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저작자표시-비영리-변경금지 2.0 대한민국 이용자는 아래의 조건을 ...

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matrix. However, CNTs are strongly affected by van der Waals force<br />

due to their small size and large surface area. These forces give rise to<br />

the formation of aggregates, which in turn, make dispersion of CNTs in<br />

the polymers difficult. In order to attain an efficient dispersion of CNTs<br />

by the physical approach, ultrasound can be applied to a dispersion of<br />

CNTs. [9] In addition, chemical methods such as covalent attachment<br />

involving the introduction of a chemical group to the nanotube wall,<br />

and non-covalent adsorption methods have been employed in order to<br />

provide chemical compatibility with the polymers, and dissolution of<br />

CNTs in organic solvents. [10-12]<br />

Generally, the following three methods for the preparation of<br />

polymer-CNTs nanocomposite are employed to promote the dispersion<br />

of controlled CNTs throughout the polymer matrix: (i) solution blending,<br />

a method for precipitating or casting a polymer-CNTs solution<br />

dissolved in a solvent, [13,14] (ii) melt mixing, which requires high<br />

temperature and shear force according to the polymer species in the<br />

mixer without a solvent and (iii) in-situ polymerization, a method to<br />

polymerize the monomer in the presence of the dispersed-CNTs. This<br />

last approach has outstanding potential which can include covalent<br />

bonding between the polymer matrix and modified-CNTs. [16,17]<br />

2

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