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Kyanite, Sillimanite, and Andalusite Deposits of the Southeastern ...

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ORIGIN 25<br />

matism in areas extending over tens <strong>of</strong> square miles<br />

could hardly have been so selective that deposition<br />

<strong>of</strong> aluminum was vertically restricted to s<strong>and</strong>stone<br />

beds, only a few feet thick in many places, <strong>and</strong> nowhere<br />

formed discordant replacement masses in<br />

s<strong>and</strong>stone or adjacent beds. In addition to <strong>the</strong><br />

quartzose rocks, aluminous schists occur in <strong>the</strong><br />

Kings Mountain district; <strong>the</strong> aluminous minerals<br />

are not distributed irregularly through <strong>the</strong>se<br />

schists, but occur in layers that probably represent<br />

<strong>the</strong> original bedding. If <strong>the</strong> Al2Si0 5 minerals in<br />

<strong>the</strong>se two districts are <strong>the</strong> result <strong>of</strong> aluminum metasomatism,<br />

no evidence whatever remains <strong>of</strong> <strong>the</strong><br />

means by which this pervasive replacement took<br />

place. In both districts, quartz veins <strong>and</strong> peg­<br />

matites are present, but <strong>the</strong> Al2Si0 5 minerals are<br />

absent from <strong>the</strong> pegmatites <strong>and</strong> are present in <strong>the</strong><br />

quartz veins only where <strong>the</strong>se veins cut <strong>the</strong> highalumina<br />

rocks. In <strong>the</strong> Kings Mountain district,<br />

quartz veins occur in most <strong>of</strong> <strong>the</strong> metamorphic<br />

rocks; a quartz-kyanite vein that cuts kyanite<br />

quartzite at Clubb Mountain is definitely later than<br />

<strong>the</strong> kyanite quartzite (fig. 25). Pegmatite bodies in<br />

<strong>the</strong> Kings Mountain district are restricted to <strong>the</strong><br />

margin <strong>of</strong> <strong>the</strong> Yorkville quartz monzonite, <strong>and</strong><br />

show no relation to <strong>the</strong> distribution <strong>of</strong> most <strong>of</strong> <strong>the</strong><br />

beds <strong>of</strong> high-alumina quartzite. Pegmatites are more<br />

widely distributed in <strong>the</strong> Farmville district; however,<br />

<strong>the</strong>y do not contain kyanite <strong>and</strong> <strong>the</strong>y are not foliated,<br />

indicating that <strong>the</strong>y are younger than <strong>the</strong><br />

well-foliated kyanite (or sillimanite) quartzite.<br />

Tourmaline is very common in many quartz veins<br />

in <strong>the</strong> Farmville district, <strong>and</strong> occurs sparingly in<br />

quartz veins in <strong>the</strong> Kings Mountain district. However,<br />

tourmaline is an extremely rare mineral in <strong>the</strong><br />

quartzose high-alumina deposits in <strong>the</strong>se districts,<br />

<strong>and</strong> kyanite was not found in any <strong>of</strong> <strong>the</strong>se tourmaline-quartz<br />

veins. Evidently <strong>the</strong> tourmaline mineralization<br />

had nothing to do with <strong>the</strong> formation <strong>of</strong><br />

kyanite in <strong>the</strong>se two districts. This is in contrast<br />

to <strong>the</strong> Bh<strong>and</strong>ara district, India, where tourmalinequartz<br />

veins are associated with kyanite deposits;<br />

Chatterjee (1931) has suggested that borates or<br />

boric acid accompanying <strong>the</strong> tourmaline mineralization<br />

acted as mineralizers to mobilize aluminum<br />

from chlorite-muscovite schists.<br />

Mobilization <strong>of</strong> aluminum by metamorphic differentiation<br />

or o<strong>the</strong>r means in <strong>the</strong> Farmville <strong>and</strong><br />

Kings Mountain districts seems to have been restricted<br />

to <strong>the</strong> formation <strong>of</strong> lenticular aggregates <strong>of</strong><br />

coarse unoriented kyanite in kyanite quartzite <strong>and</strong><br />

minor amounts <strong>of</strong> kyanite in some quartz veins that<br />

cut kyanite quartzite.<br />

The weight <strong>of</strong> <strong>the</strong> evidence seems to us to point<br />

to an origin <strong>of</strong> <strong>the</strong>se high-alumina quartzites in<br />

both <strong>the</strong> Farmville <strong>and</strong> Kings Mountain districts by<br />

