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d e c e m b e r 2 0 1 1<br />

p o l y u r e t h a n e s t o d a y<br />

1<br />

PU<br />

<strong>Today</strong>


PU<br />

<strong>Today</strong><br />

2 p o l y u r e t h a n e s t o d a y<br />

d e c e m b e r 2 0 1 1


Dear Readers,<br />

It has been almost 75 years since <strong>Polyurethane</strong>s was invented and this<br />

Industry has made rapid progress across many countries including<br />

<strong>India</strong>. <strong>Polyurethane</strong>s has contributed to several benefits to the society<br />

through innovations and by improving the life <strong>of</strong> consumers through<br />

various applications.<br />

The world continues to face many challenges and these can be summarized<br />

as leading to megatrends like Urbanization, Energy Conservation, Water<br />

conservation, Environmental protection and so on. These megatrends<br />

<strong>of</strong>fer significant challenges and opportunities to all industries including<br />

<strong>Polyurethane</strong>s. These challenges and opportunities can be met mainly<br />

by innovation that not only improve the life <strong>of</strong> consumers and do the<br />

same in a sustainable manner. Also there are some very unique <strong>India</strong>n<br />

opportunities that need uniquely <strong>India</strong>n innovative solutions<br />

This issue brings you the good news that such innovations continue to<br />

flourish in the polyurethanes industry even after over seven decades since<br />

the invention <strong>of</strong> polyurethanes. Some <strong>of</strong> these innovations developed<br />

outside <strong>India</strong> are finding application in <strong>India</strong> and also some unique <strong>India</strong><br />

needs are being addressed through disruptive innovation techniques.<br />

These innovations would go a long way in meeting the challenges and<br />

opportunities thrust upon us due to these megatrends.<br />

We hope that this issue does the dual job <strong>of</strong> your curiosity on some <strong>of</strong><br />

the application and also provide you with the assurance that innovation<br />

in polyurethanes is thriving despite the long history <strong>of</strong> this material.<br />

Best Regards,<br />

Anand G<br />

d e c e m b e r 2 0 1 1<br />

Committee Member’s Message<br />

p o l y u r e t h a n e s t o d a y<br />

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PU<br />

<strong>Today</strong><br />

Editorial<br />

RIP: Mario Miranda<br />

Dev Anand<br />

Steve Jobs<br />

Bhupen Hazarika<br />

Jagjit Singh<br />

Shammi Kapoor<br />

M F Hussain<br />

We have lost such gems this past year – all ‘Innovators’ in their fields, having<br />

left behind noteworthy footprints in the sands <strong>of</strong> time.<br />

INNOVATIONS – the theme for this issue highlights the importance for this<br />

continuous process, to help keep progress and pr<strong>of</strong>its on the upward trend. A<br />

process enabled by the input <strong>of</strong> a new method / idea / product, in any field.<br />

The more radical and revolutionary innovations tend to emerge from R&D, while<br />

more incremental innovations may emerge from practice – though there are<br />

many exceptions to each <strong>of</strong> these trends. Recent years have seen considerable<br />

progress in identifying important key factors/principles or variables that affect<br />

the probability <strong>of</strong> success in innovation. The more one can master the variables<br />

and experiment, the more will one be able to create new products, processes and<br />

services that achieve what one hopes to achieve i.e. growth objectives.<br />

BUT cost reduction and re-engineering alone cannot result in growth. Economist<br />

Joseph Schumpeter, who contributed greatly to the study <strong>of</strong> innovation, argued<br />

that industries must incessantly revolutionize the economic structure from within,<br />

that is innovate with better or more effective processes and products, such as the<br />

shift from the craft shop to factory. Innovation is the key element in providing<br />

aggressive top-line growth, and for increasing bottom-line pr<strong>of</strong>its.<br />

So, in this issue, we have strived to highlight innovations across a spectrum <strong>of</strong><br />

activities in the PU arena, and hope you enjoy the read as much as we enjoyed<br />

finding enough interesting matter to fill the pages!<br />

Last but not the least, while speaking <strong>of</strong> Innovation, we cannot ignore the Master<br />

Innovator <strong>of</strong> our times, just because he belongs to a different field – who took<br />

the world by storm, by grabbing it with both hands & making it take the giant<br />

leap with him, into the next century / the next level in technology to enable<br />

comfort, convenience, and efficiency in everyday life. I talk <strong>of</strong> none other than:<br />

Steve Jobs – an ‘iConoclastic Innovator’!<br />

Do not miss our tribute to him on the Centre spread pages & the Book Review<br />

section.<br />

Sincerely,<br />

4 p o l y u r e t h a n e s t o d a y<br />

d e c e m b e r 2 0 1 1


PUBLISHED BY THE INDIAN POLYURETHANES ASSOCIATION<br />

EDITOR<br />

MRS. MEDHA BHUTA<br />

EDITORIAL TEAM<br />

MR. RAMAMURTHY - SECRETARY IPUA<br />

MR. GOVIND GUPTA - DOW<br />

MR. PRAVIN MAHAJAN - BASF<br />

MR. PRANAV MEHTA - HONEYWELL<br />

COMPILATION & SELECTION<br />

DR. MAHESH GOPALASAMUDRAM<br />

MR. G. ANAND<br />

DESIGN CONCEPT<br />

MR. MUKESH BHUTA<br />

GRAPHIC DESIGN & LAYOUT<br />

RED SKY DESIGNS<br />

PRODUCTION & EXECUTION<br />

MR. RAMAMURTHY<br />

IPUA OFFICE BEARERS<br />

CHAIRMAN<br />

MR. RAHUL GAUTAM 0120 4162 220/4162 200 rahul@sheelafoam.com<br />

VICE CHAIRMAN<br />

DR. G. MAHESH 9122 67934904 maheshgn@dow.com<br />

Mr. MUKESH BHUTA 022 2768 0303/0404 mbhuta@expandedinc.co.in<br />

TREASURER<br />

MR. GIAN JAIN 011 2724 6907/4237 6465 gcjain@karefoam.com<br />

SECRETARY GENERAL<br />

MR. K. RAMAMURTHY 044 2499 5923 admin@pu-india.org<br />

ramamurthy_k2@dataone.in<br />

IPUA EXECUTIVE COMMITTEE MEMBERS<br />

MR. JAGANNATH SARANGAPAN +9140 23704551/3 jagannath@ufoam.com<br />

MR. G. ANAND +9122 2778 7396 anand_g@huntsman.com<br />

MR. MANDAR JOSHI +9122 6791 7420 mandar.joshi@basf.com<br />

MR. DEEPAK T. MEHTA +9179 2630 4652/3/4/5 deepakmehta@tirupatifoam.com<br />

MR. M. G. BOHRA +9144 2595 2001/2 mgb@amulpolycure.com<br />

MR. H. S. KOCHAR +91120 4080000 kochar@pfeda.com<br />

MR. S. RAJESH T. BHARGAVA +912642 247160/61/62 rtbhargava@gnfc.in<br />

MR. RABINDRA JHAJHARIA +91332229 8904/2229 5496 multiwynfoams@multiwynfoams.com<br />

MR. PRANAYA PRADHAN +9731303238 pranaya.pradhan@shell.com<br />

MR. SANJAY SANGHI +91224005 9350/51/52/53/54/55sanjay.sanghi@momentive.com<br />

MR. VINOD VORA +9122 413 5141/5889 vnvora@aromaticagencies.com<br />

MR. ASHWINI K. SEHGAL +91120 4031000 aksehgal@saanglobal.com<br />

MR. ROMESH MADAN +9111 41613643/44/45 rmadan@goodiesons.com<br />

MR. ROHIT RELAN +91124 2341258 rohitgrp@ndf.vsnl.net.in<br />

MR.AJAY DURRANI +91120 3921199 ajay.durrani@bayer.com<br />

MR RAVI MUTHUKRISHNAN +9144 25942830 mravi@manalipetro.com<br />

PERMANENT INVITEE & SPECIAL ADVISOR TO THE IPUA<br />

MR G RAMACHANDRAN +91 44 24345738 indramu123@gmail.com<br />

PERMANENT INVITEE<br />

MR. SAMIR ARORA 011 26912375/26917758/26831850 samira@airtelmail.in sam@sam3.in<br />

d e c e m b e r 2 0 1 1<br />

Contents<br />

C o n t e n t s<br />

Co m m i t t e e member’s me s s age .................. 3<br />

ed i to r i a l .............................................. 4<br />

Cr e d i t s + Co n t e n t s ............................... 5<br />

in d u s t r y up d at e s ................................... 6<br />

in t e r n at i o n a l ne w s ............................... 12<br />

pr o d u C t ne w s ....................................... 16<br />

in t e r v ie w .............................................. 20<br />

te C h n iC a l up d at e s .................................. 23<br />

te C h n iC a l artiCle ................................... 24<br />

ipua ve n t u r e s ...................................... 37<br />

speCial Fe at u r e ...................................... 40<br />

en v ir o nme n t & saFe t y ........................... 45<br />

pr e v i e w s & re p o r t s ............................... 46<br />

bo o k s & pe r i o d i C a l s .............................. 49<br />

ev e n t s & tr e n d s ................................... 50<br />

p o l y u r e t h a n e s t o d a y<br />

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Industry Updates<br />

Recticel <strong>India</strong> Pvt. Ltd. <strong>of</strong>ficially inaugurated<br />

On Sunday, November 13, 2011,<br />

the new conversion plant <strong>of</strong><br />

Recticel Flexible Foams in Mumbai<br />

was <strong>of</strong>ficially inaugurated.<br />

As <strong>India</strong> is one <strong>of</strong> the fastest growing<br />

economies worldwide with a<br />

predicted average GDP growth <strong>of</strong> 6%<br />

for the next 10 to 20 years it is a huge<br />

potential industrial and consumer<br />

market. Recticel Flexible Foams will<br />

trade and convert mainly technical<br />

flexible polyurethane foams for the<br />

local market.<br />

The 6000m² plant which is located<br />

in Taloja, Navi Mumbai, close to<br />

the Nhava Shiva port <strong>of</strong> Mumbai,<br />

will be equipped with state <strong>of</strong> the<br />

art conversion machinery (cutting,<br />

pr<strong>of</strong>iling, laminating, compressing<br />

and more) to service different market<br />

segments with high technological<br />

foam solutions.<br />

While Recticel is already market<br />

leader in <strong>India</strong> for air filter foams<br />

in the automotive sector, it will also<br />

focus on other pr<strong>of</strong>itable technical<br />

segments such as acoustics.<br />

Recticel <strong>India</strong> Pvt. Ltd. currently also<br />

has a local sales <strong>of</strong>fice in Bangalore<br />

and will open up a new warehouse<br />

and converting unit in the course<br />

<strong>of</strong> 2012 to service the South <strong>India</strong>n<br />

market.<br />

The <strong>of</strong>ficial opening ceremony <strong>of</strong><br />

the Mumbai plant, which took place<br />

onsite, was attended by a large<br />

delegation <strong>of</strong> Flemish <strong>of</strong>ficials, led<br />

by the Flemish Minister President<br />

Kris Peeters and Karl Van den<br />

Bossche, Consul-General <strong>of</strong> Belgium<br />

6 p o l y u r e t h a n e s t o d a y<br />

d e c e m b e r 2 0 1 1


in Mumbai in the presence <strong>of</strong> many<br />

<strong>India</strong>n business relations.<br />

After the ribbon cutting and<br />

traditional Hindu “Pooja” inauguration<br />

ceremony, the delegation and other<br />

invitees were invited to the ro<strong>of</strong> top<br />

terrace for a reception and walking<br />

lunch buffet.<br />

Filip Goris, Regional Manager Asia<br />

and Latin America thanked all <strong>of</strong><br />

those who helped in setting up this<br />

new entity in <strong>India</strong>, and foremost<br />

the first hour employees <strong>of</strong> Recticel<br />

<strong>India</strong> Pvt. Ltd.: Abhijit Diwadkar<br />

(General Manager), Ashok Singh Sain<br />

(Business Development Manager<br />

Mumbai), Vijay Kumar (Business<br />

Development Manager Bangalore),<br />

Deepak Sawant (Finance Manager)<br />

and Aparna Munjewar (Sales Support<br />

Officer).<br />

d e c e m b e r 2 0 1 1<br />

The Flemish Minister President<br />

Peeters on his turn praised Recticel<br />

for its pioneering and proactive<br />

approach in <strong>India</strong>, setting an example<br />

Industry Updates<br />

for other Flemish companies pursuing<br />

growth opportunities.<br />

www.recticel.co.in<br />

p o l y u r e t h a n e s t o d a y<br />

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Industry Updates<br />

Honeywell Introduces New Highly Efficient,<br />

Low-Global-Warming Blowing Agent For Foam<br />

Insulation<br />

Global adoption <strong>of</strong> Solstice Liquid Blowing Agent could save the equivalent <strong>of</strong> 60 million metric<br />

