Hazardous Chemicals Handbook (pdf) - CCC

More documents

Recommendations

Info

242 REACTIVE CHEMICALS Table 7.11 Classification of pyrotechnics Composition Behaviour Artefacts Characteristics Group 1 Chlorate and metal Burn very Flash shells (maroons) Mass explosion risk perchlorate report or violently Casings containing flash whistling compositions compositions Dry non-gelatinized Sealed hail-preventing cellulose nitrates rockets Barium peroxide/zirconium compositions Group 2 Nitrate/metal/sulphur Burn violently Large firework shells Accelerating compositions Fuse unprotected signal single-item Compositions with >65% flares explosions chlorate Non-pressed report bullets Black powder (bird scarers) Nitrate/boron compositions Report cartridges (unpacked) Black matches (uncovered) Group 3 Nitrate/metal compositions Burn fast Large firework shells Burn very without sulphur Fuse protected signal flares violently with Compositions with 60% Waterfalls; Silver wheels; lead oxides Volcanoes Perchlorate/metal Black powder delays compositions other than report Group 4 Coloured smoke compositions Low/medium Large firework shells Single-item White smoke compositions speed burning without flash ignitions/explosions (except those in Group 5) compositions in transport Compositions with
Table 7.12 General considerations for work with explosive chemicals Consult with experts on the hazards and on technical, administrative and legal requirements. The chance of accidental initiation is related to the energy imparted to the substance and the sensitivity of the compound. Hence the sensitivity of compounds should be established (e.g. Table 7.15) before devising appropriate control measures. (Many sensitive explosives have ignition energies of 1–45 mJ, while some very sensitive materials have ignition energies
Page 1:
Hazardous Chemicals Handbook
Page 4 and 5:
Butterworth-Heinemann An imprint of
Page 6 and 7:
vi CONTENTS Effects of particle or
Page 8 and 9:
viii CONTENTS 14 Marketing 443 Clas
Page 10 and 11:
x PREFACE TO THE SECOND EDITION The
Page 12 and 13:
xii PREFACE to chemical safety data
Page 14 and 15:
2 INTRODUCTION Table 1.1 Breakdown
Page 16 and 17:
4 INTRODUCTION Table 1.3 Comprehens
Page 18 and 19:
6 INTRODUCTION Table 1.5 Schedule 1
Page 20 and 21:
8 INTRODUCTION Table 1.7 Planning (
Page 22 and 23:
2 Terminology ACID A chemical compo
Page 24 and 25:
12 TERMINOLOGY initially thought to
Page 26 and 27:
14 TERMINOLOGY vapour concentration
Page 28 and 29:
16 TERMINOLOGY MULTIPLE CHEMICAL SE
Page 30 and 31:
18 TERMINOLOGY conferences of the s
Page 32 and 33:
20 TERMINOLOGY UEL, UPPER EXPLOSIVE
Page 34 and 35:
22 GENERAL PRINCIPLES OF CHEMISTRY
Page 36 and 37:
Page 38 and 39:
Page 40 and 41:
Page 42 and 43:
Page 44 and 45:
Page 46 and 47:
Page 48 and 49:
Page 50 and 51:
Page 52 and 53:
Page 54 and 55:
Page 56 and 57:
Page 58 and 59:
46 PHYSICOCHEMISTRY pa = pa′ xa w
Page 60 and 61:
48 PHYSICOCHEMISTRY Table 4.1 Densi
Page 62 and 63:
50 PHYSICOCHEMISTRY Vapour flashing
Page 64 and 65:
52 PHYSICOCHEMISTRY where N is mass
Page 66 and 67:
