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Effects of high pressure, magnetic fields, and substitutions - ICMR ...

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2. Magnetoelastic effects <strong>and</strong> spin-lattice coupling<br />

– how to measure these effects ?<br />

In multiferroics the spin-lattice interaction plays a decisive role in mediating the<br />

(improper) ferroelectricity induced by <strong>magnetic</strong> orders<br />

The measurements <strong>of</strong> the ionic displacements <strong>and</strong>/or the macroscopic lattice strain<br />

is therefore <strong>of</strong> interest<br />

Scattering experiments (x-ray, neutron) provide the tool to measure displacements<br />

on a microscopic level – but <strong>of</strong>ten lack the resolution to detect the tiny changes.<br />

Note: The atomic displacements explaining the experimental values <strong>of</strong> the FE<br />

polarization are as small as 10 -4 Å.<br />

Only a few attempts to derive structural distortions at the <strong>magnetic</strong> <strong>and</strong> ferroelectric<br />

transitions in multiferroics have been successful.

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