tons <strong>of</strong> carbon dioxide per year<br />

MUMBAI, INDIA, NOVEMBER 4,<br />

2011 – Honeywell (NYSE: HON)<br />

has introduced a new liquid blowing<br />

agent in the company’s growing<br />

family <strong>of</strong> materials with a low-globalwarming<br />

potential (LGWP).<br />

Solstice Liquid Blowing Agent can<br />

be used in a variety <strong>of</strong> insulation<br />

applications including sprayfoam,<br />

foam insulating panels and<br />

refrigerator insulation. Use <strong>of</strong> the<br />

new material can make refrigerators<br />

up to 10 to 12 percent more energy<br />

efficient than those insulated by<br />

hydrocarbon-blown foam. Because<br />

<strong>of</strong> these energy efficiency benefits,<br />

if fully adopted globally, Solstice<br />

Liquid Blowing Agent could save<br />

approximately 60 million metric<br />

tons per year <strong>of</strong> carbon dioxide<br />

equivalent, which is comparable to<br />

eliminating carbon dioxide emissions<br />

from more than 11.8 million cars<br />

every year.*<br />

“Honeywell’s new Solstice Liquid<br />

Blowing Agent excels in the four<br />

dimensions that are most important to<br />

blowing agent users: energy efficiency<br />

performance, environmental impact,<br />

safety in use, and cost-effectiveness,”<br />

said Terrence Hahn, vice president<br />

and general manager for Honeywell<br />

Fluorine Products. “We are pleased<br />

to announce this expansion <strong>of</strong><br />

our Solstice family <strong>of</strong> low-global-<br />

8 p o l y u r e t h a n e s t o d a y<br />

warming-potential products, which<br />

is helping customers around the<br />

world lower their carbon footprint<br />

while maximizing end-product<br />

performance.”<br />

In <strong>India</strong>, Honeywell supports<br />

customers with a two-step approach<br />

when it comes to blowing agents.<br />

Appliance manufacturers can meet<br />

the Montreal Protocol regulations<br />

deman ding a phas e - out <strong>of</strong><br />

hydrochlor<strong>of</strong>luorocarbons (HCFCs)<br />

by using Honeywell´s Enovate®<br />

blowing agent, a hydr<strong>of</strong>luorocarbon<br />

(HFC) also known as 245fa blowing<br />

agent. This product can be adopted<br />

as a near drop-in replacement for<br />

HCFC 141b. It is non ozone depleting,<br />

allowing manufacturers to meet the<br />

phase-out plan for <strong>India</strong>.<br />

In a second step, starting in 2013,<br />

manufacturers can adopt Solstice<br />

Liquid Blowing Agent as needed<br />

to meet further regulation. Use <strong>of</strong><br />

Solstice Liquid Blowing Agent enables<br />

manufactuers to also meet the<br />

requirements <strong>of</strong> the <strong>India</strong>n Bureau<br />

<strong>of</strong> Energy Efficiency, a department<br />

within <strong>India</strong>´s Ministry <strong>of</strong> Power,<br />

focused on energy efficiency.<br />

Solstice Liquid Blowing Agent has<br />

an extremely short atmospheric<br />

lifetime <strong>of</strong> approximately 26 days.<br />

This gives the product its superior<br />

properties – it has an ultra-low global<br />

warming potential (GWP) <strong>of</strong> less than<br />

7 and has no impact on ozone layer<br />

depletion.<br />

Solstice Liquid Blowing Agent’s GWP is<br />

a more than 99 percent improvement<br />

over the products it can replace,<br />

including HCFC-141b (which has a<br />

GWP <strong>of</strong> 725), HFC-365mfc (which has<br />

a GWP <strong>of</strong> 794) and HFC-245fa (which<br />

has a GWP <strong>of</strong> 1,030).<br />

Because Solstice Liquid Blowing<br />

Agent is non-flammable, it does<br />

not require expensive explosionpro<strong>of</strong><br />

equipment and handling,<br />

unlike hydrocarbon alternatives. It<br />

is also a near drop-in replacement<br />

for today’s most commonly used<br />

blowing agents.<br />

Honeywell’s Solstice family <strong>of</strong><br />

products are based on hydr<strong>of</strong>luoroolefin<br />

technology and <strong>of</strong>fer similar<br />

or improved performance when<br />

compared with today’s most<br />

widely used stationary and mobile<br />

refrigerants, blowing agents and<br />

aerosol propellants. The products<br />

have dramatically reduced GWPs<br />

compared with today’s widely used<br />

fluorocarbons.<br />

For more information about<br />

Honeywell’s Solstice Liquid Blowing<br />

Agent visit www.honeywell-<br />

d e c e m b e r 2 0 1 1


solsticeLBA.com.<br />

*Source: U.S. Environmental Protection<br />

Agency greenhouse gas equivalencies<br />

calculator with inputs from Honeywell<br />

and customer Solstice Liquid Blowing<br />

Agent test results. (http://www.epa.<br />

gov/cleanenergy/energy-resources/<br />

calculator.html)<br />

Honeywell Specialty Materials is a<br />

global leader in providing customers<br />

with high-performance specialty<br />

materials, including fluorine products;<br />

specialty films and additives; advanced<br />

fibers and composites; intermediates;<br />

specialty chemicals; electronic materials<br />

and chemicals; and technologies and<br />

materials for petroleum refining.<br />

Honeywell International (www.<br />

honeywell.com) is a For tune<br />

100 diversified technology and<br />

d e c e m b e r 2 0 1 1<br />

manufacturing leader, serving<br />

customers worldwide with aerospace<br />

products and services; control<br />

technologies for buildings, homes<br />

and industry; automotive products;<br />

turbochargers; and specialty materials.<br />

Based in Morris Township, N.J.,<br />

Honeywell’s shares are traded on<br />

the New York, London, and Chicago<br />

Stock Exchanges. For more news and<br />

information on Honeywell, please visit<br />

www.honeywellnow.com.<br />

This release contains certain<br />

statements that may be deemed<br />

“forward-looking statements” within<br />

the meaning <strong>of</strong> Section 21E <strong>of</strong> the<br />

Securities Exchange Act <strong>of</strong> 1934. All<br />

statements, other than statements <strong>of</strong><br />

historical fact, that address activities,<br />

events or developments that we or<br />

our management intends, expects,<br />

projects, believes or anticipates<br />

Industry Updates<br />

will or may occur in the future are<br />

forward-looking statements. Such<br />

statements are based upon certain<br />

assumptions and assessments made<br />

by our management in light <strong>of</strong> their<br />

experience and their perception <strong>of</strong><br />

historical trends, current economic and<br />

industry conditions, expected future<br />

developments and other factors they<br />

believe to be appropriate. The forwardlooking<br />

statements included in this<br />

release are also subject to a number<br />

<strong>of</strong> material risks and uncertainties,<br />

including but not limited to economic,<br />

competitive, governmental, and<br />

technological factors affecting our<br />

operations, markets, products, services<br />

and prices. Such forward-looking<br />

statements are not guarantees <strong>of</strong><br />

future performance, and actual results,<br />

developments and business decisions<br />

may differ from those envisaged by<br />

such forward-looking statements.<br />

Huntsman’s <strong>Polyurethane</strong> division presented<br />

papers at CBRI (Central Building Research<br />

Institute) Roorkee<br />

The event<br />

The two day seminar FIRST-2011<br />

(Fire Science & Technology<br />

Research and its Implementation)<br />

is an initiative taken by the fire<br />

research division <strong>of</strong> CBRI. They want<br />

to spread awareness <strong>of</strong> research<br />

work and innovation, being carried<br />

out by academia and the industry<br />

to develop fire safe habitats. It is<br />

a first <strong>of</strong> its kind seminar where<br />

most <strong>of</strong> IIT’s and NIT’s shared their<br />

research work in this field; the<br />

industry-involved in innovation and<br />

research also supported the concept<br />

and the event was sponsored by<br />

CSIR- Government <strong>of</strong> <strong>India</strong>, L&T,<br />

C&S, Omega, Shaktiman Doors, Aska<br />

Engineering, SCD and Huntsman<br />

International <strong>India</strong> Private Limited<br />

The event was divided in 4 technical<br />

sessions and 30 technical papers<br />

were presented by various authors<br />

<strong>Polyurethane</strong> discussion in<br />

the seminar<br />

S. K. Bhattacharya, Director CBRI and<br />

Dr. S.C. Saxena Director IIT Roorkee<br />

were among the key people who<br />

kicked <strong>of</strong>f the seminar, a quick visit<br />

tour <strong>of</strong> the exhibition was followed<br />

by technical sessions<br />

The first session: Fire Retardant<br />

Materials- Modern trends in building<br />

and material was chaired by Dr.<br />

Diane Deams, Fire and building code<br />

manager Huntsman polyurethanes<br />

division. She was also the key note<br />

speaker <strong>of</strong> this session and highlighted<br />

the growing use <strong>of</strong> polyurethanes for<br />

insulation in construction in Western<br />

regions and China. Dr. Deams spoke<br />

about the evolving fire legislation in<br />

China to incorporate light weight,<br />

energy efficient and sustainable<br />

construction. She assured full support<br />

<strong>of</strong> Huntsman’s polyurethane division<br />

to the people involved in drafting the<br />

building codes in <strong>India</strong> in order to<br />

p o l y u r e t h a n e s t o d a y<br />

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upgrade them for achieving superior<br />

energy performance and fire safety<br />

<strong>of</strong> buildings<br />

The key note address was followed<br />

by Huntsman polyurethanes’ paper<br />

on Fire Performance <strong>of</strong> innovative<br />

polyurethane products in <strong>India</strong>.<br />

This paper was presented by Deepak<br />

Rathi, Business development<br />

manager- Insulation, highlighting the<br />

need <strong>of</strong> effective building insulation<br />

in <strong>India</strong> and the polyurethane<br />

products locally available to achieve<br />

this. He also shared the various test<br />

results related to fire performance <strong>of</strong><br />

INSPIRE® - PIR product developed by<br />

Huntsman’s polyurethane division<br />

Other significant papers on<br />

polyurethanes products were:<br />

l Rigid polyurethane foam as a fire<br />

retardant material- Presented by Dr.<br />

R S patil and Dr.J M Paranjpe, IIT<br />

Bombay<br />

l Flammability performance <strong>of</strong><br />

rigid PU foam manufactured using<br />

d e c e m b e r 2 0 1 1<br />

Industry Updates<br />

The Big Question: Can <strong>India</strong> clean up its image?<br />

Yahoo! <strong>India</strong> News<br />

Here’s a secret that everybody<br />

already knows: <strong>India</strong> is corrupt.<br />

Now it gets murkier. Over the past year,<br />

we have been swimming deeper into<br />

the muck. According to Transparency<br />

International’s Corruption Perception<br />

Index for 2011, <strong>India</strong> has dropped<br />

from 87 to 95. <strong>India</strong>’s image is taking<br />

a beating because <strong>of</strong> the big list <strong>of</strong><br />

corruption scandals that have rocked<br />

the nation this year.<br />

Dr. Deams spoke<br />

about the evolving fire<br />

legislation in China<br />

to incorporate light<br />

weight, energy efficient<br />

and sustainable<br />

construction. She<br />

assured full support<br />

<strong>of</strong> Huntsman’s<br />

polyurethane division<br />

to the people involved<br />

in drafting the building<br />

codes in <strong>India</strong> in order<br />

to upgrade them for<br />

achieving superior<br />

energy performance<br />

and fire safety <strong>of</strong><br />

buildings<br />

different blowing agent by Dr, Harpal<br />

Singh and Dr. S K Shrama, CBRI<br />

l Comparative fire performance<br />

evaluation <strong>of</strong> fire retardant treated<br />

rigid PU foam by cone calorimeter<br />

by Dr. Maricelin, Dr.S.R. Bhalla, Dr.<br />

S. K. Sahay, IIT Delhi<br />

l Effect <strong>of</strong> FR on generation <strong>of</strong> smoke<br />

and toxic combustion products by<br />

Dr.N K Saxena IIT Roorkee<br />

Other sessions on day one and two:<br />

Fire protec tion & life safet y<br />

technologies 9 Papers<br />

Extinguishment technologies for<br />

medium and large scale fire 4<br />

papers<br />

Mathematic al modeling and<br />

predictive methodologies 8 Papers<br />

The seminar was closed by Mr.<br />

Omprakash, from the Ministry <strong>of</strong><br />

Home affairs and chairman <strong>of</strong> the fire<br />

code revision committee BIS<br />

p o l y u r e t h a n e s t o d a y<br />

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PU<br />

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International News<br />

SCG-DOW Group Reaches Key<br />

Milestone toward Thailand HPPO Plant Start-up<br />

New HPPO facility ramps up to stable production levels in preparation for full capacity run<br />

scheduled for 4Q11.<br />

MIDLAND, Mich. – Oct. 4, 2011 – The<br />

Dow Chemical Company (NYSE:Dow)<br />

announced today that the SCG-Dow<br />

Group, a joint venture between Dow<br />

and SCG, has reached a key milestone<br />

for the new propylene oxide (PO)<br />

facility in Thailand by ramping the<br />

plant up to stable production levels in<br />

preparation for the full capacity run<br />

scheduled for the fourth quarter <strong>of</strong><br />

2011. The world-scale plant, located<br />

within the Asia Industrial Estates (AIE)<br />

site near Map Ta Phut, Thailand will<br />

have a name plate capacity <strong>of</strong> 390<br />

kilotons per annum (KTA) <strong>of</strong> PO via<br />

the innovative hydrogen peroxide to<br />

propylene oxide (HPPO) technology<br />

jointly developed by Dow and BASF.<br />

“The Map Ta Phut, Thailand HPPO<br />

plant cements Dow’s existing position<br />

as the global capacity leader in PO”,<br />

explained Steven English, global<br />

vice president, Dow <strong>Polyurethane</strong>s.<br />

“Not only does this large investment<br />

exemplify Dow’s commitment to the<br />

PO-based industry, we also continue<br />

to bring value by investing in the<br />

latest technology and <strong>of</strong>fering a more<br />

sustainable PO to our customers<br />

and our downstream <strong>of</strong>ferings<br />

through Dow’s other Performance<br />

and Advanced Materials businesses,<br />

such as <strong>Polyurethane</strong>s and Propylene<br />

Glycol.”<br />

According to Holger Baer, global<br />

manufacturing and technology<br />

director, PO/PG, “Within three<br />

years, this is the second world-scale<br />

plant brought on-line with the<br />

innovative Dow-BASF HPPO process.<br />

It significantly reduces wastewater<br />

and energy consumption compared<br />

12 p o l y u r e t h a n e s t o d a y<br />

to existing PO technology, and is<br />

planned to be utilized next in the<br />

Sadara Chemicals Company project<br />

between Dow and Saudi Aramco due<br />

to the clear demonstration <strong>of</strong> the<br />

advantages <strong>of</strong> this process.”<br />

“The start-up <strong>of</strong> this PO plant<br />

has completed the downstream<br />

envelope <strong>of</strong> the SCG-DOW Group joint<br />

venture cracker in Thailand which<br />

came on-stream last year”, said<br />

Cholanat Yanaranop, president,<br />

SCG Chemicals Company Limited.<br />

“With commitment between the<br />

partners, this is proved to be another<br />

successful project.”<br />

In June <strong>of</strong> 2010, Dow and BASF were<br />

honored to receive a 2010 Presidential<br />

Green Chemistry Challenge Award for<br />

the jointly developed innovative<br />

HPPO technology – recognized as<br />

a breakthrough technology that<br />

transfers sustainability principles<br />

from the research lab into the real<br />

world to enable environmentally<br />

responsible and economically viable<br />

routes to commercial chemical<br />

manufacturing. In 2009, Dow and<br />

BASF received the Institution <strong>of</strong><br />

Chemical Engineers’ Innovation and<br />

Excellence Award in Core Engineering<br />

for their jointly developed HPPO<br />

Technology – recognized as the<br />

process that best demonstrates a<br />

chemical engineering solution to<br />

improve resource efficiency, lifetime<br />

value and/or process optimization.<br />

In December 2010, Dow announced<br />

plans to build a propylene glycol (PG)<br />

plant at the Map Ta Phut, Thailand<br />

site, with a production capacity <strong>of</strong><br />

150 KTA. The PG plant is currently<br />

on-track in the design process, and<br />

will utilize this environmentally<br />

advantaged PO from the new HPPO<br />

plant. It will be the largest PG plant<br />

in the Pacific area.<br />

The AIE site also features a specialty<br />

elastomers plant, which announced<br />

start-up earlier this year; power<br />

utilities and infrastructure; and<br />

a new liquids cracker, also jointly<br />

owned by SCG and Dow. “The new<br />

integrated Thailand site serves as<br />

a strategic source point for all <strong>of</strong><br />

Asia Pacific, and demonstrates<br />

Dow’s commitment to growing<br />

our presence to serve customers<br />

in our Performance Materials and<br />

Performance Plastics businesses<br />

across the area”, said Pat Dawson,<br />

Dow Asia Pacific president.<br />

Dow to Highlight Innovations<br />

at 2011 CPI Technical<br />

Conference<br />

About Dow <strong>Polyurethane</strong>s<br />

Dow is the world’s largest producer<br />

<strong>of</strong> propylene oxide (PO), propylene<br />

glycol (PG), and polyether polyols,<br />

and is a leading producer <strong>of</strong> quality<br />

aromatic isocyanates, such as<br />

MDI and TDI. Dow’s polyurethane<br />

products enhance a broad range <strong>of</strong><br />

applications including construction,<br />

automotive, furniture, bedding,<br />

appliance, decorative molding,<br />

athletic equipment and more. The<br />

business provides key ingredients,<br />

systems and solutions for rigid, semirigid<br />

and flexible foams, adhesives,<br />

sealants, coatings, elastomers and<br />

d e c e m b e r 2 0 1 1


inders. VORANOL VORACTIV<br />

polyols exemplify Dow’s ongoing<br />

initiative to lead the industry in<br />

providing high-performance products<br />

that meet critical consumer needs.<br />

For more information, visit www.<br />

dowpolyurethanes.com, www.dowpg.<br />

com, www.dowpo.com and www.<br />

voractiv.com.<br />

About Dow<br />

Dow combines the power <strong>of</strong> science<br />

and technology with the “Human<br />

Element” to passionately innovate<br />

what is essential to human progress.<br />

The Company connects chemistry<br />

and innovation with the principles<br />

<strong>of</strong> sustainability to help address<br />

many <strong>of</strong> the world’s most challenging<br />

problems such as the need for<br />

clean water, renewable energy<br />

generation and conservation, and<br />

increasing agricultural productivity.<br />

Dow’s diversified industry-leading<br />

New Technology From Dow and Cannon Improves Energy<br />

Efficiency <strong>of</strong> Household Refrigerators by<br />

up to 10 percent<br />

d e c e m b e r 2 0 1 1<br />

portfolio <strong>of</strong> specialty chemical,<br />

advanced materials, agrosciences<br />

and plastics businesses delivers a<br />

broad range <strong>of</strong> technology-based<br />

products and solutions to customers<br />

in approximately 160 countries<br />

and in high growth sectors such as<br />

electronics, water, energy, coatings<br />

and agriculture. In 2010, Dow had<br />

annual sales <strong>of</strong> $53.7 billion and<br />

employed approximately 50,000<br />

people worldwide. The Company’s<br />

more than 5,000 products are<br />

manufactured at 188 sites in 35<br />

countries across the globe. References<br />

to “Dow” or the “Company” mean<br />

The Dow Chemical Company and<br />

its consolidated subsidiaries unless<br />

otherwise expressly noted. More<br />

information about Dow can be found<br />

at www.dow.com.<br />

About SCG<br />

SCG, established in 1913, is publicly<br />

International News<br />

listed on the Stock Exchange <strong>of</strong><br />

Thailand. SCG is one <strong>of</strong> ASEAN<br />

leading conglomerates, comprises<br />

five core businesses: chemicals,<br />

cement, paper, building materials,<br />

and distribution. Altogether, there<br />

are over 200 companies within the<br />

group, which collectively employ<br />

more than 34,000 employees, and<br />

manufacture more than 64,000<br />

products.<br />

S CG Chemic als continue s to<br />

expand its business presence into<br />

international markets, and places<br />

a strong emphasis on innovation in<br />

products/services, processes, and<br />

business models in service <strong>of</strong> its<br />

diverse and sophisticated customer<br />

base. In addition, SCG Chemicals<br />

has partnered with a number <strong>of</strong> the<br />

world’s leading chemical firms. More<br />

information about SCG can be found<br />

at www.scg.co.th.<br />

• New insulation technology decreases fill time, doubles productivity <strong>of</strong><br />

polyurethane insulation manufacturing process<br />

• Insulation technology increases energy efficiency <strong>of</strong> refrigerators and freezers<br />

by up to 10 percent<br />

Midland, Michigan – September 8,<br />

2011 – Dow <strong>Polyurethane</strong>s, a business<br />

within The Dow Chemical Company<br />

(NYSE: Dow), in cooperation with<br />

Cannon SpA, will <strong>of</strong>ficially launch<br />

PASCAL Technology on September<br />

9 at the Shanghai Summit 2011.<br />

PASCAL, a new polyurethane foam<br />

insulation technology that improves<br />

energy efficiency <strong>of</strong> refrigerators and<br />

freezers by up to 10 percent, was first<br />

featured in household refrigerators<br />

and freezers by Haier and is now<br />

commercially available to appliance<br />

manufacturers.<br />

The Shanghai Summit<br />

2011 brings together<br />

Italian and Chinese<br />

government <strong>of</strong>ficials,<br />

academic and industry<br />

leaders and media<br />

to share innovative<br />

insights on energy conservation<br />

and explore how transformational<br />

opportunities can contribute to<br />

economic growth and environmental<br />

sustainability. The summit is just one<br />

p o l y u r e t h a n e s t o d a y<br />

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<strong>of</strong> the efforts in the collaboration <strong>of</strong><br />

