Catarina Maia Seco Seiça Neves Sistemas Aquosos Bifásicos com ...

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[C6py][Tf2N] hexylpyridinium bis(trifluoromethylsulfonyl)imide [C8py][Tf2N] octylpyridinium bis(trifluoromethylsulfonyl)imide [C3mpy][Tf2N] 1-methyl-3-propylpyridinium bis(trifluoromethylsulfonyl)imide [C4mpy][Tf2N] 1-butyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide [4-C4mpy][Tf2N] 1-butyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide [C3mpyr][Tf2N] 1-methyl-1-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide [C4mpyr][Tf2N] 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide [C3mpip][Tf2N] 1-methyl-1-propylpiperidinium bis(trifluoromethylsulfonyl)imide [im][Cl] imidazolium chloride [C1im][Cl] methylimidazolium chloride [C2im][Cl] ethylimidazolium chloride [C1mim][Cl] 1,3-dimethylimidazolium chloride [C2mim][Cl] 1-ethyl-3-methylimidazolium chloride [C4mim][Cl] 1-butyl-3-methylimidazolium chloride [C6mim][Cl] 1-hexyl-3-methylimidazolium chloride [amim][Cl] 1-allyl-3-methylimidazolium chloride [OHC2mim][Cl] 1-hydroxyethyl-3-methylimidazolium chloride [C7H7mim][Cl] 1-benzyl-3-methylimidazolium chloride [C2mim][Br] 1-ethyl-3-methylimidazolium bromide [C4mim][Br] 1-butyl-3-methylimidazolium bromide [C2mim][CH3CO2] 1-ethyl-3-methylimidazolium acetate [C4mim][CH3CO2] 1-butyl-3-methylimidazolium acetate [C2mim][CH3SO3] 1-ethyl-3-methylimidazolium methanesulfonate [C4mim][CH3SO3] 1-butyl-3-methylimidazolium methanesulfonate [C2mim][CF3SO3] 1-ethyl-3-methylimidazolium trifluoromethanesulfonate [C4mim][CF3SO3] 1-butyl-3-methyl-imidazolium trifluoromethanesulfonate [C2mim][MeSO4] 1-ethyl-3-methylimidazolium methylsulfate [C2mim][EtSO4] 1-ethyl-3-methylimidazolium ethylsulfate [C4mim][N(CN)2] 1-butyl-3-methylimidazolium dicyanamide [C4mim][HSO4] 1-butyl-3-methylimidazolium hydrogenosulfate [C4mim][TFA] 1-butyl-3-methylimidazolium trifluoroacetate VI
List of Tables Table 1. Experimental mole fraction solubility of water in ILs and respective expanded uncertainty with 95 % level of confidence, xw, as a function of temperature. .................... 14 Table 2. Experimental mole fraction solubility of water in ILs and respective expanded uncertainty with 95 % level of confidence, xIL, as a function of temperature. .................... 15 Table 3. Fitting parameters for the mole fraction solubility of water in ILs, as a function of temperature, using Eq. 1. ..................................................................................................... 20 Table 4. Fitting parameters for the mole fraction solubility of ILs in water as a function of temperature, using Eq. 2. ..................................................................................................... 21 Table 5. Used descriptors, experimental data and predicted values for mutual solubilities of water and ILs ....................................................................................................................... 29 Table 6. Hydrogen Bond Acidity () and Hydrogen Bond Basicity () of [C4mim]-Based ILs with the Solvatochromic Probe [Fe(phen)2(CN)2]ClO4 83 . ............................................ 48 Table 7. Correlation parameters used in Eq. 5 to describe the binodals.............................. 49 Table 8. Experimental data for the Tie Lines (TLs) and tie line length (TLL). .................. 50 Table 9. Weight fraction <strong>com</strong>position and partition coefficients of L-tryptophan in ILs- ABS systems. ....................................................................................................................... 52 VII
Page 1: Catarina Maia Seco Seiça Neves Uni
Page 5: Ao meu Pai e ao meu Avô…
Page 9: agradecimentos Gostaria de começar
Page 13: keywords abstract Ionic liquids, wa
Page 16 and 17: 4.2.3. Partitioning of L-tryptophan
Page 19: List of Abbreviations ABS Aqueous B
Page 23 and 24: List of Figures Figure 1. Example o
Page 25 and 26: [C4mim][TFA]; ×, [C4mim][Br]; ○,
Page 27: 1. 1. General Introduction
Page 30 and 31: Aqueous Biphasic Systems with Ionic
Page 35 and 36: ILs + H2O Binary Systems __________
Page 41 and 42: Table 2. Experimental mole fraction
Page 49: 3. 3. QSPR Modelling of ILs + H2O B
Page 61 and 62: ILs + H2O + K3PO4 Ternary Systems _
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ILs + H2O + K3PO4 Ternary Systems _
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5. 5. Final Remarks
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Aqueous Biphasic Systems with Ionic
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References ________________________
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References ________________________
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References ________________________
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7. 7. List of Publications
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Appendix A ________________________
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Appendix B
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