- Page 1: THE UI\JIVERSITY OF ALBERTA ANTIFUN
- Page 4 and 5: Abstract A fungus observed to inhib
- Page 6 and 7: Acknowledgements 1would like to exp
- Page 10 and 11: LIST OF SCHEMES Scheme Page 1. ln v
- Page 12: of the landscape. C. ulmi. causal a
- Page 15 and 16: Fig. 1. Photo of Arthrosporae fungu
- Page 17: 8 9 10 11 7 OH RI =O. Rl =
- Page 21 and 22: 18 OH anhydroarthrosporone 12 11. a
- Page 24 and 25: major components as evidenced by ex
- Page 26: The IH-NMR spectrum of arthrosporon
- Page 31 and 32: (C) 1 1 CH) o OH ml z 252 IM-) CH)
- Page 33 and 34: 28 HO OH 30 32 OH OH o o o 29 33 31
- Page 35: (C) o Àmax (calcdl 231 nm; obs. 23
- Page 39 and 40: expected to undergo a retro-aldol c
- Page 41: The HRMS of 41 exhibits a base peak
- Page 49 and 50: molecular formula was established a
- Page 55 and 56: downfield proton (H-4) at 0 3.84. T
- Page 57 and 58: Examination of the IH NMR spectra o
- Page 59 and 60:
Figure 6: Ring C viewed from the to
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Table 9: lH NMR Spectral Data for A
- Page 65 and 66:
21 Scheme XIII in which the reactio
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HO HO OH 9 21 &0 " OH 0 60 Scheme X
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fully substituted carbons bearing o
- Page 71 and 72:
83= 20 o AI R -= Ac 12 R-=H _-OH Ta
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Table 13. IR Spectral Data (CHCI] c
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47 .....OH The IH NMR data for 68 s
- Page 79:
The striking difference between the
- Page 83 and 84:
Table 18. IH NMR Spectral Data for
- Page 85:
The IH NMR spectrum of 23 (Figure 1
- Page 88:
The IH NMR spectrum of 24 (Figure 1
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Further evidence for the configurat
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(Cl XXIV H H XXII H H H XXIII H HO
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Table 20. lH NMR Spectra Data for I
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spectrometer coupled to a D5-9 comp
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Separation of the Neutral Metabolit
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An impure fraction (1 10 mg) contai
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H-9b), 1.97 (1H, brt, 12 Hz, H-1 1a
- Page 118:
The unsaturated acetate 34 (5 mg, 0
- Page 122 and 123:
cm- I . HREIMS: mlz (formula. inten
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FTIR (CHCl l , cast): 3424 (br), 29
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(ether / Skellysolve BI keta-dial 6
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Hz), 1.48 (2H, M), 1.09 (3H, s), 1.
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FTIR: (CHCI!, 0.1 MM) 3560. 1716 (s
- Page 134 and 135:
cis-2{3-3a, 10, 10-Tetramethyltricy
- Page 137 and 138:
13.5 and 4 Hz, H-6b), 2.34 (1H, td,
- Page 139 and 140:
Table 4: Antibiotic Bioassay of Cru
- Page 141 and 142:
Table 6: Antifungal Bioassay of Pur
- Page 143 and 144:
BIBLIOGRAPHY 1. Hiratsuka. Y.; Tsun
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2720. 25. Turner, W.B,; Aldridge, D
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. Dauben, W.G.; Hart, D.J. J. Org.
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69. a. Hashimoto, H.; Ito, T., Mats
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6 5 4 3 2 Figure 3. 400 MHz IH NMR
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imp. J'---J.------I • , t t ! 1 4
- Page 158:
,---r 1 1 ! , 1 ! l , 3 ( 1 ! 1 ! 2
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Entrée 1 - Préambule 2 - Abstract
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INTRODUCTION Dans le cadre de la re
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1) un carbonyle appartenant à un s
- Page 177:
V Préparation des dérivés 1 - 8-
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13 - OXYDATION DE LA DEHYDROARTHROS
- Page 182 and 183:
BIBLIOGRAPHIE 1. R. J. Stipes and R
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HC 3 C02 Et 0 C0 2 Et H 3 C H 3 C H