Hazardous Chemicals Handbook (pdf) - CCC

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520 CHEMICALS AND THE ENVIRONMENT Table 17.6 European <strong>Hazardous</strong> Waste List Code Description 02 Waste from agricultural, horticultural, hunting, fishing and aquaculture primary production, food preparation and processing 03 Wastes from wood processing and the production of paper, cardboard, pulp, panels and furniture 04 Wastes from the leather and textile industries 05 Wastes from petroleum refining, natural gas purification and pyrolitic treatment of coal 06 Wastes from inorganic chemical processes 07 Wastes from organic chemical processes 08 Wastes from the manufacture, formulation, supply and use (MFSU) of coatings (paints, varnishes and vitreous enamels), adhesive, sealants and printing inks 09 Wastes from the photographic industry 10 Inorganic wastes from thermal processes 11 Inorganic waste with metals from metal treatment and the coating of metals; non-ferrous hydro-metallurgy 12 Wastes from shaping and surface treatment of metals and plastics 13 Oil wastes (except edible oils, 0500 and 1200) 14 Wastes from organic substances employed as solvents (except 0700 and 0800) 16 Wastes not otherwise specified in the catalogue 17 Construction and demolition waste (including road construction) 18 Wastes from human or animal health care and/or related research (excluding kitchen and restaurant wastes which do not arise from immediate health care) 19 Wastes from waste treatment facilities, off-site waste water treatment plants and the water industry 20 Municipal wastes and similar commercial, industrial and institutional wastes including separately collected fractions 02 Waste from agricultural, horticultural, hunting, fishing and aquaculture primary production, food preparation and processing 0201 primary production waste 020105 agrochemical wastes 03 Wastes from wood processing and the production of paper, cardboard, pulp, panels and furniture 0302 wood preservation waste 030201 non-halogenated organic wood preservatives 030202 organochlorinated wood preservatives 030203 organometallic wood preservatives 030204 inorganic wood preservatives 04 Wastes from the leather and textile industries 0401 wastes from the leather industry 040103 degreasing wastes containing solvents without a liquid phase 0402 wastes from textile industry 040211 halogenated wastes from dressing and finishing 05 Wastes from petroleum refining, natural gas purification and pyrolitic treatment of coal 0501 oily sludges and solid wastes 050103 tank bottom sludges 050104 acid alkyl sludges 050105 oil spills 050107 acid tars 050108 other tars 0504 spent filter clays 050401 spent filter clays 0506 waste from the pyrolytic treatment of coal 050601 acid tars 050603 other tars 0507 waste from natural gas purification 050701 sludges containing mercury 0508 wastes from oil regeneration 050801 spent filter clays 050802 acid tars 050803 other tars 050804 aqueous liquid waste from oil regeneration 06 Wastes from inorganic chemical processes 0601 waste acidic solutions
Table 17.6 Cont’d Code Description WASTE MANAGEMENT 521 060101 sulphuric acid and sulphurous acid 060102 hydrochloric acid 060103 hydrofluoric acid 060104 phosphoric and phosphorus acid 060105 nitric acid and nitrous acid 060199 waste not otherwise specified 0602 alkaline solutions 060201 calcium hydroxide 060202 soda 060203 ammonia 060299 wastes not otherwise specified 0603 waste salts and their solutions 060311 salts and solutions containing cyanides 0604 metal-containing wastes 060402 metallic salts (except 0603) 060403 wastes containing arsenic 060404 wastes containing mercury 060405 wastes containing heavy metals 0607 wastes from halogen chemical processes 060701 wastes containing asbestos from electrolysis 060702 activated carbon from chlorine production 0613 wastes from other inorganic chemical processes 061301 inorganic pesticides, biocides and wood preserving agents 061302 spent activated carbon (except 060702) 07 Wastes from organic chemical processes 0701 waste from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals 070101 aqueous washing liquids and mother liquors 070103 organic halogenated solvents, washing liquids and mother liquors 070104 other organic solvents, washing liquids and mother liquors 070107 halogenated still bottoms and reaction residues 070108 other still bottoms and reaction residues 070109 halogenated filter cakes, spent absorbents 070110 other filter cakes, spent absorbents 0702 waste from the MFSU of plastics, synthetic rubber and man-made fibres 070201 aqueous washing liquids and mother liquors 070203 organic halogenated solvents, washing liquids and mother liquors 070204 other organic solvents, washing liquids and mother liquors 070207 halogenated still bottoms and reaction residues 070208 other still bottoms and reaction residues 070209 halogenated filter cakes, spent absorbents 070210 other filter cakes, spent absorbents 0703 waste from the MFSU for organic dyes and pigments (excluding 0611) 070301 aqueous washing liquids and mother liquors 070303 organic halogenated solvents, washing liquids and mother liquors 070304 other organic solvents, washing liquids and mother liquors 070307 halogenated still bottoms and reaction residues 070308 other still bottoms and reaction residues 070309 halogenated filter cakes, spent absorbents 070310 other filter cakes, spent absorbents 0704 waste from the MFSU for organic pesticides (except 020105) 070401 aqueous washing liquids and mother liquors 070403 organic halogenated solvents, washing liquids and mother liquors 070404 other organic solvents, washing liquids and mother liquors 070407 halogenated still bottoms and reaction residues 070408 other still bottoms 070409 halogenated filter cakes, spent absorbents 070410 other filter cakes, spent absorbents
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Hazardous Chemicals Handbook
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Butterworth-Heinemann An imprint of
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vi CONTENTS Effects of particle or
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viii CONTENTS 14 Marketing 443 Clas
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x PREFACE TO THE SECOND EDITION The
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xii PREFACE to chemical safety data
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2 INTRODUCTION Table 1.1 Breakdown
