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Fundamentals of Ion-Solid Interaction - SPIRIT

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<strong>Ion</strong> Beam Mixing: Thermal and Chemical Effects<br />

Radiation-enhanced<br />

interdiffusion<br />

275 keV Si<br />

→ 144 nm Nb/Si[100]<br />

radiationenhanced<br />

interdiffusion<br />

purely<br />

collisional<br />

S. Matteson et al., Rad. Eff. 42(1979)217<br />

Chemical driving forces: Enthalpy<br />

<strong>of</strong> mixing and cohesive energy<br />

d<br />

d<br />

<br />

<br />

3<br />

2<br />

S <br />

n E Hmix<br />

<br />

1<br />

K<br />

2<br />

2<br />

H<br />

H<br />

2<br />

1<br />

m n<br />

K1, K2 K1<br />

Constants<br />

<br />

coh<br />

coh<br />

Institute <strong>of</strong> <strong>Ion</strong> Beam Physics and Materials Research Pr<strong>of</strong>. Wolfhard Möller<br />

<br />

T.W. Workman et al., Appl. Phys. Lett. 50(1987)1485

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