the Italian and Chinese governments<br />

toward making China a more<br />

sustainable country.<br />

“This summit is the perfect venue to<br />

launch PASCAL,” said Bruno Barbet,<br />

Dow <strong>Polyurethane</strong>s global appliance<br />

market leader. “China is one <strong>of</strong> the<br />

largest single-home marketplaces<br />

for refrigerators and freezers, as well<br />

as a leading global export country,<br />

and PASCAL Technology can help<br />

support the goals <strong>of</strong> making China’s<br />

industrial divisions more sustainable<br />

for the future.”<br />

Combining a proprietary polyurethane<br />

foam specifically formulated for this<br />

application, PASCAL Technology<br />

doubles the efficiency <strong>of</strong> insulation<br />

while continuing to provide thermal<br />

conductivity and adhesion—qualities<br />

that distinguish polyurethane from<br />

alternative types <strong>of</strong> insulation.<br />

Caption: When compared to standard<br />

polyurethane insulation processes,<br />

PASCAL Technology out-performs<br />

both side-by-side models and<br />

bottom freezer models by up to<br />

10%. The test results shown compare<br />

PASCAL Technology against standard<br />

polyurethane insulation using<br />

cyclopentane (CP) blowing agents.<br />

“Average Results” represent the<br />

average <strong>of</strong> all tests run on a variety<br />

<strong>of</strong> standard refrigeration models.<br />

d e c e m b e r 2 0 1 1<br />

Results vary per model, and have the<br />

potential to realize up to 10% energy<br />

efficiency improvement based on<br />

a variety <strong>of</strong> influencing factors<br />

as advantages <strong>of</strong> the Technology<br />

continue to be understood.<br />

PASCAL is just one <strong>of</strong> the innovative<br />

s olutions spurre d by Dow ’s<br />

commitment to addressing the<br />

world’s most critical challenges,<br />

including the need to conserve<br />

energy.<br />

“Governments are setting more<br />

stringent mandatory minimum<br />

Energy targets, and consumers<br />

worldwide are demanding energy<br />

efficient appliances,” said Barbet.<br />

“With PASCAL, manufacturers may<br />

deliver on this demand, while also<br />

increasing energy efficiency and<br />

output during manufacturing.”<br />

PASCAL Technology incorporates<br />

v a c u u m<br />

equipment from<br />

Cannon SpA, during<br />

the insulation<br />

process to bypass<br />

the deficiencies<br />

o f s t a n d a r d<br />

insulation. The<br />

vacuum, paired<br />

with a hydrocarbon<br />

blowing agent,<br />

allows PA S C AL<br />

polyurethane foam<br />

to fit into the small<br />

spaces traditional insulation might<br />

miss, especially in modern designs,<br />

and also mold to the contours <strong>of</strong> the<br />

appliance, reducing the amount <strong>of</strong><br />

energy lost during consumer use. The<br />

resulting system can also decrease<br />

the insulation reactivity time from<br />

a standard <strong>of</strong> about five to three<br />

minutes.<br />

For more information, please visit<br />

www.dowpascal.com.<br />

International News<br />

About Dow <strong>Polyurethane</strong>s<br />

Dow is the world’s largest producer<br />

<strong>of</strong> propylene oxide (PO), propylene<br />

glycol (PG), and polyether polyols,<br />

and is a leading producer <strong>of</strong> quality<br />

aromatic isocyanates, such as<br />

MDI and TDI. Dow’s polyurethane<br />

products enhance a broad range <strong>of</strong><br />

applications including construction,<br />

automotive, furniture, bedding,<br />

appliance, decorative molding,<br />

athletic equipment and more. The<br />

business provides key ingredients,<br />

systems and solutions for rigid, semirigid<br />

and flexible foams, adhesives,<br />

sealants, coatings, elastomers and<br />

binders. VORANOL VORACTIV<br />

polyols exemplify Dow’s ongoing<br />

initiative to lead the industry in<br />

providing high-performance products<br />

that meet critical consumer needs.<br />

For more information, visit www.<br />

dowpolyurethanes.com, www.dowpg.<br />

com, www.dowpo.com and www.<br />

voractiv.com.<br />

About Dow<br />

Dow combines the power <strong>of</strong> science and<br />

technology with the “Human Element” to<br />

passionately innovate what is essential to<br />

human progress. The Company connects<br />

chemistry and innovation with the principles<br />

<strong>of</strong> sustainability to help address many <strong>of</strong> the<br />

world’s most challenging problems such as<br />

the need for clean water, renewable energy<br />

generation and conservation, and increasing<br />

agricultural productivity. Dow’s diversified<br />

industry-leading portfolio <strong>of</strong> specialty<br />

chemical, advanced materials, agrosciences<br />

and plastics businesses delivers a broad<br />

range <strong>of</strong> technology-based products and<br />

solutions to customers in approximately 160<br />

countries and in high growth sectors such<br />

as electronics, water, energy, coatings and<br />

agriculture. In 2010, Dow had annual sales<br />

<strong>of</strong> $53.7 billion and employed approximately<br />

50,000 people worldwide. The Company’s<br />

more than 5,000 products are manufactured<br />

at 188 sites in 35 countries across the globe.<br />

References to “Dow” or the “Company”<br />

mean The Dow Chemical Company and its<br />

consolidated subsidiaries unless otherwise<br />

expressly noted. More information about<br />

Dow can be found at www.dow.com.<br />

p o l y u r e t h a n e s t o d a y<br />

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PU<br />

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Product News<br />

Honeywell Fluorine Products in <strong>India</strong><br />

Overview<br />

Honeywell’s Fluorine Products<br />

business is a leader in the<br />

manufacture and supply <strong>of</strong> zero<br />

non-ozone-depleting refrigerants<br />

used by top air-conditioning and<br />

refrigeration makers worldwide, as<br />

well as blowing agents for energyefficient<br />

foam insulation, and<br />

hydr<strong>of</strong>luoric acid and precursors for<br />

nuclear fuel. The business pioneered<br />

the development <strong>of</strong> fluorocarbons<br />

used in environmentally safer<br />

refrigerants, foam blowing agents<br />

and aerosols and solvents. It is a<br />

leading producer <strong>of</strong> fluorocarbons<br />

used to replace ozone-depleting CFCs<br />

(chlor<strong>of</strong>luorocarbons) and HCFCs<br />

(hydrochlor<strong>of</strong>luorocarbons).<br />

Continuing its commitment towards<br />

more secure, safer and more<br />

energy-efficient homes and <strong>of</strong>fices,<br />

Honeywell works towards helping<br />

the world responding to its energy<br />

and environmental challenges.<br />

In 2008, Honeywell introduced<br />

the first product in its Low Global<br />

Warming Potential (LGWP) portfolio,<br />

based on hydr<strong>of</strong>luoroolefin (HFO)<br />

technology. <strong>Today</strong>, Honeywell is a<br />

pioneer in developing LGWP blowing<br />

agent technology for polyurethane<br />

and extruded polystyrene foams<br />

insulation; advanced energy-efficient<br />

refrigerants for refrigeration and air<br />

conditioning, and organic rankine<br />

cycle waste heat recovery systems;<br />

and propellants for aerosol and<br />

solvent applications.<br />

<strong>India</strong>, as a part <strong>of</strong> Article V countries <strong>of</strong><br />

Montreal Protocol on Substances That<br />

Deplete the Ozone Layer, is working<br />

16 p o l y u r e t h a n e s t o d a y<br />

toward phasing out HCFC 141b and<br />

R22 from 2013 onwards. The transition<br />

from HCFCs to environmentally<br />

friendlier alternatives is <strong>of</strong> particular<br />

significance since the country aims to<br />

not only phase out ozone depleting<br />

HCFC’s but also significantly improve<br />

the energy efficiency <strong>of</strong> domestic<br />

appliances over the next 2-3 years.<br />

Fluorine Products <strong>of</strong>fers:<br />

• F or p olyurethane foam:<br />

Honeywell Enovate blowing<br />

agent and Honeywell Solstice<br />

Liquid Blowing Agent<br />

• For extruded polystyrene foam<br />

and one-component foam:<br />

Honeywell Solstice Gas Blowing<br />

Agent<br />

• For refrigerants: Genetron®<br />

410A<br />

Meeting the Montreal Protocol<br />

regulations for HCFC phase-out,<br />

Enovate 245fa has No Ozone<br />

Depletion Potential and provides<br />

efficiencies similar to HCFC 141b<br />

blowing agent. It is non-toxic, noncorrosive,<br />

non-flammable and <strong>of</strong>fers<br />

8 to 10 percent more energy efficiency<br />

than any hydrocarbon blowing agent.<br />

Converting to Enovate 245fa incurs<br />

no significant cost or changes to the<br />

existing HCFC 141b or hydrocarbonbased<br />

foaming equipment setup.<br />

Honeywell has also developed and<br />

recently launched Solstice Liquid<br />

Blowing Agent (LBA). Solstice LBA<br />

excels in the four dimensions that<br />

are most critical to blowing agent<br />

customers: Performance, Cost-<br />

Effectiveness, Environment and<br />

Safety. This fourth generation blowing<br />

agent has been developed to have a<br />

significantly lower global-warming<br />

potential (GWP) while improving<br />

energy efficiency performance.<br />

The energy efficiency benefits <strong>of</strong><br />

Honeywell Solstice Liquid Blowing<br />

Agent, combined with its low global<br />

warming potential and safety in<br />

use, make it the right choice as a<br />

replacement for HCFC-141b, as well<br />

as hydrocarbons, for manufacture<br />

<strong>of</strong> polyurethane foam.<br />

Honeywell Specialty Materials is a<br />

leading international supplier and<br />

licensor <strong>of</strong> process technology,<br />

catalysts, adsorbents, process plants,<br />

and consulting services to the<br />

petroleum refining, petrochemical,<br />

and gas processing industries. It is<br />

a global leader in developing and<br />

manufacturing high-purity, highquality<br />

performance chemicals and<br />

materials, pharmaceutical packaging,<br />

and construction materials. Our<br />

technologies reduce emissions, stop<br />

bullets, enable the production <strong>of</strong><br />

green diesel and green gasoline,<br />

increase oil refinery capacity,<br />

speed drug discovery, and protect<br />

medicines.<br />

Honeywell is a Fortune 100 company<br />

that invents and manufactures<br />

technologies to address tough<br />

challenges linked to global macro<br />

trends such as safety, security, and<br />

energy. With approximately 122,000<br />

employees worldwide, including<br />

more than 19,000 engineers and<br />

scientists, Honeywell stands for<br />

an unrelenting focus on quality,<br />

delivery, value, and technology in<br />

everything we make and do.<br />

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Product News<br />

You’re all screwed: Assange’s message to iPhone,<br />

BB, Gmail users<br />

December 03, 2011<br />

Daily Mirror<br />

London Wiki Leaks founder Julian<br />

Assange has warned Smartphone<br />

and email users: “ You’re all<br />

screwed”.<br />

The whistle-blowing website has<br />

released details <strong>of</strong> companies it says<br />

are selling information obtained by<br />

monitoring people’s mobile phones<br />

and computers. According to Assange,<br />

more than 150 organizations around<br />

the world have the ability to use<br />

phones as tracking devices as well<br />

as intercept messages and listen to<br />

calls.<br />

Those companies then sell the<br />

wholesale information, <strong>of</strong>ten the<br />

telecommunications data <strong>of</strong> “entire<br />

populations”.<br />

He told a press conference at City<br />

University in London that the<br />

publication <strong>of</strong> the “Spy Files” is a<br />

“mass attack on this mass surveillance<br />

industry”.<br />

The 40-year-old asked the audience<br />

<strong>of</strong> students and press: “Who here<br />

has an iPhone? Who here has a<br />

BlackBerry? Who here uses Gmail?<br />

“Well, you’re all screwed.<br />

“The reality is, intelligence contractors<br />

are selling right now to countries<br />

across the world mass surveillance<br />

systems for all those products.”<br />

Assange said this interception,<br />

although lawful, is leading towards<br />

Sleep Innovations Introduces Gel Infused Memory Foam<br />

a “totalitarian surveillance state”.<br />

Wiki Leaks is releasing 287 documents<br />

today, in conjunction with website<br />

spyfiles.org. Assange said the US, UK,<br />

Australia, South Africa and Canada are<br />

all developing the “spying systems”,<br />

and the information is being sold to<br />

“dictators and democracies alike”.<br />

He said: “<strong>Today</strong> we release over<br />

287 files documenting the reality <strong>of</strong><br />

the international mass surveillance<br />

industry – which now sells equipment<br />

to dictators and democracies<br />

alike in order to intercept entire<br />

populations.”<br />

The Australian national said the<br />

surveillance industry has grown<br />

over the last 10 years from “covert,<br />

secretive and small” to one involving<br />

160 companies and 25 countries.<br />

Sleep Innovations Announces Revolutionary New<br />

Technology Proven to Help Consumers Sleep Better<br />

Gel-Infused Memor y Foam<br />

Provides Maximum Pressure-<br />

Point Relief, Improved Airflow and<br />

Reduces Heat for Better Quality<br />

Sleep<br />

WEST LONG BRANCH, N.J., Sept. 14<br />

/PRNewswire/ -- Sleep Innovations,<br />

a market leader in designing and<br />

manufacturing advanced foam<br />

comfort solutions, announced today<br />

a revolutionary new product that<br />

takes memory foam to the next<br />

level. The company’s first-<strong>of</strong>-its-kind<br />

p o l y u r e t h a n e s t o d a y<br />

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gel-infused memory foam provides<br />

