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저작자표시-비영리-변경금지 2.0 대한민국 이용자는 아래의 조건을 ...

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decreased slightly but increased gradually with increasing MWNT<br />

content. Figure 4b shows the crystallization behavior of the neat PBS<br />

and its composites. The neat PBS was crystallized at 89.55 o C, and<br />

the addition of MWNTs into the PBS matrix led to a shift of the Tc of the<br />

nanocomposites to around 87 o C. This behavior indicates that the<br />

MWNTs do not act as the efficient nucleating agent but impede the<br />

crystallization process of the nanocomposites in all samples.<br />

Consequently, lower temperature was needed to crystallize, as<br />

indicated by the cooling scans. It is shown that the PBS<br />

nanocomposite with 2 wt% MWNTs loading had a higher crystallization<br />

temperature than the other samples.<br />

3. 4. Mechanical testing<br />

The tensile strength and elongation at break curves for the neat PBS<br />

and its composites with different MWNT loadings are shown in Figure<br />

5. The three preparation methods were also compared. It was found<br />

that the nanocomposites prepared by the SOAM method exhibited a<br />

better tensile property than those prepared by solution blending and<br />

melt mixing, respectively. In this study, the ranking of high tensile<br />

mechanical property of the MWNT-reinforced nanocomposites is the<br />

14

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