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4 INTRODUCTION Table 1.3 Comprehens
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6 INTRODUCTION Table 1.5 Schedule 1
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8 INTRODUCTION Table 1.7 Planning (
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2 Terminology ACID A chemical compo
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12 TERMINOLOGY initially thought to
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14 TERMINOLOGY vapour concentration
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16 TERMINOLOGY MULTIPLE CHEMICAL SE
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18 TERMINOLOGY conferences of the s
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20 TERMINOLOGY UEL, UPPER EXPLOSIVE
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22 GENERAL PRINCIPLES OF CHEMISTRY
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46 PHYSICOCHEMISTRY pa = pa′ xa w
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48 PHYSICOCHEMISTRY Table 4.1 Densi
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50 PHYSICOCHEMISTRY Vapour flashing
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52 PHYSICOCHEMISTRY where N is mass
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54 PHYSICOCHEMISTRY where T a is th
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56 PHYSICOCHEMISTRY Table 4.8 Compa
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58 PHYSICOCHEMISTRY Table 4.10 Corr
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60 PHYSICOCHEMISTRY Table 4.12 Solv
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62 PHYSICOCHEMISTRY Table 4.13 Cont
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64 PHYSICOCHEMISTRY Table 4.13 Cont
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66 PHYSICOCHEMISTRY If pressure rel
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68 TOXIC CHEMICALS Table 5.1 Classi
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70 TOXIC CHEMICALS Table 5.2 Materi
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72 TOXIC CHEMICALS A summary of the
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74 TOXIC CHEMICALS Table 5.4 Cont
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76 TOXIC CHEMICALS Table 5.6 Some s
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78 TOXIC CHEMICALS 10 6 Boulders 10
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80 TOXIC CHEMICALS Table 5.10 Chemi
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Threshold limit values (TLV) These
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(a) should not be used as an index
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Table 5.13 Adopted biological expos
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Table 5.13 Cont’d METHYL ETHYL KE
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Table 5.14 UK biological monitoring
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Table 5.16 Substances assigned ‘R
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Table 5.16 Cont’d Ethyleneimine E
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Table 5.17 Evaluation of carcinogen
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Table 5.17 Cont’d RISK CONTROL 12
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Table 5.17 Cont’d Non-arsenical i
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Table 5.17 Cont’d 2-(2-Formylhydr
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Table 5.17 Cont’d Uracil mustard
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(e.g. with knock-out and/or scrubbi
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Typical minimum transport velocitie
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Table 5.20 Prohibition of certain s
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Keep test records Keep RPE test rec
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extend with certain exceptions to o
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Table 5.23 Frequency of thorough ex
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Table 5.26 Agents for which health
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Table 5.27 Summary of precautions f
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Long-term exposure to ferric oxide
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The STEL is 200 ppm but extended pe
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(iv) Cyanides As a group, the cyani
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Basic precautions include those in
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Table 5.38 Chlorinated hydrocarbon
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Table 5.40 Routine laboratory preca
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Table 5.43 Common anhydrous acids C
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Table 5.45 Precautions in handling
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Table 5.48 Potential pollutants fro
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Table 5.51 Physical properties of t
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Whilst the causative agent(s) have
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Table 5.54 Precautions to avoid ‘
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Table 5.57 General precautions with
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Monitor effectiveness Assess weldin
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Ammonium chloride fume - 10 - 20 -
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tert-Butyl acetate 200 950 - - 200
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2-Chloroethanol, see Ethylene chlor
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1,2-Dibromoethane, see Ethylene dib
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Dinitolmide - 5 - - - - - - Dinitro
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Ethyl ether 400 1210 500 1520 400 1
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Hydrogen bromide - - C3 C9.9 - - 3
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Inorganic forms including metallic
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Mineral wool fibre - 10 (i) Molybde
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Perlite - 10 (i) Petroleum distilla
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Quinone 0.1 0.44 - - 0.1 0.4 0.3 1.
