Damage Mechanisms Affecting Fixed Equipment in the Refining Industry
API ICP Self Study Notes
API ICP Self Study Notes
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<strong>Damage</strong> <strong>Mechanisms</strong> <strong>Affect<strong>in</strong>g</strong><br />
<strong>Fixed</strong> <strong>Equipment</strong> <strong>in</strong> <strong>the</strong><br />
Ref<strong>in</strong><strong>in</strong>g <strong>Industry</strong><br />
影 响 炼 油 行 业 固 定 设 备 的<br />
损 伤 机 理<br />
2013 年 内 部 培 训
Charlie Chong/ Fion Zhang<br />
中 国 固 有 领 土 : 钓 鱼 岛
印 度 支 那 不 就 是 “Indo-Ch<strong>in</strong>a” 吗 ?, 中 华 人 民 共 和 国 不 就 是 “People Republic of Ch<strong>in</strong>a”. 这 “Ch<strong>in</strong>a” 或<br />
“ 支 那 ” 不 是 歧 视 字 眼 .“ 支 那 ” 是 个 威 震 四 方 的 大 国 , 以 前 郑 和 下 西 洋 的 “ 支 那 “ 这 是 闻 之 丧 胆 字 眼 , 现 在<br />
我 们 也 不 渐 渐 变 成 ” 强 大 支 那 ” 了 吗 ?. 小 的 时 候 (40 年 前 ), 友 族 , 善 意 的 叫 我 “ 中 华 人 ”, 我 很 善 意 的 告 诉<br />
他 , 我 叫 “ 支 那 人 ”, 虽 然 我 只 是 东 南 亚 华 裔 , 但 我 永 远 以 “ 支 那 -Ch<strong>in</strong>a" 引 以 为 荣 . 我 爱 中 国 , 我 爱 "Ch<strong>in</strong>a"<br />
我 爱 " 支 那 ".<br />
http://news.ifeng.com/world/detail_2014_03/20/34944726_0.shtml<br />
中 国 固 有 领 土 : 钓 鱼 岛<br />
Charlie Chong/ Fion Zhang
影 响 炼 油 行 业 固 定 设 备 的<br />
损 伤 机 理 -2013 年 内 部 培 训<br />
http://www.smt.sandvik.com/en/search/?q=stress+corrosion+crack<strong>in</strong>g
Speaker: Fion Zhang<br />
2013/7/4
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For API 510 ICP - API RP 571, <strong>Damage</strong> mechanisms <strong>Affect<strong>in</strong>g</strong> <strong>Fixed</strong><br />
equipment <strong>in</strong> <strong>the</strong> Ref<strong>in</strong><strong>in</strong>g <strong>Industry</strong> ATTN: Exam<strong>in</strong>ation questions will be based on<br />
<strong>the</strong> follow<strong>in</strong>g sections only:<br />
Par. 3. – Def<strong>in</strong>itions (<strong>in</strong>cluded as a frame of reference only)<br />
4.2.3 – Temper Embrittlement<br />
4.2.7 – Brittle Fracture<br />
4.2.9 – Thermal Fatigue<br />
4.2.14 – Erosion/Erosion-Corrosion<br />
4.2.16 – Mechanical Failure<br />
4.3.2 – Atmospheric Corrosion<br />
4.3.3 – Corrosion Under Insulation (CUI)<br />
4.3.4 – Cool<strong>in</strong>g Water Corrosion<br />
4.3.5 – Boiler Water Condensate Corrosion<br />
4.3.10 – Caustic Corrosion<br />
4.4.2 – Sulfidation<br />
4.5.1 – Chloride Stress Corrosion Crack<strong>in</strong>g (Cl-SCC)<br />
4.5.2 – Corrosion Fatigue<br />
4.5.3 – Caustic Stress Corrosion Crack<strong>in</strong>g (Caustic Embrittlement)<br />
5.1.2.3 – Wet H2S <strong>Damage</strong> (Blister<strong>in</strong>g / HIC/ SOHIC/ SSC)<br />
5.1.3.1 – High Temperature Hydrogen Attack (HTHA)
For API 570 ICP - API RP 571, <strong>Damage</strong> mechanisms <strong>Affect<strong>in</strong>g</strong> <strong>Fixed</strong><br />
equipment <strong>in</strong> <strong>the</strong> Ref<strong>in</strong><strong>in</strong>g <strong>Industry</strong> ATTN: Exam<strong>in</strong>ation questions will be based on<br />
<strong>the</strong> follow<strong>in</strong>g sections only:<br />
Par. 3 – Def<strong>in</strong>itions (<strong>in</strong>cluded as a frame of reference only)<br />
4.2.7 – Brittle Fracture<br />
4.2.9 – Thermal Fatigue<br />
4.2.14 – Erosion/Erosion Corrosion<br />
4.2.16 – Mechanical Fatigue<br />
4.2.17 – Vibration-Induced Fatigue<br />
4.3.1 – Galvanic Corrosion<br />
4.3.2 – Atmospheric Corrosion<br />
4.3.3 – Corrosion Under Insulation (CUI)<br />
4.3.5 – Boiler Water Condensate Corrosion<br />
4.3.7 – Flue Gas Dew Po<strong>in</strong>t Corrosion<br />
4.3.8 – Microbiological Induced Corrosion (MIC)<br />
4.3.9 – Soil Corrosion<br />
4.4.2 – Sulfidation<br />
4.5.1 – Chloride Stress Corrosion Crack<strong>in</strong>g (Cl-SCC)<br />
4.5.3 – Caustic Stress corrosion Crack<strong>in</strong>g (Caustic Embrittlement)<br />
5.1.3.1 – High Temperature Hydrogen Attack (HTTA)
BODY OF KNOWLEDGE<br />
API-510 PRESSURE VESSEL INSPECTOR<br />
CERTIFICATION EXAMINATION<br />
August 2010 (Replaces January 2009)
API RP 571, <strong>Damage</strong> <strong>Mechanisms</strong> <strong>Affect<strong>in</strong>g</strong> <strong>Fixed</strong> equipment <strong>in</strong> <strong>the</strong> Ref<strong>in</strong><strong>in</strong>g <strong>Industry</strong><br />
ATTN: API 510 Test questions will be based on <strong>the</strong> follow<strong>in</strong>g mechanisms only:<br />
Par. 3. - Def<strong>in</strong>itions (<strong>in</strong>cluded as a frame of reference only)<br />
1. 4.2.3 – Temper Embrittlement<br />
2. 4.2.7 – Brittle Fracture<br />
3. 4.2.9 – Thermal Fatigue<br />
4. 4.2.14 – Erosion/Erosion-Corrosion<br />
5. 4.2.16 – Mechanical Failure<br />
6. 4.3.2 – Atmospheric Corrosion<br />
7. 4.3.3 – Corrosion Under Insulation (CUI)<br />
8. 4.3.4 – Cool<strong>in</strong>g Water Corrosion<br />
9. 4.3.5 – Boiler Water Condensate Corrosion<br />
10. 4.3.10 – Caustic Corrosion<br />
11. 4.4.2 – Sulfidation<br />
12. 4.5.1 – Chloride Stress Corrosion Crack<strong>in</strong>g (Cl-SCC)<br />
13. 4.5.2 – Corrosion Fatigue<br />
14. 4.5.3 – Caustic Stress Corrosion Crack<strong>in</strong>g (Caustic Embrittlement)<br />
15. 5.1.2.3 – Wet H2S <strong>Damage</strong> (Blister<strong>in</strong>g/HIC/SOHIC/SCC)<br />
16. 5.1.3.1 – High Temperature Hydrogen Attack (HTHA)
BODY OF KNOWLEDGE<br />
API-570 AUTHORIZED PIPING INSPECTOR<br />
CERTIFICATION EXAMINATION<br />
August 2010 (Replaces June 2007)
API RP 571, <strong>Damage</strong> mechanisms <strong>Affect<strong>in</strong>g</strong> <strong>Fixed</strong> equipment <strong>in</strong> <strong>the</strong> Ref<strong>in</strong><strong>in</strong>g <strong>Industry</strong><br />
ATTN: API 570 Exam<strong>in</strong>ation questions will be based on <strong>the</strong> follow<strong>in</strong>g sections only:<br />
Par. 3 – Def<strong>in</strong>itions (<strong>in</strong>cluded as a frame of reference only)<br />
1. 4.2.7 – Brittle Fracture<br />
2. 4.2.9 – Thermal Fatigue<br />
3. 4.2.14 – Erosion/Erosion Corrosion<br />
4. 4.2.16 – Mechanical Fatigue<br />
5. 4.2.17 – Vibration-Induced Fatigue<br />
6. 4.3.1 – Galvanic Corrosion<br />
7. 4.3.2 – Atmospheric Corrosion<br />
8. 4.3.3 – Corrosion Under Insulation (CUI)<br />
9. 4.3.5 – Boiler Water Condensate Corrosion<br />
10. 4.3.7 – Flue Gas Dew Po<strong>in</strong>t Corrosion<br />
11. 4.3.8 – Microbiological Induced Corrosion (MIC)<br />
12. 4.3.9 – Soil Corrosion<br />
13. 4.4.2 – Sulfidation<br />
14. 4.5.1 – Chloride Stress Corrosion Crack<strong>in</strong>g (Cl-SCC)<br />
15. 4.5.3 – Caustic Stress corrosion Crack<strong>in</strong>g (Caustic Embrittlement)
2013- API570 Exam<strong>in</strong>ation<br />
Par. 3 – Def<strong>in</strong>itions<br />
4.2.7 – Brittle Fracture<br />
4.2.9 – Thermal Fatigue<br />
4.2.14 – Erosion/Erosion Corrosion<br />
4.2.16 – Mechanical Fatigue<br />
4.2.17 – Vibration-Induced Fatigue<br />
4.3.1 – Galvanic Corrosion<br />
4.3.2 – Atmospheric Corrosion<br />
4.3.3 – Corrosion Under Insulation (CUI)<br />
4.3.5 – Boiler Water Condensate Corrosion<br />
4.3.7 – Flue Gas Dew Po<strong>in</strong>t Corrosion<br />
4.3.8 – Microbiological Induced Corrosion (MIC)<br />
4.3.9 – Soil Corrosion<br />
4.4.2 – Sulfidation<br />
4.5.1 – Chloride Stress Corrosion Crack<strong>in</strong>g (Cl-SCC)<br />
4.5.3 – Caustic Stress corrosion Crack<strong>in</strong>g<br />
5.1.3.1 – High Temperature Hydrogen Attack (HTTA)<br />
2013-API510 Exam<strong>in</strong>ation<br />
Par. 3. - Def<strong>in</strong>itions<br />
4.2.3 – Temper Embrittlement<br />
4.2.7 – Brittle Fracture<br />
4.2.9 – Thermal Fatigue<br />
4.2.14 – Erosion/Erosion-Corrosion<br />
4.2.16 – Mechanical Failure<br />
4.3.2 – Atmospheric Corrosion<br />
4.3.3 – Corrosion Under Insulation (CUI)<br />
4.3.4 – Cool<strong>in</strong>g Water Corrosion<br />
4.3.5 – Boiler Water Condensate Corrosion<br />
4.3.10 – Caustic Corrosion<br />
4.4.2 – Sulfidation<br />
4.5.1 – Chloride Stress Corrosion Crack<strong>in</strong>g (Cl-SCC)<br />
4.5.2 – Corrosion Fatigue<br />
4.5.3 – Caustic Stress Corrosion Crack<strong>in</strong>g<br />
5.1.2.3 – Wet H2S <strong>Damage</strong> (Blister/HIC/SOHIC/SCC)<br />
5.1.3.1 – High Temperature Hydrogen Attack (HTHA)
Mechanical and Metallurgical Failure <strong>Mechanisms</strong><br />
机 械 和 冶 金 失 效 机 理<br />
Graphitisation 石 墨 化<br />
800 o F for C Steel<br />
Pla<strong>in</strong> carbon steel<br />
875 o F for C ½ Mo Steel<br />
C- ½ Mo<br />
Spheroidisation 碳 化 物 球 状<br />
850 o F ~ 1400 o F<br />
Low alloy steel up to 9% Cr<br />
API510<br />
Tempered Embrittlement<br />
650 o F~ 1070 o F<br />
2 ¼ Cr-1Mo low alloy steel, 3Cr-<br />
回 火 脆 性<br />
1Mo (lesser extent), & HSLA Cr-<br />
Mo-V rotor steels<br />
Stra<strong>in</strong> Ag<strong>in</strong>g 延 伸 时 效<br />
Intermediate temperature<br />
Pre-1980’s C-steels with a large<br />
gra<strong>in</strong> size and C- ½ Mo<br />
885 o F embrittlement 脆 性<br />
600 o F~ 1000 o F<br />
300, 400 & Duplex SS conta<strong>in</strong><strong>in</strong>g<br />
ferrite phases<br />
Sigma-Phase<br />
1000 o F~ 1700 o F<br />
300, 400 & Duplex SS conta<strong>in</strong><strong>in</strong>g<br />
Embrittlement<br />
ferrite phases<br />
σ 相 脆 化<br />
API510<br />
Brittle Fracture<br />
Below DTBTT<br />
C, C- ½ Mo, 400 SS
Creep & stress rupture<br />
700 o F ~ 1000 o F<br />
All metals and alloys<br />
蠕 变 和 应 力 断 裂<br />
API510<br />
Thermal fatigues<br />
Operat<strong>in</strong>g temperature<br />
All materials of construction<br />
Short Term Overheat<strong>in</strong>g –<br />
>1000 o F<br />
All fired heater tube materials and<br />
Stress Rupture<br />
common materials of construction<br />
短 期 过 热 – 应 力 破 裂<br />
Steam Blanket<strong>in</strong>g 蒸 汽 遮 盖<br />
>1000 o F<br />
Carbon steel and low alloy steels<br />
Dissimilar Metal Weld (DMW)<br />
Operat<strong>in</strong>g temperature<br />
Carbon steel / 300 SS junction<br />
Crack<strong>in</strong>g<br />
Thermal Shock 温 度 突 然 变<br />
Cold liquid imp<strong>in</strong>ge on hot<br />
All metals and alloys.<br />
surface<br />
Flue-gas dew-po<strong>in</strong>t<br />
H 2<br />
SO 4<br />
-280 o F (138 o C),<br />
CS, low alloy and 300 SS<br />
corrosion<br />
HCL-130 o F (54 o C).<br />
CUI<br />
10 o F (–12 0 C) and 350 o F<br />
C-Steel and low alloy steel<br />
(175 o C)<br />
140 o F (60 o C) and 400 o F<br />
austenitic sta<strong>in</strong>less steels and<br />
(205 o C)<br />
duplex sta<strong>in</strong>less steels
High Temperature Corrosion [>400 o F (204 o C)]<br />
Oxidation<br />
CS - >1000 o F (538 o C)<br />
All metals and alloys<br />
氧 化<br />
300SS- >1500 o F (816 o C).<br />
API510<br />
Sulfidation<br />
Iron based alloy 500 o F (260 o C).<br />
All metals and alloys<br />
硫 腐 蚀<br />
O<strong>the</strong>rs ?<br />
Carburization<br />
>1100 o F (593 o C)<br />
All metals and alloys<br />
渗 碳<br />
Decarburization<br />
?<br />
CS and low alloy steel<br />
脱 碳<br />
Metal dust<strong>in</strong>g<br />
900 o F ~1500 o F(482 o C~ 816 o C)<br />
All metals and alloys<br />
金 属 尘 化<br />
Fuel ash corrosion<br />
> 700 o F(371 o C), varies with melt<strong>in</strong>g<br />
All metals and alloys<br />
燃 料 灰 腐 蚀<br />
po<strong>in</strong>t of salts formed.<br />
Nitrid<strong>in</strong>g<br />
>600 o F (316 o C)<br />
Carbon steels, low alloy steels, 300<br />
渗 氮<br />
Series SS and 400 Series SS
今 日 课 程 :<br />
0900~1130hrs<br />
第 一 篇 : 第 一 章 至 第 三 章 - 大 纲 与 定 义<br />
第 二 篇 : 第 四 章 - 一 般 损 伤 机 制 - 所 有 行 业<br />
1300~1700hrs<br />
第 三 篇 : 第 五 章 - 炼 油 行 业 损 坏 机 理<br />
第 四 篇 : Q&A 问 与 答
FOREWORD 前 言<br />
The overall purpose of this document is to present <strong>in</strong>formation<br />
on equipment damage mechanisms <strong>in</strong> a set format to assist <strong>the</strong><br />
reader <strong>in</strong> apply<strong>in</strong>g <strong>the</strong> <strong>in</strong>formation <strong>in</strong> <strong>the</strong> <strong>in</strong>spection and<br />
assessment of equipment from a safety and reliability standpo<strong>in</strong>t.<br />
本 文 件 的 总 体 目 标<br />
从 安 全 性 和 可 靠 性 的 角 度 , 用 预 设 的 文 件 格 式 , 提 供 设 备 损 坏 机 理<br />
信 息 , 以 协 助 读 者 应 用 此 信 息 协 助 设 备 的 (1) 检 查 和 (2) 评 估 .
这 份 文 件 反 映 了 行 业 信 息 , 但 它 不 是 一 个 强 制 性 的 标 准 或 规 范 . 这 作 业 指 导<br />
“Recommended practice 571” 是 作 为 API 检 验 规 范 如 API 510, API 570,<br />
API 653 和 执 行 基 于 风 险 的 检 验 API 580/API 581 提 供 有 用 的 信 息<br />
本 出 版 物 中 包 含 的 综 合 指 导 , 考 虑 的 事 项 有 :<br />
• 可 能 会 影 响 工 艺 设 备 的 损 伤 机 理 实 用 信 息 ,<br />
• 设 备 上 , 有 关 可 以 预 测 到 的 损 伤 类 型 和 损 害 程 度 ,<br />
• 如 何 从 这 些 知 识 帮 助 选 择 正 确 的 选 择 检 验 方 法 来<br />
发 现 / 鉴 定 与 检 测 尺 寸 .
This publication conta<strong>in</strong>s guidance for <strong>the</strong> comb<strong>in</strong>ed considerations of:<br />
• Practical <strong>in</strong>formation on damage mechanisms that can affect<br />
process equipment, 影 响 设 备 损 坏 机 理 的 实 用 信 息 ,<br />
• Assistance regard<strong>in</strong>g <strong>the</strong> type and extent of damage that can be<br />
expected, and 协 助 确 定 设 备 潜 在 的 损 伤 类 别 与 损 伤 程 度 ,<br />
• How this knowledge can be applied to <strong>the</strong> selection of effective<br />
<strong>in</strong>spection methods to detect size and characterize damage.<br />
通 过 上 述 的 知 识 确 定 如 何 选 用 真 确 的 探 测 方 法 来 对 损 伤 定 型 与 定 量 .
值 得 留 意 的 是 此 文 件 API571 没 提 到 : 材 料 选 择 作 为 损 坏 机 理 的 防 范 . 同 样<br />
的 是 , 在 ASME B31.3 300(6) Compatibility of materials with <strong>the</strong> service<br />
and hazards from <strong>in</strong>stability of conta<strong>in</strong>ed fluids are not with<strong>in</strong> <strong>the</strong> scope<br />
of this Code. See para. F323. 材 料 的 兼 容 性 对 因 所 含 流 体 ( 媒 介 ) 不 稳 定 造<br />
成 的 危 害 , 不 在 本 规 范 范 围 内 .
Table of contents 目 录<br />
1.0 Introduction and scope 简 介 及 范 围<br />
2.0 References 参 考<br />
3.0 Def<strong>in</strong>ition of terms and abbreviations<br />
定 义 , 术 语 和 缩 略 语<br />
4.0 General damage mechanisms – all <strong>in</strong>dustries<br />
一 般 损 伤 机 制 - 所 有 行 业<br />
5.0 Ref<strong>in</strong><strong>in</strong>g <strong>in</strong>dustry damage mechanisms<br />
炼 油 行 业 损 坏 机 理<br />
Appendix a – technical <strong>in</strong>quiries<br />
附 录 A - 技 术 咨 询
SECTION 1.0<br />
Introduction and scope<br />
简 介 及 范 围
1.1 Introduction 序 言<br />
ASME 和 API 加 压 设 备 的 设 计 规 范 和 标 准 - 提 供 设 计 , 制 造 , 检 验 和 测 试 “ 新 的 ” 压 力<br />
容 器 , 管 道 系 统 和 储 罐 的 规 则 . 这 些 规 范 不 解 决 设 备 在 服 务 期 间 设 备 的 老 化 , 腐 蚀 ,<br />
损 坏 等 的 考 虑 . 这 RP 主 要 针 对 在 役 设 备 上 述 信 息 .<br />
在 执 行 适 用 性 评 价 (FFS), 基 于 风 险 的 检 验 (RBI), 也 提 供 需 要 的 信 息 . 因 为 :<br />
• 进 行 FFS/ API RP 579- FFS 评 估 第 一 步 是 确 定 (1) 缺 陷 类 型 和 (2) 损 坏 的 原 因 .<br />
• 基 于 风 险 的 检 验 (RBI) 第 一 个 步 骤 也 是 正 确 的 识 别 系 统 设 备 损 伤 机 理 或 其 他 形<br />
式 的 恶 化 原 因 .
当 进 行 FFS/RBI 评 估 时 也 作 为 重 点 :<br />
• 观 察 到 的 或 预 测 的 损 坏 的 原 因<br />
• 未 来 进 一 步 损 坏 的 可 能 性 和 损 坏 程 度<br />
化 工 设 施 的 材 料 / 环 境 条 件 相 互 作 用 非 常 多 样 化 . 许 多 不 同 的 处 理 单 元 各 有 其<br />
自 身 的 进 取 过 程 , 媒 介 组 合 , 不 同 的 温 度 / 压 力 条 件 这 些 不 确 定 因 素 带 给 FFS/RBI<br />
评 估 带 来 一 些 难 度 .
当 设 备 观 察 到 的 缺 陷 时 , 这 缺 陷 可 能 是 :<br />
• 使 用 前 新 建 造 , 本 来 缺 陷 ,<br />
• 在 职 服 务 导 致 的 后 来 缺 陷 .<br />
在 役 服 务 导 致 的 后 来 缺 陷 原 因 有 :<br />
• 设 计 不 足 的 因 素 -( 包 括 材 料 的 选 择 和 缺 乏 设 计 详 细 考 虑 )<br />
• 设 备 运 行 中 的 腐 蚀 性 的 环 境 / 条 件 引 起 -( 正 常 的 服 务 或 瞬 态 期 间 )
In general, <strong>the</strong> follow<strong>in</strong>g types of damage are encountered <strong>in</strong><br />
petrochemical equipment: 化 工 设 备 一 般 损 伤 类 型<br />
1. General and local metal loss due to corrosion and/or erosion,<br />
由 于 腐 蚀 和 / 或 侵 蚀 均 匀 与 局 部 金 属 减 薄<br />
2. Surface connected crack<strong>in</strong>g, 表 面 连 接 开 裂<br />
3. Subsurface crack<strong>in</strong>g, 内 表 面 开 裂<br />
4. Microfissur<strong>in</strong>g/microvoid formation, 微 裂 纹 / 微 孔 形 成<br />
5. Metallurgical changes. 金 相 变 化
基 于 外 观 或 形 态 , 损 伤 分 类
SECTION 4.0<br />
GENERAL DAMAGE MECHANISMS – ALL INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业<br />
4.2 Mechanical and Metallurgical Failure <strong>Mechanisms</strong>. 机 械 和 冶 金 失 效 机 制<br />
4.3 Uniform or Localized Loss of Thickness. 均 衡 或 局 部 厚 度 亏 损<br />
4.4 High Temperature Corrosion [400°F (204°C)]. 高 温 腐 蚀<br />
4.5 Environment Assisted Crack<strong>in</strong>g. 环 境 辅 助 开 裂<br />
SECTION 5.0<br />
REFINING INDUSTRY DAMAGE MECHANISMS<br />
炼 油 工 业 的 损 伤 机 制<br />
5.1.1 Uniform or Localized Loss <strong>in</strong> Thickness Phenomena<br />
均 匀 或 局 部 现 象 损 失 厚 度<br />
5.1.2 Environment-Assisted Crack<strong>in</strong>g 环 境 辅 助 开 裂<br />
基 于 引 发 因 素 , 损 伤 分 类
General and local metal loss/ 均 匀 与 局 部 减 薄
General and local metal loss/<br />
均 匀 与 局 部 减 薄
General and local metal loss/ 均 匀 与 局 部 减 薄
General and local metal loss/ 均 匀 与 局 部 减 薄
General and local metal loss/ 均 匀 与 局 部 减 薄
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
Surface connected crack<strong>in</strong>g
SCC or fatigue cracks<br />
nucleate at stress<br />
concentration po<strong>in</strong>ts<br />
SCC cracks have<br />
highly branch<br />
Corrosion fatigue cracks<br />
have little branch<strong>in</strong>g<br />
Surface connected crack<strong>in</strong>g
subsurface crack<strong>in</strong>g
subsurface crack<strong>in</strong>g
subsurface crack<strong>in</strong>g
subsurface crack<strong>in</strong>g
subsurface crack<strong>in</strong>g
Microfissur<strong>in</strong>g/microvoid formation
Microfissur<strong>in</strong>g/microvoid formation<br />
http://www.aws.org/wj/supplement/WJ_1985_04_s91.pdf
Microfissur<strong>in</strong>g/microvoid formation<br />
http://www.aws.org/wj/supplement/WJ_1985_04_s91.pdf
Metallurgical changes
Metallurgical changes
Metallurgical changes
Metallurgical changes
Metallurgical changes
Each of <strong>the</strong>se general types of damage may be caused by a s<strong>in</strong>gle or<br />
multiple damage mechanisms. In addition, each of <strong>the</strong> damage<br />
mechanisms occurs under very specific comb<strong>in</strong>ations of materials,<br />
process environments, and operat<strong>in</strong>g conditions.<br />
每 个 损 伤 , 可 能 是 由 一 个 或 多 个 损 坏 机 理 造 成 . 每 一 个 损 伤 机 制 有 非 常 具<br />
体 的 (1) 材 料 (2) 过 程 环 境 和 (3) 操 作 条 件 , 的 组 合 下 发 生 .
