Hazardous Chemicals Handbook (pdf) - CCC

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592 BIBLIOGRAPHY BS EN 60079-14 AMD 1 Electrical apparatus for explosive gas atmospheres. Electrical installations in hazardous areas (other than mines). Corrigendum No. 1 (Corr. 10013) dated April 1998, superseded BS 5345: Part 1: 1989, Parts 2 and 7: 1979, Part 4: 1977, Part 5: 1983, Part 6: 1978 and Part 8: 1980 BS EN 60309-2 Plugs, socket-outlets and couplers for industrial purposes. Dimensional interchangeability requirements for pin and contact-tube accessories. Superseded BS EN 60309-2: 1998, which remains current BS EN 60432-1 AMD 1 Incandescent lamps – Safety specifications. Tungsten filament lamps for domestic and similar general lighting purposes (AMD 9775) dated January 1998. Superseded by BS EN 60432-1: 2000, but remains current BS EN 60529 AMD 1 Degrees of protection provided by enclosures (IP code) (AMD 7643) dated 15 July 1993. Superseded BS 5490: 1977 BS EN 60598-2-22 Luminaires. Part 2: Particular requirements. Particular requirements – Luminaires for emergency lighting. Incorporating Corrigendum No. 1 (AMD 10562) dated December 1999. Inc.Cor1, Superseded BS 4533: Section 102.22: 1990, which remains current BS EN 60695-11-20 Fire hazard testing. Part 11: Test flames – 500 W flame test methods. Superseded BS 2782 – 140C: 1993 BS EN 60695-2-2 AMD 1 Fire hazard testing. Part 2: Test methods. Needle-flame test (AMD 9176) dated 15 November 1996. Previously known as BS 6458: Section 2.2: 1993 BS EN 60695-4 Fire hazard testing. Terminology concerning fire tests. Superseded BS 6458: Part 1: 1990 BS EN 60707 Flammability of solid non-metallic materials when exposed to flame sources – List of test methods. Superseded BS 6334: 1983 BS EN 60721-3-1 Classification of environmental conditions. Part 3: Classification of groups of environmental parameters and their severities. Storage. Superseded BS EN 60721-3-1: 1993 BS EN 60721-3-2 Classification of environmental conditions. Part 3: Classification of groups of environmental parameters and their severities. Transportation. Superseded BS EN 60721-3-2: 1993 BS EN 60721-3-3 AMD 1 Classification of environmental conditions. Part 3: Classification of groups of environmental parameters and their severities. Stationary use at weather protected locations (AMD 9514) dated 15 June 1997. Superseded BS EN 60721-3-3: 1993. Previously BS 7527: Section 3.3: 1991 BS EN 60721-3-4 AMD 1 Classification of environmental conditions. Part 3: Classification of groups of environmental parameters and their severities. Stationary use at non-weather protected locations (AMD 9513) dated 15 June 1997. Previously BS 7527: Section 3.4: 1991 CP 15/1 Code of Practice 15/1: The safe re-rating of existing BS 5045: Part 1: 1982 Containers to amendment AMD 5145: 1986. Part 1: Permanent gas containers (excluding hydrogen trailer service) CP 15/2 Code of Practice 15/2: The safe re-rating of existing BS 5045: Part 1: Cylinders to amendment AMD 5145: 1986. Part 2: Containers for hydrogen trailer service DD 180 Guide for the assessment of toxic hazards in fire in buildings and transport. Superseded by BS 7899: Parts 1, 2 and 3 but remains current DD 189 (Withdrawn) 1990 Safety of condensing boilers (2nd and 3rd family gases). Withdrawn, superseded by BS EN 677: 1998 DD 211 (Withdrawn) 1992 Method for detection and enumeration of Legionella organisms in water and related materials. Withdrawn, superseded by BS 6068-4.12: 1998
Appendix Selected UK legislation relevant to environmental protection and occupational health and safety in relation to chemicals The general principles outlined in this work for the identification and control of hazardous chemicals are independent of legislation. However, regulatory obligations forcing compliance with national and/or local requirements should be consulted. Space prevents encyclopaedic coverage but the following brief selection of relevant UK legislation serves to illustrate the scope. It is supplemented by the lists of legislation in the Bibliography. General health and safety The minimum standards for health and safety are those outlined in numerous pieces of statutory legislation. These include the: Factories Act 1961 Health and Safety at Work etc. Act 1974 Management of Health and Safety at Work Regulations 1992 Management of Health and Safety at Work (Amendment) Regulations 1994 Manual Handling Operations Regulations 1992 All of these contain requirements of relevance to work with hazardous chemicals. Selected legislation relevant to the control of hazardous chemicals The following legislation is of direct relevance. Asbestos (Prohibitions) Regulations 1992 Cover the prohibition of the importation, supply or new use of amphibole asbestos or products containing it. Also prohibit the supply and use of a range of products containing chrysotile asbestos. Carriage of Dangerous Goods by Rail Regulations 1996 The scope includes carriage of dangerous substances by wagons, large containers, small containers and tanks. Cover the documentation requirements, the mode of transport, the information needs, loading/unloading, security, safety
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Hazardous Chemicals Handbook
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Butterworth-Heinemann An imprint of
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vi CONTENTS Effects of particle or
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viii CONTENTS 14 Marketing 443 Clas
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x PREFACE TO THE SECOND EDITION The
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xii PREFACE to chemical safety data
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2 INTRODUCTION Table 1.1 Breakdown
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4 INTRODUCTION Table 1.3 Comprehens
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6 INTRODUCTION Table 1.5 Schedule 1
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8 INTRODUCTION Table 1.7 Planning (
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2 Terminology ACID A chemical compo
