Frustrated Lewis Pairs-2 - Franklin Chm Colostate

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• Background Outline • The Beginning: H 2 AcCvaCon • Metal-‐Free HydrogenaCon • AddiCons to Unsaturated Compounds • CO 2 AcCvaCon
Lewis Acids and Bases “... we may say that a basic substance is one which has a lone pair of electrons which may be used to complete the stable group of another atom, and that an acid substance is one which can employ a lone pair from another molecule in comple@ng the stable group of one of its own atoms.” Gilbert N. Lewis base = e -‐ pair donor acid = e -‐ pair acceptor G. N. Lewis, Valence and the Structure of Atoms and Molecules, Chemical Catalogue Company, New York, 1923.
Page 1: Welch, G. C.; Stephan, D. W. J. Am.
Page 5 and 6: Brown: WiMg: Tochtermann: FLPs in H
Page 7 and 8: H 2 AcCvaCon by Main Group Compound
Page 9 and 10: Mechanism of H 2 AcCvaCon termolecu
Page 11 and 12: Bridged Phosphine-‐Borane Adduc
Page 13 and 14: Reversibility: H 2 EliminaCon
Page 15 and 16: H 2 AcCvaCon: FLPs as TransiCon Met
Page 17 and 18: • Background Outline • The Begi
Page 19 and 20: Imine HydrogenaCon Sumerin, V.; Sch
Page 21 and 22: HydrogenaCon by the Bridged FLP Spi
Page 23 and 24: Frustrated Substrates Chase, P. A.;
Page 25 and 26: 1,2 AddiCon to Carbonyl Groups Möm
Page 27 and 28: 1,4 AddiCon to Conjugated Systems U
Page 29 and 30: • Background Outline • The Begi
Page 31: Conclusion • CombinaCon of unquen

Frustrated Lewis Pairs-2 - Franklin Chm Colostate

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