1.2 Scope 范 围<br />
This recommended practice provides general guidance as to <strong>the</strong> most likely<br />
damage mechanisms affect<strong>in</strong>g common alloys used <strong>in</strong> <strong>the</strong> ref<strong>in</strong><strong>in</strong>g and<br />
petrochemical <strong>in</strong>dustry and is <strong>in</strong>tended to <strong>in</strong>troduce <strong>the</strong> concepts of service<strong>in</strong>duced<br />
deterioration and failure modes. These guidel<strong>in</strong>es provide<br />
<strong>in</strong>formation that can be utilized by plant <strong>in</strong>spection personnel to assist <strong>in</strong><br />
identify<strong>in</strong>g likely causes of damage; to assist with <strong>the</strong> development of<br />
<strong>in</strong>spection strategies; to help identify monitor<strong>in</strong>g programs to ensure<br />
equipment <strong>in</strong>tegrity. 此 规 范 对 石 油 化 工 行 业 常 用 材 料 在 役 损 蚀 与 失 效 最 可 能 的<br />
损 坏 机 理 一 般 指 导 . 协 助 检 验 人 员 识 别 可 能 导 致 伤 害 的 原 因 , 从 而 确 定 检 测 策 略 ,<br />
以 确 保 设 备 的 完 整 性 .<br />
The summary provided for each damage mechanism provides <strong>the</strong><br />
fundamental <strong>in</strong>formation required for an FFS assessment performed <strong>in</strong><br />
accordance with API 579-1/ASME FFS-1 or an RBI study performed <strong>in</strong><br />
accordance with API RP 580. 每 个 损 伤 机 理 的 总 结 作 为 提 供 RBI/FFS 评 估 所 需<br />
的 基 本 信 息 .
API571, 此 规 范 对 石 油 化 工 行 业 常 用 材 料 在 役 损 蚀 与 失 效 最 可<br />
能 的 损 坏 机 理 一 般 指 导 . 协 助 检 验 人 员 识 别 可 能 导 致 伤 害 的 原<br />
因 , 从 而 确 定 检 测 策 略 , 以 确 保 设 备 的 完 整 性 .
1.3 Organization and Use 格 式 和 使 用<br />
The <strong>in</strong>formation for each damage mechanism is provided <strong>in</strong> a set<br />
format as shown below. This recommended practice format facilitates<br />
use of <strong>the</strong> <strong>in</strong>formation <strong>in</strong> <strong>the</strong> development of <strong>in</strong>spection programs, FFS<br />
assessment and RBI applications.<br />
为 了 协 助 (1) 检 验 计 划 的 开 发 / (2) FFS 使 用 性 评 估 (3) RBI 基 于 风 险 分 析<br />
检 验 的 运 用 , 个 别 的 损 坏 机 理 的 信 息 提 供 的 格 式 如 下 :
a) Description of <strong>Damage</strong> – a basic description of <strong>the</strong> damage mechanism.<br />
损 伤 机 理 的 基 本 描 述<br />
b) Affected Materials – a list of <strong>the</strong> materials prone to <strong>the</strong> damage<br />
mechanism. 受 影 响 的 材 料<br />
c) Critical Factors – a list of factors that affect <strong>the</strong> damage mechanism (i.e.<br />
rate of damage). 破 坏 机 理 的 影 响 因 素 列 表<br />
d) Affected Units or <strong>Equipment</strong> – a list of <strong>the</strong> affected equipment and/or<br />
units where <strong>the</strong> damage mechanism commonly occurs is provided.<br />
受 影 响 的 单 元 或 设 备<br />
e) Appearance or Morphology of <strong>Damage</strong> – a description of <strong>the</strong> damage<br />
mechanism, with pictures <strong>in</strong> some cases, to assist with recognition of <strong>the</strong><br />
damage. 外 观 或 损 伤 形 态 学 .
f) Prevention / Mitigation – methods to prevent and/or mitigate<br />
damage. 预 防 / 缓 解<br />
g) Inspection and Monitor<strong>in</strong>g – recommendations for NDE for detect<strong>in</strong>g<br />
and siz<strong>in</strong>g <strong>the</strong> flaw types associated with <strong>the</strong> damage mechanism.<br />
检 查 和 监 测<br />
h) Related <strong>Mechanisms</strong> – a discussion of related damage mechanisms.<br />
相 关 的 损 伤 机 理 讨 论<br />
i) References – a list of references that provide background and o<strong>the</strong>r<br />
pert<strong>in</strong>ent <strong>in</strong>formation. 参 考 .
<strong>Damage</strong> mechanisms that are common to a variety of <strong>in</strong>dustries <strong>in</strong>clud<strong>in</strong>g<br />
ref<strong>in</strong><strong>in</strong>g and petrochemical, pulp and paper, and fossil utility are covered <strong>in</strong><br />
Section 4.0. 通 用 炼 油 化 工 , 纸 浆 和 纸 张 , 以 及 石 化 设 施 - 损 坏 机 理 信 息<br />
<strong>Damage</strong> mechanisms that are specific to <strong>the</strong> ref<strong>in</strong><strong>in</strong>g and petrochemical<br />
<strong>in</strong>dustries are covered <strong>in</strong> Section 5. 专 门 针 对 炼 油 和 石 化 工 业 - 损 坏 机 理 信 息<br />
In addition, process flow diagrams are provided <strong>in</strong> 5.2 to assist <strong>the</strong> user <strong>in</strong><br />
determ<strong>in</strong><strong>in</strong>g primary locations where some of <strong>the</strong> significant damage<br />
mechanisms are commonly found. 5.2 提 供 了 一 些 工 艺 流 程 图 主 要 的 单 元 常 见<br />
的 一 些 重 大 损 害 机 理 .
• 提 供 损 伤 机 理 作 为 定 性 定 量 的 信 息<br />
• 提 供 损 伤 机 理 作 为 FFS/RBI 评 估 有 用 的 信 息<br />
• 提 供 损 伤 机 理 作 为 API510/ 570/ 653 在 职 设 备 检 验 有 用 的 信 息<br />
• 损 伤 机 理 可 以 分 为 5 大 类 型<br />
• 设 备 损 伤 发 现 可 能 是 源 于 新 建 或 在 职 服 务 导 致 .
SECTION 2.0<br />
REFERENCES<br />
2.1 Standards<br />
2.2 O<strong>the</strong>r References
2.1 Standards<br />
API<br />
• API 530 Pressure Vessel Inspection Code<br />
• Std. 530 Calculation of Heater Tube Thickness <strong>in</strong> Petroleum Ref<strong>in</strong>eries<br />
• RP 579 Fitness-For-Service<br />
• Publ. 581 Risk-Based Inspection - Base Resource Document<br />
• Std. 660 Shell and Tube Heat Exchangers for General Ref<strong>in</strong>ery Service<br />
• RP 751 Safe Operation of Hydrofluoric Acid Alkylation Units<br />
• RP 932-B Design, Materials, Fabrication, Operation and Inspection<br />
Guidel<strong>in</strong>es for Corrosion Control <strong>in</strong> Hydroprocess<strong>in</strong>g Reactor Effluent Air<br />
Cooler (REAC) Systems<br />
• RP 934 Materials and Fabrication Requirements for 2-1/4 Cr-1Mo & 3Cr-<br />
1Mo Steel Heavy Wall Pressure Vessels for High Temperature, High<br />
Pressure Service<br />
• RP 941 Steels for Hydrogen Service at Elevated Temperatures and<br />
Pressures <strong>in</strong> Petroleum Ref<strong>in</strong>eries and Petrochemical Plants<br />
• RP 945 Avoid<strong>in</strong>g Environmental Crack<strong>in</strong>g <strong>in</strong> Am<strong>in</strong>e Units
ASM<br />
• Metals Handbook Volume 1, Properties and Selection: Iron, Steels, and<br />
High-Performance Alloys;<br />
• Volume 13, Corrosion <strong>in</strong> Petroleum Ref<strong>in</strong><strong>in</strong>g and Petrochemical Operations;<br />
• Volume 11, Failure Analysis and Prevention<br />
ASME<br />
• Boiler and Pressure Vessel Code Section III, Division I, Rules for<br />
Construction of Nuclear Power Plant Components; Section VIII, Division I,<br />
Pressure Vessels.<br />
ASTM<br />
• MNL41 Corrosion <strong>in</strong> <strong>the</strong> Petrochemical <strong>Industry</strong><br />
• STP1428 Thermo-mechanical Fatigue Behavior of Materials<br />
BSI<br />
• BSI 7910 Guidance on Methods for Assess<strong>in</strong>g <strong>the</strong> Acceptability of Flaws <strong>in</strong><br />
Fusion Welded Structures<br />
MPC<br />
• Report FS-26 Fitness-For Service Evaluation Procedures for Operat<strong>in</strong>g<br />
Pressure Vessels, Tanks and Pip<strong>in</strong>g <strong>in</strong> Ref<strong>in</strong>ery and Chemical Service
NACE<br />
• Std. MR 0103 Materials Resistant to Sulfide Stress Crack<strong>in</strong>g <strong>in</strong> Corrosive<br />
Petroleum Ref<strong>in</strong><strong>in</strong>g Environments”<br />
• RP 0169 Standard Recommended Practice: Control of External Corrosion on<br />
Underground or Submerged Metallic Pip<strong>in</strong>g Systems<br />
• RP 0170 Protection of Austenitic Sta<strong>in</strong>less Steels and O<strong>the</strong>r Austenitic Alloys from<br />
Polythionic Acid Stress Corrosion Crack<strong>in</strong>g dur<strong>in</strong>g Shutdown of Ref<strong>in</strong>ery<br />
<strong>Equipment</strong><br />
• RP 0198 The Control of Corrosion Under Thermal Insulation, and Fireproof<strong>in</strong>g – A<br />
Systems Approach<br />
• RP 0294 Design, Fabrication, and Inspection of Tanks for <strong>the</strong> Storage of<br />
Concentrated Sulfuric Acid and Oleum at Ambient Temperatures<br />
• RP 0296 Guidel<strong>in</strong>es for Detection, Repair and Mitigation of Crack<strong>in</strong>g of Exist<strong>in</strong>g<br />
Petroleum Ref<strong>in</strong>ery Pressure Vessels <strong>in</strong> Wet H 2<br />
S Environments<br />
• RP 0472 Methods and Controls to Prevent <strong>in</strong>-Service Environmental Crack<strong>in</strong>g of<br />
Carbon Steel Weldments <strong>in</strong> Corrosive Petroleum Ref<strong>in</strong><strong>in</strong>g Environments<br />
• Publ. 5A151 Materials of Construction for Handl<strong>in</strong>g Sulfuric Acid<br />
• Publ. 5A171 Materials for Receiv<strong>in</strong>g, Handl<strong>in</strong>g, and Stor<strong>in</strong>g Hydrofluoric Acid<br />
• Publ. 8X194 Materials and Fabrication
WRC<br />
• Bullet<strong>in</strong> 32 Graphitization of Steel <strong>in</strong> Petroleum Ref<strong>in</strong><strong>in</strong>g <strong>Equipment</strong> and<br />
<strong>the</strong> Effect of Graphitization of Steel on Stress-Rupture Properties<br />
• Bullet<strong>in</strong> 275 The Use of Quenched and Tempered 2-1/4Cr-1Mo Steel for<br />
Thick Wall Reactor Vessels <strong>in</strong> Petroleum Ref<strong>in</strong>ery Processes: An<br />
Interpretive Review of 25 Years of Research and Application<br />
• Bullet<strong>in</strong> 350 Design Criteria for Dissimilar Metal Welds<br />
• Bullet<strong>in</strong> 409 Fundamental Studies Of The Metallurgical Causes And<br />
Mitigation Of Reheat Crack<strong>in</strong>g In 1¼Cr-½Mo And 2¼Cr-1Mo Steels<br />
• Bullet<strong>in</strong> 418 The Effect of Crack Depth (a) and Crack-Depth to Width Ratio<br />
(a/W) on <strong>the</strong> Fracture Toughness of A533-B Steel<br />
• Bullet<strong>in</strong> 452 Recommended Practices for Local Heat<strong>in</strong>g of Welds <strong>in</strong><br />
Pressure Vessels
2.2 O<strong>the</strong>r References<br />
A list of publications that offer background and o<strong>the</strong>r <strong>in</strong>formation pert<strong>in</strong>ent<br />
to <strong>the</strong> damage mechanism is provided <strong>in</strong> <strong>the</strong> section cover<strong>in</strong>g each<br />
damage mechanism.
SECTION 3.0<br />
DEFINITION OF TERMS AND<br />
ABBREVIATIONS<br />
3.1 Terms<br />
3.2 Symbols and Abbreviations
3.1 Terms<br />
3.1.1 Austenitic 奥 氏 体 – a term that refers to a type of metallurgical structure<br />
(austenite) normally found <strong>in</strong> 300 Series sta<strong>in</strong>less steels and nickel base alloys.<br />
3.1.2 Austenitic sta<strong>in</strong>less steels 奥 氏 体 系 不 锈 钢 – <strong>the</strong> 300 Series sta<strong>in</strong>less steels<br />
<strong>in</strong>clud<strong>in</strong>g Types 304, 304L, 304H, 309, 310, 316, 316L, 316H, 321, 321H, 347,<br />
and 347H. The “L” and “H” suffixes refer to controlled ranges of low and high<br />
carbon content, respectively. These alloys are characterized by an austenitic<br />
structure.<br />
3.1.3 Carbon steel 碳 素 钢 – steels that do not have alloy<strong>in</strong>g elements <strong>in</strong>tentionally<br />
added. However, <strong>the</strong>re may be small amounts of elements permitted by<br />
specifications such as SA516 and SA106, for example that can affect corrosion<br />
resistance, hardness after weld<strong>in</strong>g, and toughness. Elements which may be found<br />
<strong>in</strong> small quantities <strong>in</strong>clude Cr, Ni, Mo, Cu, S, Si, P, Al, V and B.
3.1.4 Di-ethanolam<strong>in</strong>e 二 乙 醇 胺 (DEA) – used <strong>in</strong> am<strong>in</strong>e treat<strong>in</strong>g to remove<br />
H2S and CO2 from hydrocarbon streams.<br />
3.1.5 Duplex sta<strong>in</strong>less steel 双 相 不 锈 钢 – a family of sta<strong>in</strong>less steels that conta<strong>in</strong><br />
a mixed austenitic-ferritic structure <strong>in</strong>clud<strong>in</strong>g Alloy 2205, 2304, and 2507. The<br />
welds of 300 series sta<strong>in</strong>less steels may also exhibit a duplex structure.<br />
3.1.6 Ferritic 铁 素 体 – a term that refers to a type of metallurgical structure<br />
(ferrite) normally found <strong>in</strong> carbon and low alloy steels and many 400 series<br />
sta<strong>in</strong>less steels.<br />
3.1.7 Ferritic sta<strong>in</strong>less steels 铁 素 体 不 锈 钢 – <strong>in</strong>clude Types 405, 409, 430, 442,<br />
and 446.<br />
3.1.8 Heat Affected Zone (HAZ) – <strong>the</strong> portion of <strong>the</strong> base metal adjacent to a<br />
weld which has not been melted, but whose metallurgical microstructure and<br />
mechanical properties have been changed by <strong>the</strong> heat of weld<strong>in</strong>g, sometimes<br />
with undesirable effects.
Add Nickel<br />
Add Nickel<br />
0% Nickel-Ferrite<br />
铁 素 体<br />
5% Nickel-Duplex<br />
双 相 ( 铁 素 / 奥 氏 体 )<br />
>8% Nickel-Austenite<br />
奥 氏 体
The 1949 Schaeffler diagram
The 1949 Schaeffler diagram
The 1949 Schaeffler diagram
http://www.<strong>in</strong>techopen.com/books/environmental-and-<strong>in</strong>dustrial-corrosion-practical-and-<strong>the</strong>oreticalaspects/corrosion-behaviour-of-cold-deformed-austenitic-alloys
3.1.9 Hydrogen Induced Crack<strong>in</strong>g (HIC) 氢 致 开 裂 – describes stepwise <strong>in</strong>ternal<br />
cracks that connect adjacent hydrogen blisters on different planes <strong>in</strong> <strong>the</strong> metal, or<br />
to <strong>the</strong> metal surface. No externally applied stress is needed for <strong>the</strong> formation of<br />
HIC. The development of <strong>in</strong>ternal cracks (sometimes referred to as blister cracks)<br />
tends to l<strong>in</strong>k with o<strong>the</strong>r cracks by a transgranular plastic shear mechanism<br />
because of <strong>in</strong>ternal pressure result<strong>in</strong>g from <strong>the</strong> accumulation of hydrogen. The<br />
l<strong>in</strong>k-up of <strong>the</strong>se cracks on different planes <strong>in</strong> steels has been referred to as<br />
stepwise crack<strong>in</strong>g to characterize <strong>the</strong> nature of <strong>the</strong> crack appearance.<br />
3.1.10 Low alloy steel 低 合 金 结 构 钢 – a family of steels conta<strong>in</strong><strong>in</strong>g up to 9%<br />
chromium and o<strong>the</strong>r alloy<strong>in</strong>g additions for high temperature strength and creep<br />
resistance. The materials <strong>in</strong>clude C-0.5Mo, Mn-0.5Mo, 1Cr-0.5Mo, 1.25 Cr-0.5Mo,<br />
2.25Cr-1.0Mo, 5Cr-0.5Mo, and 9Cr-1Mo. These are considered ferritic steels.
3.1.11 Martensitic 马 氏 体 – a term that refers to a type of metallurgical<br />
structure (martensite) normally found <strong>in</strong> some 400 series sta<strong>in</strong>less steel.<br />
Heat treatment and or weld<strong>in</strong>g followed by rapid cool<strong>in</strong>g<br />
can produce this structure <strong>in</strong> carbon and low alloy steels.
3.1.12 Martensitic sta<strong>in</strong>less steel – <strong>in</strong>clude Types 410, 410S, 416, 420, 440A,<br />
440B, and 440C.<br />
3.1.13 Methyldiethanolam<strong>in</strong>e (MDEA) – used <strong>in</strong> am<strong>in</strong>e treat<strong>in</strong>g to remove H 2 S<br />
and CO 2 from hydrocarbon streams.<br />
3.1.14 Monoethanolam<strong>in</strong>e (MEA) – used <strong>in</strong> am<strong>in</strong>e treat<strong>in</strong>g to remove H 2 S and<br />
CO 2 from hydrocarbon streams.<br />
3.1.15 Nickel base alloy– a family of alloys conta<strong>in</strong><strong>in</strong>g nickel as a major<br />
alloy<strong>in</strong>g element ( Ni>30% ) <strong>in</strong>clud<strong>in</strong>g Alloys 200, 400, K-500, 800, 800H, 825,<br />
600, 600H, 617, 625, 718, X-750, and C276.
3.1.16 Stress oriented hydrogen <strong>in</strong>duced crack<strong>in</strong>g (SOHIC) 应 力 导 向 氢 致 开 裂 –<br />
describes an array of cracks, aligned nearly perpendicular to <strong>the</strong> stress, that are<br />
formed by <strong>the</strong> l<strong>in</strong>k-up of small HIC cracks <strong>in</strong> steel. Tensile strength (residual or<br />
applied) is required to produce SOHIC. SOHIC is commonly observed <strong>in</strong> <strong>the</strong> base<br />
metal adjacent to <strong>the</strong> Heat Affected Zone (HAZ) of a weld, oriented <strong>in</strong> <strong>the</strong> throughthickness<br />
direction. SOHIC may also be produced <strong>in</strong> susceptible steels at o<strong>the</strong>r<br />
high stress po<strong>in</strong>ts, such as from <strong>the</strong> tip of <strong>the</strong> mechanical cracks and defects, or<br />
from <strong>the</strong> <strong>in</strong>teraction among HIC on different planes <strong>in</strong> <strong>the</strong> steel.<br />
3.1.17 Sta<strong>in</strong>less steel 不 锈 钢 – <strong>the</strong>re are four categories of sta<strong>in</strong>less steels that are<br />
characterized by <strong>the</strong>ir metallurgical structure at room temperature: austenitic,<br />
ferritic, martensitic and duplex. These alloys have vary<strong>in</strong>g amounts of chromium<br />
and o<strong>the</strong>r alloy<strong>in</strong>g elements that give <strong>the</strong>m resistance to oxidation, sulfidation and<br />
o<strong>the</strong>r forms of corrosion depend<strong>in</strong>g on <strong>the</strong> alloy content.
