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Fundamentals of Ion-Solid Interaction - SPIRIT

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Preferential Sputtering<br />

Partial sputtering yields<br />

Y <br />

p<br />

k<br />

Y<br />

<br />

Y<br />

p<br />

A<br />

p<br />

B<br />

c<br />

c<br />

c<br />

s<br />

k<br />

s<br />

A<br />

s<br />

B<br />

Y<br />

c<br />

k<br />

are generally different<br />

Preferential sputtering if<br />

Irradiation <strong>of</strong> two-component<br />

substance A nB m<br />

k = A,B<br />

Y k c "component" sputter<br />

yields<br />

c k s surface atomic fractions<br />

Mass conservation requires<br />

Y<br />

Y<br />

p<br />

A<br />

p<br />

B<br />

t <br />

cA<br />

<br />

t <br />

cB<br />

c(x)<br />

c A<br />

c B<br />

0<br />

Example: B is preferentially sputtered<br />

A<br />

B<br />

Institute <strong>of</strong> <strong>Ion</strong> Beam Physics and Materials Research Pr<strong>of</strong>. Wolfhard Möller<br />

Y p (t)<br />

t 0<br />

0<br />

x<br />

A<br />

c(x)<br />

B<br />

c A<br />

c B<br />

0<br />

t<br />

A<br />

B<br />

t <br />

x

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