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Effects of high pressure, magnetic fields, and substitutions - ICMR ...

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Competing interactions in RMnO 3<br />

O<br />

Magnetic phase diagram <strong>of</strong> orthorhombic<br />

RMnO 3<br />

Mn<br />

a<br />

b<br />

R<br />

Superexchange couplings Mn 3+ -O -Mn 3+ :<br />

J 1 0 (AFM)<br />

depend on bond angle Φ (Mn-O-Mn), which is<br />

controlled by size <strong>of</strong> R<br />

Frustration <strong>and</strong> “exotic” phases near Φ ≈145 deg

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