3.2 Symbols and Abbreviations<br />
3.2.1 ACFM – alternat<strong>in</strong>g current magnetic flux leakage test<strong>in</strong>g.<br />
3.2.2 AE – acoustic emission.<br />
3.2.3 AET – acoustic emission test<strong>in</strong>g.<br />
3.2.4 AGO – atmospheric gas oil.<br />
3.2.5 AUBT – automated ultrasonic backscatter test<strong>in</strong>g.<br />
3.2.6 BFW – boiler feed water.<br />
3.2.7 C 2<br />
– chemical symbol referr<strong>in</strong>g to ethane or ethylene.<br />
3.2.8 C 3<br />
– chemical symbol referr<strong>in</strong>g to propane or propylene.<br />
3.2.9 C 4<br />
– chemical symbol referr<strong>in</strong>g to butane or butylenes.<br />
3.2.10 Cat – catalyst or catalytic.<br />
3.2.11 CDU – crude distillation unit.<br />
3.2.12 CH 4<br />
– methane.<br />
3.2.13 CO – carbon monoxide.<br />
3.2.14 CO 2<br />
– carbon dioxide.<br />
3.2.15 CVN – charpy v-notch.
3.2.16 CW – cool<strong>in</strong>g water.<br />
3.2.17 DIB – deisobutanizer.<br />
3.2.18 DNB – Departure from Nucleate Boil<strong>in</strong>g.<br />
3.2.19 DEA – diethanolam<strong>in</strong>e, used <strong>in</strong> am<strong>in</strong>e treat<strong>in</strong>g to<br />
remove H 2<br />
S and CO 2<br />
from hydrocarbon streams.<br />
3.2.20 EC – eddy current, test method applies primarily to nonferromagnetic<br />
materials.<br />
3.2.21 FCC – fluid catalytic cracker.<br />
3.2.22 FMR – field metallographic replication.<br />
3.2.23 H 2<br />
– hydrogen.<br />
3.2.24 H 2<br />
O – also known as water.<br />
3.2.25 H 2<br />
S – hydrogen sulfide, a poisonous gas.<br />
3.2.26 HAZ – Heat Affected Zone<br />
3.2.27 HB – Br<strong>in</strong>nell hardness numbe<br />
3.2.28 HCO – heavy cycle oil.<br />
3.2.29 HCGO – heavy coker gas oil.<br />
3.2.30 HIC – Hydrogen Induced Crack<strong>in</strong>g<br />
571-3<br />
Charlie Chong/ Fion Zhang
3.2.31 HP – high pressure.<br />
3.2.32 HPS – high pressure separator.<br />
3.2.33 HVGO – heavy vacuum gas oil.<br />
3.2.34 HSLA – high strength low alloy.<br />
3.2.35 HSAS – heat stable am<strong>in</strong>e salts.<br />
3.2.36 IC4 – chemical symbol referr<strong>in</strong>g isobutane.<br />
3.2.37 IP – <strong>in</strong>termediate pressure.<br />
3.2.38 IRIS – <strong>in</strong>ternal rotat<strong>in</strong>g <strong>in</strong>spection system.<br />
3.2.39 K.O. – knock out, as <strong>in</strong> K.O. Drum.<br />
3.2.40 LCGO – light coker gas oil.<br />
3.2.41 LCO – light cycle oil.<br />
3.2.42 LP – low pressure.<br />
3.2.43 LPS – low pressure separator.<br />
3.2.44 LVGO – light vacuum gas oil.<br />
3.2.45 MDEA – methyldiethanolam<strong>in</strong>e.<br />
3.2.46 MEA – monoethanolam<strong>in</strong>e.<br />
3.2.47 mpy – mils per year.<br />
3.2.48 MT – magnetic particle test<strong>in</strong>g
3.2.49 NAC – naph<strong>the</strong>nic acid corrosion.<br />
3.2.50 NH 4<br />
HS – ammonium bisulfide.<br />
3.2.51 PMI – positive materials identification.<br />
3.2.52 PFD – process flow diagram.<br />
3.2.53 PT – liquid penetrant test<strong>in</strong>g.<br />
3.2.54 RFEC – remote field eddy current test<strong>in</strong>g.<br />
3.2.55 RT – radiographic test<strong>in</strong>g.<br />
3.2.56 SCC – stress corrosion crack<strong>in</strong>g.<br />
3.2.57 SOHIC – Stress Oriented Hydrogen Induced Crack<strong>in</strong>g<br />
3.2.58 SS: – Sta<strong>in</strong>less Steel.<br />
3.2.59 SW – sour water.<br />
3.2.60 SWS – sour water stripper.<br />
3.2.61 SWUT – shear wave ultrasonic test<strong>in</strong>g.<br />
3.2.62 Ti – titanium.<br />
3.2.63 UT – ultrasonic test<strong>in</strong>g.<br />
3.2.64 VDU – vacuum distillation unit.<br />
3.2.65 VT – visual <strong>in</strong>spection.<br />
3.2.66 WFMT – wet fluorescent magnetic particle test<strong>in</strong>g.
SECTION 4.0<br />
GENERAL DAMAGE<br />
MECHANISMS – ALL<br />
INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业
4.1 General 大 纲<br />
4.2 Mechanical and Metallurgical Failure <strong>Mechanisms</strong>. 机 械 和 冶 金 失 效 机 制<br />
4.3 Uniform or Localized Loss of Thickness. 均 衡 或 局 部 厚 度 亏 损<br />
4.4 High Temperature Corrosion [400°F (204°C)]. 高 温 腐 蚀<br />
4.5 Environment Assisted Crack<strong>in</strong>g. 环 境 辅 助 开 裂
GENERAL DAMAGE MECHANISMS – ALL INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE MECHANISMS<br />
– ALL INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE MECHANISMS – ALL<br />
INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE MECHANISMS – ALL INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业<br />
美 国 德 克 萨 斯 化 肥 厂 爆 炸 , 死 亡 人 数 攀 升 至 35 人
GENERAL DAMAGE MECHANISMS – ALL INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE MECHANISMS – ALL<br />
INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE<br />
MECHANISMS – ALL<br />
INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE<br />
MECHANISMS – ALL<br />
INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE<br />
MECHANISMS – ALL<br />
INDUSTRIES<br />
http://edition.cnn.com/2013/04/18/us/texas-explosion/<br />
一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE<br />
MECHANISMS – ALL<br />
INDUSTRIES<br />
一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE MECHANISMS – ALL<br />
INDUSTRIES 一 般 损 伤 机 制 - 所 有 行 业
GENERAL DAMAGE MECHANISMS – ALL<br />
INDUSTRIES 一 般 损 伤 机 制 - 所 有 行 业 .<br />
API 571 人 为 的 把 损 伤 机 理 分 类 为 4 种 作 为 学 习 ;<br />
1. 机 械 和 冶 金 失 效 机 理 ,<br />
2. 均 衡 或 局 部 厚 度 亏 损 .<br />
3. 高 温 腐 蚀 ,<br />
4. 环 境 辅 助 开 裂
4.2 Mechanical &<br />
Metallurgical Failure<br />
<strong>Mechanisms</strong><br />
机 械 和 冶 金 失 效 机 理
4.3 Uniform or Localized Loss of Thickness<br />
均 衡 或 局 部 厚 度 亏 损
4.4 High<br />
Temperature<br />
Corrosion 高 温 腐 蚀
4.5 Environment Assisted<br />
Crack<strong>in</strong>g 环 境 辅 助 开 裂
4.2 Mechanical &<br />
Metallurgical Failure<br />
<strong>Mechanisms</strong><br />
机 械 和 冶 金 失 效 机 制
4.2 Mechanical and Metallurgical Failure <strong>Mechanisms</strong><br />
4.2.1 Graphitization.<br />
4.2.2 Soften<strong>in</strong>g (Spheroidization).<br />
4.2.3 Temper Embrittlement.<br />
4.2.4 Stra<strong>in</strong> Ag<strong>in</strong>g.<br />
4.2.5 885°F (475°C) Embrittlement.<br />
4.2.6 Sigma Phase Embrittlement .<br />
4.2.7 Brittle Fracture.<br />
4.2.8 Creep and Stress Rupture.<br />
4.2.9 Thermal Fatigue .<br />
4.2.10 Short Term Overheat<strong>in</strong>g – Stress Rupture.<br />
4.2.11 Steam Blanket<strong>in</strong>g.<br />
4.2.12 Dissimilar Metal Weld (DMW) Crack<strong>in</strong>g.<br />
4.2.13 Thermal Shock.<br />
4.2.14 Erosion/Erosion – Corrosion.<br />
4.2.15 Cavitation.<br />
4.2.16 Mechanical Fatigue.<br />
4.2.17 Vibration-Induced Fatigue.<br />
4.2.18 Refractory Degradation.<br />
4.2.19 Reheat Crack<strong>in</strong>g.<br />
4.2.20 GOX-Enhanced Ignition & Combustion
2013- API570 Exam<strong>in</strong>ation<br />
Par. 3 – Def<strong>in</strong>itions<br />
4.2.7 – Brittle Fracture<br />
4.2.9 – Thermal Fatigue<br />
4.2.14 – Erosion/Erosion Corrosion<br />
4.2.16 – Mechanical Fatigue<br />
4.2.17 – Vibration-Induced Fatigue<br />
4.3.1 – Galvanic Corrosion<br />
4.3.2 – Atmospheric Corrosion<br />
4.3.3 – Corrosion Under Insulation (CUI)<br />
4.3.5 – Boiler Water Condensate Corrosion<br />
4.3.7 – Flue Gas Dew Po<strong>in</strong>t Corrosion<br />
4.3.8 – Microbiological Induced Corrosion (MIC)<br />
4.3.9 – Soil Corrosion<br />
4.4.2 – Sulfidation<br />
4.5.1 – Chloride Stress Corrosion Crack<strong>in</strong>g (Cl-SCC)<br />
4.5.3 – Caustic Stress corrosion Crack<strong>in</strong>g<br />
5.1.3.1 – High Temperature Hydrogen Attack (HTTA)<br />
2013-API510 Exam<strong>in</strong>ation<br />
Par. 3. - Def<strong>in</strong>itions<br />
4.2.3 – Temper Embrittlement<br />
4.2.7 – Brittle Fracture<br />
4.2.9 – Thermal Fatigue<br />
4.2.14 – Erosion/Erosion-Corrosion<br />
4.2.16 – Mechanical Failure<br />
4.3.2 – Atmospheric Corrosion<br />
4.3.3 – Corrosion Under Insulation (CUI)<br />
4.3.4 – Cool<strong>in</strong>g Water Corrosion<br />
4.3.5 – Boiler Water Condensate Corrosion<br />
4.3.10 – Caustic Corrosion<br />
4.4.2 – Sulfidation<br />
4.5.1 – Chloride Stress Corrosion Crack<strong>in</strong>g (Cl-SCC)<br />
4.5.2 – Corrosion Fatigue<br />
4.5.3 – Caustic Stress Corrosion Crack<strong>in</strong>g<br />
5.1.2.3 – Wet H2S <strong>Damage</strong> (Blister/HIC/SOHIC/SCC)<br />
5.1.3.1 – High Temperature Hydrogen Attack (HTHA)
Exam<br />
<strong>Damage</strong> Mechanism<br />
Temperatures<br />
Affected materials<br />
Graphitisation<br />
800°F~1100°F for C Steel<br />
Pla<strong>in</strong> carbon steel<br />
875°F for C ½ Mo Steel<br />
C, C ½ Mo<br />
Spheroidisation<br />
850 °F ~ 1400 °F<br />
Low alloy steel up to 9% Cr<br />
510<br />
Tempered<br />
650 °F~ 1070 °F<br />
2 ¼ Cr-1Mo low alloy steel, 3Cr-<br />
Embrittlement<br />
1Mo (lesser extent), & HSLA Cr-<br />
Mo-V rotor steels<br />
Stra<strong>in</strong> Ag<strong>in</strong>g<br />
Intermediate temperature<br />
Pre-1980’s C-steels with a large<br />
gra<strong>in</strong> size and C- ½ Mo<br />
885°F embrittlement<br />
600 °F~ 1000 °F<br />
300, 400 & Duplex SS conta<strong>in</strong><strong>in</strong>g<br />
ferrite phases<br />
Sigma-Phase<br />
1000 °F~ 1700 °F<br />
Ferritic, austenitic & duplex SS.<br />
Embrittlement<br />
Sigma forms most rapidly from <strong>the</strong><br />
ferrite phase that exists <strong>in</strong> 300 Series<br />
SS and duplex SS weld deposits. It can<br />
also form <strong>in</strong> <strong>the</strong> 300 Series SS base<br />
metal (austenite phase) but usually<br />
more slowly.
Exam<br />
<strong>Damage</strong> Mechanism<br />
Temperatures<br />
Affected materials<br />
510/570<br />
Brittle Fracture<br />
Below DTBTT<br />
C, C- ½ Mo, 400 SS<br />
Creep & stress rupture<br />
700 °F ~ 1000 °F<br />
All metals and alloys<br />
510/570<br />
Thermal fatigues<br />
Operat<strong>in</strong>g temperature<br />
All materials of construction<br />
Short Term<br />
>1000 °F<br />
All fired heater tube materials<br />
Overheat<strong>in</strong>g – Stress<br />
and common materials of<br />
Rupture<br />
construction<br />
Steam Blanket<strong>in</strong>g<br />
>1000 °F<br />
Carbon steel and low alloy<br />
steels<br />
Dissimilar Metal Weld<br />
Operat<strong>in</strong>g temperature<br />
Carbon steel / 300 SS<br />
(DMW) Crack<strong>in</strong>g<br />
junction<br />
Thermal Shock<br />
Cold liquid imp<strong>in</strong>ge on hot<br />
All metals and alloys.<br />
surface
Exam<br />
<strong>Damage</strong> Mechanism<br />
Temperatures<br />
Affected materials<br />
570/510<br />
Erosion/Erosion<br />
Service temperature<br />
All<br />
Corrosion<br />
Cavitation<br />
Service temperature<br />
All<br />
570/510<br />
Mechanical fatigue<br />
Service temperature<br />
All<br />
570<br />
Vibration-Induced<br />
Service temperature<br />
All<br />
Fatigue<br />
Refractory<br />
Service temperature<br />
All<br />
Degradation<br />
Reheat Crack<strong>in</strong>g<br />
Service temperature<br />
CS, 300SS, Ni Based<br />
GOX enhances<br />
Service temperature<br />
All<br />
combustion
4.2.1 Graphitization<br />
石 墨 化<br />
( 不 是 API510/570 考 试 项 )
Prolong Exposure<br />
800°F ~ 1100°F for C Steel<br />
>875°F for C ½ Mo Steel
4.2.1 Graphitization 石 墨 化<br />
4.2.1.1 Description of <strong>Damage</strong><br />
a) Graphitization is a change <strong>in</strong> <strong>the</strong> microstructure of certa<strong>in</strong> carbon steels<br />
and 0.5Mo steels after long-term operation <strong>in</strong> <strong>the</strong> 800°F to 1100°F (427°C<br />
to 593°C) range that may cause a loss <strong>in</strong> strength, ductility, and/or creep<br />
resistance. 在 800°F 1100°F 长 期 运 行 后<br />
b) At elevated temperatures, <strong>the</strong> carbide phases <strong>in</strong> <strong>the</strong>se steels are unstable<br />
and may decompose <strong>in</strong>to graphite nodules. This decomposition is known<br />
as graphitization. 碳 钢 /C - ½ Mo 钢 , 在 长 期 受 到 高 温 度 影 响 , 钢 中 碳 化 物 相<br />
变 得 不 稳 定 , 从 而 分 解 成 石 墨 结 节<br />
4.2.1.2 Affected Materials<br />
Some grades of carbon steel and 0.5Mo steels. ( 普 通 碳 钢 /0.5 钼 钢 )
碳 钢 /C - ½ Mo 钢 , 在 长 期 受 到 高 温 度 影 响 , 钢<br />
中 碳 化 物 相 变 得 不 稳 定 , 从 而 分 解 成 石 墨 结 节
Graphitization Location:<br />
Areas with tubes conta<strong>in</strong><strong>in</strong>g carbon steel and C-Mo. Most likely <strong>in</strong> <strong>the</strong><br />
weld heat-affected zones and high residual stress areas.<br />
易 受 影 响 区 : 碳 钢 或 C- ½ Mo 普 通 碳 钢 , 焊 接 热 影 响 区 和 高 残 余 应 力 区
Probable cause:<br />
Prolonged exposure to above 800°F (425°C) for carbon steels and greater than<br />
875°F (470°C) for <strong>the</strong> carbon- ½ molybdenum alloys. In graphitized boiler<br />
components, <strong>the</strong> nucleation of graphite likely starts by <strong>the</strong> precipitation of<br />
“carbon” from super-saturated ferrite, an ag<strong>in</strong>g phenomenon. This nucleation is<br />
enhanced by stra<strong>in</strong>, <strong>in</strong> effect a stra<strong>in</strong> ag<strong>in</strong>g. The preferential formation of<br />
graphite with<strong>in</strong> <strong>the</strong> heat-affected zone is dependent on <strong>the</strong> balance of <strong>the</strong><br />
structure be<strong>in</strong>g nearly stra<strong>in</strong> free. Thus <strong>the</strong> “more unstable” heat-affected zone<br />
microstructure will decompose <strong>in</strong>to ferrite and graphite before <strong>the</strong> annealed<br />
ferrite and pearlite of <strong>the</strong> normalized structure will. If <strong>the</strong> base metal is coldworked,<br />
<strong>the</strong> anneal<strong>in</strong>g of <strong>the</strong> weld will slow <strong>the</strong> nucleation of graphite, and <strong>the</strong><br />
stra<strong>in</strong>ed tube will graphitize before <strong>the</strong> heat-affected zone.<br />
在 长 时 间 的 高 温 影 响 下 , 蝶 状 珠 光 体 ( 碳 化 铁 ) 首 先 转 化 为 粒 状 珠 光 体 , 然 后 碳 从 超 饱<br />
和 的 碳 化 铁 析 出 , 晶 核 形 成 石 墨 与 周 边 缺 碳 纯 铁 素 体 .
4.2.1.3 Critical Factors<br />
a) The most important factors that affect graphitization are <strong>the</strong> chemistry,<br />
stress, temperature, and time of exposure.<br />
b) In general, graphitization is not commonly observed. Some steels are much<br />
more susceptible to graphitization than o<strong>the</strong>rs, but exactly what causes<br />
some steels to graphitize while o<strong>the</strong>rs are resistant is not well understood. It<br />
was orig<strong>in</strong>ally thought that silicon and alum<strong>in</strong>um content played a major<br />
role but it has been shown that <strong>the</strong>y have negligible <strong>in</strong>fluence on<br />
graphitization.<br />
c) Graphitization has been found <strong>in</strong> low alloy C-Mo steels with up to 1% Mo.<br />
The addition of about 0.7% chromium has been found to elim<strong>in</strong>ate<br />
graphitization.<br />
d) Temperature has an important effect on <strong>the</strong> rate of graphitization. Below<br />
800°F (427°C), <strong>the</strong> rate is extremely slow. The rate <strong>in</strong>creases with<br />
<strong>in</strong>creas<strong>in</strong>g temperature.
e) There are two general types of graphitization.<br />
First is random graphitization <strong>in</strong> which <strong>the</strong> graphite nodules are<br />
distributed randomly throughout <strong>the</strong> steel. While this type of<br />
graphitization may lower <strong>the</strong> room-temperature tensile strength, it<br />
does not usually lower <strong>the</strong> creep resistance.
f) The second and more damag<strong>in</strong>g type of graphitization results <strong>in</strong> cha<strong>in</strong>s<br />
or local planes of concentrated graphite nodules.<br />
• Weld heat-affected zone graphitization is most frequently found <strong>in</strong> <strong>the</strong><br />
heat-affected zone adjacent to welds <strong>in</strong> a narrow band, is called<br />
“eyebrow,” graphitization.<br />
• Non-weld graphitization is a form of localized graphitization that<br />
sometimes occurs along planes of localized yield<strong>in</strong>g <strong>in</strong> steel. It also<br />
occurs <strong>in</strong> a cha<strong>in</strong>-like manner <strong>in</strong> regions that have experienced significant<br />
plastic deformation as a result of cold work<strong>in</strong>g operations or bend<strong>in</strong>g.
Weld heat affected zone graphitization<br />
is most frequently found <strong>in</strong> <strong>the</strong> heat-affected zone adjacent to welds <strong>in</strong> a<br />
narrow band, correspond<strong>in</strong>g to <strong>the</strong> low temperature edge of <strong>the</strong> heat affected<br />
zone. In multi-pass welded butt jo<strong>in</strong>ts, <strong>the</strong>se zones overlap each o<strong>the</strong>r,<br />
cover<strong>in</strong>g <strong>the</strong> entire cross-section. Graphite nodules can form at <strong>the</strong> low<br />
temperature edge of <strong>the</strong>se heat affected zones, result<strong>in</strong>g <strong>in</strong> a band of weak<br />
graphite extend<strong>in</strong>g across <strong>the</strong> section. Because of its appearance, this graphite<br />
formation with<strong>in</strong> heat affected zones is called “eyebrow” graphitization.<br />
Type 2: HAZ graphite nodules
eyebrow!<br />
Type2 Graphitization<br />
焊 缝 热 影 响 区 石 墨 化 现 象
eyebrow! Graphitization
eyebrow! Type 2 Graphitization<br />
焊 缝 热 影 响 区 现 象<br />
太 厉 害 了 , 别 人 的 肖 像 变 成 他 家 的 版 权 了 ..NMD
Non-weld graphitization is a form of localized graphitization that sometimes<br />
occurs along planes of localized yield<strong>in</strong>g <strong>in</strong> steel. It also occurs <strong>in</strong> a cha<strong>in</strong>-like<br />
manner <strong>in</strong> regions that have experienced significant plastic deformation as a<br />
result of cold work<strong>in</strong>g operations or bend<strong>in</strong>g.<br />
显 著 地 塑 性 变 形 区 域 , 石 墨 化 可 能 以 链 状 方 式 形 成 .<br />
Type 2: Non<br />
Weld Cha<strong>in</strong>s or<br />
local planes of<br />
concentrated<br />
graphite nodules
4.2.1.4 Affected Units or <strong>Equipment</strong><br />
a) Primarily hot-wall pip<strong>in</strong>g and equipment <strong>in</strong> <strong>the</strong> FCC, catalytic reform<strong>in</strong>g and<br />
coker units.<br />
b) Ba<strong>in</strong>itic grades are less susceptible than coarse pearlitic grades.<br />
c) Few failures directly attributable to graphitization have been reported <strong>in</strong> <strong>the</strong><br />
ref<strong>in</strong><strong>in</strong>g <strong>in</strong>dustry. However, graphitization has been found where failure<br />
resulted primarily from o<strong>the</strong>r causes.<br />
d) Several serious cases of graphitization have occurred <strong>in</strong> <strong>the</strong> reactors and<br />
pip<strong>in</strong>g of fluid catalytic crack<strong>in</strong>g units, as well as with carbon steel furnace<br />
tubes <strong>in</strong> a <strong>the</strong>rmal crack<strong>in</strong>g unit and <strong>the</strong> failure of seal welds at <strong>the</strong> bottom<br />
tube sheet of a vertical waste heat boiler <strong>in</strong> a fluid catalytic cracker. A<br />
graphitization failure was reported <strong>in</strong> <strong>the</strong> long seam weld of a C 0.5Mo<br />
catalytic reformer reactor/<strong>in</strong>ter-heater l<strong>in</strong>e.
e) Where concentrated eyebrow graphitization occurs along heat-affected<br />
zones, <strong>the</strong> creep rupture strength may be drastically lowered. Slight to<br />
moderate amounts of graphite along <strong>the</strong> heat-affected zones do not appear<br />
to significantly lower room or high-temperature properties.<br />
f) Graphitization seldom occurs on boil<strong>in</strong>g surface tub<strong>in</strong>g but did occur <strong>in</strong> low<br />
alloy C-0.5Mo tubes and headers dur<strong>in</strong>g <strong>the</strong> 1940’s. Economizer tub<strong>in</strong>g,<br />
steam pip<strong>in</strong>g and o<strong>the</strong>r equipment that operates <strong>in</strong> <strong>the</strong> range of<br />
temperatures of 850°F to 1025°F (441°C to 552°C) is more likely to suffer<br />
graphitization.
4.2.1.5 Appearance or Morphology of <strong>Damage</strong><br />
1. <strong>Damage</strong> due to graphitization is not visible or readily apparent and can only<br />
be observed by metallographic exam<strong>in</strong>ation (Figure 4-1 and Figure 4-2).<br />
2. Advanced stages of damage related to loss <strong>in</strong> creep strength may <strong>in</strong>clude<br />
micro-fissur<strong>in</strong>g / microvoid formation, subsurface crack<strong>in</strong>g or surface<br />
connected crack<strong>in</strong>g.<br />
0.5μm
Figure 4-1 – High magnification photomicrograph of metallographic sample show<strong>in</strong>g<br />
graphite nodules. Compare to normal microstructure shown <strong>in</strong> Figure 4-2.
Figure 4-2 – High magnification photomicrograph of metallographic<br />
sample show<strong>in</strong>g typical ferrite-pearlite structure of carbon steel.
4.2.1.6 Prevention / Mitigation 预 防 / 缓 解<br />
Graphitization can be prevented by us<strong>in</strong>g chromium conta<strong>in</strong><strong>in</strong>g low alloy steels<br />
for long-term operation above 800°F (427°C).<br />
The addition of about 0.7% chromium has been found to elim<strong>in</strong>ate<br />
graphitization.<br />
0.7% chromium 以 消 除 石 墨 化 .
4.2.1.7 Inspection and Monitor<strong>in</strong>g<br />
a) Evidence of graphitization is most effectively evaluated through removal<br />
of full thickness samples for exam<strong>in</strong>ation us<strong>in</strong>g metallographic<br />
techniques. <strong>Damage</strong> may occur mid-wall so that field replicas may be<br />
<strong>in</strong>adequate.<br />
b) Advanced stages of damage related to loss <strong>in</strong> strength <strong>in</strong>clude surface<br />
break<strong>in</strong>g cracks or creep deformation that may be difficult to detect.<br />
4.2.1.8 Related <strong>Mechanisms</strong><br />
Spheroidization (see 4.2.2) and graphitization are compet<strong>in</strong>g mechanisms<br />
that occur at overlapp<strong>in</strong>g temperature ranges. Spheroidization tends to<br />
occur preferentially above 1025°F (551°C), while graphitization<br />
predom<strong>in</strong>ates below this temperature.
Spheroidization (see 4.2.2) and graphitization are compet<strong>in</strong>g mechanisms that<br />
occur at overlapp<strong>in</strong>g temperature ranges. Spheroidization tends to occur<br />
preferentially above 1025°F (551°C), while graphitization predom<strong>in</strong>ates below<br />
this temperature.<br />
Graphitization can be prevented by us<strong>in</strong>g chromium conta<strong>in</strong><strong>in</strong>g low alloy steels<br />
for long-term operation above 800°F (427°C).<br />
Affected Materials: Some grades of carbon steel and 0.5Mo steels.<br />
Graphitization has been found <strong>in</strong> low alloy C-Mo steels with up to 1% Mo. The<br />
addition of about 0.7% chromium has been found to elim<strong>in</strong>ate graphitization.
Creep Type: Microvoid formation & jo<strong>in</strong>t<strong>in</strong>g of ligament between voids
Typical ferrite-pearlite structure of carbon steel.
Typical ferrite-pearlite structure of carbon steel.
Typical martensitic structure of carbon steel.