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12 TERMINOLOGY initially thought to
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14 TERMINOLOGY vapour concentration
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16 TERMINOLOGY MULTIPLE CHEMICAL SE
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18 TERMINOLOGY conferences of the s
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20 TERMINOLOGY UEL, UPPER EXPLOSIVE
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22 GENERAL PRINCIPLES OF CHEMISTRY
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46 PHYSICOCHEMISTRY pa = pa′ xa w
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48 PHYSICOCHEMISTRY Table 4.1 Densi
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50 PHYSICOCHEMISTRY Vapour flashing
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52 PHYSICOCHEMISTRY where N is mass
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54 PHYSICOCHEMISTRY where T a is th
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56 PHYSICOCHEMISTRY Table 4.8 Compa
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58 PHYSICOCHEMISTRY Table 4.10 Corr
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60 PHYSICOCHEMISTRY Table 4.12 Solv
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62 PHYSICOCHEMISTRY Table 4.13 Cont
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64 PHYSICOCHEMISTRY Table 4.13 Cont
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66 PHYSICOCHEMISTRY If pressure rel
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68 TOXIC CHEMICALS Table 5.1 Classi
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70 TOXIC CHEMICALS Table 5.2 Materi
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72 TOXIC CHEMICALS A summary of the
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74 TOXIC CHEMICALS Table 5.4 Cont
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76 TOXIC CHEMICALS Table 5.6 Some s
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78 TOXIC CHEMICALS 10 6 Boulders 10
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80 TOXIC CHEMICALS Table 5.10 Chemi
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Threshold limit values (TLV) These
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(a) should not be used as an index
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Table 5.13 Adopted biological expos
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Table 5.13 Cont’d METHYL ETHYL KE
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Table 5.14 UK biological monitoring
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Table 5.16 Substances assigned ‘R
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Table 5.16 Cont’d Ethyleneimine E
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Table 5.17 Evaluation of carcinogen
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Table 5.17 Cont’d RISK CONTROL 12
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Table 5.17 Cont’d Non-arsenical i
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Table 5.17 Cont’d 2-(2-Formylhydr
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Table 5.17 Cont’d Uracil mustard
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(e.g. with knock-out and/or scrubbi
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Typical minimum transport velocitie
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Table 5.20 Prohibition of certain s
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Keep test records Keep RPE test rec
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extend with certain exceptions to o
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Table 5.23 Frequency of thorough ex
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Table 5.26 Agents for which health
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Table 5.27 Summary of precautions f
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Long-term exposure to ferric oxide
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The STEL is 200 ppm but extended pe
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(iv) Cyanides As a group, the cyani
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Basic precautions include those in
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Table 5.38 Chlorinated hydrocarbon
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Table 5.40 Routine laboratory preca
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Table 5.43 Common anhydrous acids C
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Table 5.45 Precautions in handling
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Table 5.48 Potential pollutants fro
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Table 5.51 Physical properties of t
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Whilst the causative agent(s) have
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Table 5.54 Precautions to avoid ‘
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Table 5.57 General precautions with
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Monitor effectiveness Assess weldin
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Ammonium chloride fume - 10 - 20 -
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tert-Butyl acetate 200 950 - - 200
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2-Chloroethanol, see Ethylene chlor
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1,2-Dibromoethane, see Ethylene dib
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Dinitolmide - 5 - - - - - - Dinitro
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Ethyl ether 400 1210 500 1520 400 1
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Hydrogen bromide - - C3 C9.9 - - 3
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Inorganic forms including metallic
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Mineral wool fibre - 10 (i) Molybde
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Perlite - 10 (i) Petroleum distilla
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Quinone 0.1 0.44 - - 0.1 0.4 0.3 1.