the traditional comfort <strong>of</strong> memory<br />

foam with the additional benefits<br />

<strong>of</strong> increased support and improved<br />

airflow.<br />

Sleep Innovations is launching the<br />

patent-pending new technology<br />

in response to consumers’ need<br />

for a quality sleep experience. The<br />

gel-infused memory foam provides<br />

the ultimate solution, combining<br />

comfort, support, pressure relief<br />

and improved airflow. To create gelmemory<br />

foam, gel beads are infused<br />

into traditional memory foam. These<br />

gel beads add a layer <strong>of</strong> support<br />

within the foam, gathering together<br />

at pressure points to deliver the<br />

maximum support a person needs,<br />

exactly where it’s needed.<br />

With nearly thirty-five percent <strong>of</strong><br />

Americans not getting the quality<br />

sleep they need, the revolutionary<br />

gel-infused memory foam technology<br />

addresses one <strong>of</strong> the main reasons<br />

people are sleep deprived – poor<br />

quality sleep products. When<br />

d e c e m b e r 2 0 1 1<br />

developing products on which people<br />

spend one-third <strong>of</strong> their lives, Sleep<br />

Innovations believes it is critical to<br />

deliver a sleep solution, proven to<br />

addresses those consumer needs.<br />

Sleep Innovations’ new gel-infused<br />

memory foam technology is launching<br />

as the company expands its current<br />

<strong>of</strong>ferings to include comfort solutions<br />

for every moment in life beyond<br />

sleep. “Its advantages include better<br />

air flow for a cooler night’s sleep,<br />

more balanced support resulting<br />

in less cradling, optimal pressure<br />

point relief for improved circulation<br />

and better spinal alignment. Sleep<br />

Innovations’ new gel-infused<br />

memory foam technology <strong>of</strong>fers<br />

the perfect balance between the<br />

comfort <strong>of</strong> traditional memory foam<br />

and the support <strong>of</strong> gel,” said Mike<br />

Loomis, Vice President <strong>of</strong> Business<br />

and Product Development at Sleep<br />

Innovations<br />

Sleep Innovations is working to<br />

continuously improve existing<br />

memory foam products as well<br />

Product News<br />

as develop the next generation <strong>of</strong><br />

comfort foam solutions using this<br />

new gel-infused memory foam<br />

technology.<br />

The new gel memory foam products<br />

are currently available at leading<br />

retailers throughout the U.S. and<br />

Canada.<br />

For additional information, or to<br />

see additional retailers where the<br />

product will be available, visit www.<br />

sleepinnovations.com.<br />

About Sleep Innovations<br />

Sleep Innovations is the leader in<br />

consumer-driven foam products,<br />

proven to deliver comfort, relaxation<br />

and rejuvenation. The company<br />

designs and manufactures advanced,<br />

memory foam products, including<br />

pillows, mattress toppers and<br />

mattresses. Through extensive<br />

clinical testing, Sleep Innovations has<br />

found that its foam solutions help to<br />

improve the quality <strong>of</strong> its consumers’<br />

lives through better sleep.<br />

p o l y u r e t h a n e s t o d a y<br />

19<br />

PU<br />

<strong>Today</strong>


PU<br />

<strong>Today</strong><br />

Interview<br />

PAUL SANDERS<br />

Honeywell Solstice LBA will be more<br />

cost-effective than other solutions to meet<br />

ever-increasing energy standards globally<br />

l The energy efficiency benefits <strong>of</strong><br />

Solstice Liquid Blowing Agent (LBA),<br />

combined with its low global warming<br />

potential and safety in use, make it<br />

the right choice as a replacement<br />

for HCFC-141b, hydrocarbons, HFC-<br />

365mfc, and HFC-245fa for use as a<br />

foam insulation blowing agent.<br />

l Refrigerators using un-optimized<br />

Solstice LBA formulations have<br />

been demonstrated to be up to<br />

10-12% better than cyclopentane<br />

formulations. We expect even more<br />

as formulations are fine-tuned.<br />

l With a global warming potential<br />

(GWP) <strong>of</strong> less than 7, its widespread<br />

adoption could save about 60 million<br />

metric tons per year <strong>of</strong> CO2 equivalent,<br />

comparable to eliminating carbon<br />

dioxide emissions from more than<br />

11.8 million cars every year. (Source:<br />

GHG Equivalencies Calculator: http://<br />

www.epa.gov/cleanenergy/energy-<br />

20 p o l y u r e t h a n e s t o d a y<br />

Paul Sanders is the Commercial Director for the Fluorines<br />

business in Europe, Middle East Africa and <strong>India</strong> (EMEAI)<br />

I. He joined Honeywell in 2006 and has had several<br />

Marketing and Commercial roles for the Fluorines<br />

business in EMEAI. Paul has worked in Sales, Marketing,<br />

Asset Management and Plant Management roles for 20<br />

years in the chemical industry, previously at Rhodia and<br />

Albright & Wilson prior to joining Honeywell.<br />

Paul Sanders holds a Bachelor <strong>of</strong> Science (with special<br />

honours) in Chemistry from University Sheffield, UK.<br />

resources/calculator.html)<br />

PU TODAY: What is Solstice TM<br />

LBA?<br />

Mr. PAUL SANDERS: Honeywell<br />

Solstice LBA is the latest technological<br />

advance with a GWP <strong>of</strong> less than<br />

7. It can be used in refrigerator/<br />

freezer insulation, insulated metal<br />

panels, spray foam insulation and<br />

other applications. It is a promising<br />

replacement for foam insulation<br />

blowing agents currently in use, with<br />

the potential to make contributions<br />

to reductions in global warming.<br />

PU TODAY: How Solstice<br />

LBA is compared with (other<br />

alternatives) hydrocarbon and<br />

HCFC 141b blowing agents?<br />

Mr. PAUL SANDERS: The energy<br />

efficiency benefits <strong>of</strong> Solstice LBA,<br />

combined with its low environmental<br />

impact and non-flammability, make<br />

it the right choice as a replacement<br />

for hydrocarbons, HFCs and HCFCs<br />

for use as a foam insulation blowing<br />

agent.<br />

Solstice LBA per forms better<br />

than hydrocarbons in refrigerator<br />

applications by delivering:<br />

l Better low-temperature efficiency<br />

that saves energy costs<br />

l Lower capital costs by avoiding<br />

e xpensive flammabilit y risk<br />

mitigation equipment and preventive<br />

maintenance<br />

l Similar performance for spray and<br />

panel foam<br />

l Lower end-<strong>of</strong>-life management<br />

costs<br />

While S olstice LBA provides<br />

excellent insulation performance<br />

to polyurethane foam, it’s distinctly<br />

dif ferent from hydrocarbon<br />

d e c e m b e r 2 0 1 1


lowing agents in flammability<br />

characterization. Solstice LBA<br />

shipment, storage, handling and<br />

processing do not require flammability<br />

risk mitigation. Flammable blowing<br />

agents, such as cyclopentane, require<br />

flammability risk mitigation, which<br />

can add significant capital costs.<br />

PU TODAY: Is it a drop in<br />

replacement for HCFC 141b?<br />

What are the changes required<br />

in process equipments?<br />

Mr. PAUL SANDERS: Solstice LBA is<br />

a low cost energy efficient alternative<br />

to HCFC 141b, minimal equipment<br />

modifications may be needed as<br />

the temperature and pressure <strong>of</strong> the<br />

products differ. Please contact us to<br />

set up a time to review your current<br />

operation.<br />

PU TODAY: What are the safety<br />

precautions required while<br />

processing & transporting<br />

polyol blended with Solstice<br />

L B A a n d re c o m m e n d e d<br />

storage conditions? What is<br />

the typical shelf-life <strong>of</strong> the<br />

polyol pre-blended under<br />

the recommended storage<br />

conditions?<br />

Mr. PAUL SANDERS: While Solstice<br />

LBA provides excellent insulation<br />

performance to polyurethane<br />

foam, it’s distinctly different from<br />

hydrocarbon blowing agents in<br />

flammability characterization.<br />

Solstice LBA shipment, storage,<br />

handling and processing do not<br />

require flammability risk mitigation.<br />

Flammable blowing agents, such as<br />

cyclopentane, require flammability<br />

risk mitigation, which can add<br />

significant capital costs.<br />

Solstice LBA is non-flammable by<br />

ASTM E-861 test method and has no<br />

d e c e m b e r 2 0 1 1<br />

Honeywell Solstice LBA<br />

is the latest<br />

technological advance<br />

with a GWP <strong>of</strong> less<br />

than 7. It can be used<br />

in refrigerator/freezer<br />

insulation, insulated<br />

metal panels, spray<br />

foam insulation and<br />

other applications.<br />

limitation on hazards classification.<br />

The flammability characteristics<br />

and VOC mitigation required<br />

with other blowing agents (such<br />

as hydrocarbons) make them less<br />

desirable as replacements for existing<br />

blowing agents.<br />

PU TODAY: Is it a cost effective<br />

alternative?<br />

Mr. PAUL SANDERS: Honeywell<br />

Solstice LBA will be more cost-effective<br />

than other solutions to meet ever-<br />

increasing energy standards globally.<br />

A near drop-in replacement for liquid<br />

HCFC, HFC, hydrocarbons and other<br />

non-fluorocarbon blowing agents. It<br />

is liquid at room temperature and<br />

can be used in most existing foam<br />

equipment, regardless <strong>of</strong> current<br />

blowing agent used, with little or no<br />

modification.<br />

It does not require costly hydrocarbon<br />

storage and handling or mitigation<br />

equipment. Replacing existing<br />

blowing agents with Solstice LBA<br />

eliminates the need for large capital<br />

conversion costs.<br />

PU TODAY: When Solstice TM<br />

Interview<br />

LBA will be commercially<br />

available in <strong>India</strong>?<br />

Mr. PAUL SANDERS: In <strong>India</strong>,<br />

Honeywell supports customers<br />

with a two-step approach when<br />

it comes to blowing agents.<br />

Appliance manufacturers can meet<br />

the Montreal Protocol regulations<br />

deman ding a phas e - out <strong>of</strong><br />

hydrochlor<strong>of</strong>luorocarbons (HCFCs) by<br />

using Honeywell’s Enovate® blowing<br />

agent, a hydr<strong>of</strong>luorocarbon also<br />

known as HFC-245fa . This product<br />

can be adopted as a near dropin<br />

replacement for HCFC-141b. It<br />

is non-ozone depleting, allowing<br />

manufacturers to meet the phase-out<br />

plan for <strong>India</strong> and has been available<br />

and used globally since 2003.<br />

In a second step, starting in 2013,<br />

manufacturers can adopt Solstice<br />

LBA as needed to meet any future<br />

environmental needs concerning<br />

GWP or Climate Change and/or to<br />

further improve energy efficiency.<br />

Use <strong>of</strong> Solstice LBA enables appliance<br />

manufactuers to effectively meet<br />

the Energy standard requirements<br />

<strong>of</strong> the <strong>India</strong>n Bureau <strong>of</strong> Energy<br />