Figure 13: Lower ba<strong>in</strong>ite generated by<br />
iso<strong>the</strong>rmal transformation of 52100 steel at<br />
230C for 10h<br />
http://www.msm.cam.ac.uk/phase-trans/2011/Bear<strong>in</strong>gs/<strong>in</strong>dex.htm l
Random graphitization
Random graphitization
Cha<strong>in</strong> graphitization<br />
http://davidnfrench.com/Graphitization.html
Graphitization of A Cast Iron Ma<strong>in</strong>
800°F
石 墨 化 , 学 习 重 点 :<br />
1. 高 温 现 象 : 800°F to 1100°F<br />
2. 受 影 响 材 料 : 碳 钢 ( 不 包 括 低 合 金 钢 ), ½ Mo 钢<br />
3. 损 伤 模 式 : (1) 无 规 则 石 墨 化 ( 仅 仅 影 响 室 温 抗 拉 ) 与 (2) HAZ/ 平 面 石 墨 化<br />
( 较 为 严 厉 , 影 响 室 温 抗 拉 高 温 蠕 变 性 能 )<br />
4. 注 意 项 : ½ Mo 钢 , 抗 拒 性 较 强 , 敏 感 温 度 为 875°F 高 于 碳 钢 800°F<br />
5. 添 加 0.7%Cr 有 效 阻 止 石 墨 化 .<br />
6. 不 是 API 510/570 考 试 学 习 项 .<br />
http://www.chasealloys.co.uk/steel/alloy<strong>in</strong>g-elements-<strong>in</strong>-steel/#chromium
4.2.2 Carbide Spheroidization<br />
碳 化 物 球 化<br />
( 不 是 API510/570 考 试 项 )
Spheroidization<br />
Prolong Exposure<br />
850°F ~ 1400°F
4.2.2 Soften<strong>in</strong>g (Spheroidization) 碳 化 物 球 化<br />
4.2.2.1 Description of <strong>Damage</strong><br />
Spheroidization is a change <strong>in</strong> <strong>the</strong> microstructure of steels after exposure <strong>in</strong> <strong>the</strong><br />
850°F to 1400°F (440°C to 760°C) range, where <strong>the</strong> carbide phases 碳 化 物 <strong>in</strong><br />
carbon steels are unstable and may agglomerate from <strong>the</strong>ir normal plate-like<br />
form to a spheroidal form, or from small, f<strong>in</strong>ely dispersed carbides <strong>in</strong> low alloy<br />
steels like 1Cr-0.5Mo to large agglomerated carbides. Spheroidization may<br />
cause a loss <strong>in</strong> strength and/or creep resistance.<br />
4.2.2.2 Affected Materials<br />
All commonly used grades of carbon steel and low alloy steels <strong>in</strong>clud<strong>in</strong>g C-<br />
0.5Mo, 1Cr-0.5Mo,1.25Cr-0.5Mo, 2.25Cr-1Mo, 3Cr -1Mo, 5Cr-0.5Mo, and 9Cr-<br />
1Mo steels.<br />
高 温 现 象 : 在 长 期 高 温 下 , 细 分 散 或 板 状 碳 化 物 形 成 球 状 形 式 .<br />
涵 盖 了 普 通 碳 钢 , 0.5Mo 钢 , 低 合 金 钢 ,
Figure 9: The microstructures near <strong>the</strong> OD<br />
surface were mostly decarburized. The<br />
rema<strong>in</strong><strong>in</strong>g carbides were highly spheroidized<br />
and agglomerated along <strong>the</strong> ferrite gra<strong>in</strong><br />
boundaries. The microstructure 90° from<br />
<strong>the</strong> rupture and at <strong>the</strong> tube end is<br />
shown.(Nital etch, Mag. 500X)<br />
Figure 10: The microstructures near <strong>the</strong> ID<br />
surface consisted of partially and highly<br />
spheroidized and agglomerated carbides<br />
along <strong>the</strong> ferrite gra<strong>in</strong> boundaries. The<br />
microstructure 90° from <strong>the</strong> rupture and at<br />
<strong>the</strong> tube end is shown. (Nital etch, Mag. 500X)<br />
http://www.met-tech.com/short-term-overheat-rupture-of-t11-superheater-tube.html
Differences<br />
• Soften<strong>in</strong>g (Spheroidization), at prolong exposure to high temperature<br />
carbide phases <strong>in</strong> carbon steels are unstable and may agglomerate<br />
from <strong>the</strong>ir normal plate-like form to a spheroidal form, or from small,<br />
f<strong>in</strong>ely dispersed carbides <strong>in</strong> low alloy steels like 1Cr-0.5Mo to large<br />
agglomerated carbides. 在 长 期 高 温 工 作 下 , 低 合 金 碳 钢 , 碳 化 物 相 变 得<br />
不 稳 定 , 导 致 正 常 板 状 形 式 凝 聚 成 一 个 球 状 形 式 .<br />
• Graphitisation, <strong>the</strong> carbide phases <strong>in</strong> carbon/Molydenum steels are<br />
unstable and may decompose <strong>in</strong>to graphite nodules. 在 高 温 长 期 工 作<br />
下 , 普 通 碳 钢 /0.5 钼 钢 中 的 化 物 相 变 得 不 稳 定 , 这 碳 化 物 分 解 成 石 墨 结 节 .<br />
影 响 的 材 料 差 别 为 ;<br />
(1) 普 通 碳 钢 / 受 石 墨 化 影 响<br />
(2) 低 合 金 含 铬 钼 高 强 度 , 高 温 钢 受 碳 化 物 球 化
Spheroidization 球 化<br />
<strong>in</strong> physical metallurgy, a process<br />
consist<strong>in</strong>g <strong>in</strong> <strong>the</strong> transition of<br />
excess-phase crystals <strong>in</strong>to a<br />
globular (spheroidal) form. The<br />
transition occurs at relatively high<br />
temperatures and is associated with<br />
a decrease <strong>in</strong> <strong>the</strong> <strong>in</strong>terfacial energy<br />
高 温 下 界 面 的 能 量 减 少 . Of particular<br />
importance is <strong>the</strong> spheroidization of<br />
<strong>the</strong> cementite plates conta<strong>in</strong>ed <strong>in</strong><br />
pearlite. In this process, <strong>the</strong> lamellar<br />
pearlite is converted <strong>in</strong>to granular<br />
pearlite 片 状 珠 光 体 转 变 为 粒 状 珠 光<br />
体 . As a result, <strong>the</strong> hardness and <strong>the</strong><br />
strength of <strong>the</strong> metal are<br />
significantly decreased, but <strong>the</strong><br />
ductility is <strong>in</strong>creased.
Carbide Spheroidization 碳 化 物 球 化<br />
Figure 1. Corroded sheath<br />
exterior (0.85X Orig<strong>in</strong>al<br />
Magnification)<br />
Figure 2. Etched sample of<br />
a section of non-corroded<br />
material (200X Orig<strong>in</strong>al<br />
Magnification with Nital<br />
Etch)
http://www.matter.org.uk/steelmatter/form<strong>in</strong>g/4_5.html
• Graphitisation and spheroidization both were<br />
high temperature phenomenon. 石 墨 化 与 球 化 都<br />
是 材 料 高 温 效 应<br />
• Graphitisation affect normal carbon steel. It is a<br />
break down of carbides <strong>in</strong>to ferrite and free<br />
graphite (carbon) nodules. 石 墨 化 是 高 温 下 , 碳 化<br />
物 分 解 为 铁 素 体 和 游 离 石 墨 / 碳 .<br />
• Spheroidization affect Cr-Mo low carbon steel up<br />
to 9%Cr. It is a agglomeration of carbides<br />
form<strong>in</strong>g spheroidal carbides. 球 化 是 高 温 下 , 界 面<br />
的 能 量 减 少 导 致 片 状 珠 光 体 转 变 为 粒 状 珠 光 体
Spheroidization affect Cr-Mo low carbon steel up to 9% Cr. It is a<br />
agglomeration of carbides form<strong>in</strong>g spheroidal carbides 影 响 达 9%Cr 低 合 金<br />
碳 钢 , 高 温 下 界 面 的 能 量 减 少 , 片 状 珠 光 体 转 变 为 粒 状 珠 光 体 ( 片 状 碳 化 物 集 聚<br />
形 成 球 状 碳 化 物 ).<br />
含 9% Chromium 碳 化 物 球 化 影 响 范 围 .
• Residual stress & cold works accelerated graphitization. 残 余 应<br />
力 和 冷 工 程 加 速 石 墨 化 .<br />
• For spheroidisation coarse-gra<strong>in</strong>ed steels are more resistant<br />
than f<strong>in</strong>e-gra<strong>in</strong>ed. F<strong>in</strong>e gra<strong>in</strong>ed silicon-killed steels are more<br />
resistant than alum<strong>in</strong>um killed.<br />
• 粗 粒 度 的 钢 比 细 粒 度 更 抗 拒 碳 化 物 球 化 .<br />
• 细 晶 硅 镇 静 钢 比 铝 镇 静 更 抗 拒 碳 化 物 球 化 .
Susceptibility to Spheroidization 球 化 易 感 性<br />
• Annealed steels 退 火 钢 材 are more resistant to spheroidization than<br />
normalized steels.<br />
• Coarse-gra<strong>in</strong>ed steels 粗 粒 度 钢 材 are more resistant than f<strong>in</strong>e-gra<strong>in</strong>ed.<br />
• F<strong>in</strong>e gra<strong>in</strong>ed silicon-killed steels are more resistant than alum<strong>in</strong>um-killed.<br />
• The loss <strong>in</strong> strength 强 度 损 失 may be as high as about 30% but failure is not<br />
likely to occur except under very high applied stresses.
Exam<br />
DM<br />
Temperatures<br />
Affected materials<br />
NO<br />
Graphitisation<br />
800°F~1100°F for C Steel<br />
Pla<strong>in</strong> carbon steel<br />
875°F for C ½ Mo Steel<br />
C, C ½ Mo<br />
• Some grades of carbon steel and 0.5Mo steels.<br />
NO<br />
Spheroidisation<br />
850°F ~ 1400°F<br />
Low alloy steel up to 9% Cr.<br />
•All commonly used grades of carbon steel and low alloy steels <strong>in</strong>clud<strong>in</strong>g C-0.5Mo,<br />
1Cr-0.5Mo,1.25Cr-0.5Mo, 2.25Cr-1Mo, 3Cr-1Mo, 5Cr-0.5Mo, and 9Cr-1Mo steels.<br />
Spheroidization (see 4.2.2) and graphitization are compet<strong>in</strong>g mechanisms that occur at<br />
overlapp<strong>in</strong>g temperature ranges. Spheroidization tends to occur preferentially above 1025°F<br />
(551°C), while graphitization predom<strong>in</strong>ates below this temperature.<br />
Discussion: Graphitization occurs on some carbon steel and 0.5Mo steels only.
Spheroidization is a change <strong>in</strong> <strong>the</strong> microstructure of steels after<br />
exposure <strong>in</strong> <strong>the</strong> 850°F to 1400°F (440°C to 760°C) range,<br />
where <strong>the</strong> carbide phases <strong>in</strong> carbon steels are unstable and may<br />
agglomerate from <strong>the</strong>ir normal plate-like form to a spheroidal form.<br />
碳 化 物 球 化 学 习 重 点 :<br />
1. 高 温 现 象 –850°F to 1400°F,<br />
2. 原 理 : 低 合 金 碳 钢 , 高 温 下 界 面 的 能 量 减 少 , 片 状 珠 光 体 转 变 为 粒 状 珠 光<br />
体 ( 片 状 碳 化 物 集 聚 形 成 球 状 碳 化 物 ),<br />
3. 受 影 响 材 质 : 涵 盖 了 普 通 碳 钢 , 0.5Mo 钢 , 低 合 金 钢 至 9Cr1Mo 钢 ,<br />
4. 粗 粒 度 的 钢 比 细 粒 度 更 抗 拒 碳 化 物 球 化 ,<br />
5. 细 晶 硅 镇 静 钢 比 铝 镇 静 更 抗 拒 碳 化 物 球 化 ,<br />
6. 不 同 于 石 墨 化 , 碳 化 物 还 是 碳 化 物 只 不 过 高 温 下 聚 集 成 为 球 状 ,<br />
7. 非 API 510/570 考 试 题 非 API 510/570 考 试 题
4.2.3 Temper Embrittlement<br />
回 火 脆 化<br />
API510-Exam
650 o F~ 1070 o F<br />
API510-Exam
API510-Exam<br />
Graphitization<br />
石 墨 化<br />
Spheroidization 碳<br />
化 物 球 化<br />
Tempered<br />
Embrittlement<br />
回 火 脆 化<br />
800°F~1100°F for C Steel<br />
875°F for C ½ Mo Steel<br />
850°F ~ 1400°F<br />
650°F~ 1070°F<br />
Pla<strong>in</strong> carbon steel / 0.5Mo<br />
Steel<br />
0.5Mo Steel, Low alloy steel<br />
up to 9 % Cr<br />
2 ¼ Cr-1Mo low alloy steel,<br />
3Cr-1Mo (lesser extent), &<br />
HSLA Cr-Mo-V rotor steels
API510-Exam<br />
4.2.3 Temper Embrittlement 回 火 脆 化<br />
4.2.3.1 Description of <strong>Damage</strong><br />
Temper embrittlement is <strong>the</strong> reduction <strong>in</strong> toughness due to a metallurgical<br />
change that can occur <strong>in</strong> some low alloy steels as a result of long term<br />
exposure <strong>in</strong> <strong>the</strong> temperature range of about 650°F to 1100°F (343°C to<br />
593°C) . This change causes an upward shift <strong>in</strong> <strong>the</strong> ductile-to-brittle transition<br />
temperature as measured by Charpy impact test<strong>in</strong>g. Although <strong>the</strong> loss of<br />
toughness is not evident at operat<strong>in</strong>g temperature, equipment that is temper<br />
embrittled may be susceptible to brittle fracture dur<strong>in</strong>g start-up and shutdown.<br />
2¼ Cr-1Mo ~ 3Cr-1Mo 量 低 合 金 钢 在 650°F to 1100°F 工 作 下 , 导 致 受 影 响 材 质 ,<br />
韧 脆 转 变 温 度 向 上 移 位 . 工 作 状 态 下 , 设 备 不 会 受 到 此 损 伤 机 理 任 何 影 响 , 但 在<br />
关 机 , 重 启 时 的 低 温 下 , 材 料 会 因 回 火 脆 性 的 损 伤 机 理 导 致 产 生 设 备 受 压 母 材 脆<br />
裂 .
API510-Exam<br />
Temper embrittlement is <strong>the</strong> reduction <strong>in</strong> toughness due to a metallurgical<br />
change that can occur <strong>in</strong> some low alloy steels as a result of long term<br />
exposure <strong>in</strong> <strong>the</strong> temperature range of about 650°F to 1100°F (343°C to<br />
593°C) . 2¼ Cr-1Mo~ 3Cr-1Mo 钢 材 在 650°F to 1100°F 工 作 下 , 导 致 受 影 响 材 质 ,<br />
韧 脆 转 变 温 度 向 上 移 位 .
API510-Exam<br />
4.2.3.2 Affected Materials<br />
a) Primarily 2 ¼ Cr-1Mo (P5A) low alloy steel, 3Cr-1Mo (P5A) (to a lesser<br />
extent), and <strong>the</strong> high-strength low alloy Cr-Mo-V (P5C) rotor steels.<br />
b) Older generation 2 ¼ Cr-1Mo materials manufactured prior to 1972 may be<br />
particularly susceptible. Some high strength low alloy steels are also<br />
susceptible.<br />
c) The C- ½ Mo (P3) and 1 ¼ Cr- ½ Mo (P4) alloy steels are not significantly<br />
affected by temper embrittlement. However, o<strong>the</strong>r high temperature<br />
damage mechanisms promote metallurgical changes that can alter <strong>the</strong><br />
toughness or high temperature ductility of <strong>the</strong>se materials.<br />
主 要 是 对 2¼ Cr-1Mo~ 3Cr-1Mo 低 合 金 钢 , Cr-Mo-V 轴 钢 受 影 响 .
API510-Exam<br />
Temper<br />
Embrittlement<br />
回 火 脆 性 易 感 性<br />
Primarily 2.25Cr-1Mo low<br />
alloy steel. and <strong>the</strong> highstrength<br />
low alloy Cr-Mo-V<br />
rotor steels.<br />
3Cr-1Mo<br />
(to a lesser extent)<br />
The C-0.5Mo, 1Cr-<br />
0.5Mo and 1.25Cr-<br />
0.5Mo alloy steels are<br />
not significantly<br />
affected.
[Embrittlement temperature 650°F~1070°F]<br />
API510-Exam
[Embrittlement temperature 650°F~1070°F]<br />
API510-Exam
[Embrittlement temperature 650°F~1070°F]<br />
API510-Exam
韧 脆 转 变 温 度<br />
API510-Exam
韧 脆 转 变 温 度 向 上 移 位<br />
API510-Exam
API510-Exam<br />
脆 性 转 变 温 度 向 上 移 位 . 另<br />
个 特 征 是 回 火 脆 化 , 不 会 对<br />
脆 性 转 变 点 上 搁 架 冲 击 功 有<br />
任 何 影 响 .
API510-Exam<br />
SEM fractographs of<br />
tempered embrittled<br />
material show<br />
primarily <strong>in</strong>tergranular<br />
crack<strong>in</strong>g due to<br />
impurity segregation at<br />
gra<strong>in</strong> boundaries<br />
材 料 的 回 火 脆 化 , 主 要<br />
是 由 于 晶 界 杂 质 偏 聚<br />
导 致 是 沿 晶 开 裂
http://www.twi.co.uk/news-events/bullet<strong>in</strong>/archive/1999/januaryfebruary/weld<strong>in</strong>g-and-fabrication-of-high-temperature-components-foradvanced-power-plant-part-1/<br />
API510-Exam
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4.2.3.3 Critical Factors 关 键 因 素<br />
a) Alloy steel composition, <strong>the</strong>rmal history, metal temperature and exposure<br />
time are critical factors. 受 热 历 史 , 金 属 温 度 和 受 感 时 间 是 关 键 因 素<br />
b) Susceptibility to temper embrittlement is largely determ<strong>in</strong>ed by <strong>the</strong><br />
presence of <strong>the</strong> alloy<strong>in</strong>g elements manganese and silicon, and <strong>the</strong> tramp<br />
elements phosphorus, t<strong>in</strong>, antimony, and arsenic. The strength level and<br />
heat treatment/fabrication history should also be considered. 回 火 脆 化 敏 感<br />
性 很 大 程 度 上 决 定 于 锰 / 硅 与 杂 元 素 ( 磷 / 锡 / 锑 和 砷 ) 含 量 .<br />
c) Temper embrittlement of 2.25Cr-1Mo steels develops more quickly at<br />
900°F (482°C) than <strong>in</strong> <strong>the</strong> 800°F to 850°F (427°C to 440°C) range, but <strong>the</strong><br />
damage is more severe after long-term exposure at 850°F (440°C). 高 温 下<br />
易 感 性 较 大 , 但 在 低 温 下 伤 害 较 为 严 重 .
API510-Exam<br />
d) Some embrittlement can occur dur<strong>in</strong>g fabrication heat treatments, but most<br />
of <strong>the</strong> damage occurs over many years of service <strong>in</strong> <strong>the</strong> embrittl<strong>in</strong>g<br />
temperature range. 有 的 损 伤 是 因 建 造 热 处 理 引 发 , 但 一 般 上 大 多 数 受 感 于 长<br />
期 在 敏 感 温 度 下 操 作 引 发 的 .<br />
e) This form of damage will significantly reduce <strong>the</strong> structural <strong>in</strong>tegrity of a<br />
component conta<strong>in</strong><strong>in</strong>g a crack-like flaw. An evaluation of <strong>the</strong> materials<br />
toughness may be required depend<strong>in</strong>g on <strong>the</strong> flaw type, <strong>the</strong> severity of <strong>the</strong><br />
environment, and <strong>the</strong> operat<strong>in</strong>g conditions, particularly <strong>in</strong> hydrogen service.<br />
含 裂 纹 状 缺 陷 的 部 件 会 减 弱 结 构 完 整 性 . 特 别 是 氢 服 务 设 备 , 应 在 考 虑 缺 陷 的<br />
类 型 , 处 理 工 艺 的 严 峻 性 与 操 作 条 件 , 进 行 材 料 的 韧 性 评 估 .
API510-Exam<br />
4.2.3.4 Affected Units or <strong>Equipment</strong><br />
a) Temper embrittlement occurs <strong>in</strong> a variety of process units after long term<br />
exposure to temperatures above 650°F (343°C). It should be noted that<br />
<strong>the</strong>re have been very few <strong>in</strong>dustry failures related directly to temper<br />
embrittlement.<br />
b) <strong>Equipment</strong> susceptible to temper embrittlement is most often found <strong>in</strong><br />
hydroprocess<strong>in</strong>g units, particularly reactors, hot feed/effluent exchanger<br />
components, and hot HP separators. O<strong>the</strong>r units with <strong>the</strong> potential for<br />
temper embrittlement <strong>in</strong>clude catalytic reform<strong>in</strong>g units (reactors and<br />
exchangers), FCC reactors, coker and visbreak<strong>in</strong>g units.<br />
c) Welds <strong>in</strong> <strong>the</strong>se alloys are often more susceptible than <strong>the</strong> base metal and<br />
should be evaluated.<br />
受 影 响 的 设 备 主 要 是 用 于 高 温 处 理 单 元 , 例 如 加 氢 装 置 , 催 化 重 整 装 置 , 催 化 裂<br />
化 反 应 器 , 炼 焦 器 , 减 粘 裂 化 单 元 , 等 . 焊 接 部 位 受 感 性 比 母 材 强 , 这 位 应 当 作 为<br />
评 估 考 虑 部 位 .
API510-Exam<br />
http://www.twi-global.com/technical-knowledge/job-knowledge/defectsimperfections-<strong>in</strong>-welds-reheat-crack<strong>in</strong>g-048/<br />
http://en.wikipedia.org/wiki/Weld<strong>in</strong>g_defect
API510-Exam
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4.2.3.5 Appearance or Morphology of <strong>Damage</strong><br />
a) Temper embrittlement is a metallurgical change that is not readily apparent<br />
and can be confirmed through impact test<strong>in</strong>g. <strong>Damage</strong> due to temper<br />
embrittlement may result <strong>in</strong> catastrophic brittle fracture.<br />
外 观 变 化 不 明 显 , 需 要 通 过 冲 击 试 验 证 实 .<br />
b) Temper embrittlement can be identified by an upward shift <strong>in</strong> <strong>the</strong> ductile-tobrittle<br />
transition temperature measured <strong>in</strong> a Charpy V-notch impact test, as<br />
compared to <strong>the</strong> non-embrittled or de-embrittled material (Figure 4-5).<br />
Ano<strong>the</strong>r important characteristic of temper embrittlement is that <strong>the</strong>re is no<br />
effect on <strong>the</strong> upper shelf energy. 夏 比 V 型 缺 口 冲 击 试 验 证 实 韧 性 - 脆 性 转 变<br />
温 度 向 上 移 位 . 另 个 特 征 是 回 火 脆 化 , 不 会 对 脆 性 转 变 点 上 搁 架 冲 击 功 有 任 何<br />
影 响 .<br />
c) SEM fractographs of severely temper embrittled material show primarily<br />
<strong>in</strong>tergranular crack<strong>in</strong>g due to impurity segregation at gra<strong>in</strong> boundaries.<br />
主 要 为 晶 间 开 裂
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Intergranular Crack<strong>in</strong>g<br />
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Intergranular<br />
Crack<strong>in</strong>g<br />
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Metal surface<br />
Cr 5<br />
C 2<br />
/ Cr 3<br />
C 2<br />
precipitated<br />
Low Cr gra<strong>in</strong><br />
boundary<br />
Crack <strong>in</strong>itiation &<br />
growth<br />
Progressive crack
API510-Exam<br />
Embrittlement Mechanism<br />
Tensile stress<br />
Cr depleted gra<strong>in</strong><br />
boundary<br />
PPT as<br />
Cr 5 C 2 /Cr 3 C 2<br />
Gra<strong>in</strong><br />
Boundary<br />
Gra<strong>in</strong> boundary<br />
decohesion-<br />
Crack <strong>in</strong>itiation pt.
API510-Exam<br />
4.2.3.6 Prevention / Mitigation<br />
a) Exist<strong>in</strong>g Materials<br />
1. Temper embrittlement cannot be prevented if <strong>the</strong> material conta<strong>in</strong>s critical<br />
levels of <strong>the</strong> embrittl<strong>in</strong>g impurity elements and is exposed <strong>in</strong> <strong>the</strong> embrittl<strong>in</strong>g<br />
temperature range.<br />
2. To m<strong>in</strong>imize <strong>the</strong> possibility of brittle fracture dur<strong>in</strong>g startup and shutdown,<br />
many ref<strong>in</strong>ers use a pressurization sequence to limit system pressure to<br />
about 25 percent of <strong>the</strong> maximum design pressure for temperatures below a<br />
M<strong>in</strong>imum Pressurization Temperature (MPT). Note that MPT is not a s<strong>in</strong>gle<br />
po<strong>in</strong>t but ra<strong>the</strong>r a pressure temperature envelope which def<strong>in</strong>es safe<br />
operat<strong>in</strong>g conditions to m<strong>in</strong>imize <strong>the</strong> likelihood of brittle fracture.
