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8<br />

June 2010<br />

Instruments for Gas Analysis<br />

Michael P. Valoski, Chief,<br />

Toxic Agents Branch,<br />

MSHA, gave a presentation<br />

to the SME Annual Meeting<br />

entitled Instruments for Gas<br />

Analysis at Mine Fires/Explosions.<br />

Mine fires and explosions are<br />

horrible events that affect miners,<br />

mine operators, and the surrounding<br />

community see Figure 1. While<br />

these events still occur, they have<br />

become fairly uncommon events.<br />

Recent mine fires/explosions were<br />

at Sago, Alma No. 1, and Kentucky<br />

Darby. At these mines, nineteen<br />

miners died and mines permanently<br />

closed. MSHA monitors the situation<br />

via gas analysis to assist the<br />

District Manager in determining<br />

the appropriateness of the action<br />

being contemplated by the mine<br />

operator. MSHA wants to minimize<br />

unnecessary risks.<br />

Instruments can be detector<br />

tubes, handheld instruments,<br />

portable instruments, or gas chromatographs.<br />

All sampling must be<br />

conducted safely. For example, the<br />

instruments should be held in the<br />

exhaust air while the operator<br />

remains in fresh air. Also, samples<br />

should be collected as soon as<br />

possible so mine rescue teams will<br />

have information when they arrive<br />

at the mine.<br />

Detector tubes should be intrinsically<br />

safe, inexpensive, easy-touse,<br />

small size, and as accurate as<br />

possible, measuring one gas at a<br />

time, cross sensitivity, and may<br />

have limited shelf life. Only detector<br />

tubes that take one stroke<br />

should be used. Multiple stroke<br />

tubes take too long to determine<br />

the gas concentration. The exposure<br />

to the possible hazardous<br />

environment should be limited.<br />

Detector tube is shown in Figure 2<br />

and gases detected are shown in<br />

Figure 3.<br />

Handheld instruments can be<br />

accurate, small, fast response,<br />

alarm when in dangerous environment,<br />

require calibration gas, may<br />

Fig 1 Farmington 1968<br />

have a short sensor life, cross sensitivity,<br />

and the gases can destroy<br />

the sensor. These are carried by<br />

mine rescue teams and some can<br />

measure up to five gases. Some<br />

can store the measurements for<br />

time study. Handheld instruments<br />

are shown in Figure 4, and the<br />

gases measured are shown in<br />

Figure 5.<br />

Portable instruments can constantly<br />

sample the environment,<br />

have a wide dynamic range, are not<br />

intrinsically safe, can be large,<br />

require gas calibration, require an<br />

electric line, and require a pump to<br />

pull the sample to the sensor.<br />

MSHA carries these to the mines,<br />

can quickly collect a sample if a<br />

change in the gas level is seen.<br />

Portable instruments are shown in<br />

Figure 6 and the gases measured<br />

are shown in Figure 7.<br />

Gas chromatographs are stable,<br />

measure ten gases from one injection,<br />

require calibration gas, specific<br />

for gas, wide dynamic range,<br />

not intrinsically safe, require electric<br />

line, very expensive, and need<br />

trained operators. MSHA has a<br />

Mobile Gas Laboratory with gas<br />

chromatographs. There are many<br />

ways to configure the gas chromatograph<br />

to obtain gas levels.<br />

MSHA has gas chromatographs<br />

stationed in Denver, Colorado and<br />

Pittsburgh, Pennsylvania, as well<br />

as Mt. Hope, West Virginia. These<br />

must be constantly used because<br />

the retention times change. Few<br />

mines have gas chromatographs.<br />

Gas samples are collected in evacuated<br />

glass bottles, mylar, or tedlar<br />

bags, or plastic syringes. The gases<br />

measured are CO, CO2, O2, N2,<br />

AR, CH4, C2H6, and H2. A software<br />

suite allows the calculation of the<br />

important mine fire indices. Gas<br />

chromatograph s can be benchtop<br />

or portable. The benchtop are used<br />

for laboratory work, while the<br />

portable are able to travel. The<br />

portable type produces faster<br />

results, but the lower detection<br />

limit is poorer than the benchtop.<br />

The mobile gas laboratory is<br />

shown in Figure 8. Gas chromatographs<br />

are carried inside the<br />

lab. The lab is totally self sufficient.<br />

The benchtop gas chromatograph<br />

is shown in Figure 9. The micro gas<br />

chromatograph is shown in Figure<br />

10.<br />

The author concluded that gas<br />

chromatographs are essential and<br />

there is the need to obtain information<br />

using different types of instruments.<br />

Each instrument type has<br />

its uses. Detector tubes provide the<br />

least useful information and handheld<br />

instruments need to be used<br />

by Mine Rescue Teams.<br />

Fig 2 Detector Tube Fig 3 Gases Detected Fig 4 Handheld Instruments<br />

Fig 5 Gases Measured Fig 6 Portable Instruments Fig 7 Gases Measures with Portable Instruments<br />

Fig 8 Mobile Gas Laboratory Fig 9 Bench Top Gas Chromatograph Fig 10 Micro Gas Chromatograph

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