<strong>the</strong> recrystallization <strong>of</strong> clay-quartz s<strong>and</strong> sediments.<br />

In <strong>the</strong> Kings Mountain district, sillimanite was<br />

formed instead <strong>of</strong> kyanite in <strong>the</strong> highest temperature<br />

zones near <strong>the</strong> Yorkville quartz monzonite.<br />

REPLACEMENT DEPOSITS<br />

Quartzose deposits <strong>of</strong> Al2Si0 5 minerals that seem<br />

to be <strong>of</strong> replacement origin are <strong>the</strong> deposits <strong>of</strong> kyanite-quartz<br />

rock at Hagers Mountain, N.C., <strong>the</strong><br />

Corbett property, North Carolina, Little Mountain,<br />

S.C., <strong>and</strong> Graves Mountain, Ga.; <strong>the</strong> <strong>and</strong>alusitepyrophyllite-quartz<br />

deposits <strong>of</strong> <strong>the</strong> North Carolina<br />

pyrophyllite belt; <strong>and</strong> <strong>the</strong> Brewer mine <strong>and</strong> Boles<br />

Mountain, S.C. These replacement deposits all occur<br />

in <strong>the</strong> belt <strong>of</strong> volcanic flows, tuffs, <strong>and</strong> slates in <strong>the</strong><br />

eastern Piedmont.<br />

These replacement deposits are each made up <strong>of</strong><br />

many lenticular segments, which are generally<br />

conformable to <strong>the</strong> enclosing schists, but which are<br />

partly discordant at Graves Mountain, Ga., <strong>and</strong> at<br />

<strong>the</strong> Brewer deposit, South Carolina. This discordance<br />

is one evidence <strong>of</strong> replacement origin.<br />

Relict minerals or structures <strong>of</strong> <strong>the</strong> original rock<br />

are strong evidence <strong>of</strong> replacement in some deposits.<br />

Large grains <strong>of</strong> blue quartz, some being well-formed<br />

bipyramidal crystals, are abundant in some <strong>of</strong> <strong>the</strong><br />

kyanite-quartz rock at Graves Mountain (p. 98; fig.<br />

1). They are most likely relict quartz phenocrysts<br />

in an igneous rock that has been almost completely<br />

replaced by silicon <strong>and</strong> aluminum. At <strong>the</strong> Brewer<br />

deposit, South Carolina, <strong>the</strong> original structures <strong>of</strong><br />

breccia tuffs <strong>and</strong> <strong>of</strong> bedding or foliation are preserved<br />

in silicified rock (Pardee <strong>and</strong> Park, 1948).<br />

Similar features are found in some <strong>of</strong> <strong>the</strong> North<br />

Carolina pyrophyllite deposits (Stuckey, 1928);<br />

masses or lenses <strong>of</strong> unaltered or only partly altered<br />

country rock are also found in some <strong>of</strong> <strong>the</strong>se pyrophyllite<br />

deposits.<br />

The quartz that forms <strong>the</strong> matrix is extremely<br />

fine grained in all <strong>the</strong>se deposits, similar to much<br />

quartz <strong>of</strong> replacement origin. Silicification was <strong>the</strong><br />

first stage <strong>of</strong> mineralization; <strong>the</strong> aluminous minerals<br />

vein <strong>and</strong> replace quartz. <strong>Kyanite</strong> occurs in<br />

irregular bodies <strong>and</strong> crosscutting veins in kyanitequartz<br />

rock. Topaz forms irregular masses <strong>and</strong> networks<br />

<strong>of</strong> veins in <strong>the</strong> Brewer deposit; it also occurs<br />

in <strong>the</strong> Bowlings Mountain deposit, North Carolina.<br />

Pyrophyllite is invariably <strong>the</strong> latest aluminous mineral;<br />

it replaces quartz, kyanite, <strong>and</strong>alusite, diaspore,<br />

<strong>and</strong> topaz (figs. 17,18,19).

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