API510-Exam<br />
3. MPT’s generally range from 350°F (171°C) for <strong>the</strong> earliest, most highly<br />
temper embrittled steels, down to 125°F (52°C) or lower for newer, temper<br />
embrittlement resistant steels (as required to also m<strong>in</strong>imize effects of<br />
hydrogen embrittlement).<br />
4. If weld repairs are required, <strong>the</strong> effects of temper embrittlement can be<br />
temporarily reversed (de-embrittled) by heat<strong>in</strong>g at 1150°F (620°C)<br />
[compared: embrittlement temperature 650°F~1070°F] for two hours per <strong>in</strong>ch<br />
of thickness, and rapidly cool<strong>in</strong>g to room temperature. It is important to note<br />
that re-embrittlement will occur over time if <strong>the</strong> material is re-exposed to <strong>the</strong><br />
embrittl<strong>in</strong>g temperature range.
API510-Exam<br />
Exist<strong>in</strong>g Material: De-embrittlement treatment.<br />
Heat<strong>in</strong>g at 1150°F (620°C)<br />
[compared: embrittlement<br />
temperature 650°F~1070°F<br />
(343°C to 593°C) ] for two<br />
hours per <strong>in</strong>ch of thickness,<br />
and rapidly cool<strong>in</strong>g to room<br />
temperature.
) New Materials<br />
API510-Exam<br />
The best way to m<strong>in</strong>imize <strong>the</strong> likelihood and extent of temper embrittlement is to<br />
limit <strong>the</strong> acceptance levels of manganese, silicon, phosphorus, t<strong>in</strong>, antimony,<br />
and arsenic <strong>in</strong> <strong>the</strong> base metal and weld<strong>in</strong>g consumables. In addition,<br />
strength levels and PWHT procedures should be specified and carefully<br />
controlled. 最 好 的 缓 解 方 法 是 控 制 母 材 / 焊 材 的 锰 , 硅 , 磷 , 锡 , 锑 , 砷 的 成 分 .<br />
Acceptance Level of Mn, Si, P, Sn, Sb, As.
API510-Exam<br />
Susceptibility to temper embrittlement<br />
A common way to m<strong>in</strong>imize temper embrittlement is to limit <strong>the</strong> "J*" Factor for<br />
base metal and <strong>the</strong> "X" Factor for weld metal, based on material composition as<br />
follows:<br />
J* = (Si + Mn) x (P + Sn) x 104 {elements <strong>in</strong> wt%}<br />
X = (10P + 5Sb + 4Sn + As)/100 {elements <strong>in</strong> ppm}
API510-Exam<br />
Typical J* and X factors used for 2.25 Cr steel are a maximum of 100 and 15,<br />
respectively. Studies have also shown that limit<strong>in</strong>g <strong>the</strong> (P + Sn) to less than 0.01% is<br />
sufficient to m<strong>in</strong>imize temper embrittlement because (Si + Mn) control <strong>the</strong> rate of<br />
embrittlement.<br />
J* : 100 Max. (Base metal)<br />
X<br />
: 15 Max. (Weld metal)
API510-Exam<br />
4.2.3.7 Inspection and Monitor<strong>in</strong>g<br />
a) a) A common method of monitor<strong>in</strong>g is to <strong>in</strong>stall blocks of orig<strong>in</strong>al heats of<br />
<strong>the</strong> alloy steel material <strong>in</strong>side <strong>the</strong> reactor. Samples are periodically removed<br />
from <strong>the</strong>se blocks for impact test<strong>in</strong>g to monitor/establish <strong>the</strong> ductile-brittle<br />
transition temperature. The test blocks should be strategically located near<br />
<strong>the</strong> top and bottom of <strong>the</strong> reactor to make sure that <strong>the</strong> test material is<br />
exposed to both <strong>in</strong>let and outlet conditions.<br />
b) Process conditions should be monitored to ensure that a proper<br />
pressurization sequence is followed to help prevent brittle fracture due to<br />
temper embrittlement.<br />
4.2.3.8 Related <strong>Mechanisms</strong><br />
Not applicable.
Figure 4-5 – Plot of<br />
CVN toughness as a<br />
function of<br />
temperature show<strong>in</strong>g a<br />
shift <strong>in</strong> <strong>the</strong> 40-ft-lb<br />
transition temperature.<br />
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Temper embrittlement is <strong>in</strong>herent <strong>in</strong> many steels and can be characterized<br />
by reduced impact toughness. The state of temper embrittlement has practically no<br />
effect on o<strong>the</strong>r mechanical properties at room temperature. Figure 1 shows<br />
schematically <strong>the</strong> effect of temperature on impact toughness of alloy steel which is<br />
strongly liable to temper embrittlement. Many alloy steels have two temperature<br />
<strong>in</strong>tervals of temper embrittlement. For <strong>in</strong>stance, irreversible temper brittleness may<br />
appear with<strong>in</strong> <strong>the</strong> <strong>in</strong>terval of 250-400°C and reversible temper brittleness, with<strong>in</strong><br />
450°C-650°C.<br />
http://www.keytometals.com/Articles/Art102.htm
API510-Exam<br />
irreversible temper<br />
brittleness may appear<br />
with<strong>in</strong> <strong>the</strong> <strong>in</strong>terval of<br />
250-400°C<br />
reversible temper brittleness,<br />
with<strong>in</strong> 450°C-650°C.
API510-Exam<br />
Metallurgy of Mo <strong>in</strong> alloy steel & iron<br />
Temper embrittlement may occur when steels are slowly cooled after temper<strong>in</strong>g<br />
through <strong>the</strong> temperature range between 450 and 550°C. This is due to <strong>the</strong><br />
segregation of impurities such as phosphorus, arsenic, antimony and t<strong>in</strong> on <strong>the</strong><br />
gra<strong>in</strong> boundaries. The molybdenum atom is very large relative to o<strong>the</strong>r alloy<strong>in</strong>g<br />
elements and impurities. It effectively impedes <strong>the</strong> migration of those elements<br />
and <strong>the</strong>reby provides resistance to temper embrittlement.<br />
http://www.imoa.<strong>in</strong>fo/molybdenum_uses/moly_grade_alloy_steels_irons/temper<strong>in</strong>g.php<br />
O<strong>the</strong>r/ 其 他 阅 读<br />
O<strong>the</strong>r reference: http://www.twi.co.uk/technical-knowledge/faqs/material-faqs/faq-what-is-temperembrittlement-and-how-can-it-be-controlled/
回 火 脆 化 学 习 重 点 :<br />
1. 高 温 现 象 : 650°F to 1100°F,<br />
2. 原 理 : 材 料 的 回 火 脆 化 , 主 要 是 由 于 晶 界 杂 质 偏 聚 导 致 是 沿 晶 开 裂<br />
3. 受 影 响 材 质 :, 2.25Cr1Mo ~ 3Cr1Mo 低 合 金 钢 与 轴 钢 , 不 涵 盖 普 通 碳 钢 ,<br />
4. 最 好 的 缓 解 方 法 是 控 制 母 材 / 焊 材 的 锰 , 硅 , 磷 , 锡 , 锑 , 砷 的 成 分 ,<br />
5. 其 他 缓 解 方 法 : 控 制 材 料 强 度 (?) 与 热 处 理 受 感 温 度 ,<br />
6. 这 种 脆 化 现 象 不 能 在 高 于 受 感 温 度 热 处 理 逆 转 恢 复 .<br />
7. 除 了 低 温 冲 击 功 , 不 影 响 其 他 高 低 温 机 械 性 能 .
4.2.4 Stra<strong>in</strong> Ag<strong>in</strong>g<br />
时 效 伸 张<br />
( 不 是 API510/570 考 试 项 )
Intermediate<br />
temperature
Graphitisation<br />
Spheroidization<br />
Tempered Embrittlement<br />
Stra<strong>in</strong> Ag<strong>in</strong>g<br />
800°F for C Steel<br />
875°F for C ½ Mo Steel<br />
850 o F ~ 1400 o F<br />
650°F~ 1070°F<br />
Intermediate temperature<br />
Pla<strong>in</strong> carbon steel<br />
Pla<strong>in</strong> carbon + Low alloy steel<br />
up to 9% Cr<br />
2 ¼ Cr-1Mo low alloy steel, 3Cr-<br />
1Mo (lesser extent), & HSLA<br />
Cr-Mo-V rotor steels<br />
pre-1980’s carbon steels with a<br />
large gra<strong>in</strong> size and C-0.5 Mo<br />
885 o F embrittlement<br />
600°F~ 1000°F<br />
受 影 响 的 材 质 是 那 些 老 工 艺 的 炼 钢 方 法 的 普 通 碳 钢 与<br />
0.5Mo 钢 – 含 有 高 成 分 的 关 键 杂 质 元 素 与 粗 晶 粒 .<br />
300, 400 & Duplex SS<br />
conta<strong>in</strong><strong>in</strong>g ferrite phases
4.2.4 Stra<strong>in</strong> Ag<strong>in</strong>g 伸 张 时 效<br />
4.2.4.1 Description of <strong>Damage</strong><br />
Stra<strong>in</strong> ag<strong>in</strong>g is a form of damage found mostly <strong>in</strong> older v<strong>in</strong>tage carbon<br />
steels and C-0.5 Mo low alloy steels under <strong>the</strong> comb<strong>in</strong>ed effects of<br />
deformation and ag<strong>in</strong>g at an <strong>in</strong>termediate temperature. This results <strong>in</strong> an<br />
<strong>in</strong>crease <strong>in</strong> hardness and strength with a reduction <strong>in</strong> ductility and<br />
toughness.<br />
4.2.4.2 Affected Materials<br />
Mostly older (pre-1980’s) carbon steels with a large gra<strong>in</strong> size and C-0.5<br />
Mo low alloy steel.<br />
When susceptible materials are plastically deformed and exposed to<br />
<strong>in</strong>termediate temperatures, <strong>the</strong> zone of deformed material may become<br />
hardened and less ductile.<br />
一 般 上 受 影 响 的 是 1980 年 或 更 早 前 的 碳 钢 ( 特 别 是 大 粒 径 / C- ½ Mo), 当 这 些<br />
敏 感 的 材 料 , 经 过 塑 性 变 形 和 接 触 中 间 温 度 作 业 时 , 这 变 形 材 料 区 可 能 变 硬<br />
和 延 展 性 与 韧 性 降 低 。
http://l<strong>in</strong>k.spr<strong>in</strong>ger.com/article/10.1007%2Fs11668-006-5014-3#page-1<br />
http://l<strong>in</strong>k.spr<strong>in</strong>ger.com/article/10.1007%2FBF02715166#page-1<br />
http://matperso.m<strong>in</strong>es-paristech.fr/Donnees/data03/386-belotteau09.pdf<br />
Most of <strong>the</strong> effects of cold work on<br />
<strong>the</strong> strength and ductility of<br />
structural steels can be elim<strong>in</strong>ated<br />
by <strong>the</strong>rmal treatment, such as<br />
stress reliev<strong>in</strong>g, normaliz<strong>in</strong>g, or<br />
anneal<strong>in</strong>g. However, such<br />
treatment is not often necessary.<br />
伸 张 时 效 对 强 度 和 韧 性 的 影 响 能 以<br />
热 处 理 逆 转 恢 复 .
韧 性 减 低 / 抗 拉 曾 强
拉<br />
力<br />
AISC- Guide to Design Criteria for Bolted and Riveted Jo<strong>in</strong>ts
拉<br />
力<br />
AISC- Guide to Design Criteria for Bolted and Riveted Jo<strong>in</strong>ts
4.2.4.3 Critical Factors 关 键 因 素<br />
a) Steel composition and manufactur<strong>in</strong>g process determ<strong>in</strong>e steel susceptibility.<br />
b) Steels manufactured by <strong>the</strong> Bessemer or open hearth process conta<strong>in</strong><br />
higher levels of critical impurity elements than newer steels manufactured<br />
by <strong>the</strong> Basic Oxygen Furnace (BOF) process.<br />
c) In general, steels made by BOF and fully killed with alum<strong>in</strong>um will not be<br />
susceptible. The effect is found <strong>in</strong> rimmed and capped steels with higher<br />
levels of nitrogen and carbon, but not <strong>in</strong> <strong>the</strong> modern fully killed carbon<br />
steels manufactured to a f<strong>in</strong>e gra<strong>in</strong> practice.<br />
受 感 性 强 材 质 :<br />
• 含 有 高 成 分 的 关 键 杂 质 元 素 的 转 炉 或 平 炉 炼 钢 法 ( 老 炼 钢 法 ),<br />
• 含 大 量 的 氢 与 碳 元 素 的 压 盖 钢 / 半 镇 静 钢 / 沸 腾 钢<br />
不 受 影 响 材 质 :<br />
• 碱 性 氧 气 转 炉 炼 钢 法 , 铝 镇 静 钢 , 细 晶 粒 实 践 钢 .
d) Stra<strong>in</strong> ag<strong>in</strong>g effects are observed <strong>in</strong> materials that have been cold worked<br />
and placed <strong>in</strong>to service at <strong>in</strong>termediate temperatures without stress<br />
reliev<strong>in</strong>g. 冷 加 工 件 ( 无 热 处 理 ) 用 于 中 等 温 度 服 务 .<br />
e) Stra<strong>in</strong> ag<strong>in</strong>g is a major concern for equipment that conta<strong>in</strong>s cracks. If<br />
susceptible materials are plastically deformed and exposed to <strong>in</strong>termediate<br />
temperatures, <strong>the</strong> zone of deformed material may become hardened and<br />
less ductile. This phenomenon has been associated with several vessels<br />
that have failed by brittle fracture. 塑 性 变 材 料 当 接 触 到 中 等 温 度 时 , 变 形 的<br />
区 域 会 变 硬 与 减 少 韧 性 , 如 这 材 料 带 裂 缝 时 会 导 致 设 备 脆 性 断 裂 .<br />
f) The pressurization sequence versus temperature is a critical issue to<br />
prevent brittle fracture of susceptible materials. 加 压 顺 序 与 温 度 是 预 防 时 效<br />
伸 张 开 裂 的 关 键 方 法 .<br />
g) Stra<strong>in</strong> ag<strong>in</strong>g can also occur when weld<strong>in</strong>g <strong>in</strong> <strong>the</strong> vic<strong>in</strong>ity of cracks and<br />
notches <strong>in</strong> a susceptible material. 焊 接 加 热 也 会 加 剧 带 裂 纹 的 受 感 材 料 .
Bessemer Process
Bessemer Process
Bessemer Process
Bessemer Process
Open hearth Process
Open hearth Process
Open hearth Process
Open hearth Process 平 炉 炼 钢 法
Basic Oxygen Process<br />
碱 性 氧 气 转 炉 炼 钢 法
Basic Oxygen Process
Basic Oxygen Process
Metallurgy for Dummies<br />
http://metallurgyfordummies.com/steelmak<strong>in</strong>g-technology/
Capped Steel 半 镇 静 钢 , 加 盖 钢 :<br />
• It has characteristics similar to those of rimmed steels but to a degree<br />
<strong>in</strong>termediate between those of rimmed and semi-killed steels.<br />
• A deoxidizer may be added to effect a controlled runn<strong>in</strong>g action when<br />
<strong>the</strong> steel is cast. <strong>the</strong> gas entrapped dur<strong>in</strong>g solidification is <strong>in</strong> excess of<br />
that needed to counteract normal shr<strong>in</strong>kage, result<strong>in</strong>g <strong>in</strong> a tendency for<br />
<strong>the</strong> steel to rise <strong>in</strong> <strong>the</strong> mould.<br />
• The capp<strong>in</strong>g operation caused <strong>the</strong> steel to solidify faster, <strong>the</strong>reby<br />
limit<strong>in</strong>g <strong>the</strong> time of gas evolution, and prevents <strong>the</strong> formation of an<br />
excessive number of gas voids with<strong>in</strong> <strong>the</strong> <strong>in</strong>got.<br />
• Capped steel is generally cast <strong>in</strong> bottle-top moulds us<strong>in</strong>g a heavy metal<br />
cap.<br />
• Capped steel may also be cast <strong>in</strong> open-top moulds, by add<strong>in</strong>g alum<strong>in</strong>um<br />
or ferro-silicon on <strong>the</strong> top of molten steel, to cause <strong>the</strong> steel on <strong>the</strong><br />
surface to lie quietly and solidify rapidly.
4) Rimmed Steel 沸 腾 钢 , 不 脱 氧 钢 :<br />
• In rimmed steel, <strong>the</strong> aim is to produce a clean surface low <strong>in</strong> carbon<br />
content. Rimmed steel is also known as draw<strong>in</strong>g quality steel.<br />
• The typical structure results for a marked gas evolution dur<strong>in</strong>g solidification<br />
of outer rim.<br />
• They exhibit greatest difference <strong>in</strong> chemical composition across sections<br />
and from top to bottom of <strong>the</strong> <strong>in</strong>got.<br />
• They have an outer rim that is lower <strong>in</strong> carbon, phosphorus, and sulphur<br />
than <strong>the</strong> average composition of <strong>the</strong> whole <strong>in</strong>got and an <strong>in</strong>ner portion or<br />
core that is higher <strong>the</strong> average <strong>in</strong> those elements.<br />
• In rimm<strong>in</strong>g, <strong>the</strong> steel is partially deoxidized. Carbon content is less than<br />
0.25% and manganese content is less than 0.6%.<br />
• They do not reta<strong>in</strong> any significant percentage of highly oxidizable elements<br />
such as Alum<strong>in</strong>um, silicon or titanium.<br />
• A wide variety of steels for deep draw<strong>in</strong>g is made by <strong>the</strong> rimm<strong>in</strong>g process,<br />
especially where ease of form<strong>in</strong>g and surface f<strong>in</strong>ish are major<br />
considerations.<br />
• These steel are, <strong>the</strong>refore ideal for roll<strong>in</strong>g, large number of applications,<br />
and is adapted to cold-bend<strong>in</strong>g, cold-form<strong>in</strong>g and cold header applications.
应 变 时 效 学 习 重 点 :<br />
1. 中 等 温 度 现 象 –?°F to ?°F,<br />
2. 受 感 材 质 : 含 有 高 成 分 的 关 键 杂 质 元 素 的 转 炉 或 平 炉 炼 钢 法 , 未 经 过 热 处<br />
理 冷 加 工 件 . 粗 晶 粒 钢 .<br />
3. 受 感 设 备 : 高 厚 度 非 热 处 理 受 感 材 质 设 备 .<br />
4. 碱 性 氧 气 转 炉 炼 钢 法 , 铝 镇 静 钢 , 细 晶 粒 实 践 钢 不 受 影 响 .<br />
5. 蓝 脆 性 为 别 名 .<br />
6. 非 API 510/570 考 试 题 非 API 510/570 考 试 题
4.2.5 885°F (475°C) embrittlement<br />
885°F 脆 化 - 铁 素 体 不 锈 钢 / 双 相 钢<br />
( 不 是 API510/570 考 试 项 )
885°F (475°C) embrittlement<br />
600°F~ 1000°F
Graphitisation<br />
Spheroidization<br />
Tempered Embrittlement<br />
Stra<strong>in</strong> Ag<strong>in</strong>g<br />
885°F embrittlement<br />
800°F for C Steel<br />
875°F for C ½ Mo Steel<br />
850 o F ~ 1400 o F<br />
650°F~ 1070°F<br />
Intermediate temperature<br />
600°F~ 1000°F<br />
Pla<strong>in</strong> carbon steel<br />
Pla<strong>in</strong> carbon + Low alloy steel<br />
up to 9% Cr<br />
2 ¼ Cr-1Mo low alloy steel, 3Cr-<br />
1Mo (lesser extent), & HSLA<br />
Cr-Mo-V rotor steels<br />
pre-1980’s carbon steels with a<br />
large gra<strong>in</strong> size and C-0.5 Mo<br />
300*, 400 & Duplex SS<br />
conta<strong>in</strong><strong>in</strong>g ferrite phases<br />
受 影 响 的 材 质 : 含 铁 素 土 的 不 锈 钢 .<br />
* 锻 与 铸 件 奥 氏 体 不 锈 钢 .
4.2.5 885°F (475°C) Embrittlement<br />
4.2.5.1 Description of <strong>Damage</strong><br />
• 885°F (475°C) embrittlement is a loss <strong>in</strong> toughness due to a metallurgical<br />
change that can occur <strong>in</strong> sta<strong>in</strong>less steel conta<strong>in</strong><strong>in</strong>g a ferrite phase, as a<br />
result of exposure <strong>in</strong> <strong>the</strong> temperature range 600°F~1000°F (316°C to<br />
540°C).<br />
4.2.5.2 Affected Materials<br />
a) 400 Series SS- ferritic & martensitic<br />
(e.g., 405, 409, 410, 410S, 430, and 446).<br />
b) Duplex sta<strong>in</strong>less steels such as Alloys 2205, 2304, and 2507.<br />
c) Wrought and cast 300 Series SS conta<strong>in</strong><strong>in</strong>g ferrite, particularly welds and<br />
weld overlay.<br />
高 温 现 象 : 600°F to 1000°F<br />
含 有 铁 素 体 相 不 锈 钢 ( 铁 素 体 / 马 氏 体 / 双 相 / 奥 氏 体 - 全 包 含 ) 由 于 冶 金 的 变 化 韧<br />
性 的 损 失 现 象 .
885°F (475°C) embrittlement<br />
Embrittlement of sta<strong>in</strong>less steels conta<strong>in</strong><strong>in</strong>g ferrite phase upon extended<br />
exposure to temperatures between 730°F and 930°F (400°C and 510°C ).<br />
This type of embrittlement is caused by f<strong>in</strong>e, chromium-rich precipitates that<br />
segregate at gra<strong>in</strong> boundaries: time at temperature directly <strong>in</strong>fluences <strong>the</strong><br />
amount of segregation. Gra<strong>in</strong>-boundary segregation of <strong>the</strong> chromium-rich<br />
precipitates <strong>in</strong>creases strength and hardness, decreases ductility and<br />
toughness, and changes corrosion resistance. This type of embrittlement<br />
can be reversed by heat<strong>in</strong>g above <strong>the</strong> precipitation range.<br />
885°F 脆 化 , 这 种 类 型 的 脆 化 是 由 于 富 含 铬 的 析 出 物 在 晶 界 处 偏 析 出 . 晶 界 偏 析<br />
的 富 含 铬 的 析 出 增 加 强 度 和 硬 度 , 降 低 塑 性 和 韧 性 和 耐 腐 蚀 变 化 ( 减 弱 ). 这 种 脆<br />
化 现 象 能 在 高 于 析 出 温 度 热 处 理 逆 转 恢 复 .<br />
http://www.keytometals.com/page.aspx?ID=CheckArticle&site=kts&LN=CN&NM=102
• Most ref<strong>in</strong><strong>in</strong>g companies limit <strong>the</strong> use of ferritic sta<strong>in</strong>less steels to nonpressure<br />
boundary applications because of this damage mechanism.<br />
• 885°F embrittlement is a metallurgical change that is not readily apparent<br />
with metallography but can be confirmed through bend or impact test<strong>in</strong>g<br />
(Figure 4-6).
• The existence of 885°F embrittlement can be identified by an <strong>in</strong>crease <strong>in</strong><br />
hardness <strong>in</strong> affected areas. Failure dur<strong>in</strong>g bend test<strong>in</strong>g or impact test<strong>in</strong>g of<br />
samples removed from service is <strong>the</strong> most positive <strong>in</strong>dicator of 885°F<br />
embrittlement.<br />
• 885°F embrittlement is reversible by heat treatment to dissolve precipitates,<br />
followed by rapid cool<strong>in</strong>g. The de-embrittl<strong>in</strong>g heat treatment temperature is<br />
typically 1100°F (593°C) or higher and may not be practical for many<br />
equipment items. If <strong>the</strong> de-embrittled component is exposed to <strong>the</strong> same<br />
service conditions it will re-embrittle faster than it did <strong>in</strong>itially.
