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Kyanite, Sillimanite, and Andalusite Deposits of the Southeastern ...

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KYANITE, SILLIMANITE, AND ANDALUSITE DEPOSITS OF THE SOUTHEASTERN<br />

STATES<br />

By GILBERT H. ESPENSHADE <strong>and</strong> DONALD B. POTTER<br />

ABSTRACT<br />

<strong>Deposits</strong> <strong>of</strong> <strong>the</strong> Al2SiO5 minerals kyanite, sillimanite, <strong>and</strong><br />

<strong>and</strong>alusite in <strong>the</strong> Sou<strong>the</strong>ast were investigated during 1950<br />

to 1953. These minerals, particularly kyanite, are useful in<br />

<strong>the</strong> manufacture <strong>of</strong> high-alumina refractory materials. <strong>Deposits</strong><br />

in <strong>the</strong> Sou<strong>the</strong>ast have been important sources <strong>of</strong> kyanite<br />

since <strong>the</strong> 1920's.<br />

These deposits occur in <strong>the</strong> large area <strong>of</strong> metamorphic<br />

rocks in <strong>the</strong> Blue Ridge <strong>and</strong> Piedmont provinces that extends<br />

for nearly 700 miles from <strong>the</strong> Potomac River to central Alabama.<br />

The AUSiOs minerals are found here in four major<br />

types <strong>of</strong> deposits: (a) in quartzose rocks, (b) in micaceous<br />

schists <strong>and</strong> gneisses, (c) in quartz veins <strong>and</strong> pegmatites, <strong>and</strong><br />

(d) in residual soils <strong>and</strong> placers. The quartzose deposits<br />

generally have a higher content <strong>of</strong> ALSiOs minerals than <strong>the</strong><br />

o<strong>the</strong>r deposits; kyanite-quartz deposits have been <strong>the</strong> most<br />

productive in <strong>the</strong> region.<br />

<strong>Kyanite</strong>-quartz rock, sillimanite-quartz rock, <strong>and</strong> <strong>and</strong>alusitepyrophyllite-quartz<br />

rock are <strong>the</strong> main varieties <strong>of</strong> quartzose<br />

deposits in <strong>the</strong> region; <strong>the</strong>y seem to be more numerous in <strong>the</strong><br />

Sou<strong>the</strong>ast than in o<strong>the</strong>r parts <strong>of</strong> <strong>the</strong> country. Although <strong>the</strong>se<br />

varieties differ in <strong>the</strong>ir mineral content <strong>and</strong> o<strong>the</strong>r geologic<br />

features, <strong>the</strong>y are similar in chemical composition, consisting<br />

principally <strong>of</strong> SiO2 <strong>and</strong> ALO3.<br />

<strong>Deposits</strong> <strong>of</strong> kyanite-quartz rock are <strong>the</strong> largest <strong>and</strong> most<br />

numerous <strong>of</strong> <strong>the</strong> group. <strong>Kyanite</strong> <strong>and</strong> quartz are <strong>the</strong> predominant<br />

minerals; kyanite generally constitutes 10 to 30<br />

percent <strong>of</strong> <strong>the</strong> rock; muscovite is generally present, <strong>and</strong> rutile<br />

is a widespread but minor constituent, generally in amounts<br />

between % <strong>and</strong> 1 percent; pyrite is also common; o<strong>the</strong>r minor<br />

constituents in some deposits are pyrophyllite, lazulite, topaz,<br />

<strong>and</strong> clay minerals. The deposits have a great range in size.<br />

The largest <strong>and</strong> most persistent are in <strong>the</strong> Farmville districtr<br />

Virginia, <strong>the</strong> Kings Mountain district, North Carolina-South<br />

Carolina, <strong>and</strong> at Graves Mountain, Ga. The rock is extremely<br />

resistant to wea<strong>the</strong>ring <strong>and</strong> erosion, <strong>and</strong> <strong>the</strong> larger deposits<br />

form prominent ridges or monadnocks several hundred feet<br />

high <strong>and</strong> a mile or more long. <strong>Sillimanite</strong> quartzite deposits<br />

are small, few in number, <strong>and</strong> have been found only in <strong>the</strong><br />

Kings Mountain district, North Carolina-South Carolina.<br />

<strong>Sillimanite</strong> makes up from 10 to 35 percent <strong>of</strong> this rock;<br />

<strong>and</strong>alusite <strong>and</strong> kyanite are also present in places. O<strong>the</strong>r<br />

aluminous minerals occurring locally in amounts <strong>of</strong> a few<br />

percent are white mica, chloritoid, diaspore, topaz, <strong>and</strong> lazulite;<br />

rutile is a widespread accessory mineral. Significant<br />

amounts <strong>of</strong> <strong>and</strong>alusite, generally accompanied by a little<br />

diaspore, are present in some <strong>of</strong> <strong>the</strong> North Carolina pyrophyllite<br />

deposits; small amounts <strong>of</strong> kyanite, topaz, corundum,<br />

<strong>and</strong> lazulite are also present locally; rutile is a persistent<br />

accessory mineral. A new deposit <strong>of</strong> this type was discovered<br />

at Boles Mountain, S.C., during <strong>the</strong> present investigation.<br />