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Synthetic vitreous fibres Continuou
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Tricyclohexyltin hydroxide, see Cyh
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(d) Simple asphyxiant. Some gases a
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6 Flammable chemicals Certain chemi
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198 FLAMMABLE CHEMICALS these are n
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Table 6.3 Sources of ignition Mecha
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Table 6.4 Approximate temperatures
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Table 6.6 Approximate temperatures
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Table 6.7 Cont’d Wood flour Wool
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Table 6.10 Electrochemical series M
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Table 6.11 Control measures for wor
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• The type of hazard - determines
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Table 6.13 General requirements for
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The minimum fire instruction and tr
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n-Amyl alcohol 0.82 3.0 33 300 1-10
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Butyl cellosolve 0.91 4.1 61 244 1.
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Cumene 0.86 4.1 44 424 0.9-6.5 152
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Diethyl sulphate Diglycol, see Diet
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Ethylene chlorohydrin 1.21 2.78 60o
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p-Mentha-1,8-diene 3.84 7.4 45 237
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Nitroethane 1.05 2.58 38 360-415 3.
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Propionitrile 0.77 1.9 2 - 3.1- 97
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Trimethyl amine 0.66 2.0 -7 190 2-1
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Benzoyl peroxide - - - 21 - Berylli
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Copper-zinc, gold bronze 370 190 1.
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Hydrazine acid tartrate 570 0.175 4
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Phthalimide 630 - 0.030 50 89 4800
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Sodium toluene sulphonate 530 - - -
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7 Reactive chemicals From Chapter 3
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230 REACTIVE CHEMICALS Table 7.1 Wa
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232 REACTIVE CHEMICALS Table 7.3 Va
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234 REACTIVE CHEMICALS (e.g. concen
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236 REACTIVE CHEMICALS Table 7.7 At
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238 REACTIVE CHEMICALS Table 7.9 Se
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240 REACTIVE CHEMICALS Table 7.9 Co
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242 REACTIVE CHEMICALS Table 7.11 C
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244 REACTIVE CHEMICALS High e.g. sl
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246 REACTIVE CHEMICALS Table 7.14 S
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248 REACTIVE CHEMICALS Table 7.17 G
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250 REACTIVE CHEMICALS Table 7.20 P
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252 REACTIVE CHEMICALS Incorrect ki
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254 REACTIVE CHEMICALS Table 7.22 H
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256 REACTIVE CHEMICALS Erlenmeyer r
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8 Cryogens Cryogenics, or low-tempe
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260 CRYOGENS Table 8.3 General prec
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262 CRYOGENS to liquefy. The triple
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264 CRYOGENS Table 8.6 Effect of ca
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266 COMPRESSED GASES Table 9.1 Comp
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268 COMPRESSED GASES Table 9.1 Cont
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270 COMPRESSED GASES Table 9.1 Cont
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272 COMPRESSED GASES Table 9.3 prov
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274 COMPRESSED GASES Table 9.4 Phys
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276 COMPRESSED GASES The precaution
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278 COMPRESSED GASES Vapour pressur
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280 COMPRESSED GASES CO + Cl 2 →
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284 COMPRESSED GASES Hydrogen chlor
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286 COMPRESSED GASES • Avoid galv
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292 COMPRESSED GASES Table 9.16 Gen
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296 COMPRESSED GASES Table 9.20 Phy
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302 COMPRESSED GASES 16 hr per day
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304 COMPRESSED GASES where R 1 and
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308 MONITORING TECHNIQUES Table 10.
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310 MONITORING TECHNIQUES such that
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314 MONITORING TECHNIQUES industria
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Table 10.12 Selected examples of sa
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Table 10.15 Charcoal tube user guid
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Table 10.15 Cont’d Substance Expe
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Table 10.17 Compounds detectable by
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Table 10.17 Cont’d Compound Analy
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Table 10.23 Cont’d Principle Exam
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Table 10.30 Methods for sampling an
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Table 10.30 Cont’d Substance Samp
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386 MONITORING TECHNIQUES Existing
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11 Radioactive chemicals The main c
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392 RADIOACTIVE CHEMICALS Table 11.