54 PHYSICOCHEMISTRY where T a is th
Page 68 and 69:
56 PHYSICOCHEMISTRY Table 4.8 Compa
Page 70 and 71:
58 PHYSICOCHEMISTRY Table 4.10 Corr
Page 72 and 73:
60 PHYSICOCHEMISTRY Table 4.12 Solv
Page 74 and 75:
62 PHYSICOCHEMISTRY Table 4.13 Cont
Page 76 and 77:
64 PHYSICOCHEMISTRY Table 4.13 Cont
Page 78 and 79:
66 PHYSICOCHEMISTRY If pressure rel
Page 80 and 81:
68 TOXIC CHEMICALS Table 5.1 Classi
Page 82 and 83:
70 TOXIC CHEMICALS Table 5.2 Materi
Page 84 and 85:
72 TOXIC CHEMICALS A summary of the
Page 86 and 87:
74 TOXIC CHEMICALS Table 5.4 Cont
Page 88 and 89:
76 TOXIC CHEMICALS Table 5.6 Some s
Page 90 and 91:
78 TOXIC CHEMICALS 10 6 Boulders 10
Page 92 and 93:
80 TOXIC CHEMICALS Table 5.10 Chemi
Page 94 and 95:
Threshold limit values (TLV) These
Page 96 and 97:
(a) should not be used as an index
Page 98 and 99:
Table 5.13 Adopted biological expos
Page 100 and 101:
Table 5.13 Cont’d METHYL ETHYL KE
Page 102 and 103:
Table 5.14 UK biological monitoring
Page 104 and 105:
Table 5.16 Substances assigned ‘R
Page 106 and 107:
Table 5.16 Cont’d Ethyleneimine E
Page 108 and 109:
Table 5.17 Evaluation of carcinogen
Page 110 and 111:
Table 5.17 Cont’d RISK CONTROL 12
Page 112 and 113:
Table 5.17 Cont’d Non-arsenical i
Page 114 and 115:
Table 5.17 Cont’d 2-(2-Formylhydr
Page 116 and 117:
Table 5.17 Cont’d Uracil mustard
Page 118 and 119:
(e.g. with knock-out and/or scrubbi
Page 120 and 121:
Typical minimum transport velocitie
Page 122 and 123:
Table 5.20 Prohibition of certain s
Page 124 and 125:
Keep test records Keep RPE test rec
Page 126 and 127:
extend with certain exceptions to o
Page 128 and 129:
Table 5.23 Frequency of thorough ex
Page 130 and 131:
Table 5.26 Agents for which health
Page 132 and 133:
Table 5.27 Summary of precautions f
Page 134 and 135:
Long-term exposure to ferric oxide
Page 136 and 137:
The STEL is 200 ppm but extended pe
Page 138 and 139:
(iv) Cyanides As a group, the cyani
Page 140 and 141:
Basic precautions include those in
Page 142 and 143:
Table 5.38 Chlorinated hydrocarbon
Page 144 and 145:
Table 5.40 Routine laboratory preca
Page 146 and 147:
Table 5.43 Common anhydrous acids C
Page 148 and 149:
Table 5.45 Precautions in handling
Page 150 and 151:
Table 5.48 Potential pollutants fro
Page 152 and 153:
Table 5.51 Physical properties of t
Page 154 and 155:
Whilst the causative agent(s) have
Page 156 and 157:
Table 5.54 Precautions to avoid ‘
Page 158 and 159:
Table 5.57 General precautions with
Page 160 and 161:
Monitor effectiveness Assess weldin
Page 162 and 163:
Ammonium chloride fume - 10 - 20 -
Page 164 and 165:
tert-Butyl acetate 200 950 - - 200
Page 166 and 167:
2-Chloroethanol, see Ethylene chlor
Page 168 and 169:
1,2-Dibromoethane, see Ethylene dib
Page 170 and 171:
Dinitolmide - 5 - - - - - - Dinitro
Page 172 and 173:
Ethyl ether 400 1210 500 1520 400 1
Page 174 and 175:
Hydrogen bromide - - C3 C9.9 - - 3
Page 176 and 177:
Inorganic forms including metallic
Page 178 and 179:
Mineral wool fibre - 10 (i) Molybde
Page 180 and 181:
Perlite - 10 (i) Petroleum distilla
Page 182 and 183:
Quinone 0.1 0.44 - - 0.1 0.4 0.3 1.
