Frustrated Lewis Pairs-2 - Franklin Chm Colostate

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H 2 Cleavage by Phosphines and Boranes strict steric and electronic requirements for H 2 ac@va@on Welch, G. C.; Stephan, D. W. J. Am. Chem. Soc. 2007, 129, 1880.
Mechanism of H 2 AcCvaCon termolecular collision = entropically disfavored H 2 adduct formaCon disfavored due to Pauli repulsion weak associaCon of LB and LA generates a ‘frustrated complex’ Rokob, T. A.; Hamza, A.; SCrling, A.; Soós, T.; Pápai, I. Angew. Chem. Int. Ed. 2008, 47, 2435.
Page 1 and 2: Welch, G. C.; Stephan, D. W. J. Am.
Page 3 and 4: Lewis Acids and Bases “... we may
Page 5 and 6: Brown: WiMg: Tochtermann: FLPs in H
Page 7: H 2 AcCvaCon by Main Group Compound
Page 11 and 12: Bridged Phosphine-‐Borane Adduc
Page 13 and 14: Reversibility: H 2 EliminaCon
Page 15 and 16: H 2 AcCvaCon: FLPs as TransiCon Met
Page 17 and 18: • Background Outline • The Begi
Page 19 and 20: Imine HydrogenaCon Sumerin, V.; Sch
Page 21 and 22: HydrogenaCon by the Bridged FLP Spi
Page 23 and 24: Frustrated Substrates Chase, P. A.;
Page 25 and 26: 1,2 AddiCon to Carbonyl Groups Möm
Page 27 and 28: 1,4 AddiCon to Conjugated Systems U
Page 29 and 30: • Background Outline • The Begi
Page 31: Conclusion • CombinaCon of unquen

Frustrated Lewis Pairs-2 - Franklin Chm Colostate

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