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394 RADIOACTIVE CHEMICALS D t = D 0
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12 Safety by design Plant and equip
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398 SAFETY BY DESIGN Table 12.2 Che
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400 SAFETY BY DESIGN Table 12.5 Fea
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402 SAFETY BY DESIGN Table 12.7 Sel
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404 SAFETY BY DESIGN Equipment desi
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406 SAFETY BY DESIGN Table 12.11 Sa
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408 SAFETY BY DESIGN Table 12.12 Ra
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410 SAFETY BY DESIGN Table 12.13 Co
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13 Operating procedures Safety is a
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414 OPERATING PROCEDURES Table 13.1
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418 OPERATING PROCEDURES Work can b
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420 OPERATING PROCEDURES PLANT DETA
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422 OPERATING PROCEDURES CERTIFICAT
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424 OPERATING PROCEDURES • Have e
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426 OPERATING PROCEDURES Calling in
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430 OPERATING PROCEDURES Cuts is un
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436 OPERATING PROCEDURES There are
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442 OPERATING PROCEDURES Monitoring
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444 MARKETING Table 14.1 Legislatio
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446 MARKETING Table 14.2 Indication
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448 MARKETING Table 14.3 ‘Risk’
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450 MARKETING Table 14.3 Cont’d 4
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452 MARKETING Table 14.5 Classifica
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454 MARKETING Table 14.6 Cont’d C
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456 MARKETING Table 14.9 Compatibil
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458 MARKETING • Substances intend
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15 Transport of chemicals Transport
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462 TRANSPORT OF CHEMICALS Legislat
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464 TRANSPORT OF CHEMICALS • in a
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466 TRANSPORT OF CHEMICALS Table 15
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468 TRANSPORT OF CHEMICALS Table 15
Page 482 and 483: 470 TRANSPORT OF CHEMICALS Table 15
Page 494 and 495: 482 TRANSPORT OF CHEMICALS water sp
Page 500 and 501: 16 Chemicals and the environment: s
Page 502 and 503: 490 CHEMICALS AND THE ENVIRONMENT:
Page 524 and 525: 17 Chemicals and the environment: m
Page 526 and 527: 514 CHEMICALS AND THE ENVIRONMENT D
Page 528 and 529: 516 CHEMICALS AND THE ENVIRONMENT T
Page 540 and 541: 528 CHEMICALS AND THE ENVIRONMENT A
Page 542 and 543: 530 CHEMICALS AND THE ENVIRONMENT P
Page 556 and 557: 544 CONVERSION TABLES AND MEASUREME
Page 562 and 563: Emission rates To obtain: g/s g/min
Page 564 and 565: 19 Bibliography It is impractical t
Page 566 and 567: 554 BIBLIOGRAPHY Be Prepared for an
Page 568 and 569: 556 BIBLIOGRAPHY Kletz, T.A. (1989)
Page 570 and 571: 558 BIBLIOGRAPHY Selected statutory
Page 572 and 573: 560 BIBLIOGRAPHY European legislati
Page 574 and 575: 562 BIBLIOGRAPHY 95/50/EC Directive
Page 576 and 577: 564 BIBLIOGRAPHY 2000/166/EC Decisi
Page 578 and 579: 566 BIBLIOGRAPHY European legislati
Page 580 and 581: 568 BIBLIOGRAPHY SI 1989/1149 Contr
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570 BIBLIOGRAPHY Selected decisions
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572 BIBLIOGRAPHY BPM 20 Iron works
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574 BIBLIOGRAPHY EH 65/30 Review of
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576 BIBLIOGRAPHY HS(G)123 Working t
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578 BIBLIOGRAPHY INDG 136 COSHH: a
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580 BIBLIOGRAPHY L73 RIDDOR explain
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582 BIBLIOGRAPHY MDHS 70 General me
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584 BIBLIOGRAPHY SHW 396 Effects of
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586 BIBLIOGRAPHY Publications by th
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588 BIBLIOGRAPHY BS 3951 (Withdrawn
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590 BIBLIOGRAPHY BS EN 54-2 Fire de
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592 BIBLIOGRAPHY BS EN 60079-14 AMD
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594 APPENDIX: SELECTED UK LEGISLATI
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596 APPENDIX: SELECTED UK LEGISLATI
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Absorption: gas, 314 percutaneous,
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systems of work, See Systems of wor
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Gloves, See Hand protection Glutera
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physical properties, 301 precaution
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Spillage, 427, 428, 429 Spontaneous
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