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ALBERTO BOLLERO REAL

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2.2 Magnetic properties<br />

Fig. 2.6: Hysteresis loop for a permanent magnet material indicating by dashed lines the<br />

characteristic initial magnetisation curve for the case of pinning and nucleation<br />

mechanisms (from Skomski and Coey [19]).<br />

single domain size diameter [11,27]. The detailed demagnetisation behaviour of such<br />

materials will depend on the type and the strength of the magnetic interaction between the<br />

small grains. The magnetisation process of a certain class of fine-grained magnets will be<br />

discussed in Section 3.3 and Chapter 8.<br />

The pinning mechanism is typical of materials with pronounced nanoscale<br />

inhomogeneities. The effectiveness of the pinning will depend on the geometry and spatial<br />

distribution of the pinning centers, being necessary a sufficiently high density of such<br />

centers not uniformly distributed [28]. The pinning will be most pronounced when the size<br />

of the pinning centers is comparable to the domain wall width. In addition sharp<br />

boundaries may be very effective pinning centers. Sm 2 Co 17 -based magnets constitute a<br />

good example of this type of magnets where the pinning of the domain walls takes place in<br />

the SmCo 5 boundary phase [28,29].<br />

15

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