4.2.5.3 Critical Factors 关 键 因 素<br />
a) The alloy composition, particularly chromium content, amount of ferrite<br />
phase, and operat<strong>in</strong>g temperature are critical factors.<br />
铬 , 铁 素 体 相 的 数 量 和 操 作 温 度<br />
b) Increas<strong>in</strong>g amounts of ferrite phase <strong>in</strong>crease susceptibility to damage<br />
when operat<strong>in</strong>g <strong>in</strong> <strong>the</strong> high temperature range of concern. A dramatic<br />
<strong>in</strong>crease <strong>in</strong> <strong>the</strong> ductile-to-brittle transition temperature will occur.<br />
越 来 越 多 的 铁 素 体 相 的 增 加 损 伤 的 易 感 性 ( 韧 脆 转 变 温 度 显 著 提 高 )<br />
c) A primary consideration is operat<strong>in</strong>g time at temperature with<strong>in</strong> <strong>the</strong> critical<br />
temperature range. <strong>Damage</strong> is cumulative and results from <strong>the</strong><br />
precipitation of an embrittl<strong>in</strong>g <strong>in</strong>termetallic phase that occurs most readily<br />
at approximately 885°F (475°C). Additional time is required to reach<br />
maximum embrittlement at temperatures above or below 885°F (475°C).<br />
For example, many thousands of hours may be required to cause<br />
embrittlement at 600°F (316°C). 损 伤 是 因 在 受 感 温 度 操 作 时 , 金 属 间 项<br />
(<strong>in</strong>termetallic phase) 的 溢 出 / 沉 淀 在 晶 间 导 致 的 .
d) S<strong>in</strong>ce 885°F embrittlement can occur <strong>in</strong> a relatively short period of time, it<br />
is often assumed that susceptible materials that have been exposed to<br />
temperatures <strong>in</strong> <strong>the</strong> 700°F to 1000°F (371°C to 538°C) range are affected.<br />
受 感 温 度 一 般 上 定 义 为 700°F 至 1000°F 之 间<br />
e) The effect on toughness is not pronounced at <strong>the</strong> operat<strong>in</strong>g temperature,<br />
but is significant at lower temperatures experienced dur<strong>in</strong>g plant<br />
shutdowns, startups or upsets. 对 韧 性 的 影 响 体 现 在 较 低 于 操 作 温 度 例 如 在<br />
停 机 , 启 动 和 颠 覆 状 态 时 .<br />
f) Embrittlement can result from temper<strong>in</strong>g at higher temperatures or by<br />
hold<strong>in</strong>g with<strong>in</strong> or cool<strong>in</strong>g through <strong>the</strong> transformation range.<br />
在 受 感 温 度 回 火 热 处 理 或 当 冷 却 时 在 受 感 ( 转 变 ) 温 度 停 留 会 导 致 885°F 脆 化 .
Fig. 2—Microstructure of solution-annealed 304LN sta<strong>in</strong>less steel
Fig. 3—Oxalic acid etched microstructures of 304LN sta<strong>in</strong>less steel sensitized for (a)<br />
1 h, (b) 25 h, (c) 50 h, and (d) 100 h.
4.2.5.7 Inspection and Monitor<strong>in</strong>g<br />
a) Impact or bend test<strong>in</strong>g of samples removed from service is <strong>the</strong> most positive<br />
<strong>in</strong>dicator of a problem.<br />
b) Most cases of embrittlement are found <strong>in</strong> <strong>the</strong> form of crack<strong>in</strong>g dur<strong>in</strong>g<br />
turnarounds, or dur<strong>in</strong>g startup or shutdown when <strong>the</strong> material is below about<br />
200°F (93°C) and <strong>the</strong> effects of embrittlement are most detrimental.<br />
c) An <strong>in</strong>crease <strong>in</strong> hardness is ano<strong>the</strong>r method of evaluat<strong>in</strong>g 885°F<br />
embrittlement.
Impact energy and br<strong>in</strong>ell hardness as function of time exposure qt 475°C<br />
475 o C Embrittlement <strong>in</strong> a Duplex Sta<strong>in</strong>less Steel UNS S31803
475 o C Embrittlement <strong>in</strong> a Duplex Sta<strong>in</strong>less Steel UNS S31803<br />
http://www.scielo.br/scielo.php?pid=S1516-14392001000400003&script=sci_arttext
http://www.sciencedirect.com/science/article/pii/S0921509309000197
• 885°F (475°C) Embrittlement of sta<strong>in</strong>less steels <strong>in</strong> alloys conta<strong>in</strong><strong>in</strong>g<br />
a ferrite phase (Ferritic/Martensitic/Duplex sta<strong>in</strong>less steel and ferrite<br />
phases <strong>in</strong> austenitic sta<strong>in</strong>less steel e.g. weld areas) 影 响 材 质 : 含 铁 素<br />
体 的 不 锈 钢<br />
• Gra<strong>in</strong>-boundary segregation of <strong>the</strong> chromium-rich precipitates<br />
<strong>in</strong>creases strength and hardness, decreases ductility and toughness,<br />
and changes corrosion resistance (lower). 含 富 铬 金 属 间<br />
(<strong>in</strong>termetallic) 在 晶 间 溢 出 导 致 脆 化 .<br />
• This type of embrittlement can be reversed by heat<strong>in</strong>g above <strong>the</strong><br />
precipitation range. 可 以 通 过 加 热 逆 转 恢 复<br />
• Impact test<strong>in</strong>g/bend test & hardness test<strong>in</strong>g used to evaluate<br />
susceptibility. 冲 击 试 验 , 弯 曲 试 验 , 硬 度 试 验 作 为 易 感 性 的 评 估 .<br />
• Restrict <strong>the</strong> used of ferritic steel to non-pressure boundary application.<br />
限 制 铁 素 体 不 锈 钢 用 于 非 受 压 用 途 .
4.2.6 Sigma-Phase Embrittlement<br />
“ 西 格 玛 ” 相 脆 化<br />
( 不 是 API510/570 考 试 项 )
Sigma-Phase Embrittlement<br />
1000 o F~1700 o F
885°F embrittlement<br />
Sigma phase embrittlement<br />
600°F~ 1000°F<br />
1000°F~ 1700°F<br />
300*, 400 & Duplex SS<br />
conta<strong>in</strong><strong>in</strong>g ferrite phase<br />
300, 400 & Duplex SS<br />
conta<strong>in</strong><strong>in</strong>g ferrite phases<br />
受 影 响 的 材 质 : 含 铁 素 体 的 不 锈 钢 ,<br />
* 锻 与 铸 件 奥 氏 体 不 锈 钢
4.2.6 Sigma Phase Embrittlement<br />
4.2.6.1 Description of <strong>Damage</strong><br />
Formation of a metallurgical phase known as sigma phase can result <strong>in</strong> a loss<br />
of fracture toughness <strong>in</strong> some sta<strong>in</strong>less steels as a result of high<br />
temperature exposure.<br />
4.2.6.2 Affected Materials<br />
a) 300 Series SS wrought metals, weld metal, and cast<strong>in</strong>gs. Cast 300 Series<br />
SS <strong>in</strong>clud<strong>in</strong>g <strong>the</strong> HK and HP alloys are especially susceptible to sigma<br />
formation because of <strong>the</strong>ir high (10-40%) ferrite content.<br />
b) The 400 Series SS and o<strong>the</strong>r ferritic and martensitic SS with 17% Cr or<br />
more are also susceptible (e.g., Types 430 and 440).<br />
c) Duplex sta<strong>in</strong>less steels.<br />
受 影 响 的 材 质 : 铁 素 体 不 锈 钢 , 含 铁 素 体 的 马 氏 体 , 奥 氏 体 不 锈 钢 和 双 相 不 锈 钢 .<br />
脆 化 原 因 : 在 受 感 温 度 下 , 西 格 玛 相 形 成 , 在 铁 素 体 项 析 出 导 致 脆 化 .<br />
http://www.h<strong>in</strong>dawi.com/journals/isrn.metallurgy/2012/732471/
Sigma-Phase Embrittlement 西 格 玛 相 脆 化<br />
Description: Embrittlement of iron-chromium alloys caused by precipitation<br />
at gra<strong>in</strong> boundaries of <strong>the</strong> hard, brittle <strong>in</strong>termetallic sigma phase σ dur<strong>in</strong>g<br />
long periods of exposure to temperatures between approximately 565 o C and<br />
980 o C (1050 o F and 1800 o F). Sigma phase embrittlement results <strong>in</strong> severe<br />
loss <strong>in</strong> toughness and ductility and can make <strong>the</strong> embrittled material<br />
structure susceptible to <strong>in</strong>tergranular corrosion.<br />
在 长 时 间 暴 露 在 温 度 约 565 o C ~ 980 o C (1050 o F ~ 1800 o F) 之 间 , 硬 而 脆 的 金<br />
属 间 化 合 物 (σ 相 ) 在 铁 素 体 晶 界 处 析 出 , σ 相 脆 化 导 致 的 韧 性 和 延 展 性 严 重 损 失<br />
与 导 致 易 受 晶 间 腐 蚀 .<br />
http://www.keytometals.com/page.aspx?ID=CheckArticle&site=kts&LN=CN&NM=102
4.2.6.3 Critical Factors 关 键 因 素<br />
a) Alloy composition, time and temperature are <strong>the</strong> critical factors.<br />
化 学 成 分 , 时 间 , 温 度 都 是 关 键 因 素 .<br />
b) In susceptible alloys, <strong>the</strong> primary factor that affects sigma phase<br />
formation is <strong>the</strong> time of exposure at elevated temperature. 易 感 材 料 ; 时 间<br />
与 经 历 温 度 为 主 要 因 素 .<br />
c) Sigma phase occurs <strong>in</strong> ferritic (Fe-Cr), martensitic (Fe-Cr), austenitic (Fe-<br />
Cr-Ni) and duplex sta<strong>in</strong>less steels when exposed to temperatures <strong>in</strong> <strong>the</strong><br />
range of 1000°F to 1700°F (538°C to 927°C). Embrittlement can result by<br />
hold<strong>in</strong>g with<strong>in</strong> or cool<strong>in</strong>g through <strong>the</strong> transformation range. 铁 素 体 , 马 氏 体 ,<br />
奥 氏 体 , 双 相 钢 , 当 停 留 或 冷 却 途 径 1000°F to 1700°F 温 度 时 , 产 生 σ 相 析 出 .<br />
d) Sigma forms most rapidly from <strong>the</strong> ferrite phase that exists <strong>in</strong> 300 Series<br />
SS and duplex SS weld deposits. It can also form <strong>in</strong> <strong>the</strong> 300 Series SS<br />
base metal (austenite phase) but usually more slowly. σ 相 以 较 快 的 速 度<br />
在 铁 素 体 相 析 出 , 但 也 会 在 奥 氏 体 项 较 慢 的 速 度 析 出 .
e) The 300 Series SS can exhibit about 10% to 15% sigma phase. Cast<br />
austenitic sta<strong>in</strong>less steels can develop considerably more sigma.<br />
σ 相 在 奥 氏 体 不 锈 钢 以 10%~15% 表 现 出 来 , 铸 件 可 能 还 高 .<br />
f) Formation of sigma phase <strong>in</strong> austenitic sta<strong>in</strong>less steels can also occur <strong>in</strong> a<br />
few hours, as evidenced by <strong>the</strong> known tendency for sigma to form if an<br />
austenitic sta<strong>in</strong>less steel is subjected to a post weld heat treatment at<br />
1275°F (690°C).<br />
σ 相 在 奥 氏 体 的 析 出 只 需 几 个 小 时 , 这 脆 化 趋 向 可 以 从 1275°F 焊 接 热 处 理 后 ,<br />
出 现 σ 相 的 到 证 明 .<br />
g) The tensile and yield strength of sigmatized sta<strong>in</strong>less steels <strong>in</strong>creases<br />
slightly compared with solution annealed material. This <strong>in</strong>crease <strong>in</strong><br />
strength is accompanied by a reduction <strong>in</strong> ductility (measured by percent<br />
elongation and reduction <strong>in</strong> area) and a slight <strong>in</strong>crease <strong>in</strong> hardness.<br />
σ 相 脆 化 后 , 抗 拉 强 度 . 硬 度 相 比 固 溶 退 火 材 料 略 有 增 加 , 同 时 , 延 展 性 与 韧 性<br />
减 少 .
Σ(σ)phase<br />
<strong>in</strong> austenitic<br />
matrix<br />
http://www.<strong>in</strong>techo<br />
pen.com/books/met<br />
allurgy-advances<strong>in</strong>-materials-andprocesses/homogeni<br />
zation-heattreatment-toreduce-<strong>the</strong>-failureof-heat-resistantsteel-cast<strong>in</strong>gs
Σ(σ)phase<br />
<strong>in</strong> austenitic<br />
matrix
h) Sta<strong>in</strong>less steels with sigma can normally withstand normal operat<strong>in</strong>g<br />
stresses, but upon cool<strong>in</strong>g to temperatures below about 500°F (260°C)<br />
may show a complete lack of fracture toughness as measured <strong>in</strong> a Charpy<br />
impact test. Laboratory tests of embrittled weld metal have shown a<br />
complete lack of fracture toughness below 1000°F (538°C)<br />
一 般 上 材 料 在 正 常 操 作 温 度 时 不 受 西 格 玛 相 脆 化 影 响 , 但 是 当 材 料 温 度 降 至<br />
500°F 材 料 完 全 缺 乏 韧 性 ( 实 验 室 导 致 完 全 缺 乏 韧 性 的 温 度 可 能 高 至 1000°F).<br />
i) The metallurgical change is actually <strong>the</strong> precipitation of a hard, brittle<br />
<strong>in</strong>termetallic compound that can also render <strong>the</strong> material more susceptible<br />
to <strong>in</strong>tergranular corrosion. The precipitation rate <strong>in</strong>creases with <strong>in</strong>creas<strong>in</strong>g<br />
chromium and molybdenum content. 缺 乏 韧 性 是 因 硬 脆 性 金 属 间 化 合 物 沉<br />
淀 在 晶 间 . 随 着 铬 和 钼 含 量 提 高 , 沉 淀 率 相 应 加 速 .
σ 相 脆 化 - 缺 乏 韧 性 是 因 硬 脆 性 金 属 间 (<strong>in</strong>termetallic-sigma phase) 化 合 物 沉 淀<br />
在 晶 间 . 随 着 铬 和 钼 含 量 提 高 , 沉 淀 率 相 应 加 速 .<br />
Cr% & Mo%<br />
铬 和 钼 含 量 增 加<br />
The precipitation<br />
rate <strong>in</strong>creases<br />
σ 相 析 出 增 加
4.2.6.4 Affected Units or <strong>Equipment</strong><br />
a) Common examples <strong>in</strong>clude sta<strong>in</strong>less steel cyclones, pip<strong>in</strong>g ductwork and<br />
valves <strong>in</strong> high temperature FCC (fluidized catalytic crack<strong>in</strong>g )Regenerator<br />
service.<br />
b) 300 Series SS weld overlays and tube-to-tubesheets attachment welds can<br />
be embrittled dur<strong>in</strong>g PWHT treatment of <strong>the</strong> underly<strong>in</strong>g CrMo base metal.<br />
c) Sta<strong>in</strong>less steel heater tubes are susceptible and can be embrittled.
FCC (fluidized catalytic crack<strong>in</strong>g )<br />
Regenerator service
FCC (fluidized catalytic<br />
crack<strong>in</strong>g )<br />
Regenerator service
FCC (fluidized catalytic crack<strong>in</strong>g )<br />
Regenerator service<br />
http://www.phxequip.com/plant.73/fluid-catalytic-cracker-unit.aspx
FCC (fluidized catalytic crack<strong>in</strong>g )<br />
Regenerator service
FCC (fluidized catalytic crack<strong>in</strong>g )<br />
Regenerator service
Sta<strong>in</strong>less steel heater tubes
Sta<strong>in</strong>less steel heater tubes
tube-to-tubesheets attachment
tube-to-tubesheets attachment
tube-to-tubesheets attachment
tube-to-tubesheets attachment
4.2.6.5 Appearance or Morphology of <strong>Damage</strong> 损 伤 外 观 形 态<br />
a) Sigma phase embrittlement is a metallurgical change that is not readily<br />
apparent, and can only be confirmed through metallographic exam<strong>in</strong>ation<br />
and impact test<strong>in</strong>g. (Tables 4-1 and 4-2) 外 观 上 不 能 体 现 损 伤 , 只 能 依 靠 金 相<br />
分 析 和 冲 击 试 验<br />
b) <strong>Damage</strong> due to sigma phase embrittlement appears <strong>in</strong> <strong>the</strong> form of crack<strong>in</strong>g,<br />
particularly at welds or <strong>in</strong> areas of high restra<strong>in</strong>t. σ 相 脆 化 一 般 上 以 开 裂 的 形<br />
态 出 现 特 别 是 在 焊 缝 与 高 抑 制 区 域 .<br />
c) Tests performed on sigmatized 300 Series SS (304H) samples from FCC<br />
regenerator <strong>in</strong>ternals have shown that even with 10% sigma formation, <strong>the</strong><br />
Charpy impact toughness was 39 ft-lbs (53 J) at 1200°F (649°C).<br />
材 料 : 304H<br />
敏 化 度 : 10%σ 相<br />
温 度 / 冲 击 功 : 649°C / 53J
设 备 : 催 化 裂 化 再 生 器<br />
材 料 : 304H<br />
敏 化 度 : 10%σ 相<br />
温 度 / 冲 击 功 : 649°C / 53J<br />
新 材 料 的 机 械 性 能 :<br />
SPECIFICATION FOR HEAT-RESISTING<br />
CHROMIUM AND CHROMIUM-NICKEL STAINLESS<br />
STEEL PLATE, SHEET, AND STRIP FOR<br />
PRESSURE VESSELS<br />
ASTM SA-240
SPECIFICATION FOR HEAT-RESISTING CHROMIUM AND CHROMIUM-NICKEL STAINLESS STEEL PLATE,<br />
SHEET, AND STRIP FOR PRESSURE VESSELS ASTM SA-240
d) For <strong>the</strong> 10% sigmatized specimen, <strong>the</strong> values ranged from 0% ductility at<br />
room temperature to 100% at 1200°F (649°C). Thus, although <strong>the</strong> impact<br />
toughness is reduced at high temperature, <strong>the</strong> specimens broke <strong>in</strong> a<br />
100% ductile fashion, <strong>in</strong>dicat<strong>in</strong>g that <strong>the</strong> wrought material is still suitable<br />
at operat<strong>in</strong>g temperatures. See Figures 4-7 to 4-11. 敏 化 材 料 的 室 温 延 展<br />
性 或 许 降 至 为 零 . 但 在 1200°F 材 料 的 延 展 性 可 能 不 受 任 何 的 影 响 .<br />
e) Cast austenitic sta<strong>in</strong>less steels typically have high ferrite/sigma content<br />
(up to 40%) and may have very poor high temperature ductility. 铸 造 奥 氏<br />
体 不 锈 钢 敏 化 都 可 能 高 至 40% 的 σ 相 , 这 导 致 很 差 的 高 温 塑 性 / 延 展 性 .
Evaluation of Sigma Phase Embrittlement of a Sta<strong>in</strong>less Steel<br />
304H Fluid Catalyst Crack<strong>in</strong>g Unit Regenerator Cyclone 不 锈 钢<br />
304H 催 化 裂 化 再 生 旋 风 器 σ 相 脆 化 评 价 .<br />
Authors: Ali Y. Al-Kawaie and Abdelhak Kermad<br />
ABSTRACT<br />
Test<strong>in</strong>g was performed on a 304H sta<strong>in</strong>less steel sample removed from a Fluid Catalyst Crack<strong>in</strong>g<br />
Unit (FCCU) regenerator cyclone after 25 years of service to check for sigma phase formation.<br />
Sigma phase is a nonmagnetic <strong>in</strong>ter-metallic phase composed ma<strong>in</strong>ly of iron and chromium (Fe-<br />
Cr), which forms <strong>in</strong> ferritic and austenitic sta<strong>in</strong>less steels dur<strong>in</strong>g exposure at <strong>the</strong> temperature<br />
range 1,050 °F to 1,800 °F (560 °C to 980 °C), caus<strong>in</strong>g loss of ductility and toughness. Crack<strong>in</strong>g<br />
may also occur if <strong>the</strong> component was impact-loaded or excessively stressed dur<strong>in</strong>g shutdown or<br />
ma<strong>in</strong>tenance work. This article discusses <strong>the</strong> effect of sigma phase embrittlement on <strong>the</strong> FCCU<br />
regenerator cyclone after extended high temperature service.<br />
http://www.saudiaramco.com/content/dam/Publications/Journa<br />
l%20of%20Technology/Spr<strong>in</strong>g2011/Art%2012%20-<br />
%20JOT%20Internet.pdf
Table 2. Impact test<strong>in</strong>g (Test Method: ASTM E23)<br />
Table 3. Micro-hardness<br />
test<strong>in</strong>g. Test load: 200 g,<br />
Calibration Block Hardness:<br />
256 + 10 HV, Measured<br />
Hardness of <strong>the</strong> calibration<br />
block: 258 VHN.
Fig. 1. Cyclone<br />
sample, as received.
Fig. 2. Micrograph<br />
show<strong>in</strong>g carburized<br />
layer at <strong>the</strong> outer (top)<br />
surface, 100x (As<br />
received).
Note: solution anneal<strong>in</strong>g at 1,066 °C for four hours, followed by a water<br />
quench before test<strong>in</strong>g.<br />
Fig. 3. Micrograph<br />
show<strong>in</strong>g <strong>the</strong><br />
microstructure at <strong>the</strong><br />
outer (top) surface,<br />
100x (Heat treaded).
Fig. 4. Micrograph<br />
show<strong>in</strong>g sigma<br />
formation at <strong>the</strong> center<br />
of <strong>the</strong> sample.<br />
Estimated volume<br />
fraction 7%, 100x (As<br />
received).
Note: solution anneal<strong>in</strong>g at 1,066 °C for four hours, followed by a water<br />
quench before test<strong>in</strong>g.<br />
Fig. 5. Micrograph<br />
show<strong>in</strong>g <strong>the</strong><br />
microstructure at <strong>the</strong><br />
center of <strong>the</strong> heat<br />
treated sample, 100x<br />
(Heat treated).
Fig. 6. Micrograph<br />
show<strong>in</strong>g sigma phase<br />
at <strong>the</strong> <strong>in</strong>ner (bottom)<br />
surface of <strong>the</strong> orig<strong>in</strong>al<br />
sample, 100x (As<br />
received).
Note: solution anneal<strong>in</strong>g at 1,066 °C for four hours, followed by a water<br />
quench before test<strong>in</strong>g.<br />
Fig. 7. Micrograph<br />
show<strong>in</strong>g <strong>the</strong><br />
microstructure at <strong>the</strong><br />
<strong>in</strong>ner surface of <strong>the</strong><br />
heat treated sample,<br />
100x (Heat treated).
Fig. 8a. SEM fractography show<strong>in</strong>g <strong>the</strong> brittle fracture surface (Top - As received)
Fig. 8b. SEM fractography show<strong>in</strong>g <strong>the</strong> ductile fracture (Bottom - Heat treated) of <strong>the</strong><br />
impact tested samples.
4.2.6.6 Prevention / Mitigation<br />
a) The best way to prevent sigma phase embrittlement is to use alloys that are<br />
resistant to sigma formation or to avoid expos<strong>in</strong>g <strong>the</strong> material to <strong>the</strong><br />
embrittl<strong>in</strong>g range. 最 好 的 预 防 方 法 是 不 用 易 敏 材 料 与 避 免 使 材 料 暴 露 在 脆 化<br />
温 度 范 围 作 业 ( 这 牵 涉 到 设 定 合 适 的 IOW)<br />
b) The lack of fracture ductility at room temperature <strong>in</strong>dicates that care should<br />
be taken to avoid application of high stresses to sigmatized materials dur<strong>in</strong>g<br />
shutdown, as a brittle fracture could result. 室 温 断 裂 韧 性 不 足 是 σ 相 脆 化 损<br />
伤 机 理 的 特 点 . 这 显 著 地 影 响 设 备 在 启 动 , 关 断 与 瞬 态 状 态 的 使 用 ; 在 设 备 处 于<br />
低 温 状 态 时 避 免 设 备 受 到 高 应 力 ( 设 备 随 着 温 度 提 高 增 加 设 备 受 压 ).*<br />
c) The 300 Series SS can be de-sigmatized by solution anneal<strong>in</strong>g at 1950°F<br />
(1066°C) for four hours followed by a water quench. However, this is not<br />
practical for most equipment. σ 相 脆 化 损 伤 可 以 可 以 通 过 加 热 逆 转 恢 复 ( 温 度<br />
1950°F 固 溶 退 火 ). 然 而 这 往 往 并 不 是 在 役 设 备 实 用 的 修 护 方 案 .<br />
Note* 注 意 设 备 压 力 试 验 时 可 能 导 致 低 温 脆 裂 的 危 险 .
d) Sigma phase <strong>in</strong> welds can be m<strong>in</strong>imized by controll<strong>in</strong>g ferrite <strong>in</strong> <strong>the</strong> range of 5% to<br />
9% for Type 347 and somewhat less ferrite for Type 304. The weld metal ferrite<br />
content should be limited to <strong>the</strong> stated maximum to m<strong>in</strong>imize sigma formation<br />
dur<strong>in</strong>g service or fabrication, and must meet <strong>the</strong> stated m<strong>in</strong>imum <strong>in</strong> order to<br />
m<strong>in</strong>imize hot short crack<strong>in</strong>g dur<strong>in</strong>g weld<strong>in</strong>g. 奥 氏 体 不 锈 钢 铁 素 体 含 量 的 控 制 用<br />
于 减 少 σ 相 脆 化 的 形 成 .<br />
e) For sta<strong>in</strong>less steel weld overlay clad Cr-Mo components, <strong>the</strong> exposure time to<br />
PWHT temperatures should be limited wherever possible. 铬 钼 覆 盖 层 焊 后 热 处 理<br />
尽 量 减 少 暴 露 时 间 .