Efficiency, a department within<br />

<strong>India</strong>´s Ministry <strong>of</strong> Power, focused on<br />

energy efficiency.<br />

Disclaimer:<br />

The information provided herein are<br />

believed to be accurate and reliable,<br />

but are presented without guarantee or<br />

warranty <strong>of</strong> any kind, express or implied.<br />

User assumes all risk and liability for use<br />

<strong>of</strong> the information and results obtained.<br />

Statements or suggestions concerning<br />

possible use <strong>of</strong> materials and processes are<br />

made without representation or warranty<br />

that any such recommendations to infringe<br />

any patent. The user should not assume that<br />

all safety measures are indicated herein, or<br />

that other measures may not be required.<br />

p o l y u r e t h a n e s t o d a y<br />

21<br />

PU<br />

<strong>Today</strong>


PU<br />

<strong>Today</strong><br />

22 p o l y u r e t h a n e s t o d a y<br />

d e c e m b e r 2 0 1 1


RAMPF at Plast<strong>India</strong> 2012<br />

“Material and machine technology” from a<br />

single source<br />

Grafenberg, Zimmern, November<br />

30, 2011 – In hall 13 on stand<br />

12 F7 visitors to Plast<strong>India</strong> 2012 will<br />

have the opportunity to see both the<br />

material and machine technology <strong>of</strong><br />

RAMPF from a single source. RAMPF<br />

Dosiertechnik will provide a live<br />

demonstration <strong>of</strong> the contour-precise<br />

application <strong>of</strong> a two-component<br />

system based on polyurethane <strong>of</strong><br />

the product range RAKU-PUR® on<br />

the DC-CNC low-pressure mixing and<br />

dispensing system.<br />

The company has specialized in<br />

the development, production and<br />

sale <strong>of</strong> polyure-thane, silicone and<br />

epoxy resin systems since 1980. Its<br />

product portfolio includes liquid<br />

and thixotropic sealing systems,<br />

electro casting resins, edge and filter<br />

casting resins and two-component<br />

adhesives. RAMPF Giessharze <strong>of</strong>fers<br />

solutions for all key industries around<br />

the globe.<br />

The compact DC-CNC dispensing cell<br />

is the optimum solution for the 2D<br />

or 3D ap-plication <strong>of</strong> casting, sealing<br />

and adhesive systems. The basic setup<br />

<strong>of</strong> the fully en-closed DC-CNC is<br />

equipped with an integrated control<br />

cabinet and a 2-component material<br />

conditioning system. Further features<br />

include the Siemens Sinumerik<br />

modular control system and<br />

integrated process control for<br />

continuous monitoring <strong>of</strong> pressure,<br />

fill level and speed. The mixing and<br />

dispensing system can optionally be<br />

equipped with a high-pressure rinse<br />

agent recycling system, high-pressure<br />

d e c e m b e r 2 0 1 1<br />

water rinsing or various items <strong>of</strong><br />

automation equipment depending<br />

on the application in question.<br />

With more than 2,200 system<br />

solutions on the market worldwide,<br />

RAMPF Dosiertechnik from Zimmern<br />

o.R., Germany, is one <strong>of</strong> the leading<br />

manufacturers <strong>of</strong> low-pressure<br />

mixing and dispensing systems and<br />

serves customers in the automo-tive,<br />

electrical, household appliance and<br />

filter industries. With a global service<br />

net-work and numerous branches<br />

in France, Spain, Eastern Europe,<br />

the United States, China, Korea and<br />

<strong>India</strong>, the company has a strong<br />

international presence.<br />

www.rampf-dosiertechnik.de<br />

With 2,200 system solutions on the market<br />

worldwide, RAMPF Dosiertechnik from<br />

Zimmern o.R., Germany, is one <strong>of</strong> the<br />

leading manufacturers <strong>of</strong> low-pressure<br />

mixing and dispensing systems. As a supplier<br />

<strong>of</strong> innovative systems for processing one-,<br />

two- and multi-component reaction resin<br />

systems, RAMPF Dosiertechnik serves<br />

customers in the automotive, electrical,<br />

household appliance and filter industries.<br />

Particular asset <strong>of</strong> the company, which is<br />

part <strong>of</strong> the international RAMPF Group since<br />

2003, is its broad-ranging product portfolio.<br />

This stretches from simple manual systems<br />

all the way through to fully automated<br />

production plants. RAMPF Dosiertechnik<br />

has carved out a name for itself on an<br />

international stage. With a global service<br />

network and numerous branches in France,<br />

Spain, East-ern Europe, the United States,<br />

China and Korea, the company has a strong<br />

international presence.<br />

www.rampf-giessharze.de<br />

RAMPF Giessharze GmbH & Co. KG,<br />

the nucleus <strong>of</strong> the RAMPF Group, is<br />

Technical Updates<br />

Abb.1: The working axle, material<br />

preparation and the dispensing technique<br />

<strong>of</strong> the DC-CNC is a com-pact unit.<br />

headquartered in Grafenberg, Germany.<br />

The company has specialized in the<br />

development, production and sale <strong>of</strong> polyurethane<br />

silicone, and epoxy resin systems<br />

since 1980. Its product portfolio includes<br />

liquid and thixo-tropic sealing systems,<br />

electro and engineering casting resins, edge<br />

and filter casting resins and two-component<br />

adhesives. RAMPF Giessharze <strong>of</strong>fers solutions<br />

for all key industries around the globe.<br />

POLYURETHANE FOAM<br />

MANUFACTURERS/IMPORTERS:<br />

We <strong>of</strong>fer TDI 80/20 and Polyether<br />

Polyol different grades for your direct<br />

import from our overseas suppliers.<br />

Please Contact:<br />

Global Impex Corporation<br />

# 4 Leela Nilayam, Road # 3,<br />

Tank Pakkadi, Sahar, Mumbai 400 099<br />

Telefax: 022-2822 8113<br />

Cell: 099876 37385<br />

E-mail: epgloimpex@ sify.com<br />

p o l y u r e t h a n e s t o d a y<br />

23<br />

PU<br />

<strong>Today</strong>


PU<br />

<strong>Today</strong><br />

Technical Article<br />

Cannon V.A.I.: Vacuum-Assisted Injection<br />

Technology for Refrigerators Production,<br />

Providing Cost-Effective Eco-design and Superior<br />

Energy Savings<br />

PIERO CORRADI<br />

Cannon Group<br />

Via Resistenza, 12<br />

Peschiera Borromeo (Milano) Italy<br />

Abstract<br />

Cannon announces the first<br />

industrial mass production <strong>of</strong><br />

domestic refrigerators manufactured<br />

with the new Cannon V.A.I. technology,<br />

a vacuum-assisted injection method<br />

specifically developed for the<br />

production <strong>of</strong> white cold appliances.<br />

An injection method introduced in<br />

1998 - applying vacuum into the mold<br />

cavity where insulated sandwich<br />

panels are manufactured with the<br />

discontinuous production process -<br />

the vacuum-assisted injection has<br />

now successfully been applied to<br />

the geometrically complex design <strong>of</strong><br />

domestic refrigerators.<br />

Prior to the foaming operation,<br />

a controlled degree <strong>of</strong> vacuum is<br />

applied into the jig where the empty<br />

refrigerator cabinet is positioned..<br />

The reduced pressure applied into<br />

the cavity during the injection and<br />

the expansion <strong>of</strong> the foam facilitates<br />

the filling <strong>of</strong> the cabinet, providing<br />

substantial benefits:<br />

l optimized distribution <strong>of</strong> foam<br />

density throughout the entire<br />

cabinet.<br />

l the polymerization time per<br />

foaming station has been cut nearly<br />

in half due to the possibility <strong>of</strong> using<br />

high reactivity formulations providing<br />

24 p o l y u r e t h a n e s t o d a y<br />

MAX TAVERNA<br />

Cannon Group<br />

Via Resistenza, 12<br />

Peschiera Borromeo (Milano) Italy<br />

a significantly higher productivity.<br />

l reduced plant’s floor space in half<br />

when using the new “twin” foaming<br />

fixture - the RotoJig – specifically<br />

conceived for this technology.<br />

A partnership with Dow allowed for<br />

the development <strong>of</strong> PASCAL , an<br />

innovative technological solution that<br />

draws new frontiers in the production<br />

<strong>of</strong> refrigerators. The new <strong>Polyurethane</strong><br />

chemistry, specifically developed<br />

for this application, reduces the<br />

foam thermal conductivity to a new<br />

reference level, while maintaining the<br />

density at least within the industry<br />

state-<strong>of</strong>-the-art levels and allowing<br />

for a shorter polymerization time.<br />

Several patents have been applied by<br />

the two companies in their respective<br />

fields <strong>of</strong> activity.<br />

In order to produce a refrigerator<br />

characterized by the same thermal<br />

conductivity in all its components,<br />

the vacuum-assisted injection<br />

technology has been extended to<br />

the door’s production method: the<br />

well known “Drum” Unit – a rotating<br />

multiple-mold manufacturing tool<br />

originally patented by Cannon in the<br />

early 1980’s – has been redesigned<br />

applying the vacuum capability,<br />

obtaining the same advantages<br />

described for the cabinets.<br />

The presentation <strong>of</strong> this Paper will<br />

be illustrated by a video, featuring<br />

the vacuum-assisted injection system<br />

during the validation phase, and<br />

by the updated results <strong>of</strong> the first<br />

industrial plant in operation at<br />

HAIER, the major global appliances<br />

producer based in P.R. <strong>of</strong> China.<br />

Initial Developments<br />

An innovative method for foaming<br />

sandwich insulation panels using<br />

vacuum during the injection phase was<br />

jointly developed – back in 1998 – by<br />

MISA (an Italian panel manufacturer),<br />

Manni (a polymerization press<br />

manufacturer), Cannon (the foaming<br />

machine producer) and Dow Italia<br />

(the supplier <strong>of</strong> the <strong>Polyurethane</strong><br />

chemicals). Its functioning concept<br />

relied on the controlled application<br />

<strong>of</strong> vacuum into the polymerization<br />

cavity <strong>of</strong> the press, maintaining a<br />

constant level <strong>of</strong> negative pressure<br />

within the polymerization cavity<br />

during the entire injection and foam<br />

expansion’s time (Picture 1). High<br />

productivity (more than 300 large<br />

Picture 1 – Manufacture <strong>of</strong> sandwich panels<br />

with V.A.I. (Vacuum Assisted Injection)<br />

technology<br />

d e c e m b e r 2 0 1 1


panels per shift), enhanced panel<br />

quality, savings in raw materials<br />

and labor cost, and a very clean<br />

workplace characterized this new<br />

process (Picture 2). Blowing agents<br />

with a wider range <strong>of</strong> boiling points<br />

could be used and, very remarkable,<br />

Picture 2 – Demolding time greatly reduced<br />

due to the effect <strong>of</strong> vacuum during foam<br />

injection<br />

polyisocyanurate foam could be easily<br />

processed with the new injection<br />

technique. The resulting panels were<br />

filled with a foam characterized by an<br />

almost perfect distribution <strong>of</strong> density<br />

across the entire length (thus avoiding<br />

overweight, a widely used practice to<br />

guarantee a minimum safe density in<br />

the most remote corners <strong>of</strong> the panel)<br />

and by very high values <strong>of</strong> adhesion<br />

between foam and metal facings<br />

(deriving from the very low level <strong>of</strong><br />

water required in the formulation to<br />

provide expansion, a practice which<br />

avoids the production in the foam<br />

<strong>of</strong> undesired Urea crystals that spoil<br />

adhesion properties).<br />

The Vacuum Effect<br />

As shown in Picture 3, the Pressure<br />

vs. Time graph shows the build-up<br />

<strong>of</strong> pressure in the polymerization<br />

cavity. The practice shows that safe<br />

demolding (when a panel can be<br />

demolded without the risk <strong>of</strong> swelling)<br />

can be performed at a residual<br />

pressure <strong>of</strong> approx. 200 mbar. The<br />

upper curve refers to a conventional<br />

d e c e m b e r 2 0 1 1<br />

Picture 3 – Demolding time shortens because<br />

<strong>of</strong> reduced pressure build-up in the mold<br />

Picture<br />

PUR formulation, and the demolding<br />

time can be reached after 1800 s<br />

for a given thickness. The lower<br />

curve, referring to a vacuum-assisted<br />

injection system, shows that the<br />

application <strong>of</strong> 500 mBar <strong>of</strong> vacuum<br />

in the polymerization cavity allows to<br />

fill it faster and with a lower residual<br />

pressure. This means that the moment<br />

for safe demolding can be reached<br />

earlier, approximately at 360 s.<br />

A faster demolding that occurs<br />

without any loss <strong>of</strong> mechanical<br />

properties: in fact the structure <strong>of</strong> the<br />

foam results much finer (due to the<br />

fast-reacting formulation that can be<br />

employed) and more homogeneous<br />

in density across the entire panel due<br />

to the lower effort that the expanding<br />

mass must spend to reach the remote<br />

corners <strong>of</strong> the cavity (Picture 4).<br />

Picture 4 – Initial development with vacuum<br />

assisted molding gave promising results<br />

The minimum density at which<br />

the cavity is fully filled with foam<br />

decreases as the pressure is reduced.<br />

Working at 0.7 bar in the mold, the<br />

minimum filling density lowers by<br />

Technical Article<br />

25%. (It has to be said that this huge<br />

savings cannot be fully exploited in<br />

practical terms <strong>of</strong> thermal insulation,<br />

since the mechanical properties <strong>of</strong><br />

foam are also directly linked with its<br />

final molded density.) What can be<br />

concluded at this respect is that the<br />

applied vacuum helps the foam flowproperties,<br />

and the minimum filling<br />

density is significantly reduced.<br />

New Ideas Are Born<br />

It goes without saying that the<br />

successful use <strong>of</strong> vacuum-assisted<br />

injection immediately stimulated<br />

the idea to extend this technology<br />

to other application fields, beginning<br />

with the production <strong>of</strong> refrigerators<br />

and freezers. The technical problems<br />

– and the deriving advantages –<br />

were common among the two<br />

industries, but basic differences<br />

were to be found in the geometry <strong>of</strong><br />

their respective final products. While<br />

it proved sufficiently easy to apply<br />

vacuum in the regular polymerization<br />

cavity <strong>of</strong> a sandwich panel and to<br />

obtain a perfect result, the complex<br />

geometry <strong>of</strong> a refrigerator’s cabinet<br />

immediately showed that much more<br />

engineering work was demanded to<br />

guarantee the same performance in<br />

a fridge: a 3D part with a complex<br />

inner core, “the plug” (Picture 5).<br />

Several metal parts must be moved<br />

hundreds <strong>of</strong> times per shift, in order<br />

to lock the refrigerator cabinet into<br />

its foaming position. Various sizes <strong>of</strong><br />

cabinets must be feasible in the same<br />

Picture 5 – A combi refrigerator shows the<br />

difficult geometry, difficult to be filled with<br />

conventional foam and vacuum<br />

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Technical Article<br />

foaming station, thus requiring an<br />

almost automatic adjustment <strong>of</strong> the<br />

jig’s walls, to be performed quickly.<br />

The foaming concept had to be rethought,<br />

as well as the design <strong>of</strong> the<br />

required tool.<br />

The same approach had to be followed<br />

for the chemical side, for the very good<br />

reason that a major change in foaming<br />

technology would not be adopted by<br />

the appliance manufacturers if the<br />

obtained savings were not more than<br />

substantial in terms <strong>of</strong> foam’s lambda<br />

value, demolding time and molded<br />

density. Here, too, a major amount<br />

<strong>of</strong> R&D work was demanded to the<br />

chemical specialists.<br />

The V.A.I. Project<br />

Cannon approached this project<br />

– named V.A.I. (Vacuum Assisted<br />

Injection) – using the human, financial<br />

and technical resources available<br />

in their two Divisions involved in<br />

refrigerators manufacturing: Cannon<br />

Afros for the metering and mixing<br />

equipment, and Cannon Crios for the<br />

cabinet’s polymerization and handling<br />

solutions. A team <strong>of</strong> specialists<br />

identified a number <strong>of</strong> technical<br />

problems, and soon started to suggest<br />

various hypothetically viable solutions,<br />

to be ground tested in Cannon R&D<br />

laboratories. The development work<br />

took several months.<br />

After a number <strong>of</strong> unsuccessful<br />

attempts with available formulations<br />

modified on purpose, a new,<br />

dedicated chemistry was developed<br />

by Dow. Cannon in the meantime<br />

designed the first industrial solution<br />

for the production jig.<br />

The V.A.I. Jig construction<br />

The new jig has the same functionality<br />

and movements <strong>of</strong> a standard jig but<br />

28 p o l y u r e t h a n e s t o d a y<br />

its lateral sides, the upper plate<br />

which holds the plug and the top and<br />

bottom walls are fitted with special<br />

seals that, when the jig is locked,<br />

provide an airtight cavity (Picture 6).<br />

The vacuum is applied through the<br />

upper plate. The main difference<br />

Picture 6 – The Cannon V.A.I. foaming jig<br />

with a standard polymerization jig<br />

is the use <strong>of</strong> a sliding plate, called<br />

pallet, where the back wall <strong>of</strong> the<br />

fridge rests. This pallet is sliding in<br />

and out from the jig for the cabinet’s<br />

loading and unloading operations.<br />

It is not recirculated around the<br />

plant and thus can be permanently<br />

connected to a hot water circuit for a<br />

very efficient thermostatization.<br />

The V.A.I. module:<br />

Productivity/investment<br />

optimization<br />

An industrial foaming plant based<br />

on V.A.I. jig is typically composed <strong>of</strong><br />

eight jigs placed side-by-side, each <strong>of</strong><br />

them served by one loading and one<br />

unloading conveyor (Picture 7). The<br />

two automatic devices travel above<br />

these conveyors: the loader picks the<br />

empty, warm cabinet coming from<br />

Picture 7 – A typical foaming plant with<br />

eight Cannon V.A.I. foaming jigs<br />

the pre-heating oven (on the far right<br />

<strong>of</strong> the plant) and carries it towards<br />

the jig that has produced the latest<br />

cured cabinet. The unloader picks it<br />

from the pallet where it is carried,<br />

and moves to the left <strong>of</strong> the plant to<br />

the discharge area. In the meantime<br />

the loader moves right over the pallet<br />

and unloads on it the empty cabinet,<br />

which immediately is brought in<br />

the waiting jig. The cycle starts, as<br />

described before. Productivity <strong>of</strong><br />

this configuration can be up to two<br />

cabinets per minute.<br />

V.A.I. – Main Advantages<br />

Several innovative features provide a<br />

number <strong>of</strong> interesting advantages:<br />

l Faster demolding time, up to 50%<br />

less than with conventional foams<br />

l The system is suitable for difficult<br />

cabinet geometries: even the<br />

combined use <strong>of</strong> VIP (Vacuum<br />

Insulated Panels) is possible, since<br />

the foam filling operation is much<br />

easier than with a slow, conventional<br />

formulation.<br />

l k-factor values <strong>of</strong> the foamed<br />

refrigerators are very low, due to the<br />

finer cell structure and the very even<br />

distribution <strong>of</strong> densities across the<br />

entire cabinet.<br />

The Rotojig Development<br />

In order to reduce the service time<br />

to get full advantage <strong>of</strong> this new<br />

fast curing formulation, Cannon<br />

developed a new solution for the<br />

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polymerization jig, by designing a<br />

rotating jig holding two fixtures fitted<br />

on the opposite sides <strong>of</strong> a common<br />

platform. In this way the foot print<br />

<strong>of</strong> the plant can be halved, also<br />

reducing the travelling time <strong>of</strong> the<br />

mixhead overhead carrier and the<br />

cabinet’s loading and unloading<br />

carts.<br />

The concept derives from a wellproven<br />

Cannon solution, the RotoPlug<br />

system. Patented by Cannon Crios<br />

in the early 1980’s, the RotoPlug<br />

polymerization jig hosts two male<br />

plugs mounted on the opposite sides<br />

<strong>of</strong> a rotating platform. While the<br />

lower plug is in the polymerization<br />

phase, the upper plug stands on the<br />

upper side, where adjustment and<br />

maintenance work can be executed<br />

without interrupting the production<br />

cycle.<br />

An evolution <strong>of</strong> the RotoPlug, the<br />

new RotoJig was designed and built<br />

for the VAI project. In this version,<br />

at the end <strong>of</strong> the foam-filling phase<br />

the entire jig - not only the male<br />

plug - is rotated (Picture 8). Curing<br />

occurs in the upper station while<br />

loading, unloading, foam injection<br />

Picture 8 – The Cannon RotoJig features two<br />

foaming jigs rotating on a common platform.<br />

Injection <strong>of</strong> chemicals, under vacuum, occurs<br />

in the bottom position, foam curing in the<br />

upper one.<br />

d e c e m b e r 2 0 1 1<br />

and cavity filling occurs in the lower<br />

one (Picture 9).<br />

Picture 9 – A RotoJig during the validation<br />

phase, at Cannon Afros R&D laboratory in<br />

Italy<br />

The foaming cycle <strong>of</strong> a RotoJig station<br />

can be described as follows:<br />

l The large metal plate where the<br />

back <strong>of</strong> the fridge will rest (the pallet)<br />

fully slides out from the RotoJig to a<br />

nearby handling station. An empty<br />

cabinet, arriving from a pre-heating<br />

oven, is laid on the pallet, which reenters<br />

in the foaming station.<br />

l Once it is in position, the pallet with<br />

the cabinet is lifted towards the male<br />

plug, the four lateral mold’s walls are<br />

closed on the cabinet and the entire<br />

jig is locked. The cabinet is now held<br />

in position on its six sides, and all the<br />

foamed seals mounted to keep the<br />

vacuum in the jig are compressed<br />

by the walls.<br />

l The mixing head, which is mounted<br />

on a sliding support, is introduced in<br />

front <strong>of</strong> the injection hole, positioned<br />

in the refrigerator’s compressor<br />

cavity.<br />

l Vacuum is applied throughout the<br />

entire cavity containing the empty<br />

cabinet. In a few seconds most <strong>of</strong><br />

the contained air is extracted and<br />

the vacuum level reaches the desired<br />

value (around 300 mbar).<br />

Technical Article<br />

l The foam injection starts: metered<br />

by a high-pressure two-component<br />

dosing unit, the chemicals are mixed<br />

within the mixing head that works<br />

with an output rate at approximately<br />

1.5-2 kg/s. The desired amount <strong>of</strong><br />

foam – that for a large 2 m high<br />

Combi freezer&fridge model can<br />

reach 9 kg <strong>of</strong> weight – is injected<br />

in 4 to 6 seconds in the cabinet’s<br />

empty cavity, between the external<br />

metal sheet and the internal plastic<br />

liner. The vacuum level is maintained<br />

constant during the entire injection<br />

and foam-filling operation, so that<br />

the expansion <strong>of</strong> the foam can be<br />

helped by the vacuum in the very<br />

same way from the first to the last<br />

moment <strong>of</strong> this delicate phase.<br />

l Helped by this favorable condition,<br />

the foam rapidly fills the complex<br />

cavity and is distributed evenly in<br />

the most remote corners and thinner<br />

parts <strong>of</strong> the cabinet’s walls.<br />

l At the end <strong>of</strong> this phase the vacuum<br />

is no longer required and the cabinet,<br />

held between the male plug and<br />

the lateral walls, is moved with a<br />

180° platform’s rotation from the<br />

lower position <strong>of</strong> the station to the<br />

upper one; it will rest there for the<br />

remaining cycle time.<br />

l When the foam ends its curing phase,<br />

becoming firm and dimensionally<br />

stable, then another 180° rotation<br />

<strong>of</strong> the platform brings it back to the<br />

lower level: here, in the meantime,<br />

another cabinet was loaded, foamed<br />

and waited to “go up” for the curing<br />

phase. One 180° rotation <strong>of</strong> the<br />

platform does the two jobs at the<br />

same time: it sends up a foamed<br />

cabinet for curing, and brings down<br />

a cured cabinet for extraction in a<br />

masked time.<br />

l The pallet holding the cured<br />

cabinet is automatically extracted<br />

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from the RotoJig and goes to the<br />

nearby handling station: here the<br />

ready cabinet is automatically<br />

removed, an empty cabinet is laid<br />

on the pallet, which re-enters in<br />

the foaming station for the next<br />

injection cycle.<br />

When using a RotoJig plant instead <strong>of</strong><br />

a single V.A.I. jig further advantages<br />

are immediately understandable:<br />

with two curing stations working<br />

with one shifting injection head or<br />

two fixed injection heads.<br />

l Factory floor space is cut by 50% for<br />

the same daily product output.<br />

l Cycle time is further reduced due to<br />

shorter travelling paths <strong>of</strong> the mixing<br />

head carrier and loading/unloading<br />

carts<br />

Cabinet Performances<br />

Refrigerator cabinets produced with the<br />

PASCAL Technology are characterized<br />

by the lowest levels <strong>of</strong> k-factor value<br />

among all the <strong>Polyurethane</strong>-insulated<br />

fridges made with single injection<br />

technology. Thermal transmission<br />

coefficients <strong>of</strong> 18.0 – 18.5 mW m °K<br />

(at 10 °C) have been measured after<br />

evaluation trials run on commercial<br />

refrigerators foamed with the PASCAL<br />

Technology by a major refrigerator’s<br />

manufacturer.<br />

The first industrial products made<br />

with this technology can be sold within<br />

the A++++ Energy Conservation<br />

Class and an Energy Consumption<br />

Value <strong>of</strong> 0.19 kWh per day by HAIER<br />

in China (Picture 10).<br />

Since 2006 Cannon has filed four<br />

international patents related to<br />

this process – two <strong>of</strong> them are<br />

published.<br />

d e c e m b e r 2 0 1 1<br />

Picture 10 – The first industrially-produced<br />

refrigerators made with the V.A.I. – PASCAL<br />

technology by HAIER<br />

Doors<br />

In order to produce a refrigerator<br />

characterized by the same thermal<br />

conductivity in all its components,<br />

the new vacuum-assisted injection<br />

technology has been extended to<br />

the door’s production method: the<br />

well known “Drum” Unit – a rotating<br />

multiple-mold manufacturing tool<br />

originally patented by Cannon in the<br />

early 1980’s – has been redesigned<br />

applying the vacuum capability,<br />

obtaining the same advantages<br />

described for the cabinets (Picture<br />

11). A four-mold version has been<br />

designed, able to manufacture one<br />

large door or two small ones every<br />

50 s.<br />

Picture 11 – A Cannon Drum-4 Unit for the<br />

production <strong>of</strong> refrigerator’s doors using the<br />

V.A.I. – PASCAL technology<br />

Technical Article<br />

The Drum unit’s functional sequence<br />

can be described as follows:<br />

l At the end <strong>of</strong> a polymerization<br />

phase the mold opening device<br />

opens the lower part <strong>of</strong> the mold<br />

standing in vertical position.<br />

l The lower mold half is tilted by 45°<br />

towards the operator.<br />

l The operator – standing in front <strong>of</strong><br />

one <strong>of</strong> the four molds, opened for<br />

the service operations – extracts a<br />

filled door from its polymerization<br />

cavity and fits one empty door shell<br />

in the mold.<br />

l The conveyor is rotated by 90° and<br />

the mold is automatically closed in<br />

its horizontal position.<br />

l The mixing head is inserted in the<br />

injection hole, vacuum is applied<br />

into this empty mold, the injection<br />

<strong>of</strong> chemicals starts, the mold is filled<br />

in very few seconds.<br />

l The Drum can be rotated again<br />

by 90°. The filled mold enters in the<br />

polymerization area that covers two<br />

<strong>of</strong> the four positions <strong>of</strong> the Drum and<br />

a sequence like the one described<br />

above is performed.<br />

Dow – Pascal<br />

Within the Dow-Cannon partnership<br />

agreement, Dow has been working<br />

on the chemistry side for an indepth<br />

PU system re-design aiming<br />

at developing new solutions able<br />

to capture the maximum PU foam<br />

performance advantages while<br />

using the vacuum-assisted injection<br />

technology, irrespective to the<br />

blowing agent employed.<br />

This fundamental R&D work has led<br />

to the development <strong>of</strong> a completely<br />

new series <strong>of</strong> PU systems that are<br />

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the core <strong>of</strong> the Dow Pascal TM<br />

technology which, in essence,<br />

combine the application <strong>of</strong> lower inmold<br />

pressure to achieve maximum<br />

PU foam insulation and process<br />

performance.<br />

Lower in-mold pressure results in:<br />

l Easier flow due to the resulting<br />

lower cavity’s back-pressure<br />

l Better demolding time due to the<br />

lower foam pressure in-mold at the<br />

time <strong>of</strong> demolding the units (Picture<br />

3)<br />

Improved flow gives options for<br />

improving foam k-factor hence<br />

cabinet’s energy consumption using<br />

fast reactive PU foam systems without<br />

penalties on density and demolding<br />

as it happens with the conventional<br />

foaming process. As known, PU foam<br />

k-factor is the sum <strong>of</strong> three main<br />

contributions:<br />

k-f PU foam = k gas + k solid +<br />

k radiative<br />

Fast reactive systems are known to<br />

give very uniform and finer cell size<br />

showing improved foam k-factor as<br />

a consequence <strong>of</strong>:<br />

l Optimized cell gas composition<br />

(best balance <strong>of</strong> CO2 and physical<br />

Blowing Agent) enhancing the k gas<br />

contribution<br />

l Finer cell size enhancing the k radiative<br />

contribution (Pictures 12 and 13)<br />

In this case, the finer foam cell<br />

size well explains the k-factor<br />

improvement according to the Booth<br />

equation [1].<br />

S ome <strong>of</strong> the main PU foam<br />

characteristics <strong>of</strong> the new Pascal TM<br />

technology system compared to<br />

standard K and Low K C-Pentane<br />

32 p o l y u r e t h a n e s t o d a y<br />

Picture 12 – Picture from Standard K foam,<br />

cell size 270 – 300 micron<br />

Picture 13 – Picture from Pascal TM foam, cell<br />

size 150 – 180 micron<br />

blown systems now in the market<br />

are summarized in the following<br />

table (average data measured from<br />

a foamed Combi-Bottom freezer<br />

European cabinet design, 178 x 60<br />

x 60 cm):<br />

Reference PU System Standard Low Pascal TM<br />

k-factor C-p k-factor C-p TM System<br />

System reactivity (sec) 40 38 20<br />

Applied density (kg/m3) Reference +3% Reference<br />

Foam k-factor at 10°C (mW/m.K) 20.5 19.7 18.5<br />

Average cell size (micron) 270 - 300 240 – 270 150 - 180<br />

Demolding time (min) 5 5 2.5<br />

Haier<br />

The first industrial plant for the<br />

application <strong>of</strong> the PASCAL Technology<br />

was designed for HAIER, the world<br />

leader in the manufacture <strong>of</strong><br />

refrigerators and a major player<br />

in the entire appliance industry.<br />

Confronted with the need to <strong>of</strong>fer an<br />

extremely efficient refrigerator model<br />

within their wide catalogue, HAIER<br />

decided to invest in a completely new<br />

concept <strong>of</strong> a foaming plant to achieve<br />

their goal. DOW and Cannon jointly<br />

discussed the technical options<br />

with HAIER, and defined the most<br />

appropriate solution for a fastdemolding<br />

foaming plant.<br />

Sixteen VAI jigs, in two rows <strong>of</strong> eight<br />

jigs each, are fed by two high pressure<br />

metering units through four mixing<br />

heads mounted on traverse carriers<br />

(Picture 14). One loading and one<br />

unloading aerial carts handle each<br />

row <strong>of</strong> eight jigs. Vacuum to the jigs<br />

Picture 14 – The first industrial plant using<br />

the V.A.I. – PASCAL technology is in<br />

production at Haier, P.R. <strong>of</strong> China<br />

is provided by two separate vacuum<br />

pumps with accumulators. If needed,<br />

the vacuum pumps can be switched<br />

between the two rows <strong>of</strong> jigs to<br />

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ensure uninterrupted service to the<br />

