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Plastics PRAXIS - PFERD

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Which groups of plastics exist?<br />

<strong>Plastics</strong> can be divided into the following groups on the basis of the differences in their<br />

thermal-mechanical behaviour in accordance with DIN 7724:<br />

■■ Duroplastics (thermosets)<br />

■■ Thermoplastics<br />

■■ Elastomers<br />

■■ Thermoplastic elastomers<br />

<strong>Plastics</strong><br />

Groups of <strong>Plastics</strong> and their Properties<br />

Properties Duroplastics Thermoplastics Elastomers Thermoplastic<br />

elastomers<br />

Structure Close-meshed<br />

three-dimensionally<br />

chemically cross-linked<br />

macro-molecules<br />

Behaviour at normal<br />

temperature<br />

Forming<br />

Hard and brittle to<br />

viscoplastic<br />

Cannot be formed<br />

plastically following<br />

cross-linking<br />

Chain-shaped<br />

macro-molecules with<br />

little or no branching<br />

Amorphous<br />

Completely disordered<br />

structure of the polymer<br />

chains<br />

Partially crystalline<br />

Contains areas with parallel<br />

arrangement of the polymer<br />

chains<br />

Soft to hard-viscous or<br />

hard-brittle<br />

Can be formed plastically<br />

at increased temperature<br />

Wide-meshed<br />

three-dimensionally<br />

chemically cross-linked<br />

rubber macro-molecules<br />

Co-polymer comprising<br />

hard and soft blocks<br />

or<br />

Blend of thermoplastic<br />

with (non-/partially)<br />

cross-linked rubber<br />

Soft/rubbery and<br />

hard/glass-like areas<br />

Rubbery-elastic Rubbery-elastic<br />

Can only be formed<br />

elastically<br />

Meltability No Yes No Yes<br />

Behaviour towards<br />

solvents<br />

■■swellable ■■soluble No<br />

No<br />

Yes<br />

Yes<br />

Yes<br />

No<br />

Plastic pipes.<br />

Resistance to chemicals High High Moderate High<br />

Weldability No Yes No Yes<br />

Adhesive ability Yes Mainly yes Yes Mainly yes<br />

Machinability Yes Yes Yes Yes<br />

Recycling ability No Yes No Yes<br />

Can be formed plastically<br />

at increased temperature<br />

(yield range)<br />

Yes<br />

Yes<br />

5

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