What causes knife-l<strong>in</strong>e attack?<br />
For stabilized sta<strong>in</strong>less steels and alloys, carbon<br />
is bonded with stabilizers (TiC or NbC) and no<br />
weld decay occurs <strong>in</strong> <strong>the</strong> heat affected zone<br />
dur<strong>in</strong>g weld<strong>in</strong>g. In <strong>the</strong> event of a subsequent heat<br />
treatment or weld<strong>in</strong>g (above 1200 o C), however,<br />
first <strong>the</strong> TiC / NbC may dissociated <strong>in</strong>to free Ti,<br />
Nb and C, on cool<strong>in</strong>g precipitation of chromium<br />
carbide Cr 23 C 6 is possible and this leaves <strong>the</strong><br />
narrow band adjacent to <strong>the</strong> fusion l<strong>in</strong>e<br />
susceptible to <strong>in</strong>tergranular corrosion.<br />
What causes weld decay? As <strong>in</strong> <strong>the</strong> case of <strong>in</strong>tergranular corrosion, gra<strong>in</strong> boundary precipitation, notably<br />
chromium carbides <strong>in</strong> non-stabilized sta<strong>in</strong>less steels, is a well recognized and accepted mechanism of weld<br />
decay. In this case, <strong>the</strong> precipitation of chromium carbides is <strong>in</strong>duced by <strong>the</strong> weld<strong>in</strong>g operation when <strong>the</strong><br />
heat affected zone (HAZ) experiences a particular temperature range (550 o C~850 o C). The precipitation of<br />
chromium carbides consumed <strong>the</strong> alloy<strong>in</strong>g element - chromium from a narrow band along <strong>the</strong> gra<strong>in</strong><br />
boundary and this makes <strong>the</strong> zone anodic to <strong>the</strong> unaffected gra<strong>in</strong>s. The chromium depleted zone becomes <strong>the</strong><br />
preferential path for corrosion attack or crack propagation if under tensile stress.
Anodic site
4.2.6.7 Inspection and Monitor<strong>in</strong>g 检 验 与 监 测<br />
a) Physical test<strong>in</strong>g of samples removed from service is <strong>the</strong> most positive<br />
<strong>in</strong>dicator of a problem. 设 备 采 样 机 械 试 验 时 最 好 的 方 法 确 认 损 伤 机 制 .<br />
b) Most cases of embrittlement are found <strong>in</strong> <strong>the</strong> form of crack<strong>in</strong>g <strong>in</strong> both<br />
wrought and cast (welded) metals dur<strong>in</strong>g turnarounds, or dur<strong>in</strong>g startup or<br />
shutdown when <strong>the</strong> material is below about 500°F (260°C) and <strong>the</strong> effects<br />
of embrittlement are most pronounced. σ 相 脆 化 开 裂 失 效 模 式 一 般 出 现 于 设<br />
备 温 度 处 于 低 于 500°F (260°C) 状 态 例 如 当 设 备 周 转 , 启 动 , 关 断 时 .<br />
4.2.6.8 Related <strong>Mechanisms</strong> 相 关 机 制<br />
Not applicable. 不 适 用
Figure 10: Shaeffler diagram show<strong>in</strong>g <strong>the</strong> embrittlement region of <strong>the</strong>σphase [33].<br />
http://www.h<strong>in</strong>dawi.com/journals/isrn.metallurgy/2012/732471/
http://www.metalconsult.com/failure-analysis-furnace-tubes.html
http://www.metalconsult.com/failure-analysis-furnace-tubes.html
http://www.metalconsult.com/failure-analysis-furnace-tubes.html
http://www.metallograf.de/start-eng.htm?/untersuchungen-eng/sigmaphase/sigmaphase.htm
http://www.<strong>in</strong>dustrialheat<strong>in</strong>g.com/articles/90371-sigma-phase-embrittlement<br />
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762009000300017
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762009000300017
Table 4: Chemical composition of ferrite austenite and sigma phases at 900 o C
Polish<strong>in</strong>g mark<strong>in</strong>gs
Improperly etched specimen show<strong>in</strong>g little or no sign of sigma phase
NaOH etched
Oxalic acid etched-<br />
Duplex SS
Sigma-phase embrittlement<br />
• 高 温 现 象 :1000 o F~1700 o F<br />
• 影 响 材 质 : 铁 铬 合 金<br />
• 原 理 :σ 相 脆 化 损 伤 机 理 : 是 当 铁 铬 合 金 暴 露 在 高 温 下 , 硬 , 脆 性 的 σ 相 金 属 间<br />
化 合 物 晶 界 沉 淀 引 起 的 脆 性 现 象 .<br />
• 解 决 方 法 : σ 相 脆 化 损 伤 可 以 可 以 通 过 加 热 逆 转 恢 复 ( 温 度 1950°F 固 溶 退 火 ).<br />
然 而 这 往 往 并 不 是 在 役 设 备 实 用 的 修 护 方 案 .<br />
• 非 API 510/570 考 试 项
4.2.7 Brittle Fracture<br />
脆 性 破 裂<br />
API 510/570 考 试 学 习 科 目<br />
API510/570-Exam
Brittle Fracture<br />
Below DTBTT<br />
DTBT: Ductile to brittle<br />
transition temperature.<br />
API510/570-Exam
No shear lip, little micro void coalescence, little deformation<br />
API510/570-Exam
API510/570-Exam<br />
4.2.7 Brittle Fracture 脆 性 断 裂<br />
4.2.7.1 Description of <strong>Damage</strong> 损 伤 描 述<br />
Brittle fracture is <strong>the</strong> sudden rapid fracture under stress (residual or applied)<br />
where <strong>the</strong> material exhibits little or no evidence of ductility or plastic<br />
deformation. 脆 性 断 裂 - 在 应 力 ( 残 余 或 应 用 ) 作 用 下 突 然 快 速 断 裂 . 材 料 表 现 出 很<br />
少 的 延 展 性 , 塑 性 变 形 .<br />
4.2.7.2 Affected Materials 受 影 响 材 质<br />
Carbon steels and low alloy steels are of prime concern, particularly older<br />
steels. 400 Series SS are also susceptible. 受 影 响 的 材 质 有 ; 碳 钢 , 低 合 金 钢 与<br />
铁 素 体 / 马 氏 体 不 锈 钢<br />
Affected Materials Ferritic/Martensitic STEELS 只 对 铁 素 体 / 马 氏 体 钢 材 影 响
API510/570-Exam<br />
4.2.7.3 Critical Factors 关 键 因 素<br />
a) When <strong>the</strong> critical comb<strong>in</strong>ation of three factors is reached, brittle fracture can<br />
occur:<br />
1. The materials’ fracture toughness (resistance to crack like flaws) as<br />
measured <strong>in</strong> a Charpy impact test; 断 裂 韧 性<br />
2. The size, shape and stress concentration effect of a flaw;<br />
应 力 的 形 状 与 大 小<br />
3. The amount of residual and applied stresses on <strong>the</strong> flaw.<br />
残 余 或 外 加 应 力<br />
b) Susceptibility to brittle fracture may be <strong>in</strong>creased by <strong>the</strong> presence of<br />
embrittl<strong>in</strong>g phases. 晶 体 脆 化 相 存 在 会 增 加 脆 裂 易 感 性<br />
c) Steel cleanl<strong>in</strong>ess and gra<strong>in</strong> size have a significant <strong>in</strong>fluence on toughness<br />
and resistance to brittle fracture. 钢 的 纯 净 度 和 晶 粒 大 小 显 著 地 影 响 材 料 韧 性<br />
和 断 裂 抗 拒 能 力 .
API510/570-Exam<br />
d) Thicker material sections also have a lower resistance to brittle fracture<br />
due to higher constra<strong>in</strong>t which <strong>in</strong>creases triaxial stresses at <strong>the</strong> crack tip.<br />
较 厚 的 材 料 因 更 高 的 应 力 约 束 , 增 加 了 在 裂 纹 尖 端 的 三 轴 应 力 ; 导 致 较 低 的 断<br />
裂 阻 力<br />
d) In most cases, brittle fracture occurs only at temperatures below <strong>the</strong><br />
Charpy impact transition temperature (or ductile-to-brittle transition<br />
temperature), <strong>the</strong> po<strong>in</strong>t at which <strong>the</strong> toughness of <strong>the</strong> material drops off<br />
sharply. 一 般 上 脆 裂 发 生 在 低 于 韧 脆 转 变 温 度 .
API510/570-Exam<br />
Def<strong>in</strong>ition of Brittle Fracture 脆 性 断 裂 定 义<br />
a steel member may experience a brittle fracture. Three basic factors contribute to a<br />
brittle-cleavage type of fracture. They are;<br />
• a triaxial state of stress,<br />
• a low temperature, and<br />
• a high stra<strong>in</strong> rate or rapid rate of load<strong>in</strong>g.<br />
All <strong>the</strong>se factors need not be present. Crack often propagates by cleavage –<br />
break<strong>in</strong>g of atomic bonds along specific crystallographic planes (cleavage planes),<br />
propagate rapidly without fur<strong>the</strong>r <strong>in</strong>crease <strong>in</strong> applied stress (applied or residual)<br />
with little <strong>in</strong>dication of plastic deformation.<br />
In contrast, a ductile fracture occurs ma<strong>in</strong>ly by shear, usually preceded by<br />
considerable plastic deformation.
API510/570-Exam
API510/570-Exam
API510/570-Exam
API510/570-Exam<br />
Figure 7: The fracture exam<strong>in</strong>ation us<strong>in</strong>g a SEM on C1 and C2 revealed features<br />
typical of transgranular fracture (left and middle) and signatures of <strong>in</strong>tergranular<br />
crack<strong>in</strong>g (left and right). The presence of both <strong>in</strong>tergranular and transgranular features<br />
<strong>in</strong>dicates a mixed-mode fracture morphology.<br />
http://www.drill<strong>in</strong>gcontractor.org/tubular-fractur<strong>in</strong>g-p<strong>in</strong>po<strong>in</strong>t<strong>in</strong>g-<strong>the</strong>-cause-14544
API510/570-Exam<br />
In Case 2 from Oklahoma, <strong>the</strong> p<strong>in</strong> connection twisted off while mak<strong>in</strong>g up<br />
<strong>the</strong> p<strong>in</strong> connection of a saver sub.<br />
http://www.drill<strong>in</strong>gcontractor.org/tubular-fractur<strong>in</strong>g-p<strong>in</strong>po<strong>in</strong>t<strong>in</strong>g-<strong>the</strong>-cause-14544
Figure 4: The fracture on <strong>the</strong> Case 1 sub showed a gra<strong>in</strong>y texture and “chevron<br />
marks” that po<strong>in</strong>t toward <strong>the</strong> <strong>in</strong>itiation site, which is typical morphology for brittle<br />
crack<strong>in</strong>g<br />
API510/570-Exam
API510/570-Exam<br />
Figure 5: The fracture<br />
on C3 exhibited a<br />
small fatigue region<br />
that was followed by<br />
brittle fracture. The<br />
fracture surface had a<br />
gra<strong>in</strong>y appearance<br />
and presented a<br />
m<strong>in</strong>uscule shear lip,<br />
which is also typical<br />
of a brittle fracture
API510/570-Exam<br />
Various stages dur<strong>in</strong>g ductile fracture 韧 性 断 裂 are schematically shown <strong>in</strong> above figure.<br />
(a) Neck<strong>in</strong>g, 缩 颈<br />
(b) Cavity formation (microvoid), 微 孔 形 成<br />
(c) Cavity coalescence to form a crack (microvoid coalescence), 微 孔 的 聚 结<br />
(d) Crack propagation, 裂 缝 蔓 延<br />
(e) Fracture (shear fracture). 断 裂 ( 剪 切 断 裂 )
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API510/570-Exam
API510/570-Exam<br />
Brittle fracture of a shaft caused by a<br />
small fatigue crack close to <strong>the</strong> keyway.<br />
The fatigue would be expected to start<br />
at <strong>the</strong> keyway root but actually began at<br />
a surface defect.<br />
http://www.surescreen.com/scientifics/library-of-failures.php
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http://www.wermac.org/misc/pressuretest<strong>in</strong>gfailure2.html<br />
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4.2.7.4 Affected Units or <strong>Equipment</strong> 受 影 响 的 单 元 或 设 备<br />
a) <strong>Equipment</strong> manufactured to <strong>the</strong> ASME Boiler and Pressure Vessel Code,<br />
Section VIII, Division 1, prior to <strong>the</strong> December 1987 Addenda, were made<br />
with limited restrictions on notch toughness for vessels operat<strong>in</strong>g at cold<br />
temperatures. However, this does not mean that all vessels fabricated prior<br />
to this date will be subject to brittle fracture. Many designers specified<br />
supplemental impact tests on equipment that was <strong>in</strong>tended to be <strong>in</strong> cold<br />
service.<br />
ASME 锅 炉 和 压 力 容 器 规 范 1987 年 12 月 前 , 因 为 对 低 温 操 作 设 备 缺 乏 材 料 韧 性<br />
要 求 的 限 制 , 这 些 设 备 可 能 有 脆 裂 的 隐 患 . 然 而 虽 然 不 是 规 范 要 求 , 有 的 设 计 会 因<br />
设 备 低 温 操 作 , 对 材 质 附 加 低 温 冲 击 要 求 .<br />
b) <strong>Equipment</strong> made to <strong>the</strong> same code after this date were subject to<br />
<strong>the</strong> requirements of UCS 66 (impact exemption curves).<br />
引 用 ASME VIII DIV1 UCS 66 对 材 料 冲 击 要 求 宽 松 条 款 的 设 备 .
API510/570-Exam<br />
c) Most processes run at elevated temperature so <strong>the</strong> ma<strong>in</strong> concern is for brittle<br />
fracture dur<strong>in</strong>g startup, shutdown, or hydrotest/tightness test<strong>in</strong>g. Thick wall<br />
equipment on any unit should be considered. 在 设 备 因 周 转 , 启 动 , 停 机 时 低 温<br />
状 态<br />
d) Brittle fracture can also occur dur<strong>in</strong>g an auto-refrigeration event <strong>in</strong> units<br />
process<strong>in</strong>g light hydrocarbons such as methane, ethane/ethylene,<br />
propane/propylene, or butane. This <strong>in</strong>cludes alkylation units, olef<strong>in</strong> units and<br />
polymer plants (polyethylene and polypropylene). Storage bullets/spheres for<br />
light hydrocarbons may also be susceptible. 蒸 发 自 动 冷 却 服 务 .<br />
e) Brittle fracture can occur dur<strong>in</strong>g ambient temperature hydrotest<strong>in</strong>g due to<br />
high stresses and low toughness at <strong>the</strong> test<strong>in</strong>g temperature. 室 温 试 压 时
UCS-66 MATERIALS.<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
The ma<strong>in</strong> material property that API 510 / ASME VIII is concerned<br />
with is that of resistance to brittle fracture. The fundamental issue is<br />
<strong>the</strong>refore whe<strong>the</strong>r a material is suitable for <strong>the</strong> m<strong>in</strong>imum design metal<br />
temperature (MDMT design ) for which a vessel is designed. This topic is<br />
covered by clause UCS-66 of ASME VIII.<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
Steps:<br />
1. UG-20 for exemption on impact test<strong>in</strong>g.<br />
2. UCS-66.<br />
• Identified material Group A,B,C,D.<br />
• Figure UCS-66 to determ<strong>in</strong>e <strong>the</strong> allowable MDMT.<br />
• Figure UCS-66.1 to determ<strong>in</strong>e <strong>the</strong> reduction <strong>in</strong> MDMT based on<br />
co<strong>in</strong>cident ratio.<br />
3. UCS-68(c) to determ<strong>in</strong>e on fur<strong>the</strong>r reduction <strong>in</strong> MDMT.<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
Figure UCS 66.1 Co<strong>in</strong>cident Ratio<br />
The Co<strong>in</strong>cident Ratio is based on a vessel’s extra thickness due to its<br />
design calculations which were based on its Maximum Temperature.<br />
Mean<strong>in</strong>g that; As metal’s temperature <strong>in</strong>creases its strength decreases,<br />
hotter means weaker, <strong>the</strong>refore <strong>the</strong> allowable stress is decreased dur<strong>in</strong>g<br />
calculations result<strong>in</strong>g <strong>in</strong> vessel that requires thicker walls when hot<br />
than when it is operat<strong>in</strong>g at its coldest temperature, <strong>the</strong> MDMT.<br />
This ratio takes credit for <strong>the</strong> extra wall thickness that is present, but<br />
not needed to resist pressure at <strong>the</strong> MDMT. The follow<strong>in</strong>g graphic will<br />
help. Usually when <strong>the</strong>re is a drop <strong>in</strong> temperature <strong>the</strong>re is also a drop<br />
<strong>in</strong> <strong>the</strong> pressure. The two operat<strong>in</strong>g conditions are calculated and <strong>the</strong><br />
Ratio is determ<strong>in</strong>ed. This Ratio is given on <strong>the</strong> exam and you need<br />
only use <strong>the</strong> table to apply this rule.<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
How to use FIG. UCS-66 & FIG. UCS-66.1 to<br />
determ<strong>in</strong>e allowable impact test value<br />
(MDMT allowable )<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
Steps:<br />
1. Determ<strong>in</strong>e material group.<br />
2. Determ<strong>in</strong>e MDMT allowable on<br />
<strong>the</strong> graph.<br />
3. If Design MDMT higher than<br />
MDMT allowable , no test requires.<br />
4. If MDMT allowable is higher than<br />
design MDMT goto FIG. UCS-<br />
66.1<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
Steps:<br />
5. If <strong>the</strong> co<strong>in</strong>cident ratio is 0.70<br />
reduction of 30 o F from <strong>the</strong><br />
MDMT allowable . The revised<br />
MDMT’ allowable = 59 o F.<br />
6. If <strong>the</strong> revised MDMT’<br />
allowable is higher than <strong>the</strong><br />
design MDMT, check on<br />
item 7.<br />
7. If material is P1, UCS-68(c)<br />
If postweld heat treat<strong>in</strong>g is<br />
performed when it is not<br />
o<strong>the</strong>rwise a requirement of<br />
this Division, a reduction of<br />
30 o F. The result<strong>in</strong>g MDMT<br />
allowable may be colder than -<br />
55 o F.<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
Once <strong>the</strong> MDMT allowable had been ascerta<strong>in</strong>ed, fur<strong>the</strong>r reductions are<br />
possible by with<strong>in</strong> -55ºF capp<strong>in</strong>g with exception<br />
1. Low co<strong>in</strong>cident stress ratio<br />
2. postweld heat treat<strong>in</strong>g is performed when it is not o<strong>the</strong>rwise a requirement<br />
of this Division on P1 materials.<br />
-55 o F<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
UCS-66 (b2) For m<strong>in</strong>imum design metal temperatures colder than -55ºF (-<br />
48ºC), impact test<strong>in</strong>g is required for all materials, except as allowed <strong>in</strong> (b)(3)<br />
below and <strong>in</strong> UCS-68(c).<br />
UCS-66 (b3) When <strong>the</strong> m<strong>in</strong>imum design metal temperature is colder than -<br />
55ºF (-48ºC) and no colder than -155ºF (-105ºC), and <strong>the</strong> co<strong>in</strong>cident ratio<br />
def<strong>in</strong>ed <strong>in</strong> Fig. UCS-66.1 is less than or equal to 0.35, impact test<strong>in</strong>g is not<br />
required.<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
UCS-66 (b2) For m<strong>in</strong>imum design metal temperatures colder than -55ºF (-<br />
48ºC), impact test<strong>in</strong>g is required for all materials, except as allowed <strong>in</strong> (b)(3)<br />
below and <strong>in</strong> UCS-68(c).<br />
UCS-68(c) If postweld heat treat<strong>in</strong>g is performed when it is not o<strong>the</strong>rwise a<br />
requirement of this Division, a 30ºF (17ºC) reduction <strong>in</strong> impact test<strong>in</strong>g<br />
exemption temperature may be given to <strong>the</strong> m<strong>in</strong>imum permissible<br />
temperature from Fig. UCS-66 for P-No. 1 materials. The result<strong>in</strong>g<br />
exemption temperature may be colder than -55ºF (-48ºC).<br />
ASME VIII Div.1- Charlie Chong/ Fion Zhang<br />
UCS-66
API510/570-Exam<br />
4.2.7.5 Appearance or Morphology of <strong>Damage</strong><br />
a) Cracks will typically be straight, non-branch<strong>in</strong>g, and largely devoid of any<br />
associated plastic deformation (no shear lip or localized neck<strong>in</strong>g around<br />
<strong>the</strong> crack) (Figure 4-6 to Figure 4-7).<br />
宏 观 : 直 , 不 分 枝 , 并 在 很 大 程 度 上 没 有 任 何 相 关 的 塑 性 变 形 .<br />
b) Microscopically, <strong>the</strong> fracture surface will be composed largely of cleavage,<br />
with limited <strong>in</strong>tergranular crack<strong>in</strong>g and very little microvoid coalescence.<br />
微 观 : 主 要 为 分 裂 ( 少 量 的 沿 晶 开 裂 ?) 与 非 常 小 的 微 孔 聚 合
API510/570-Exam
Crack propagation (cleavage) <strong>in</strong> brittle materials occurs through planar<br />
section<strong>in</strong>g of <strong>the</strong> atomic bonds between <strong>the</strong> atoms at <strong>the</strong> crack tip.<br />
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4.2.7.6 Prevention / Mitigation 预 防 / 缓 解<br />
a) For new equipment, brittle fracture is best prevented by us<strong>in</strong>g materials<br />
specifically designed for low temperature operation <strong>in</strong>clud<strong>in</strong>g upset and autorefrigeration<br />
events. Materials with controlled chemical composition, special heat<br />
treatment and impact test verification may be required. Refer to UCS 66 <strong>in</strong><br />
Section VIII of <strong>the</strong> ASME BPV Code. 低 温 设 备 选 材 合 适 冲 击 要 求 材 料<br />
b) Brittle fracture is an “event” driven damage mechanism. For exist<strong>in</strong>g materials,<br />
where <strong>the</strong> right comb<strong>in</strong>ation of stress, material toughness and flaw size govern <strong>the</strong><br />
probability of <strong>the</strong> event, an eng<strong>in</strong>eer<strong>in</strong>g study can be performed <strong>in</strong> accordance<br />
with API 579-1/ASME FFS-1 , Section 3, Level 1 or 2. 脆 裂 为 “ 事 件 ” 驱 动 的 损<br />
伤 机 制 ( 因 素 : 应 力 , 韧 性 和 裂 纹 尺 寸 ) 应 用 FFS-1 适 用 性 分 析 , 评 估 设 备 完 整 性 .<br />
c) Preventative measures to m<strong>in</strong>imize <strong>the</strong> potential for brittle fracture <strong>in</strong> exist<strong>in</strong>g<br />
equipment are limited to controll<strong>in</strong>g <strong>the</strong> operat<strong>in</strong>g conditions (pressure,<br />
temperature), m<strong>in</strong>imiz<strong>in</strong>g pressure at ambient temperatures dur<strong>in</strong>g startup and<br />
shutdown, and periodic <strong>in</strong>spection at high stress locations. 维 持 IOW 操 作 参 数 ,<br />
周 转 期 间 启 动 , 关 断 设 备 受 压 与 温 度 控 制 与 在 高 应 力 区 的 定 期 检 查 .
API510/570-Exam<br />
d) Some reduction <strong>in</strong> <strong>the</strong> likelihood of a brittle fracture may be achieved by:<br />
缓 解 行 动 有 ;<br />
1. Perform<strong>in</strong>g a post weld heat treatment (PWHT) on <strong>the</strong> vessel if it was not<br />
orig<strong>in</strong>ally done dur<strong>in</strong>g manufactur<strong>in</strong>g; or if <strong>the</strong> vessel has been weld<br />
repaired/modified while <strong>in</strong> service without <strong>the</strong> subsequent PWHT. 焊 后 热<br />
处 理<br />
2. Perform a “warm” pre-stress hydrotest followed by a lower temperature<br />
hydrotest to extend <strong>the</strong> M<strong>in</strong>imum Safe Operat<strong>in</strong>g Temperature (MSOT)<br />
envelope. 周 转 期 间 水 压 试 验 / 温 度 控 制 .