entire plant. Also the two metering<br />

units are fully interchangeable, should<br />

one <strong>of</strong> them be stopped.<br />

Due to the fast demolding properties<br />

<strong>of</strong> the PASCAL Technology, HAIER<br />

achieved for this first plant a<br />

production capacity <strong>of</strong> one unit every<br />

15 seconds. The thermal insulation<br />

performance <strong>of</strong> these models is<br />

rated A++++ and the new line <strong>of</strong><br />

refrigerators, launched at the World<br />

Appliance Expo in Shanghai on March<br />

16, 2011 – is getting a very positive<br />

response from the consumers. The<br />

PASCAL Technology used for this<br />

refrigerator contributes for 5% to the<br />

energy savings.<br />

A very positive environmental impact<br />

already oriented a wide number <strong>of</strong><br />

Chinese consumers towards this model<br />

<strong>of</strong> refrigerator for their home.<br />

The emissions deriving from the use<br />

<strong>of</strong> this white appliance are calculated<br />

d e c e m b e r 2 0 1 1<br />

to be reduced by an average <strong>of</strong> 8 kg <strong>of</strong><br />

CO 2 -equivalent per every year <strong>of</strong> use<br />

<strong>of</strong> the refrigerator.<br />

Conclusions<br />

The vacuum-assisted injection<br />

has been successfully applied to<br />

the complex design <strong>of</strong> domestic<br />

refrigerators. A partnership between<br />

Cannon and Dow allowed for the<br />

development <strong>of</strong> PASCAL, we believe<br />

it is an innovative technological<br />

solution that draws new frontiers in<br />

the production <strong>of</strong> refrigerators.<br />

The reduced pressure applied into<br />

the cavity during the injection and<br />

the expansion <strong>of</strong> the foam facilitates<br />

the filling <strong>of</strong> the cabinet, providing<br />

substantial benefits:<br />

l optimized distribution <strong>of</strong> foam<br />

density throughout the entire<br />

cabinet.<br />

l the polymerization time per foaming<br />

station has been cut nearly in half<br />

due to the possibility <strong>of</strong> using high<br />

reactivity formulations providing a<br />

significantly higher productivity.<br />

l reduced plant’s floor space in half<br />

when using the new “twin” foaming<br />

fixture - the RotoJig – specifically<br />

conceived for this technology.<br />

The new <strong>Polyurethane</strong> formulation,<br />

specifically developed for this<br />

application, reduces the foam thermal<br />

conductivity to a new reference level,<br />

while maintaining the density at list<br />

within the industry state <strong>of</strong> the art<br />

levels and allowing for a shorter<br />

polymerization time.<br />

p o l y u r e t h a n e s t o d a y<br />

References<br />

1. H. Kramer, V. Parenti, “Novel rigid<br />

polyurethane formulations <strong>of</strong>fering<br />

combined high energy efficiency and<br />

fast productivity for outstanding<br />

performance in the domestic appliance<br />

industry”, Proceeding the 2007 CPI<br />

Conference, Orlando USA.<br />

Vydro®: Smart Water Management Substrate Set<br />

to Transform Green Ro<strong>of</strong> & Vertical Walls Market<br />

Skygardens are a growing phenomenon.<br />

In towns and cities around the world,<br />

a quiet architectural revolution is<br />

occurring. At first glance the changes<br />

might not be noticeable, particularly<br />

from street level, but look closely<br />

at the skyline or out <strong>of</strong> a high-rise<br />

window and the transformation might<br />

become more apparent.<br />

Slowly but surely, green ro<strong>of</strong>s and<br />

skyrise gardens are being added to<br />

public and private buildings in a<br />

quantum shift in the s<strong>of</strong>t landscaping<br />

<strong>of</strong> our metropolitan areas.<br />

Driven by the need to respond to<br />

climate change, many government<br />

authorities are now actively<br />

encouraging architects and<br />

construction companies to make<br />

green or ‘living’ ro<strong>of</strong>s a standard<br />

design feature in new buildings.<br />

As part <strong>of</strong> a wider drive on sustainability,<br />

building certification programs such<br />

as BREAM [1] and LEED (Leadership in<br />

Energy and Environmental Design)<br />

now acknowledge the importance<br />

<strong>of</strong> green ro<strong>of</strong>s. As such, many<br />

Technical Article<br />

construction-related credit systems,<br />

grants and other financial incentives<br />

are being put in place to encourage<br />

adoption and new ro<strong>of</strong>ing-related<br />

legislation is also coming into force.<br />

In 2010, in a bid to become the world’s<br />

first carbon neutral city, Copenhagen<br />

introduced a mandatory green ro<strong>of</strong><br />

policy. Legally, all new buildings in<br />

the Danish capital with a ro<strong>of</strong> pitch<br />

<strong>of</strong> less than 30 degrees now have<br />

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to feature some sort <strong>of</strong> green or soil<br />

element. [2] The city <strong>of</strong> Toronto has<br />

also introduced similar by-laws and<br />

other major urban centers are sure<br />

to follow suit.<br />

Widely regarded as an effective tool<br />

in the creation <strong>of</strong> sustainable, low<br />

carbon developments, green ro<strong>of</strong>s<br />

have an array <strong>of</strong> public and private<br />

benefits. When developed correctly<br />

they can:<br />

Assist with water management:<br />

By retaining rainwater for plant<br />

consumption, run <strong>of</strong>f is minimized<br />

reducing the risk <strong>of</strong> localized<br />

flooding.<br />

Improve a building’s insulating<br />

envelope: Adding an extra layer<br />

<strong>of</strong> insulation in the form <strong>of</strong> a green<br />

ro<strong>of</strong> can boost energy efficiency and<br />

reduce heating and cooling costs by<br />

up to 5%.<br />

Reduce the impact <strong>of</strong> urbanization:<br />

Plants improve urban air quality by<br />

filtering out polluting particles that<br />

can create smog. According to US<br />

industry association, Green Ro<strong>of</strong>s For<br />

Healthy Cities; “One square meter <strong>of</strong><br />

grass ro<strong>of</strong> can remove up to 2.0kg<br />

<strong>of</strong> airborne particles every year,<br />

depending on foliage type.” [3]<br />

Decrease the Urban Heat Island<br />

Effect (UHIE): Cities can be up to<br />

10 degrees hotter than rural areas<br />

because <strong>of</strong> the widespread use <strong>of</strong><br />

heat absorbing materials like concrete<br />

and asphalt. Adding more foliage<br />

into metropolitan areas reduces this<br />

problem.<br />

Improve biodiversity: Green ro<strong>of</strong>s<br />

provide a safe refuge for native insect,<br />

bird and animal species that<br />

might otherwise struggle to thrive<br />

amid a mass <strong>of</strong> concrete, glass and<br />

asphalt.<br />

d e c e m b e r 2 0 1 1<br />

Counter urban sprawl: Green ro<strong>of</strong>s<br />

can help create a more aesthetically<br />

pleasing built environment. A<br />

sanctuary away from the hustle and<br />

bustle <strong>of</strong> metropolitan life they are<br />

more visually appealing and can serve<br />

as a relaxing outdoor space for the<br />

people that live, work or regularly<br />

visit a building. They can also reduce<br />

noise pollution by dampening sound<br />

and decreasing the number <strong>of</strong> hard<br />

surfaces available for sound to reflect<br />

<strong>of</strong>f.<br />

Reduce building maintenance<br />

costs: Green ro<strong>of</strong>s can dramatically<br />

increase a ro<strong>of</strong>’s life expectancy by<br />

shielding it from inclement weather.<br />

To realize all <strong>of</strong> these associated<br />

benefits, it is vital that the correct<br />

decisions are made when planning a<br />

green ro<strong>of</strong>. Until recently, the main<br />

materials available to specifiers<br />

were lava stone or heavy bulky<br />

substrates. While effective, these<br />

solutions can prove prohibitive<br />

when it comes to weight, ease <strong>of</strong><br />

installation and sustainability. <strong>Today</strong>,<br />

a new generation <strong>of</strong> lightweight,<br />

intelligent materials is emerging<br />

that have the ability to improve the<br />

construction, maintenance and longterm<br />

performance <strong>of</strong> green ro<strong>of</strong>s.<br />

The construction <strong>of</strong> green ro<strong>of</strong>s,<br />

skyrise gardens and vertical walls<br />

that enhance the sustainability <strong>of</strong> new<br />

buildings or properties undergoing<br />

renovation is now much easier<br />

thanks to an innovative growing<br />

substrate developed by Huntsman<br />

<strong>Polyurethane</strong>s.<br />

VYDRO® substrate is a unique<br />

hydrophilic material unlike any other<br />

currently available. Capable <strong>of</strong> storing<br />

up to 30 times its own weight in water,<br />

and retaining large amounts for a long<br />

period <strong>of</strong> time, this breakthrough<br />

smart water management solution is<br />

Technical Article<br />

a highly effective planting medium for<br />

intensive, extensive green ro<strong>of</strong>s and<br />

vertical walls.<br />

VYDRO® substrate works by locking<br />

in exactly the right balance <strong>of</strong> air and<br />

water needed to optimize successful<br />

plant development. Plant roots can<br />

easily penetrate the inert, PH-neutral<br />

open structured foam enabling rapid<br />

growth and improved crop yields:<br />

third party trials have shown that<br />

plants cultivated using VYDRO®<br />

substrate can generate 5% higher<br />

yields than those produced using<br />

conventional growing methods.<br />

VYDRO® water retention chart<br />

Proven to function where other<br />

materials fail, VYDRO® substrate<br />

enables the creation <strong>of</strong> green ro<strong>of</strong>s in<br />

locations where they were previously<br />

ruled out. In the case <strong>of</strong> vertical walls,<br />

VYDRO® substrate makes it possible<br />

to significantly reduce the costs (up<br />

to 50%) <strong>of</strong> the metal frame structure<br />

needed to sustain the vertical wall<br />

itself. With the ability to rehydrate<br />

over multiple growing cycles and a<br />

water buffering capacity <strong>of</strong> 60%, it can<br />

be used in hot, dry climates. And with<br />

weight savings <strong>of</strong> up to 70% on <strong>of</strong>fer<br />

compared to standard greenro<strong>of</strong>s<br />

systems. It can dramatically simplify<br />

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Technical Article<br />

the installation <strong>of</strong> ‘living’ ro<strong>of</strong>s,<br />

particularly on properties where<br />

weight and structural strength are<br />

a critical factor, for example, in<br />

retr<strong>of</strong>itting older buildings. A one<br />

meter cubed area <strong>of</strong> VYDRO® substrate<br />

weighs just 30 kg. The same area <strong>of</strong><br />

lava stone weighs approximately<br />

1500 kg.<br />

VYDRO® living ro<strong>of</strong>s installed to<br />

date have reduced the weight <strong>of</strong> the<br />

standard substrate down virtually<br />

to zero. In fact, by using a “smart”<br />

solution, comprising a layer <strong>of</strong> VYDRO®<br />

substrate and a sedum carpet on top,<br />

it is possible to achieve a total weight<br />

<strong>of</strong> 40 kg/m2, including 30 l/m2 <strong>of</strong><br />

water retention.<br />

The standard VYDRO® build-up<br />

Weight 50-60 kg/m2 / slope <strong>of</strong> min.<br />

three degrees (Fully saturated)<br />

Super lightweight VYDRO® build-up<br />

a Total weight <strong>of</strong> 40 kg/m2, including<br />

30 l/m2 <strong>of</strong> water retention<br />

a Reduces installation cost.<br />

VYDRO® vertical walls, as mentioned,<br />

can help to drastically reduce total<br />

system weight, and ensure that the<br />

walls remain wet for longer periods<br />

than conventional substrates. In the<br />

VYDRO® vertical walls installed so far,<br />

it has been proven that the weight<br />

reduction achieved, had a strong<br />

36 p o l y u r e t h a n e s t o d a y<br />

impact on the total installation cost<br />

(up to 40% cheaper, due the to lighter<br />

metal frame structure), <strong>of</strong>fering the<br />

same visual effect <strong>of</strong> the finished work<br />

as a standard vertical wall.<br />

VYDRO® build-up for light and<br />

efficient vertical walls<br />

a Total weight reduction<br />

a Installation cost up to 40%<br />

cheaper.<br />

Switching to VYDRO® substrate as<br />

a replacement green ro<strong>of</strong> substrate<br />

brings numerous other benefits.<br />

With superior insulating properties<br />

VYDRO® substrate can improve<br />

a building’s envelope, helping to<br />

minimize temperature loss, reduce<br />

energy consumption levels and cut<br />

heating and cooling costs by up to 5%.<br />

It can also:<br />

• Reduce the risk <strong>of</strong> flooding by<br />

minimizing rainwater run <strong>of</strong>f and<br />

retaining it for plant growth<br />

• Improve air quality: Green ro<strong>of</strong>s<br />

act as filters absorbing polluting<br />

particles that cause smog<br />

• Reduce noise pollution: Vegetation<br />

in cities dampens sound reflection<br />

<strong>of</strong>f hard surfaces<br />

• Minimize the Urban Heat Island<br />

Effect (UHIE): Cities are generally<br />

hotter than rural areas because<br />

<strong>of</strong> the widespread use <strong>of</strong> heat<br />

absorbing materials like concrete<br />

and asphalt. Adding more foliage<br />

into metropolitan areas in the form<br />

<strong>of</strong> green ro<strong>of</strong>s can help mitigate this<br />

problem<br />

• Improve biodiversity: Green ro<strong>of</strong>s<br />

provide a safe refuge for insects,<br />

birds and wildlife<br />

• Save time and money: VYDRO®<br />

substrate is inherently light and can<br />

be compressed, vacuum packed and<br />

shaped to ease transportation and<br />

installation logistics.<br />

Huntsman has a strong network <strong>of</strong><br />

VYDRO® substrate ro<strong>of</strong>ing partners in<br />

place across Europe and interest in the<br />

product is growing with a global list <strong>of</strong><br />

high-pr<strong>of</strong>ile reference sites.<br />

As well as transforming green<br />

ro<strong>of</strong>ing projects in the sustainable<br />

building sector, VYDRO® substrate<br />

is also expected to prove popular in<br />

agricultural initiatives. Its excellent<br />

water retention properties will enable<br />

growers to save money on irrigation<br />

costs, reduce water consumption and<br />

lessen their overall environmental<br />

impact. VYDRO® substrate can also be<br />

used in the manufacture <strong>of</strong> flowerpots<br />

and landscaping and sports projects.<br />

Conclusion<br />

VYDRO® substrate has been created by<br />

Huntsman <strong>Polyurethane</strong>s in response to<br />

some <strong>of</strong> the world’s major environmental<br />

concerns; water scarcity, climate change<br />

and increased urbanization.<br />

Finding new ways to tackle climate change<br />

and manage water in an intelligent way<br />

is vital, particularly in urban areas<br />

where populations are increasing and<br />

urbanization is having a stark impact on<br />

the environment. Getting more vegetation<br />

into cities and reducing the use <strong>of</strong> hard<br />

landscaping materials, is now a priority<br />

for many countries and installing green<br />

ro<strong>of</strong>s is an effective way to achieve this.<br />

With government legislation, financial<br />

incentives and new buildings standards<br />

encouraging the adoption <strong>of</strong> green ro<strong>of</strong>s,<br />

the sector is buoyant. What better time<br />

to launch VYDRO® substrate – a product<br />

that makes it far easier to create green<br />

ro<strong>of</strong>s and vertical walls, and helps embed<br />

smart water management capabilities<br />

into horticultural applications, bringing<br />

sustainability benefits to people and the<br />

planet.<br />

d e c e m b e r 2 0 1 1


Report: IPUA & Honeywell’s Seminar on<br />

Next Generation Blowing Agents for<br />

<strong>Polyurethane</strong> Foam<br />

Mumbai, November 4, 2011<br />

Honeywell Specialty Materials,<br />

in association with <strong>India</strong>n<br />

<strong>Polyurethane</strong> <strong>Association</strong> (IPUA)<br />

organized a conference for the <strong>India</strong>n<br />

<strong>Polyurethane</strong> Industry in Mumbai,<br />

<strong>India</strong> on 04th November, 2011.<br />

Titled ‘Next Generation Blowing<br />

Agents for <strong>Polyurethane</strong> Foam’<br />

the conference witnessed the<br />

participation <strong>of</strong> Honeywell Fluorine<br />

Products team led by Mr. Paul<br />

Sanders, Managing Director, Fluorine<br />

Products, EMEAI, Mr. Sanjeev Rastogi,<br />

Global Business Director, Honeywell<br />

– Foams and Mr. David Williams,<br />

Technical Director, Blowing Agents<br />

along with Mr. Mukesh Bhuta, Vice<br />

-Chairman, IPUA.<br />

The event also marked the launch<br />

<strong>of</strong> Honeywell’s new Solstice Liquid<br />

Blowing Agent by Paul Sanders and<br />

Sanjeev Rastogi in <strong>India</strong>. Speaking<br />

on the launch, Paul Sanders, said,<br />

“With Solstice Liquid Blowing Agent,<br />

we are pleased to announce the<br />

expansion <strong>of</strong> our family <strong>of</strong> lowglobal-warming-potential<br />

products,<br />

which are helping our customers<br />

around the world lower their carbon<br />

footprint while maximizing endproduct<br />

performance.”<br />

Delivering the key-note address,<br />

Mr. Mukesh Bhuta spoke about<br />

the current transition scenario and<br />

challenges for ozone depleting HCFC<br />

blowing agents in <strong>India</strong>. Speaking on<br />

the conference, he said, “The event<br />

d e c e m b e r 2 0 1 1<br />

IPUA Ventures<br />

Mr. Paul Sanders, Managing Director, Honeywell Fluorine Products - EMEAI<br />

IPUA Vice Chairman Mr. Mukesh Bhuta<br />

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eceived an excellent participation<br />

especially from Mumbai and near<br />

by regions. IPUA and Honeywell<br />

will take this forward and conduct<br />

more such conferences across the<br />

country to meet our industry peers<br />

and educate them about these latest<br />

product developments.” Regarding<br />

the launch <strong>of</strong> Solstice Liquid Blowing<br />

agent from Honeywell Fluorine<br />

Products, Mr. Bhuta said, “ Looking<br />

at the information shared on Solstice<br />

Liquid Blowing Agent, it seems to be<br />

a very promising product with great<br />

potential to be a drop in solution to<br />

HCFCs and hydrocarbons and with<br />

improved product performance”.<br />

Technical papers presented at the<br />

conference by Honeywell’s David<br />

Williams and Ben Lu highlighted the<br />

Blowing Agent’s four dimensional<br />

excellence <strong>of</strong>fered through its<br />

energy efficiency performance,<br />

environmental impact, safety in use,<br />

and cost-effectiveness.<br />

The event was well attended by<br />

the <strong>India</strong>n Poyurethane Industry<br />

including leading system houses,<br />

PU panel manufacturers, domestic<br />

and commercial refrigerator<br />

manufacturers and spray foam<br />

companies.<br />

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Honeywell Seminar<br />

Honeywell Seminar<br />

Honeywell Seminar<br />

IPUA Ventures<br />

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Polyols for improved HR slabstock foams<br />