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Synthetic vitreous fibres Continuou
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Tricyclohexyltin hydroxide, see Cyh
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(d) Simple asphyxiant. Some gases a
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6 Flammable chemicals Certain chemi
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198 FLAMMABLE CHEMICALS these are n
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Table 6.3 Sources of ignition Mecha
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Table 6.4 Approximate temperatures
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Table 6.6 Approximate temperatures
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Table 6.7 Cont’d Wood flour Wool
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Table 6.10 Electrochemical series M
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Table 6.11 Control measures for wor
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• The type of hazard - determines
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Table 6.13 General requirements for
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The minimum fire instruction and tr
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n-Amyl alcohol 0.82 3.0 33 300 1-10
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Butyl cellosolve 0.91 4.1 61 244 1.
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Cumene 0.86 4.1 44 424 0.9-6.5 152
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Diethyl sulphate Diglycol, see Diet
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Ethylene chlorohydrin 1.21 2.78 60o
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p-Mentha-1,8-diene 3.84 7.4 45 237
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Nitroethane 1.05 2.58 38 360-415 3.
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Propionitrile 0.77 1.9 2 - 3.1- 97
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Trimethyl amine 0.66 2.0 -7 190 2-1
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Benzoyl peroxide - - - 21 - Berylli
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Copper-zinc, gold bronze 370 190 1.
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Hydrazine acid tartrate 570 0.175 4
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Phthalimide 630 - 0.030 50 89 4800
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Sodium toluene sulphonate 530 - - -
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7 Reactive chemicals From Chapter 3
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230 REACTIVE CHEMICALS Table 7.1 Wa
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232 REACTIVE CHEMICALS Table 7.3 Va
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234 REACTIVE CHEMICALS (e.g. concen
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236 REACTIVE CHEMICALS Table 7.7 At
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238 REACTIVE CHEMICALS Table 7.9 Se
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240 REACTIVE CHEMICALS Table 7.9 Co
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242 REACTIVE CHEMICALS Table 7.11 C
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244 REACTIVE CHEMICALS High e.g. sl
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246 REACTIVE CHEMICALS Table 7.14 S
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248 REACTIVE CHEMICALS Table 7.17 G
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250 REACTIVE CHEMICALS Table 7.20 P
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252 REACTIVE CHEMICALS Incorrect ki
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254 REACTIVE CHEMICALS Table 7.22 H
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256 REACTIVE CHEMICALS Erlenmeyer r
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8 Cryogens Cryogenics, or low-tempe
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260 CRYOGENS Table 8.3 General prec
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262 CRYOGENS to liquefy. The triple
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264 CRYOGENS Table 8.6 Effect of ca
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266 COMPRESSED GASES Table 9.1 Comp
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268 COMPRESSED GASES Table 9.1 Cont
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270 COMPRESSED GASES Table 9.1 Cont
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272 COMPRESSED GASES Table 9.3 prov
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274 COMPRESSED GASES Table 9.4 Phys
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276 COMPRESSED GASES The precaution
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278 COMPRESSED GASES Vapour pressur
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280 COMPRESSED GASES CO + Cl 2 →
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284 COMPRESSED GASES Hydrogen chlor
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286 COMPRESSED GASES • Avoid galv
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292 COMPRESSED GASES Table 9.16 Gen
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296 COMPRESSED GASES Table 9.20 Phy
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302 COMPRESSED GASES 16 hr per day
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304 COMPRESSED GASES where R 1 and
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308 MONITORING TECHNIQUES Table 10.
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310 MONITORING TECHNIQUES such that
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314 MONITORING TECHNIQUES industria
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Table 10.12 Selected examples of sa
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Table 10.15 Charcoal tube user guid
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Table 10.15 Cont’d Substance Expe
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Table 10.17 Compounds detectable by
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Table 10.17 Cont’d Compound Analy
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Table 10.23 Cont’d Principle Exam
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Table 10.30 Methods for sampling an
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Table 10.30 Cont’d Substance Samp
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386 MONITORING TECHNIQUES Existing
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11 Radioactive chemicals The main c
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392 RADIOACTIVE CHEMICALS Table 11.
