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Hydrates and Glycols - NTNU

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Hydrate equilibrium curve<br />

200<br />

What have we learned?<br />

HYDRATES<br />

Pressure (bar)<br />

180<br />

160<br />

140<br />

120<br />

100<br />

80<br />

Hydrats can form<br />

Equilbrium curve<br />

40<br />

•<strong>Hydrates</strong><br />

20<br />

–An ice/snow like solid<br />

0<br />

–Forms at low temperature <strong>and</strong> high pressure<br />

• Need water (liquid or solid) + small molecules (e.g. CH 4 , C 2 H 6 )<br />

–Reversible reaction<br />

• i.e. can be removed by de-pressurization or heating<br />

•Hydrate formation can be inhibited by:<br />

–Anything that dilutes water i.e. is mixable with water<br />

• Salt<br />

• Alcohol<br />

–Works because water molecules are separated<br />

60<br />

Hydrats can NOT form<br />

0 5 10 15 20 25<br />

Temperature (°C)<br />

•MEG<br />

–Denotes Mono Ethylene Glycol<br />

• Is an alcohol<br />

–Used as antifreeze agent in cars<br />

–Much used as hydrate inhibitor in oil industry<br />

• Methanol <strong>and</strong> ethanol are other much used chemicals<br />

Classification: Internal 2010-08-25

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