Frustrated Lewis Pairs-2 - Franklin Chm Colostate

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CO 2 AcCvaCon and ReducCon Mömming, C. M.; Oten, E.; Kehr, G.; Fröhlich, R.; Grimme, S.; Stephan, D. W.; Erker, G. Angew. Chem. Int. Ed. 2009, 48, 6643. Ashley, A. E.; Thompson, A. L.; O’Hare, D. Angew. Chem. Int. Ed. 2009, 48, 9839.
Conclusion • CombinaCon of unquenched acidity and basicity lends unique reacCvity to frustrated <strong>Lewis</strong> pairs • FLP small molecule acCvaCon and reacCons with π systems suggest a parallel with transiCon metal chemistry • FLP catalysis provides a mild, metal-‐free alternaCve for hydrogenaCon
Page 1 and 2: Welch, G. C.; Stephan, D. W. J. Am.
Page 3 and 4: Lewis Acids and Bases “... we may
Page 5 and 6: Brown: WiMg: Tochtermann: FLPs in H
Page 7 and 8: H 2 AcCvaCon by Main Group Compound
Page 9 and 10: Mechanism of H 2 AcCvaCon termolecu
Page 11 and 12: Bridged Phosphine-‐Borane Adduc
Page 13 and 14: Reversibility: H 2 EliminaCon
Page 15 and 16: H 2 AcCvaCon: FLPs as TransiCon Met
Page 17 and 18: • Background Outline • The Begi
Page 19 and 20: Imine HydrogenaCon Sumerin, V.; Sch
Page 21 and 22: HydrogenaCon by the Bridged FLP Spi
Page 23 and 24: Frustrated Substrates Chase, P. A.;
Page 25 and 26: 1,2 AddiCon to Carbonyl Groups Möm
Page 27 and 28: 1,4 AddiCon to Conjugated Systems U
Page 29: • Background Outline • The Begi

Frustrated Lewis Pairs-2 - Franklin Chm Colostate

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