K.Pickin, Corporate Business Development Manager, PCC SE<br />

High resilience (HR) foams have<br />

been utilized by the furnishings<br />

and mattress manufacturing industry<br />

for decades, with several polyurethane<br />

raw material suppliers <strong>of</strong>fering<br />

various solutions. The key property<br />

driving the adoption <strong>of</strong> these types <strong>of</strong><br />

flexible foams compared to standard<br />

foams is superior comfort at the<br />

same foam density. However, despite<br />

their long history, wide adoption<br />

and the expertise <strong>of</strong> competent<br />

foam manufacturers these HR foams<br />

types have not been fully optimized<br />

in terms <strong>of</strong>, for instance, yield and<br />

physical properties.<br />

Introduction<br />

In recent years there has been<br />

a significant increase in the<br />

manufacture <strong>of</strong> HR foams in Europe<br />

and, as expected, HR foams are now<br />

attracting the attention <strong>of</strong> many foam<br />

manufacturers in North America and<br />

Asia. Foam manufacturers in <strong>India</strong><br />

who are seeking to expand their<br />

foam range into superior comfort,<br />

high quality applications will find<br />

this development particularly<br />

interesting. In discussion with<br />

customers, especially in relation to<br />

future developments, PCC Rokita, a<br />

subsidiary <strong>of</strong> PCC SE headquartered<br />

in Duisburg, Germany, was made<br />

aware <strong>of</strong> the potential improvements<br />

that customers would like achieve<br />

with their HR foams.<br />

Thus improved HR foam technology<br />

became a key element in PCC<br />

Rokita’s emerging product expansion<br />

strategy.<br />

With this knowledge the research and<br />

40 p o l y u r e t h a n e s t o d a y<br />

development experts then set about<br />

developing new materials to enable<br />

the production <strong>of</strong> a range <strong>of</strong> superior<br />

HR foams featuring:<br />

• High comfort factor<br />

• Excellent durability<br />

• Class leading shape retention<br />

• Low odour<br />

• Wide density/hardness range<br />

• High yield<br />

Rokopol iPol – a case history<br />

In addition to the usual in-depth<br />

technical expertise and production<br />

know-how <strong>of</strong> different high resilience<br />

foam technologies, to improve the<br />

final foam and in turn mattress<br />

comfort properties, a study was<br />

undertaken to provide a genuine<br />

understanding <strong>of</strong> the needs <strong>of</strong> the<br />

whole supply change. In this case<br />

study, within the section <strong>of</strong> the supply<br />

chain involving polyols producer to<br />

end user there are essentially four<br />

key levels:<br />

1. Polyols producer<br />

2. Foam manufacturer<br />

3. Mattress manufacturer<br />

4. Retailer/End user<br />

Traditionally the supply chain<br />

is viewed as a flow <strong>of</strong> materials<br />

going, in this case, from polyols<br />

supplier to foam manufacturer<br />

to mattress producer to end user.<br />

Information usually follows in the<br />

same direction. However adding a<br />

flow <strong>of</strong> information in the reverse<br />

direction from end user to mattress<br />

producer to foam manufacturer to<br />

polyols producer gives an insight in<br />

to the needs throughout the supply<br />

chain. With this valuable information<br />

it is possible to target exactly what<br />

should be improved to meet the<br />

needs <strong>of</strong> each level in the chain<br />

and ultimately add value for every<br />

member <strong>of</strong> that chain.<br />

The supply chain needs analysis for<br />

Rokopol iPol is illustrated below:<br />

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In this illustration the material flow<br />

is shown in the top section from left<br />

to right but the information flow<br />

informing what needs to be improved<br />

is from right to left as shown in the<br />

middle section. There are <strong>of</strong> course<br />

some overarching considerations<br />

such as statutory compliance which<br />

is indicated in the arrow headed text<br />

box. Clearly not every articulated<br />

need is listed here. It is important to<br />

note that information doesn’t have<br />

to be passed along in sequence;<br />

it can be very helpful to highlight<br />

needs directly to the company in<br />

the supply chain that can actually<br />

<strong>of</strong>fer a solution. Yes, talking to<br />

customers’ customers can be a source<br />

<strong>of</strong> friction but careful explanation <strong>of</strong><br />

the benefits <strong>of</strong> finding value-adding<br />

solutions throughout the supply<br />

chain was found to minimize any<br />

sensitivity.<br />

Needs examples range from the very<br />

specific “we want to reduce cold<br />

flow” (foam manufacturer), “we don’t<br />

want mattress cores snapping in two<br />

during transport/handling” (mattress<br />

producer) to generic “we would like<br />

more comfort” (user). Interpreting the<br />

causes <strong>of</strong> these weaknesses or sources<br />

<strong>of</strong> improvement and providing<br />

subsequent solutions brings tangible<br />

benefits to the relevant section <strong>of</strong> the<br />

supply chain.<br />

This solutions engineering involved<br />

the following series <strong>of</strong> activities<br />

leading to new polyol for HR foams.<br />

Benchmark existing HR<br />

technologies<br />

i<br />

Screen potential HR technologies<br />

for development<br />

i<br />

Select key improvements<br />

(determined from supply chain<br />

needs analysis)<br />

i<br />

d e c e m b e r 2 0 1 1<br />

Develop candidate polyols<br />

i<br />

Develop effective foam<br />

formulations<br />

i<br />

Trials at foam manufacturers<br />

i<br />

Verification at mattress producer<br />

The overall aim was met:<br />

To <strong>of</strong>fer a polyol which enables foam<br />

manufacturers to produce a wide<br />

range <strong>of</strong> high yield, cost effective,<br />

durable high comfort foams.<br />

Easy processing<br />

Foam manufacturers highlighted the<br />

need for easy, fault free processing<br />

which in turn has a significant impact<br />

on end–<strong>of</strong>-line prime foam yield.<br />

They also needed to be able to provide<br />

consistent foams (e.g. minimise top/<br />

bottom variation) with a wide density<br />

and hardness range. By utilising<br />

extensive technical service knowhow<br />

to develop suitable practical<br />

foam formulations and working with<br />

leading foam manufacturers the<br />

following was achieved:<br />

• Easy Processing on trough<br />

or reciprocating head type,<br />

high or low pressure foam<br />

manufacturing machinery.<br />

• Wide Processing Window.<br />

• Simple Foam Formulations<br />

minimizing capital investment<br />

• Wide Density and Hardness<br />

range<br />

• High Yield with good Block<br />

Shape (no cold flow)<br />

• Excellent Density and Hardness<br />

Distribution<br />

Fire safety test compliance<br />

Depending on the geographic location<br />

and local regulatory or purchaser<br />

specified test criteria various fire test<br />

Special Feature<br />

standards must be complied with.<br />

Rokopol iPol technology <strong>of</strong>fers cost<br />

effective compliance by utilising low<br />

levels <strong>of</strong> halogenated fire retardants<br />

and /or melamine. Compliance<br />

examples:<br />

• FMVSS 302 (no flame retardant<br />

additive depending on foam<br />

density)<br />

• California 117 A and D (small<br />

amount <strong>of</strong> flame retardant<br />

additive)<br />

• Crib 5 BS 5852 part 2 (limited<br />

addition <strong>of</strong> flame retardant<br />

additive or without melamine)<br />

• B2 to EN ISO 11925-2 (limited<br />

addition <strong>of</strong> flame retardant<br />

additive or without melamine)<br />

Example formulation and physical<br />

properties <strong>of</strong> a CMHR type foam produced<br />

on a low pressure Maxfoam machine:<br />

Rokopol iPol M 90phr<br />

Rokopol M6000 10phr<br />

TDI Index 99<br />

Total water 2.53phr<br />

DEOA 1.02phr<br />

Antiblaze WR30 LV 15phr<br />

+ standard HR additives,<br />

NO melamine<br />

Density 41kg/<br />

m3<br />

CLD 40% 3.0kPa<br />

Tensile strength 130kPa<br />

Elongation 103%<br />

Compression set 5.5%<br />

22h/50%/70degC<br />

Sag factor 3.3<br />

Resilience (ball rebound) 65%<br />

BS5852 part 2 crib 5 Pass<br />

Data courtesy <strong>of</strong> CT Formpolster<br />

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Rokopol iPol typical<br />

properties<br />

Appearance homogeneous<br />

white liquid<br />

Hydroxyl value 50 mg KOH/g<br />

Water content max. 0.1%(m/m)<br />

Acid Value max. 0.1<br />

mgKOH/g<br />

Viscosity at 25 o C 3,000 mPas<br />

Density at 25 o C 1.047<br />

Low odour<br />

An issue reported by foam and<br />

mattress manufacturers alike is that<br />

<strong>of</strong> foam odour. Prevention is the<br />

key here. By elimination <strong>of</strong> odour<br />

creating components such as styrene,<br />

acrylonitrile, DBTDL catalyst and<br />

polymerisation initiator and with<br />

correct choice <strong>of</strong> ancillary chemicals<br />

at the foam manufacturing stage low<br />

odour foams were achieved.<br />

As an example, residual VOC (Volatile<br />

Organic Compound) tests carried out<br />

to LGA standard on a Rokopol iPol<br />

based foam <strong>of</strong> 60 kg/m3 density<br />

showed the following results:<br />

Total Emmissions 60 kg/m3 foam<br />

After 3 days 95 ppm<br />

After 7 days 25ppm<br />

As a comparison, typical levels<br />

for a similar styrene/acrylonitrile<br />

copolymer polyol foam are:<br />

220ppmm after 3days and 100ppm<br />

after 7days.<br />

Physical properties<br />

It is clear that all HR foams must meet<br />

customer specifications. However<br />

foam “touch” has an important part<br />

to play in conveying high quality<br />

d e c e m b e r 2 0 1 1<br />

and perceived comfort. Foam<br />

manufacturers and users frequently<br />

describe this touch as “latex- like”.<br />

In terms <strong>of</strong> measurable physical<br />

properties two items are generally<br />

considered to be associated with<br />

this feature:<br />

Resilience (ball rebound) and Sag<br />

Factor (extracted from stress/strain<br />

hysteresis data) where numerical<br />

values <strong>of</strong> >60% and >3 respectively<br />

are considered to be good results.<br />

Rokopol iPol derived HR foams<br />

are notable for their latex-like feel<br />

with externally verified foam tests<br />

showing up to almost 70% resilience<br />

and Sag Factors exceeding 3.3.<br />

Examples <strong>of</strong> externally independently<br />

measured physical properties for<br />

typical HR foams are given below:<br />

Property summary<br />

Throughout the supply chain<br />

performance targets were met or<br />

Special Feature<br />

exceeded. Each <strong>of</strong> the highlighted<br />

features below represents a value<br />

adding benefit for members <strong>of</strong><br />

the supply chain <strong>of</strong>ten creating<br />

important selling points for their<br />

direct customers.<br />

• Easy processing<br />

• High yield<br />

• Very High Resilience – up to 70%<br />

DIN 5357(Type A)<br />

• Latex-Like Comfort, Sag factor<br />

typically 3.3<br />

• First-Rate Compression Set<br />

• Excellent Flex Fatigue Properties<br />

• Superior Latex-Like Touch<br />

• Low Odour foams<br />

• Cost effective Fire Test Compliance<br />

Property Foam A Foam B Foam C Test Method Units<br />

Density 38.5 35 58 DIN EN ISO 845 kg/m3<br />

CLD 40% 2.5 2.72 4.1 EN ISO 3386-1 kPa<br />

Tensile Strength 108 123 103 EN ISO 1798 kPa<br />

Elongation to Break 110 116 93 EN ISO 1798 %<br />

Resilience 69 66 69 DIN 5357 (Type A) %<br />

Compression Set 3.4 3.7 2.2 DIN EN ISO1856 %<br />

(70 o C, 22hr, 50%)<br />

Flex Fatigue CLD Loss 18 24 n/a DIN EN ISO 3385 %<br />

Flex Fatigue Height Loss 1.5 2.8 n/a DIN EN ISO 3385 %<br />

p o l y u r e t h a n e s t o d a y<br />

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PU<br />

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44 p o l y u r e t h a n e s t o d a y<br />

d e c e m b e r 2 0 1 1


d e c e m b e r 2 0 1 1<br />

Environment & Safety<br />

China may agree to binding CO2 cuts - envoy<br />

By Stian Reklev | Reuters<br />

DURBAN (Reuters) - China gave<br />

U.N. climate talks a lift on Friday<br />

by confirming it may sign up to a<br />

legally binding deal to cut emissions<br />

<strong>of</strong> heat-trapping gases, a move<br />

that could help rescue talks about<br />

the future <strong>of</strong> the Kyoto Protocol,<br />

observers said.<br />

Delegates from more than 190<br />

nations are in the coastal city <strong>of</strong><br />

Durban to try to break a four-year<br />

deadlock to secure a new global deal<br />

that will bind countries to cut and<br />

slow down growth in emissions <strong>of</strong> six<br />

main greenhouse gases.<br />

“We do not rule out the possibility <strong>of</strong><br />

legally binding. It is possible for us,<br />

but it depends on the negotiations,”<br />

Su Wei, China’s lead negotiator, said<br />

- speaking in English - at a media<br />

briefing on the sidelines <strong>of</strong> the twoweek<br />

talks in South Africa.<br />

The EU has said it will sign up to a<br />

second round <strong>of</strong> targets under the<br />

1997 Kyoto Protocol, but only if all<br />

big emitters agree legally binding<br />

cuts that will start in 2020.<br />

So far, China, <strong>India</strong> and the United<br />

States, the world’s top three emitters,<br />

are not bound by Kyoto and have<br />

refused to commit to legal targets,<br />

raising the prospect that no country<br />

will have targets to cut emissions<br />

after 2012.<br />

“Since the EU is the only group <strong>of</strong><br />

parties that is ready to consider a<br />

second commitment period (under<br />

Kyoto) we are ready and willing to<br />

engage constructively with the EU,”<br />

said Su.<br />

Li Yan, a campaigner with Greenpeace<br />

China said, “China is trying to find a<br />

middle ground, especially with<br />

Europe, which would need to<br />

reconcile with China’s priorities for<br />

the conference, which are a second<br />

commitment period <strong>of</strong> the Kyoto<br />

Protocol and operationalisation <strong>of</strong><br />

the Green Climate Fund.”<br />

China wants negotiations to kick<br />

start a fund that would contribute<br />

to raising $100 billion a year by 2020<br />

to help the poorest nations adapt<br />

to climate change and cut their<br />

emissions.<br />

Traction<br />

Time is running out to reach<br />

agreement on a deal for meaningful<br />

cuts in the emissions blamed for<br />

worsening storms and raising sea<br />

levels to a point that would wipe out<br />

several small island states, experts<br />

said.<br />

Earlier in the day, senior EU negotiator,<br />

Tomasz Chruszczow, said the bloc’s<br />

plan to have a deal in place by 2015<br />

and entering into force in 2020 was<br />

“getting traction”.<br />

China has previously said it supported<br />

legal targets for others, but not for<br />

itself.<br />

The talks end on December 9 and<br />

South Africa’s President Jacob Zuma<br />

signalled the host is looking for a<br />

deal that puts more <strong>of</strong> an onus on<br />

rich nations to cut greenhouses gases<br />

than the developing nations most<br />

harmed by rising temperatures.<br />

Canada and Russia have bluntly<br />

So far, China, <strong>India</strong><br />

and the United States,<br />

the world’s top three<br />

emitters, are not bound<br />

by Kyoto and have<br />

refused to commit to<br />

legal targets, raising<br />

the prospect that no<br />

country will have<br />

targets to cut emissions<br />

after 2012.<br />

refused to sign another target under<br />

Kyoto, while Japan on Friday asked<br />

for a fresh look on a new treaty that<br />

encompasses all major emitters.<br />

Negotiators said the outline <strong>of</strong> the<br />

EU plan <strong>of</strong>fers a political cushion for<br />

many countries by setting 2015 as a<br />

deadline for a new deal, which would<br />

be implemented by 2020.<br />

Meanwhile, negotiators from small<br />

island states most at risk <strong>of</strong> rising<br />

sea levels want a new deal to start<br />

in 2013, although observers say this<br />

is highly unlikely to happen.<br />

Envoys could say they made<br />

progress in Durban by agreeing to<br />

an encompassing agreement, leaving<br />

the details <strong>of</strong> how the deal would<br />

work to a later date.<br />

(Additional reporting by Michael<br />

Szabo and Jon Herskovitz; Writing<br />

by Andrew Allan; Editing by Louise<br />

Ireland)<br />

p o l y u r e t h a n e s t o d a y<br />

45<br />

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PU<br />

<strong>Today</strong><br />

Previews & Reports<br />

Leading International Exhibition<br />

& Conference Celebrates 75 Years <strong>of</strong> Global<br />

<strong>Polyurethane</strong>s Industry<br />

UTECH Europe Exhibition and Conference, 17-19 April 2012, MECC, Maastricht, The Netherlands<br />

