
d e c e m b e r 2 0 1 1<br />
p o l y u r e t h a n e s t o d a y<br />
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d e c e m b e r 2 0 1 1<br />
FOR PRIVATE CIRCULATION ONLY. Edited by Ms Medha Bhuta Published by K. Ramamurthy for <strong>India</strong>n <strong>Polyurethane</strong> <strong>Association</strong><br />
Printed by