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394 RADIOACTIVE CHEMICALS D t = D 0
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12 Safety by design Plant and equip
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398 SAFETY BY DESIGN Table 12.2 Che
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400 SAFETY BY DESIGN Table 12.5 Fea
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402 SAFETY BY DESIGN Table 12.7 Sel
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404 SAFETY BY DESIGN Equipment desi
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406 SAFETY BY DESIGN Table 12.11 Sa
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408 SAFETY BY DESIGN Table 12.12 Ra
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410 SAFETY BY DESIGN Table 12.13 Co
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13 Operating procedures Safety is a
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414 OPERATING PROCEDURES Table 13.1
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418 OPERATING PROCEDURES Work can b
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420 OPERATING PROCEDURES PLANT DETA
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422 OPERATING PROCEDURES CERTIFICAT
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424 OPERATING PROCEDURES • Have e
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426 OPERATING PROCEDURES Calling in
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430 OPERATING PROCEDURES Cuts is un
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436 OPERATING PROCEDURES There are
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442 OPERATING PROCEDURES Monitoring
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444 MARKETING Table 14.1 Legislatio
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446 MARKETING Table 14.2 Indication
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448 MARKETING Table 14.3 ‘Risk’
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450 MARKETING Table 14.3 Cont’d 4
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452 MARKETING Table 14.5 Classifica
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454 MARKETING Table 14.6 Cont’d C
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456 MARKETING Table 14.9 Compatibil
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458 MARKETING • Substances intend
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15 Transport of chemicals Transport
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462 TRANSPORT OF CHEMICALS Legislat
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464 TRANSPORT OF CHEMICALS • in a
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466 TRANSPORT OF CHEMICALS Table 15
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482 TRANSPORT OF CHEMICALS water sp
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16 Chemicals and the environment: s
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490 CHEMICALS AND THE ENVIRONMENT:
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17 Chemicals and the environment: m
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514 CHEMICALS AND THE ENVIRONMENT D
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516 CHEMICALS AND THE ENVIRONMENT T
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528 CHEMICALS AND THE ENVIRONMENT A
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530 CHEMICALS AND THE ENVIRONMENT P
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Page 554 and 555: 542 CHEMICALS AND THE ENVIRONMENT T
Page 556 and 557: 544 CONVERSION TABLES AND MEASUREME
Page 562 and 563: Emission rates To obtain: g/s g/min
Page 564 and 565: 19 Bibliography It is impractical t
Page 566 and 567: 554 BIBLIOGRAPHY Be Prepared for an
Page 568 and 569: 556 BIBLIOGRAPHY Kletz, T.A. (1989)
Page 570 and 571: 558 BIBLIOGRAPHY Selected statutory
Page 572 and 573: 560 BIBLIOGRAPHY European legislati
Page 574 and 575: 562 BIBLIOGRAPHY 95/50/EC Directive
Page 576 and 577: 564 BIBLIOGRAPHY 2000/166/EC Decisi
Page 578 and 579: 566 BIBLIOGRAPHY European legislati
Page 580 and 581: 568 BIBLIOGRAPHY SI 1989/1149 Contr
Page 582 and 583: 570 BIBLIOGRAPHY Selected decisions
Page 584 and 585: 572 BIBLIOGRAPHY BPM 20 Iron works
Page 586 and 587: 574 BIBLIOGRAPHY EH 65/30 Review of
Page 588 and 589: 576 BIBLIOGRAPHY HS(G)123 Working t
Page 590 and 591: 578 BIBLIOGRAPHY INDG 136 COSHH: a
Page 592 and 593: 580 BIBLIOGRAPHY L73 RIDDOR explain
Page 594 and 595: 582 BIBLIOGRAPHY MDHS 70 General me
Page 596 and 597: 584 BIBLIOGRAPHY SHW 396 Effects of
Page 598 and 599: 586 BIBLIOGRAPHY Publications by th
Page 600 and 601: 588 BIBLIOGRAPHY BS 3951 (Withdrawn
Page 602 and 603: 590 BIBLIOGRAPHY BS EN 54-2 Fire de
Page 606 and 607: 594 APPENDIX: SELECTED UK LEGISLATI
Page 608 and 609: 596 APPENDIX: SELECTED UK LEGISLATI
Page 610 and 611: Absorption: gas, 314 percutaneous,
Page 612 and 613: systems of work, See Systems of wor
Page 614 and 615: Gloves, See Hand protection Glutera
Page 616 and 617: physical properties, 301 precaution
Page 618 and 619: Spillage, 427, 428, 429 Spontaneous
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