29 November 2011 – 75 years<br />

after Pr<strong>of</strong>. Otto Bayer’s initial patent<br />

marking the advent <strong>of</strong> polyurethanes<br />

chemistry in 1937, the organisers <strong>of</strong><br />

UTECH Europe 2012 taking place<br />

in Maastricht, The Netherlands 17-<br />

19 April, have announced the full<br />

speaker programme for the threeday<br />

conference and confirmed that<br />

the accompanying exhibition will<br />

be the biggest ever staged. Anyone<br />

wishing to book a place at the<br />

conference or register for the freeto-attend<br />

exhibition can now do so<br />

online at www.utecheurope.eu<br />

Often described as the hidden<br />

polymer, polyurethanes are ever<br />

more widely used throughout<br />

manufacturing and construction<br />

industries today. Applications are as<br />

diverse as automotive, aerospace,<br />

building and construction, furniture<br />

and bedding, electrical and electrotechnical,<br />

footwear and textiles,<br />

mining and <strong>of</strong>fshore, pipes and<br />

pipelines, refrigeration and insulation<br />

as well as specialist surgical and<br />

medical.<br />

The UTECH Europe 2012 exhibition<br />

and conference <strong>of</strong>fers materials<br />

specialists from across all these<br />

industries the perfect opportunity<br />

to see global advancements in<br />

polyurethane technology including<br />

all the latest products and machines.<br />

Among more than 100 exhibitors<br />

are industry leaders Bayer, BASF,<br />

Huntsman, BorsodChem, Wanhua,<br />

Shell, Repsol, Baule, Dow, Silcart<br />

and Evonik as well as systems<br />

houses, technical consultancies, and<br />

46 p o l y u r e t h a n e s t o d a y<br />

test laboratories.<br />

“Interest from exhibitors has been<br />

so strong that we have just had to<br />

extend the exhibition space to cater<br />

for increased demand and this too<br />

is selling fast,” said Sue Rothwell,<br />

Business Development Director at<br />

Crain Communications, organisers <strong>of</strong><br />

UTECH Europe. “This is set to be our<br />

most successful event ever.”<br />

Opening the UTECH Europe threeday<br />

conference will be a keynote<br />

presentation from Ding Jiansheng,<br />

Chairman <strong>of</strong> Yantai Wanhua<br />

<strong>Polyurethane</strong>s Co Ltd, China, leading<br />

into a Plenary Session focused on<br />

celebrating the 75th Anniversary<br />

<strong>of</strong> the invention <strong>of</strong> polyurethanes<br />

chemistry. Six further presentations<br />

look back over the history <strong>of</strong> the<br />

industry and assess its prospects for<br />

the future. Experts will discuss the<br />

development <strong>of</strong> the key raw materials<br />

and processing equipment used to<br />

make these versatile materials.<br />

In the afternoon <strong>of</strong> the first day two<br />

papers look at the development<br />

<strong>of</strong> and prospects for the global<br />

markets amid the current turmoil<br />

in the world’s leading economies,<br />

including a special report on the<br />

development <strong>of</strong> the polyurethanes<br />

industry in Indonesia. This is followed<br />

by an Innovations session, with eight<br />

papers detailing recent work from the<br />

world’s leading suppliers. The parallel<br />

session in the afternoon comprises 10<br />

papers looking at the latest advances<br />

in “Green” chemistry, raw materials<br />

based on renewable resources.<br />

The main technical conference<br />

continues through to 19 April, in a<br />

series <strong>of</strong> half-day sessions focused<br />

on the key technical developments<br />

in the use <strong>of</strong> polyurethanes to<br />

make rigid and flexible foams, and<br />

CASE products (coatings, adhesives,<br />

sealants and elastomers), with a<br />

separate session on the final day<br />

discussing more scientific approaches<br />

to the production <strong>of</strong> PU-based<br />

products.<br />

In addition to the technical<br />

programme, there will be separate<br />

sessions created by ISOPA (the<br />

European Diisocyanate and Polyols<br />

Producers <strong>Association</strong>) and the<br />

Polyurea Development <strong>Association</strong><br />

Europe. The first <strong>of</strong> these, in the<br />

afternoon <strong>of</strong> the second day <strong>of</strong> the<br />

conference, will address key safety,<br />

health and environmental issues<br />

including an overview <strong>of</strong> the latest<br />

life-cycle analysis work on rigid<br />

PU foams and details <strong>of</strong> the latest<br />

US legislation, Chemical Action<br />

Plans, and their likely impact on the<br />

industry.<br />

“In the 75th Year <strong>of</strong> <strong>Polyurethane</strong>,<br />

which is also the 25th anniversary<br />

<strong>of</strong> ISOPA, the visibility <strong>of</strong> this ‘hidden’<br />

polymer still has to be increased,”<br />

said Dr. Frank Wolfram, ISOPA’s<br />

Secretary General. “ISOPA will have<br />

a strong presence at UTECH Europe<br />

2012 and we look forward to seeing<br />

everyone in Maastricht.”<br />

“Our keynote speaker will be the<br />

ISOPA president Steven English<br />

and the ISOPA stand will convey<br />

d e c e m b e r 2 0 1 1


two key messages, which are both<br />

part <strong>of</strong> the special ISOPA session,”<br />

Wolfram continued. “These are<br />

the launch <strong>of</strong> our new Product<br />

Stewardship program Walk the<br />

Talk 2nd generation focusing on<br />

the requirements <strong>of</strong> REACH and an<br />

update <strong>of</strong> the new <strong>Polyurethane</strong><br />

Passive House Project in Brussels,<br />

which positions <strong>Polyurethane</strong> as the<br />

high performing and sustainable<br />

insulation material contributing to<br />

reduce Europe’s CO² emissions.”<br />

In the second special session,<br />

on the morning <strong>of</strong> the final day<br />

d e c e m b e r 2 0 1 1<br />

<strong>of</strong> the conference, 19 April, the<br />

latest commercial and technical<br />

developments relating to the fastgrowing<br />

polyureas market will be<br />

discussed.<br />

Last time the event was held in<br />

2009 visitors came from more<br />

than 85 dif ferent countrie s<br />

worldwide. In 2012, thousands are<br />

expected to travel to Maastricht<br />

for all the latest information on<br />

polyurethane technology from<br />

isocyanates, polyester polyols,<br />

polyether polyols, formulated<br />

systems and ancillary chemicals, as<br />

p u t o d a y a d v e r t i s e m e n t ta r i f f<br />

Previews & Reports<br />

Advertisement 1 Issue 2 Issues 4 Issues<br />

Back Cover 16,000.00 15,000.00 14,000.00<br />

USD 355 USD 335 USD 310<br />

Inside Front Cover 12,000.00 11,000.00 10,000.00<br />

USD 265 USD 245 USD 225<br />

Inside Back Cover 12,000.00 11,000.00 10,000.00<br />

USD 265 USD 245 USD 225<br />

Full Page Colour 10,000.00 9,500.00 9,000.00<br />

USD 225 USD 215 USD 200<br />

Half Page Colour 6,000.00 5,500.00 5,000.00<br />

USD 135 USD 130 USD 125<br />

Quarter Page 4,000.00 3,500.00 3,000.00<br />

USD 90 USD 80 USD 70<br />

1/8th Page 2,000.00 1,750.00 1,500.00<br />

Sponsored Feature (2 pages ) Rs 12,000 (USD 270)<br />

Each Additional Page Rs 4000 (USD 100)<br />

well as surfactants, catalysts and<br />

flame retardants. Manufacturing<br />

technology innovations unveiled at<br />

the exhibition will include the latest<br />

cutting equipment and machinery<br />

for making flexible foams, rigid<br />

foams, elastomers, reaction injection<br />

moulding and test equipment.<br />

Anyone wishing to attend the<br />

paid-for UTECH Europe conference<br />

and the free-to-attend exhibition<br />

can now register online at www.<br />

utecheurope.eu A wealth <strong>of</strong> travel and<br />

accommodation information is also<br />

available on the event website.<br />

Service Tax is applicable at the rate <strong>of</strong> 10.30% as per Government rules. The Inside Front & Back Covers And Back Cover<br />

are already booked for the next four issues.<br />

Technical Details <strong>of</strong> the Ad<br />

Bleed Size: 8.5 In X 11 In (21.59 Cm W X 27.94 In H) (Letter Size)<br />

Print Area: 7 in x 9.24 in (17.8 cm W x 29.50 cm H)<br />

YOU HAVE TO SEND THE MATTER IN A PDF FILE OR EPS OR TIFF FORMATS<br />

ALL MATTER TO BE SENT TO<br />

Ramamurthy K<br />

Secretary<br />

INDIAN POLYURETHANE ASSOCIATION<br />

Flat 7, III Floor, Shakti Mahal, New 24, Old 41, First Main Road, CIT Colony,<br />

Mylapore, CHENNAI 600 004. Tel/Fax: 044 2499 5923, H/P: 94440 55923<br />

Email: ramamurthy_k2@dataone.in admin@pu-india.org ramapu42@gmail.com<br />

p o l y u r e t h a n e s t o d a y<br />

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PU<br />

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48 p o l y u r e t h a n e s t o d a y<br />

d e c e m b e r 2 0 1 1


Book Description<br />

Publication Date: September 20, 2010<br />

A “Think Different” Approach to<br />

Innovation Based on The Seven Guiding<br />

Principles <strong>of</strong> Apple CEO Steve Jobs<br />

In his acclaimed bestseller The<br />

Presentation Secrets <strong>of</strong> Steve Jobs<br />

author Carmine Gallo laid out a simple<br />

step-by-step program <strong>of</strong> powerful tools<br />

and proven techniques inspired by Steve<br />

Jobs’s legendary presentations. Now, he<br />

shares the Apple CEO’s most famous,<br />

most original, and most effective<br />

strategies for sparking true creativity<br />

and real innovation in any workplace.<br />

The Innovation Secrets Of<br />

Steve Jobs<br />

“Steve Jobs has reinvented music<br />

distribution, the mobile telephone,<br />

and book publishing. You might want<br />

to take a look at how someone creates<br />

multi-billion dollar ideas, and turns<br />

them into multi-billion dollar products<br />

that everyone loves and admires. This<br />

book is not an option. Buy it now, bank<br />

it tomorrow.”<br />

– Jeffrey Gitomer, author <strong>of</strong> The Little<br />

Red Book <strong>of</strong> Selling<br />

“In The Innovation Secrets <strong>of</strong> Steve Jobs,<br />

Carmine Gallo captures the true mindset<br />

<strong>of</strong> Jobs and Apple. This book is not just<br />

for the techie and marketing crowd,<br />

although they will gain valuable insight<br />

that can be applied to their worlds. It is<br />

also for anyone who loves technology<br />

and wants to understand how to create<br />

simple devices that are easy to use and<br />

can impact our lives.”<br />

– Tim Bajarin, president, Creative<br />

Strategies, Inc.<br />

“An inspiring roadmap for anyone<br />

who wants to live a life <strong>of</strong> passion and<br />

purpose.”<br />

d e c e m b e r 2 0 1 1<br />

– Tony Hsieh, author <strong>of</strong> Delivering<br />

Happiness and CEO <strong>of</strong> Zappos.com,<br />

Inc.<br />

“Apple changed the world with the Mac<br />

and hasn’t stopped innovating since.<br />

Carmine Gallo reveals the secrets and<br />

gives you the tools to unleash your<br />

inner Steve.”<br />

– Marc Beni<strong>of</strong>f, chairman and CEO<br />

<strong>of</strong> salesforce.com and author <strong>of</strong> the<br />

national bestseller Behind the Cloud<br />

Learn how to RETHINK your business,<br />

REINVENT your produc ts, and<br />

REVITALIZE your vision <strong>of</strong> success the<br />

Steve Jobs way.<br />

When it comes to innovation, Apple CEO<br />

Steve Jobs is legendary. His company<br />

slogan “Think Different” is more than<br />

a marketing tool. It’s a way <strong>of</strong> life a<br />

powerful, positive, game changing<br />

approach to innovation that anyone can<br />

apply to any field <strong>of</strong> endeavor.<br />

These are the Seven Principles <strong>of</strong><br />

Innovation, inspired by the master<br />

himself:<br />

1. Do What You Love.<br />

Think differently about your<br />

career.<br />

2. Put a Dent in the Universe.<br />

Think differently about your<br />

vision.<br />

3. Kick Start Your Brain.<br />

Think differently about how you<br />

think.<br />

4. Sell Dreams, Not Products.<br />

Think differently about your<br />

customers.<br />

Books & Periodicals<br />

5. Say No to 1,000 Things.<br />

Think differently about design.<br />

6. C r e a t e I n s a n e l y G r e a t<br />

Experiences.<br />

Think differently about your brand<br />

experience.<br />

7. Master the Message.<br />

Think differently about your<br />

story.<br />

By following Steve Jobs’s visionary<br />

example, you’ll discover exciting new<br />

ways to unlock your creative potential<br />

and to foster an environment that<br />

encourages innovation and allows<br />

it to flourish. You’ll learn how to<br />

match and beat the most powerful<br />

competitors, develop the most<br />

revolutionary products, attract the<br />

most loyal customers, and thrive in<br />

the most challenging times. Bestselling<br />

business journalist Carmine Gallo has<br />

interviewed hundreds <strong>of</strong> successful<br />

pr<strong>of</strong>essionals-from CEOs, managers, and<br />

entrepreneurs to teachers, consultants,<br />

and stay at home moms to get to the core<br />

<strong>of</strong> Steve Jobs’s innovative philosophies.<br />

These are the simple, meaningful, and<br />

attainable principles that drive us all to<br />

“Think Different.”<br />

The Innovation Secrets <strong>of</strong> Steve Jobs<br />

<strong>of</strong>fers precious guidance as it presents<br />

key principles that allowed Steve Jobs to<br />

constantly, brilliantly innovate.<br />

p o l y u r e t h a n e s t o d a y<br />

49<br />

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PU<br />

<strong>Today</strong><br />

Events & Trends<br />

30 Jan - 02 Feb 2012<br />

Sprayfoam Convention & Expo<br />

2012<br />

Spray <strong>Polyurethane</strong> Foam<br />

Alliance<br />

Dallas<br />

01 - 06 Feb 2012<br />

Plastindia 2012<br />

Plastindia Foundatio<br />

New Delhi<br />

07 - 08 Mar 2012<br />

26th IKV International Plastics<br />

Technology<br />

kv Aachen<br />

ColloquiumI<br />

22 - 21 Mar 2012<br />

Plastics In Automotive<br />

Engineering 2012<br />

Vdi Wissensforum Gmbh<br />

Mannheim<br />

26 - 29 Mar 2012<br />

PDA National Conference 2012<br />

Polyurea Development<br />

<strong>Association</strong><br />

Orlando<br />

01 - 05 Apr 2012<br />

NPE 2012<br />

Spi - Society Of The Plastics<br />

Industry<br />

Orlando<br />

50 p o l y u r e t h a n e s t o d a y<br />

Events Calendar<br />

INTERNATIONAL<br />

01 - 05 Apr 2012<br />

Antec 2012<br />

Society Of Plastics Engineers<br />

Orlando<br />

15 - 17 Apr 2012<br />

Adhesive And Sealant Spring<br />

Convention<br />

The Adhesive And Sealant<br />

Council, Inc<br />

Denver<br />

16 - 17 Apr 2012<br />

3rd International Confernce On<br />

Flame Retardants<br />

Sino - German Plastic<br />

Technology Ser...<br />

Shanghai<br />

17 - 19 Apr 2012<br />

Utech Europe 2012<br />

Crain Communications<br />

Maastricht Netherlands<br />

18- 21 April 2012<br />

Chinaplas 2012<br />

Adsale Exhibition Services Ltd<br />

Shanghai<br />

07 - 10 May 2012<br />

American Coatings Show And<br />

Conference 2012<br />

Vincentz Network Gmbh & Co.<br />

Kg<br />

<strong>India</strong>napolis<br />

08 - 12 May 2012<br />

Plast 2012<br />

Fiera Milano International S.P.A.<br />

Milano<br />

14 - 17 May 2012<br />

Plastivision Arabia<br />

Expo Centre Sharjah<br />

Sharjah<br />

16 – 21 Sept 2012<br />

World Adhesive Conference<br />

Feica<br />

Paris<br />

16-23 Oct 2013<br />

K 2013<br />

Messe Düsseldorf Gmbh<br />

Dusseldorf<br />

08 - 14 May 2014<br />

Interpack<br />

Messe Düsseldorf Gmbh<br />

Dusseldorf<br />

d e c e m b e r 2 0 1 1


d e c e m b e r 2 0 1 1<br />

p o l y u r e t h a n e s t o d a y<br />

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PU<br />

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52 p o l y u r e t h a n e s t o d a y<br />

d e c e m b e r 2 0 1 1<br />

FOR PRIVATE CIRCULATION ONLY. Edited by Ms Medha Bhuta Published by K. Ramamurthy for <strong>India</strong>n <strong>Polyurethane</strong> <strong>Association</strong><br />

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