American Coal Concert Series Launched - Coal News
American Coal Concert Series Launched - Coal News
American Coal Concert Series Launched - Coal News
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
8<br />
June 2010<br />
Instruments for Gas Analysis<br />
Michael P. Valoski, Chief,<br />
Toxic Agents Branch,<br />
MSHA, gave a presentation<br />
to the SME Annual Meeting<br />
entitled Instruments for Gas<br />
Analysis at Mine Fires/Explosions.<br />
Mine fires and explosions are<br />
horrible events that affect miners,<br />
mine operators, and the surrounding<br />
community see Figure 1. While<br />
these events still occur, they have<br />
become fairly uncommon events.<br />
Recent mine fires/explosions were<br />
at Sago, Alma No. 1, and Kentucky<br />
Darby. At these mines, nineteen<br />
miners died and mines permanently<br />
closed. MSHA monitors the situation<br />
via gas analysis to assist the<br />
District Manager in determining<br />
the appropriateness of the action<br />
being contemplated by the mine<br />
operator. MSHA wants to minimize<br />
unnecessary risks.<br />
Instruments can be detector<br />
tubes, handheld instruments,<br />
portable instruments, or gas chromatographs.<br />
All sampling must be<br />
conducted safely. For example, the<br />
instruments should be held in the<br />
exhaust air while the operator<br />
remains in fresh air. Also, samples<br />
should be collected as soon as<br />
possible so mine rescue teams will<br />
have information when they arrive<br />
at the mine.<br />
Detector tubes should be intrinsically<br />
safe, inexpensive, easy-touse,<br />
small size, and as accurate as<br />
possible, measuring one gas at a<br />
time, cross sensitivity, and may<br />
have limited shelf life. Only detector<br />
tubes that take one stroke<br />
should be used. Multiple stroke<br />
tubes take too long to determine<br />
the gas concentration. The exposure<br />
to the possible hazardous<br />
environment should be limited.<br />
Detector tube is shown in Figure 2<br />
and gases detected are shown in<br />
Figure 3.<br />
Handheld instruments can be<br />
accurate, small, fast response,<br />
alarm when in dangerous environment,<br />
require calibration gas, may<br />
Fig 1 Farmington 1968<br />
have a short sensor life, cross sensitivity,<br />
and the gases can destroy<br />
the sensor. These are carried by<br />
mine rescue teams and some can<br />
measure up to five gases. Some<br />
can store the measurements for<br />
time study. Handheld instruments<br />
are shown in Figure 4, and the<br />
gases measured are shown in<br />
Figure 5.<br />
Portable instruments can constantly<br />
sample the environment,<br />
have a wide dynamic range, are not<br />
intrinsically safe, can be large,<br />
require gas calibration, require an<br />
electric line, and require a pump to<br />
pull the sample to the sensor.<br />
MSHA carries these to the mines,<br />
can quickly collect a sample if a<br />
change in the gas level is seen.<br />
Portable instruments are shown in<br />
Figure 6 and the gases measured<br />
are shown in Figure 7.<br />
Gas chromatographs are stable,<br />
measure ten gases from one injection,<br />
require calibration gas, specific<br />
for gas, wide dynamic range,<br />
not intrinsically safe, require electric<br />
line, very expensive, and need<br />
trained operators. MSHA has a<br />
Mobile Gas Laboratory with gas<br />
chromatographs. There are many<br />
ways to configure the gas chromatograph<br />
to obtain gas levels.<br />
MSHA has gas chromatographs<br />
stationed in Denver, Colorado and<br />
Pittsburgh, Pennsylvania, as well<br />
as Mt. Hope, West Virginia. These<br />
must be constantly used because<br />
the retention times change. Few<br />
mines have gas chromatographs.<br />
Gas samples are collected in evacuated<br />
glass bottles, mylar, or tedlar<br />
bags, or plastic syringes. The gases<br />
measured are CO, CO2, O2, N2,<br />
AR, CH4, C2H6, and H2. A software<br />
suite allows the calculation of the<br />
important mine fire indices. Gas<br />
chromatograph s can be benchtop<br />
or portable. The benchtop are used<br />
for laboratory work, while the<br />
portable are able to travel. The<br />
portable type produces faster<br />
results, but the lower detection<br />
limit is poorer than the benchtop.<br />
The mobile gas laboratory is<br />
shown in Figure 8. Gas chromatographs<br />
are carried inside the<br />
lab. The lab is totally self sufficient.<br />
The benchtop gas chromatograph<br />
is shown in Figure 9. The micro gas<br />
chromatograph is shown in Figure<br />
10.<br />
The author concluded that gas<br />
chromatographs are essential and<br />
there is the need to obtain information<br />
using different types of instruments.<br />
Each instrument type has<br />
its uses. Detector tubes provide the<br />
least useful information and handheld<br />
instruments need to be used<br />
by Mine Rescue Teams.<br />
Fig 2 Detector Tube Fig 3 Gases Detected Fig 4 Handheld Instruments<br />
Fig 5 Gases Measured Fig 6 Portable Instruments Fig 7 Gases Measures with Portable Instruments<br />
Fig 8 Mobile Gas Laboratory Fig 9 Bench Top Gas Chromatograph Fig 10 Micro Gas Chromatograph