Very fine grained topaz is <strong>the</strong> most abundant aluminous<br />

mineral in parts <strong>of</strong> <strong>the</strong> Brewer deposit, South Carolina;<br />

<strong>and</strong>alusite, kyanite, <strong>and</strong> pyrophyllite are also present.<br />

<strong>Kyanite</strong> occurs in micaceous schist <strong>and</strong> gneiss in extensive<br />

areas <strong>of</strong> <strong>the</strong> Blue Ridge <strong>of</strong> western North Carolina <strong>and</strong><br />

nor<strong>the</strong>rn Georgia. The kyanite content <strong>of</strong> large bodies <strong>of</strong><br />

rock ranges from a few percent to about 10 percent, though<br />

some individual layers contain 15 percent or more. Several<br />

deposits <strong>of</strong> this type have been mined in North Carolina <strong>and</strong><br />

Georgia. <strong>Sillimanite</strong> schist is ra<strong>the</strong>r widespread in a belt in<br />

<strong>the</strong> western Piedmont that extends from North Carolina to<br />

eastern Georgia, <strong>and</strong> in ano<strong>the</strong>r belt in <strong>the</strong> Blue Ridge <strong>of</strong><br />

North Carolina <strong>and</strong> Georgia. <strong>Sillimanite</strong> usually is in very<br />

fine crystals that are intimately intergrown with mica; it<br />

generally forms less than 10 percent <strong>of</strong> <strong>the</strong> rock. <strong>Sillimanite</strong><br />

schists have been explored ra<strong>the</strong>r extensively, but none have<br />

been mined. Large crystals <strong>of</strong> kyanite are common in quartz<br />

veins <strong>and</strong> pegmatites in <strong>the</strong> kyanite schist areas <strong>of</strong> <strong>the</strong> Blue<br />

Ridge. Such deposits are small <strong>and</strong> irregular, <strong>and</strong> attempts<br />

to mine <strong>the</strong>m have not been successful. In <strong>the</strong> kyanite schist<br />

belt <strong>of</strong> Habersham <strong>and</strong> Rabun Counties, Ga., kyanite has<br />

accumulated in <strong>the</strong> residual soil <strong>and</strong> in stream placers; <strong>the</strong>se<br />

deposits have been mined at several places. <strong>Kyanite</strong> <strong>and</strong><br />

sillimanite are among <strong>the</strong> heavy minerals in s<strong>and</strong>y formations<br />

<strong>of</strong> <strong>the</strong> Atlantic Coastal Plain.<br />

We believe that <strong>the</strong> kyanite <strong>and</strong> sillimanite in <strong>the</strong> micaceous<br />

schists <strong>and</strong> gneisses were formed by <strong>the</strong> metamorphism <strong>of</strong><br />

.aluminous sedimentary rocks. Some geologists have thought<br />

that <strong>the</strong> alumina was brought in by hydro<strong>the</strong>rmal solutions,<br />

possibly from igneous sources, <strong>and</strong> regard <strong>the</strong> kyanite-bearing<br />

quartz veins <strong>and</strong> pegmatites that occur in kyanite schist <strong>and</strong><br />

gneiss as having been <strong>the</strong> agents that introduced alumina.<br />

However, this is quite unlikely, because kyanite in <strong>the</strong> quartz<br />

veins <strong>and</strong> pegmatites appears to be younger than kyanite in<br />

<strong>the</strong> country rock; alumina probably was transferred from <strong>the</strong><br />

country rock to <strong>the</strong> quartz veins <strong>and</strong> pegmatites.<br />

On <strong>the</strong> o<strong>the</strong>r h<strong>and</strong>, <strong>the</strong> quartzose deposits <strong>of</strong> AlzSiOs minerals<br />

seem to have been formed by two distinct modes <strong>of</strong><br />

origin: metamorphism <strong>of</strong> aluminous sedimentary rocks <strong>and</strong> by<br />

hydro<strong>the</strong>rmal activity. Both types occur with, or in <strong>the</strong> vicinity<br />

<strong>of</strong>, volcanic rocks. <strong>Kyanite</strong> quartzite in <strong>the</strong> Farmville<br />

district, Virginia, <strong>and</strong> kyanite quartzite <strong>and</strong> sillimanite<br />

quartzite in <strong>the</strong> Kings Mountain district, North Carolina-<br />

South Carolina, are folded concordantly with <strong>the</strong> o<strong>the</strong>r metamorphic<br />

rocks <strong>and</strong> have <strong>the</strong> distribution patterns <strong>of</strong> stratigraphic<br />

units. There seem to be only two possible modes <strong>of</strong><br />

origin for <strong>the</strong> high-alumina quartzite deposits in <strong>the</strong>se districts:<br />

ei<strong>the</strong>r by <strong>the</strong> metamorphism <strong>of</strong> clay-s<strong>and</strong> sediments or<br />

by <strong>the</strong> introduction <strong>of</strong> alumina selectively into s<strong>and</strong>stone beds.<br />

There is no evidence for large-scale introduction <strong>of</strong> alumina,

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