Page 184 and 185:
Synthetic vitreous fibres Continuou
Page 186 and 187:
Tricyclohexyltin hydroxide, see Cyh
Page 188 and 189:
(d) Simple asphyxiant. Some gases a
Page 190 and 191:
6 Flammable chemicals Certain chemi
Page 192 and 193:
198 FLAMMABLE CHEMICALS these are n
Page 194 and 195:
Table 6.3 Sources of ignition Mecha
Page 196 and 197:
Table 6.4 Approximate temperatures
Page 198 and 199:
Table 6.6 Approximate temperatures
Page 200 and 201:
Table 6.7 Cont’d Wood flour Wool
Page 202 and 203:
Table 6.10 Electrochemical series M
Page 204 and 205: Table 6.11 Control measures for wor
Page 206 and 207: • The type of hazard - determines
Page 208 and 209: Table 6.13 General requirements for
Page 210 and 211: The minimum fire instruction and tr
Page 212 and 213: n-Amyl alcohol 0.82 3.0 33 300 1-10
Page 214 and 215: Butyl cellosolve 0.91 4.1 61 244 1.
Page 216 and 217: Cumene 0.86 4.1 44 424 0.9-6.5 152
Page 218 and 219: Diethyl sulphate Diglycol, see Diet
Page 220 and 221: Ethylene chlorohydrin 1.21 2.78 60o
Page 222 and 223: p-Mentha-1,8-diene 3.84 7.4 45 237
Page 224 and 225: Nitroethane 1.05 2.58 38 360-415 3.
Page 226 and 227: Propionitrile 0.77 1.9 2 - 3.1- 97
Page 228 and 229: Trimethyl amine 0.66 2.0 -7 190 2-1
Page 230 and 231: Benzoyl peroxide - - - 21 - Berylli
Page 232 and 233: Copper-zinc, gold bronze 370 190 1.
Page 234 and 235: Hydrazine acid tartrate 570 0.175 4
Page 236 and 237: Phthalimide 630 - 0.030 50 89 4800
Page 238 and 239: Sodium toluene sulphonate 530 - - -
Page 240 and 241: 7 Reactive chemicals From Chapter 3
Page 242 and 243: 230 REACTIVE CHEMICALS Table 7.1 Wa
Page 244 and 245: 232 REACTIVE CHEMICALS Table 7.3 Va
Page 246 and 247: 234 REACTIVE CHEMICALS (e.g. concen
Page 248 and 249: 236 REACTIVE CHEMICALS Table 7.7 At
Page 250 and 251: 238 REACTIVE CHEMICALS Table 7.9 Se
Page 252 and 253: 240 REACTIVE CHEMICALS Table 7.9 Co
Page 256 and 257: 244 REACTIVE CHEMICALS High e.g. sl
Page 258 and 259: 246 REACTIVE CHEMICALS Table 7.14 S
Page 260 and 261: 248 REACTIVE CHEMICALS Table 7.17 G
Page 262 and 263: 250 REACTIVE CHEMICALS Table 7.20 P
Page 264 and 265: 252 REACTIVE CHEMICALS Incorrect ki
Page 266 and 267: 254 REACTIVE CHEMICALS Table 7.22 H
Page 268 and 269: 256 REACTIVE CHEMICALS Erlenmeyer r
Page 270 and 271: 8 Cryogens Cryogenics, or low-tempe
Page 272 and 273: 260 CRYOGENS Table 8.3 General prec
Page 274 and 275: 262 CRYOGENS to liquefy. The triple
Page 276 and 277: 264 CRYOGENS Table 8.6 Effect of ca
Page 278 and 279: 266 COMPRESSED GASES Table 9.1 Comp
Page 280 and 281: 268 COMPRESSED GASES Table 9.1 Cont
Page 282 and 283: 270 COMPRESSED GASES Table 9.1 Cont
Page 284 and 285: 272 COMPRESSED GASES Table 9.3 prov
Page 286 and 287: 274 COMPRESSED GASES Table 9.4 Phys
Page 288 and 289: 276 COMPRESSED GASES The precaution
Page 290 and 291: 278 COMPRESSED GASES Vapour pressur
Page 292 and 293: 280 COMPRESSED GASES CO + Cl 2 →
Page 296 and 297: 284 COMPRESSED GASES Hydrogen chlor
Page 298 and 299: 286 COMPRESSED GASES • Avoid galv
Page 304 and 305:
292 COMPRESSED GASES Table 9.16 Gen
Page 306 and 307:
294 COMPRESSED GASES Vapour pressur
Page 308 and 309:
296 COMPRESSED GASES Table 9.20 Phy
Page 310 and 311:
Page 312 and 313:
300 COMPRESSED GASES Vapour pressur
Page 314 and 315:
302 COMPRESSED GASES 16 hr per day
Page 316 and 317:
304 COMPRESSED GASES where R 1 and
Page 318 and 319:
Page 320 and 321:
308 MONITORING TECHNIQUES Table 10.
Page 322 and 323:
310 MONITORING TECHNIQUES such that
Page 324 and 325:
Page 326 and 327:
314 MONITORING TECHNIQUES industria
Page 328 and 329:
Page 330 and 331:
Page 332 and 333:
Table 10.12 Selected examples of sa
Page 334 and 335:
Table 10.15 Charcoal tube user guid
Page 336 and 337:
Table 10.15 Cont’d Substance Expe
Page 338 and 339:
Page 340 and 341:
Page 342 and 343:
Page 344 and 345:
Page 346 and 347:
Table 10.17 Compounds detectable by
Page 348 and 349:
Table 10.17 Cont’d Compound Analy
Page 350 and 351:
Page 352 and 353:
Page 354 and 355:
Page 356 and 357:
Page 358 and 359:
Page 360 and 361:
Page 362 and 363:
Page 364 and 365:
Page 366 and 367:
Page 368 and 369:
Table 10.23 Cont’d Principle Exam
Page 370 and 371:
Page 372 and 373:
Page 374 and 375:
Page 376 and 377:
Page 378 and 379:
Page 380 and 381:
Page 382 and 383:
Page 384 and 385:
Table 10.30 Methods for sampling an
Page 386 and 387:
Table 10.30 Cont’d Substance Samp
Page 388 and 389:
Page 390 and 391:
Page 392 and 393:
Page 394 and 395:
Page 396 and 397:
Page 398 and 399:
386 MONITORING TECHNIQUES Existing
Page 400 and 401:
Page 402 and 403:
11 Radioactive chemicals The main c
Page 404 and 405:
392 RADIOACTIVE CHEMICALS Table 11.
Page 406 and 407:
394 RADIOACTIVE CHEMICALS D t = D 0
Page 408 and 409:
12 Safety by design Plant and equip
Page 410 and 411:
398 SAFETY BY DESIGN Table 12.2 Che
Page 412 and 413:
400 SAFETY BY DESIGN Table 12.5 Fea
Page 414 and 415:
402 SAFETY BY DESIGN Table 12.7 Sel
Page 416 and 417:
404 SAFETY BY DESIGN Equipment desi
Page 418 and 419:
406 SAFETY BY DESIGN Table 12.11 Sa
Page 420 and 421:
408 SAFETY BY DESIGN Table 12.12 Ra
Page 422 and 423:
410 SAFETY BY DESIGN Table 12.13 Co
Page 424 and 425:
13 Operating procedures Safety is a
Page 426 and 427:
414 OPERATING PROCEDURES Table 13.1
Page 428 and 429:
Page 430 and 431:
418 OPERATING PROCEDURES Work can b
Page 432 and 433:
420 OPERATING PROCEDURES PLANT DETA
Page 434 and 435:
422 OPERATING PROCEDURES CERTIFICAT
Page 436 and 437:
424 OPERATING PROCEDURES • Have e
Page 438 and 439:
426 OPERATING PROCEDURES Calling in
Page 440 and 441:
Page 442 and 443:
430 OPERATING PROCEDURES Cuts is un
Page 444 and 445:
Page 446 and 447:
Page 448 and 449:
436 OPERATING PROCEDURES There are
Page 450 and 451:
Page 452 and 453:
Page 454 and 455:
442 OPERATING PROCEDURES Monitoring
Page 456 and 457:
444 MARKETING Table 14.1 Legislatio
Page 458 and 459:
446 MARKETING Table 14.2 Indication
Page 460 and 461:
448 MARKETING Table 14.3 ‘Risk’
Page 462 and 463:
450 MARKETING Table 14.3 Cont’d 4
Page 464 and 465:
452 MARKETING Table 14.5 Classifica
Page 466 and 467:
454 MARKETING Table 14.6 Cont’d C
Page 468 and 469:
456 MARKETING Table 14.9 Compatibil
Page 470 and 471:
458 MARKETING • Substances intend
Page 472 and 473:
15 Transport of chemicals Transport
Page 474 and 475:
462 TRANSPORT OF CHEMICALS Legislat
Page 476 and 477:
464 TRANSPORT OF CHEMICALS • in a
Page 478 and 479:
466 TRANSPORT OF CHEMICALS Table 15
Page 480 and 481:
Page 482 and 483:
Page 484 and 485:
Page 486 and 487:
Page 488 and 489:
Page 490 and 491:
Page 492 and 493:
Page 494 and 495:
482 TRANSPORT OF CHEMICALS water sp
Page 496 and 497:
Page 498 and 499:
Page 500 and 501:
16 Chemicals and the environment: s
Page 502 and 503:
490 CHEMICALS AND THE ENVIRONMENT:
Page 504 and 505:
Page 506 and 507:
Page 508 and 509:
Page 510 and 511:
Page 512 and 513:
Page 514 and 515:
Page 516 and 517:
Page 518 and 519:
Page 520 and 521:
Page 522 and 523:
Page 524 and 525:
17 Chemicals and the environment: m
Page 526 and 527:
514 CHEMICALS AND THE ENVIRONMENT D
Page 528 and 529:
516 CHEMICALS AND THE ENVIRONMENT T
Page 530 and 531:
Page 532 and 533:
Page 534 and 535:
Page 536 and 537:
Page 538 and 539:
Page 540 and 541:
528 CHEMICALS AND THE ENVIRONMENT A
Page 542 and 543:
530 CHEMICALS AND THE ENVIRONMENT P
Page 544 and 545:
Page 546 and 547:
Page 548 and 549:
Page 550 and 551:
Page 552 and 553:
Page 554 and 555:
Page 556 and 557:
544 CONVERSION TABLES AND MEASUREME
Page 558 and 559:
Page 560 and 561:
Page 562 and 563:
Emission rates To obtain: g/s g/min
Page 564 and 565:
19 Bibliography It is impractical t
Page 566 and 567:
554 BIBLIOGRAPHY Be Prepared for an
Page 568 and 569:
556 BIBLIOGRAPHY Kletz, T.A. (1989)
Page 570 and 571:
558 BIBLIOGRAPHY Selected statutory
Page 572 and 573:
560 BIBLIOGRAPHY European legislati
Page 574 and 575:
562 BIBLIOGRAPHY 95/50/EC Directive
Page 576 and 577:
564 BIBLIOGRAPHY 2000/166/EC Decisi
Page 578 and 579:
566 BIBLIOGRAPHY European legislati
Page 580 and 581:
568 BIBLIOGRAPHY SI 1989/1149 Contr
Page 582 and 583:
570 BIBLIOGRAPHY Selected decisions
Page 584 and 585:
572 BIBLIOGRAPHY BPM 20 Iron works
Page 586 and 587:
574 BIBLIOGRAPHY EH 65/30 Review of
Page 588 and 589:
576 BIBLIOGRAPHY HS(G)123 Working t
Page 590 and 591:
578 BIBLIOGRAPHY INDG 136 COSHH: a
Page 592 and 593:
580 BIBLIOGRAPHY L73 RIDDOR explain
Page 594 and 595:
582 BIBLIOGRAPHY MDHS 70 General me
Page 596 and 597:
584 BIBLIOGRAPHY SHW 396 Effects of
Page 598 and 599:
586 BIBLIOGRAPHY Publications by th
Page 600 and 601:
588 BIBLIOGRAPHY BS 3951 (Withdrawn
Page 602 and 603:
590 BIBLIOGRAPHY BS EN 54-2 Fire de
Page 604 and 605:
592 BIBLIOGRAPHY BS EN 60079-14 AMD
Page 606 and 607:
594 APPENDIX: SELECTED UK LEGISLATI
Page 608 and 609:
596 APPENDIX: SELECTED UK LEGISLATI
Page 610 and 611:
Absorption: gas, 314 percutaneous,
Page 612 and 613:
systems of work, See Systems of wor
Page 614 and 615:
Gloves, See Hand protection Glutera
Page 616 and 617:
physical properties, 301 precaution
Page 618 and 619:
Spillage, 427, 428, 429 Spontaneous
show all

Hazardous Chemicals Handbook (pdf) - CCC

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?