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View/Open - ARAN - National University of Ireland, Galway

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Introduction<br />

where the ratio <strong>of</strong> the peak amplitude b to the base amplitude a, b/a = m is termed<br />

the modulation <strong>of</strong> the incident light. As described above, the phase and modulation<br />

<strong>of</strong> the emission will be different but at the same frequency. The population <strong>of</strong> the<br />

excited state is:<br />

N(t) = A + B sin(ωt − φ) (1.21)<br />

The demodulation is given by the ratio <strong>of</strong> the amplitudes B/A and phase shift<br />

φ. Recall the single exponential intensity decay (Equation 1.13). Differentiating the<br />

single exponential intensity decay gives an expression for the time-dependent excited<br />

state population:<br />

dN(t)<br />

dt = −1/τN(t) + I0(t) (1.22)<br />

Using d/dx(sin u) = cos u du/dx, the derivative <strong>of</strong> Equation 1.21 gives:<br />

dN(t)<br />

dt<br />

Substitution <strong>of</strong> equation 1.23 into equation 1.22 yields:<br />

= ωB cos(ωt − φ) (1.23)<br />

ωB cos(ωt − φ) = −1/τ[A + B sin(ωt − φ)] + a + b sin ωt (1.24)<br />

If the sin and cos functions are expanded using the standard trigonometric identities<br />

i.e.:<br />

Cosine Expansion : cos(α − β) = cos α cos β + sin α sin β<br />

Sine Expansion : sin(α − β) = sin α cos β − sin β cos α<br />

then the following relationships can be found by equating the constant terms and<br />

those terms in φ and ωt.<br />

a − (1/τ)A = 0 (1.25)<br />

This base amplitude is commonly called the Direct Component (DC) <strong>of</strong>fset. This term comes<br />

from the function for a sinusoidal wave as opposed to the b term or Alternate Component (AC)<br />

part.<br />

32

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