API510/570-Exam<br />
4.2.7.7 Inspection and Monitor<strong>in</strong>g 检 验 与 监 测<br />
a) Inspection is not normally used to mitigate brittle fracture. 检 验 不 能 用 来 缓<br />
解 脆 性 开 裂<br />
b) Susceptible vessels should be <strong>in</strong>spected for pre-exist<strong>in</strong>g flaws/defects. 易<br />
感 容 器 的 存 在 缺 陷 的 监 测
API510/570-Exam<br />
4.2.7.8 Related <strong>Mechanisms</strong> 相 关 机 理<br />
Temper embrittlement (see 4.2.3), stra<strong>in</strong> age embrittlement (see 4.2.4), 885 o F<br />
(475 o C) embrittlement (see4.2.5), titanium hydrid<strong>in</strong>g (see 5.1.3.2) and sigma<br />
embrittlement (see 4.2.6).<br />
脆 性 破 裂 作 为 形 态 定 义 时 , 上 述 损 坏 机 理 , 破 断 形 态 可 以 归 类 为 ” 脆 性 破 裂 ”<br />
Temper embrittlement
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Ductile fracture (non creep type)
Microvoid due to plastid yield<strong>in</strong>g & ductile<br />
fracture (non creep type)
API510/570-Exam
API510/570-Exam<br />
Fur<strong>the</strong>r read<strong>in</strong>g:<br />
http://www.sut.ac.th/eng<strong>in</strong>eer<strong>in</strong>g/metal/pdf/MechMet/14_Brittle%20fracture%20and%20impact%20test<strong>in</strong>g.pdf<br />
http://lecture.civileng<strong>in</strong>eer<strong>in</strong>gx.com/structural-analysis/structural-steel/brittle-fracture/<br />
http://www.keytometals.com/articles/art136.htm<br />
http://people.virg<strong>in</strong>ia.edu/~lz2n/mse209/Chapter8.pdf<br />
http://www.keytometals.com/page.aspx?ID=CheckArticle&site=kts&LN=CN&NM=136<br />
http://www.techtransfer.com/resources/wiki/entry/3645/
API510/570-Exam<br />
Brittle Fracture<br />
• 低 温 现 象 : 室 温 / 低 于 400 o F,<br />
• 影 响 材 质 : 铁 素 体 / 马 氏 体 钢 ,<br />
• 焊 后 热 处 理 作 为 预 防 与 缓 解 方 法 ,<br />
• 周 转 期 间 设 备 处 于 低 温 状 态 时 的 受 压 控 制 (MSOT),<br />
• 应 用 FFS-1 合 适 性 分 析 , 评 估 带 缺 陷 的 设 备 可 用 性 ,<br />
• 导 致 脆 性 开 裂 的 因 素 有 ; (1) 低 韧 性 铁 素 体 钢 材 , (2) 服 务 导 致 脆 化 , 例 如 ; 回 火<br />
脆 化 , 应 变 时 效 脆 性 ,885 o F 脆 化 , 钛 氢 化 , 西 格 玛 的 脆 化 .
4.2.8 Creep & Stress Rupture<br />
蠕 变 和 应 力 断 裂<br />
非 API 510/570 考 试 科 目
Creep & Stress<br />
Rupture<br />
700 o F ~ 1000 o F
Graphitisation<br />
Spheroidization<br />
Tempered Embrittlement<br />
Stra<strong>in</strong> Ag<strong>in</strong>g<br />
885 o F embrittlement<br />
Sigma-Phase<br />
Embrittlement<br />
Brittle Fracture<br />
Creep & stress rupture<br />
800 o F for C Steel<br />
875 o F for C ½ Mo Steel<br />
850 o F ~ 1400 o F<br />
650 o F~ 1070 o F<br />
Intermediate<br />
temperature<br />
600 o F~ 1000 o F<br />
1000 o F~ 1700 o F<br />
Below DTBTT<br />
700 o F ~ 1000 o F<br />
Pla<strong>in</strong> carbon steel<br />
C- ½ Mo<br />
Low alloy steel up to 9% Cr<br />
2 ¼ Cr-1Mo low alloy steel, 3Cr-1Mo (lesser<br />
extent), & HSLA Cr-Mo-V rotor steels<br />
Pre-1980’s C-steels with large gra<strong>in</strong> size and C- ½<br />
Mo<br />
300, 400 & Duplex SS conta<strong>in</strong><strong>in</strong>g ferrite phases<br />
300, 400 & Duplex SS conta<strong>in</strong><strong>in</strong>g ferrite phases<br />
C, C- ½ Mo, 400 SS<br />
All metals and alloys
4.2.8 Creep and Stress Rupture 蠕 变 和 应 力 开 裂<br />
4.2.8.1 Description of <strong>Damage</strong> 描 述<br />
a) At high temperatures, metal components can slowly and cont<strong>in</strong>uously<br />
deform under load below <strong>the</strong> yield stress. This time dependent deformation<br />
of stressed components is known as creep.<br />
b) Deformation leads to damage that may eventually lead to a rupture.<br />
在 高 温 和 载 荷 低 于 屈 服 应 力 下 , 金 属 部 件 缓 慢 , 持 续 下 的 变 形 . 这 变 形 导 致 损 伤 ,<br />
最 终 可 能 破 裂 .<br />
4.2.8.2 Affected Materials 受 影 响 的 材 料<br />
All metals and alloys. 所 有 的 金 属 和 合 金 。
http://www.ejsong.com/mdme/me<br />
mmods/MEM30007A/properties/Pr<br />
operties.html
4.2.8.3 Critical Factors 蠕 变 和 应 力 断 裂 关 键 因 素<br />
a) The rate of creep deformation is a function of <strong>the</strong> material, load, and<br />
temperature. The rate of damage (stra<strong>in</strong> rate) is sensitive to both load and<br />
temperature. Generally, an <strong>in</strong>crease of about 25°F (12°C) or an <strong>in</strong>crease of<br />
15% on stress can cut <strong>the</strong> rema<strong>in</strong><strong>in</strong>g life <strong>in</strong> half or more, depend<strong>in</strong>g on <strong>the</strong><br />
alloy.<br />
影 响 蠕 变 的 因 素 : (1) 材 质 易 感 性 , (2) 负 载 和 (3) 温 度 , 例 子 : 25°F(12°C) 或 15%<br />
应 力 增 加 一 般 上 导 致 使 用 寿 面 减 半 .<br />
b) Table 4-3 lists threshold temperatures above which creep damage is a<br />
concern. If <strong>the</strong> metal temperature exceeds <strong>the</strong>se values, <strong>the</strong>n creep damage<br />
and creep crack<strong>in</strong>g can occur.<br />
表 4-3 列 出 不 同 材 料 的 易 感 温 度
c) The level of creep damage is a function of <strong>the</strong> material and <strong>the</strong> co<strong>in</strong>cident<br />
temperature/stress level at which <strong>the</strong> creep deformation occurs. 蠕 变 破 坏 依<br />
赖 温 度 与 应 力 的 组 合 影 响 .<br />
d) The life of metal components becomes nearly <strong>in</strong>f<strong>in</strong>ite at temperatures below<br />
<strong>the</strong> threshold limit (Table 4-3) even at <strong>the</strong> high stresses near a crack tip.<br />
低 于 易 感 温 度 时 , 甚 至 在 高 应 力 的 使 用 下 , 材 料 几 乎 是 无 限 的 不 受 蠕 变 的 影 响 .<br />
e) The appearance of creep damage with little or no apparent deformation is<br />
often mistakenly referred to as creep embrittlement, but usually <strong>in</strong>dicates<br />
that <strong>the</strong> material has low creep ductility. 不 是 所 有 的 蠕 变 失 效 具 有 明 显 的 外 表<br />
变 形 . 低 延 展 性 蠕 变 在 外 观 上 不 容 易 被 识 别 .
f) Low creep ductility is: 低 延 展 性 蠕 变<br />
1) More severe for higher tensile strength materials and welds. 高 强 材 料<br />
2) More prevalent at <strong>the</strong> lower temperatures <strong>in</strong> <strong>the</strong> creep range, or low<br />
stresses <strong>in</strong> <strong>the</strong> upper creep range. 普 遍 于 (1) 蠕 变 低 温 度 范 围 或 (2) 低 应<br />
力 高 温 度 范 围 .<br />
3) More likely <strong>in</strong> a coarse-gra<strong>in</strong>ed material than a f<strong>in</strong>e-gra<strong>in</strong>ed material.<br />
粗 晶 材 料<br />
4) Not evidenced by a deterioration of ambient temperature properties.<br />
低 温 机 械 性 能 不 显 著 地 退 化 .<br />
5) Promoted by certa<strong>in</strong> carbide types <strong>in</strong> some CrMo steels.<br />
某 些 碳 化 物 促 进 破 坏<br />
g) Increased stress due to loss <strong>in</strong> thickness from corrosion will reduce time to<br />
failure. 腐 蚀 厚 度 损 失 加 剧 蠕 变 破 坏
不 是 所 有 的 蠕 变 失 效 具 有 明 显 的 外 表 变 形 !<br />
低 延 展 性 蠕 变<br />
Is all creep failure associated with apparent deformation?<br />
The appearance of creep damage with little or no apparent deformation is<br />
often mistakenly referred to as creep embrittlement, but usually <strong>in</strong>dicates that<br />
<strong>the</strong> material has low creep ductility. 经 常 被 误 称 蠕 变 脆 化 其 实 是 低 延 展 性 蠕 变
4.2.8.4 Affected Units or <strong>Equipment</strong> 受 影 响 的 设 备<br />
a) Creep damage is found <strong>in</strong> high temperature equipment operat<strong>in</strong>g above<br />
<strong>the</strong> creep range. Heater tubes <strong>in</strong> fired heaters are especially susceptible<br />
as well as tube supports, hangers and o<strong>the</strong>r furnace <strong>in</strong>ternals. 一 切 高 温 设<br />
备 , 特 别 是 加 热 器 的 加 热 管 , 管 支 架 , 吊 架 和 炉 内 附 件 等 .<br />
b) Pip<strong>in</strong>g and equipment, such as hot-wall catalytic reform<strong>in</strong>g reactors and<br />
furnace tubes, hydrogen reform<strong>in</strong>g furnace tubes, hot wall FCC reactors,<br />
FCC ma<strong>in</strong> fractionator and regenerator <strong>in</strong>ternals all operate <strong>in</strong> or near <strong>the</strong><br />
creep range. 催 化 裂 化 反 应 器 的 管 道 , 罐 壁 , 氢 转 化 炉 炉 管 , 炉 管 等 .
c) Low creep ductility failures have occurred <strong>in</strong> weld heat-affected zones<br />
(HAZ) at nozzles and o<strong>the</strong>r high stress areas on catalytic reformer<br />
reactors. Crack<strong>in</strong>g has also been found at long seam welds <strong>in</strong> some high<br />
temperature pip<strong>in</strong>g and <strong>in</strong> reactors on catalytic reformers.<br />
催 化 重 整 反 应 器 焊 缝 与 热 影 响 区<br />
d) Welds jo<strong>in</strong><strong>in</strong>g dissimilar materials (ferritic to austenitic welds) may suffer<br />
creep related damage at high temperatures due to differential <strong>the</strong>rmal<br />
expansion stresses. 异 种 材 料 的 焊 接 接 合 ( 例 如 : 铁 素 体 / 奥 氏 体 ) 经 历 因 热 膨<br />
胀 差 异 导 致 的 应 力 与 高 温 蠕 变 .
4.2.8.6 Prevention / Mitigation 预 防 与 缓 解<br />
a) There is little that <strong>in</strong>spectors or operators can do to prevent this damage<br />
once a susceptible material has been placed <strong>in</strong>to creep service, o<strong>the</strong>r<br />
than to m<strong>in</strong>imize <strong>the</strong> metal temperature, particularly with fired heater tubes.<br />
Avoid<strong>in</strong>g stress concentrators is important dur<strong>in</strong>g design and fabrication.<br />
(1) 温 度 控 制 与 (2) 设 计 时 避 免 应 力 集 中 点 .<br />
b) Low creep ductility can be m<strong>in</strong>imized by <strong>the</strong> careful selection of chemistry<br />
for low alloy materials. Higher post weld heat treatment temperatures may<br />
help m<strong>in</strong>imize creep crack<strong>in</strong>g of materials with low creep ductility such as<br />
1.25Cr-0.5Mo.<br />
低 合 金 钢 的 低 延 性 蠕 变 ; (1) 通 过 焊 后 热 处 理 , (2) 材 料 化 学 成 分 控 制 .
c) Creep damage is not reversible. Once damage or crack<strong>in</strong>g is detected<br />
much of <strong>the</strong> life of <strong>the</strong> component has been used up and typically <strong>the</strong><br />
options are to repair or replace <strong>the</strong> damaged component. Higher PWHT <strong>in</strong><br />
some cases can produce a more creep ductile material with longer life. 蠕<br />
变 损 伤 是 不 可 逆 转<br />
1. <strong>Equipment</strong> – Repair of creep damaged catalytic reformer reactor nozzles<br />
has been successfully accomplished by gr<strong>in</strong>d<strong>in</strong>g out <strong>the</strong> affected area<br />
(mak<strong>in</strong>g sure all <strong>the</strong> damaged metal is removed), re-weld<strong>in</strong>g and careful<br />
blend gr<strong>in</strong>d<strong>in</strong>g to help m<strong>in</strong>imize stress concentration. PWHT temperatures<br />
must be carefully selected and may require a higher PWHT than orig<strong>in</strong>ally<br />
specified.<br />
催 化 重 整 反 应 器 管 口 修 护 例 子 : (1) 磨 出 受 影 响 的 区 域 , (2) 修 补 焊 接 填 充 , (3)<br />
打 磨 平 滑 减 少 应 力 集 中 , (4) 高 于 原 设 计 的 焊 后 热 处 理 .
c2 Fired Heater Tubes 炉 管<br />
• Alloys with improved creep resistance may be required for longer life.<br />
改 进 的 抗 蠕 变 性 合 金 管<br />
• Heaters should be designed and operated to m<strong>in</strong>imize hot spots and<br />
localized overheat<strong>in</strong>g (Figure 4-19).<br />
减 少 热 点 和 局 部 过 热<br />
• Visual <strong>in</strong>spection followed by thickness measurements and or strap<br />
read<strong>in</strong>gs may be required to assess rema<strong>in</strong><strong>in</strong>g life of heater tubes <strong>in</strong><br />
accordance with API 579-1/ASME FFS-1.<br />
目 视 , 捆 扎 法 ( 测 量 外 径 变 化 ) 以 识 别 受 影 响 的 管 道 . 运 用 合 适 性 分 析 法 FFS, 评<br />
估 受 影 响 的 管 道 是 否 能 继 续 的 使 用 .<br />
• M<strong>in</strong>imiz<strong>in</strong>g process side foul<strong>in</strong>g/deposits and fire side deposits/scal<strong>in</strong>g<br />
can maximize tube life.<br />
减 少 工 艺 侧 的 污 垢 / 堆 积 , 火 侧 的 堆 积 / 氧 化 皮 加 厚
4.2.8.7 Inspection and Monitor<strong>in</strong>g 检 验 与 监 测<br />
a) Creep damage with <strong>the</strong> associated microvoid formation, fissur<strong>in</strong>g and<br />
dimensional changes is not effectively found by any one <strong>in</strong>spection<br />
technique. A comb<strong>in</strong>ation of techniques (UT, RT, EC, dimensional<br />
measurements and replication) should be employed. Destructive sampl<strong>in</strong>g<br />
and metallographic exam<strong>in</strong>ation are used to confirm damage. 蠕 变 体 现 为<br />
微 孔 , 裂 隙 与 尺 寸 变 化 . 当 个 无 损 探 伤 方 法 或 许 不 容 易 探 测 到 蠕 变 破 坏 . 综 合<br />
考 虑 运 用 多 种 探 伤 方 法 与 晶 相 模 塑 法 (<strong>in</strong>-situ replication) 或 切 片 晶 相 微 观 观<br />
察 .<br />
b) For pressure vessels, <strong>in</strong>spection should focus on welds of CrMo alloys<br />
operat<strong>in</strong>g <strong>in</strong> <strong>the</strong> creep range. The 1 Cr-0.5Mo and 1.25Cr-0.5Mo materials<br />
are particularly prone to low creep ductility. Most <strong>in</strong>spections are<br />
performed visually and followed by PT or WFMT on several-year <strong>in</strong>tervals.<br />
Angle beam (shear wave) UT can also be employed, although <strong>the</strong> early<br />
stages of creep damage are very difficult to detect. Initial fabrication flaws<br />
should be mapped and documented for future reference. 铬 钼 材 质 特 别 是<br />
焊 缝 区 域 是 检 验 关 注 点 . 多 数 的 检 验 步 骤 为 ; (1) 外 观 目 视 (2) PT/WFMT (2+)<br />
斜 束 剪 切 波 UT. ( 提 防 建 造 缺 陷 导 致 误 判 )
c) Fired heater tubes should be <strong>in</strong>spected for evidence of overheat<strong>in</strong>g,<br />
corrosion, and erosion as follows: 炉 管 检 验<br />
1. Tubes should be VT exam<strong>in</strong>ed for bulg<strong>in</strong>g, blister<strong>in</strong>g, crack<strong>in</strong>g,<br />
sagg<strong>in</strong>g and bow<strong>in</strong>g. 目 视 观 察 ; 鼓 , 起 泡 , 开 裂 和 弯 曲 与 垂 落 .<br />
2. Wall thickness measurements of selected heater tubes should be<br />
made where wall losses are most likely to occur. 厚 度 检 测<br />
3. Tubes should be exam<strong>in</strong>ed for evidence of diametric growth (creep)<br />
with a strap or go/no go gauge, and <strong>in</strong> limited cases by metallography<br />
on <strong>in</strong> place replicas or tube samples. However, metallography on <strong>the</strong><br />
OD of a component may not provide a clear <strong>in</strong>dication of subsurface<br />
damage. 检 测 外 径 变 化 ( 上 下 限 制 测 量 规 ), 现 场 晶 相 模 塑 法 (replica)<br />
4. Retirement criteria based on diametric growth and loss of wall<br />
thickness is highly dependent on <strong>the</strong> tube material and <strong>the</strong> specific<br />
operat<strong>in</strong>g conditions. 基 于 直 径 生 长 和 损 失 的 壁 厚 的 报 废 准 则 很 大 程 度<br />
上 依 赖 于 管 材 与 具 体 操 作 条 件 .
4.2.8.8 Related <strong>Mechanisms</strong> 相 关 机 理<br />
a) Creep damage that occurs as a result of exposure to very high<br />
temperatures is described <strong>in</strong> 4.2.10. (Overheat<strong>in</strong>g stress rupture 过 热 的 应<br />
力 破 裂 )<br />
b) Reheat crack<strong>in</strong>g (see 4.2.19) is a related mechanism found <strong>in</strong> heavy wall<br />
equipment. 再 热 裂 纹 - 厚 壁 的 设 备 发 现 的 相 关 机 理
Figure 4-17 – P<strong>in</strong>ched<br />
Alloy 800H pigtail<br />
opened up creep<br />
fissures on <strong>the</strong> surface.
Figure 4-18 – Creep rupture of an HK40 heater tube.
a<br />
b<br />
Figure 4-19 – Creep Failure of 310 SS Heater Tube Guide Bolt after approximately 7<br />
years service at 1400°F (760°C). a.) Cross-section at 10X, as-polished.
a<br />
b<br />
Figure 4-19 – Creep Failure of 310 SS Heater Tube Guide Bolt after approximately 7 years service<br />
at 1400°F (760°C). b) Voids and <strong>in</strong>tergranular separation characteristic of long term creep, 100X,<br />
etched.
蠕 变 和 应 力 开 裂 学 习 重 点 :<br />
1. 温 度 : 高 温 ,<br />
2. 原 理 : 在 高 温 和 载 荷 低 于 屈 服 应 力 下 , 金 属 部 件 缓 慢 , 持 续 下 的 变 形 . 这 变<br />
形 导 致 损 伤 , 最 终 可 能 破 裂 .<br />
3. 易 感 材 质 : 全 部 工 程 材 料 .<br />
4. 易 感 设 备 : 一 切 高 温 设 备 , 特 别 是 加 热 器 的 加 热 管 , 内 构 件 .<br />
5. 非 API 510/570 考 试 题 非 API 510/570 考 试 题
4.2.9 Thermal Fatigue<br />
热 疲 劳<br />
API510/570-Exam
Thermal Fatigue<br />
Operat<strong>in</strong>g Temp.<br />
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Graphitisation<br />
Spheroidization<br />
Tempered Embrittlement<br />
Stra<strong>in</strong> Ag<strong>in</strong>g<br />
885 o F embrittlement<br />
Sigma-Phase<br />
Embrittlement<br />
Brittle Fracture<br />
Creep & stress rupture<br />
Thermal fatigues<br />
800 o F for C Steel<br />
875 o F for C ½ Mo Steel<br />
850 o F ~ 1400 o F<br />
650 o F~ 1070 o F<br />
Intermediate<br />
temperature<br />
600 o F~ 1000 o F<br />
1000 o F~ 1700 o F<br />
Below DTBTT<br />
700 o F ~ 1000 o F<br />
Operat<strong>in</strong>g temp.<br />
Pla<strong>in</strong> carbon steel<br />
C- ½ Mo<br />
Low alloy steel up to 9% Cr<br />
2 ¼ Cr-1Mo low alloy steel, 3Cr-1Mo (lesser<br />
extent), & HSLA Cr-Mo-V rotor steels<br />
Pre-1980’s C-steels with large gra<strong>in</strong> size and C- ½<br />
Mo<br />
300, 400 & Duplex SS conta<strong>in</strong><strong>in</strong>g ferrite phases<br />
300, 400 & Duplex SS conta<strong>in</strong><strong>in</strong>g ferrite phases<br />
C, C- ½ Mo, 400 SS<br />
All metals and alloys<br />
All metals and alloys
API510/570-Exam<br />
4.2.9 Thermal Fatigue 热 疲 劳<br />
4.2.9.1 Description of <strong>Damage</strong> 损 伤 描 述<br />
Thermal fatigue is <strong>the</strong> result of cyclic stresses caused by variations <strong>in</strong><br />
temperature. <strong>Damage</strong> is <strong>in</strong> <strong>the</strong> form of crack<strong>in</strong>g that may occur anywhere <strong>in</strong> a<br />
metallic component where relative movement or differential expansion is<br />
constra<strong>in</strong>ed, particularly under repeated <strong>the</strong>rmal cycl<strong>in</strong>g.<br />
热 疲 劳 开 裂 是 由 温 度 变 化 引 起 循 环 应 力 引 起 的 开 裂 .<br />
4.2.9.2 Affected Materials 受 影 响 的 材 料<br />
All materials of construction. 所 有 施 工 材 料
API510/570-Exam<br />
4.2.9.3 Critical Factors 关 键 因 素<br />
a) Key factors affect<strong>in</strong>g <strong>the</strong>rmal fatigue are <strong>the</strong> magnitude of <strong>the</strong> temperature<br />
sw<strong>in</strong>g and <strong>the</strong> frequency (number of cycles). 温 度 摆 动 的 幅 度 和 频 率<br />
b) Time to failure is a function of <strong>the</strong> magnitude of <strong>the</strong> stress and <strong>the</strong> number of<br />
cycles and decreases with <strong>in</strong>creas<strong>in</strong>g stress and <strong>in</strong>creas<strong>in</strong>g cycles. 故 障 时 间<br />
有 赖 于 (1) 温 度 摆 动 的 幅 度 (2) 频 率 (3) 应 力 的 大 小<br />
c) Startup and shutdown of equipment <strong>in</strong>crease <strong>the</strong> susceptibility to <strong>the</strong>rmal<br />
fatigue. There is no set limit on temperature sw<strong>in</strong>gs; however, as a practical<br />
rule, crack<strong>in</strong>g may be suspected if <strong>the</strong> temperature sw<strong>in</strong>gs exceeds about<br />
200°F (93°C). 周 转 / 启 动 / 停 机 增 加 热 疲 劳 的 易 感 性 . 作 为 一 个 实 际 的 规 则 大 于<br />
200°F 摆 动 幅 度 作 为 热 疲 劳 损 伤 怀 疑 点 .
API510/570-Exam<br />
d) <strong>Damage</strong> is also promoted by rapid changes <strong>in</strong> surface temperature that<br />
result <strong>in</strong> a <strong>the</strong>rmal gradient through <strong>the</strong> thickness or along <strong>the</strong> length of a<br />
component. For example: cold water on a hot tube (<strong>the</strong>rmal shock); rigid<br />
attachments and a smaller temperature differential; <strong>in</strong>flexibility to<br />
accommodate differential expansion. 促 进 因 素 : 沿 着 管 道 长 度 或 厚 度 的 温 度 偏<br />
差 , 自 由 膨 胀 阻 碍 ( 缺 少 弹 性 的 设 计 )<br />
e) Notches (such as <strong>the</strong> toe of a weld) and sharp corners (such as <strong>the</strong><br />
<strong>in</strong>tersection of a nozzle with a vessel shell) and o<strong>the</strong>r stress concentrations<br />
may serve as <strong>in</strong>itiation sites. 缺 口 - 焊 趾 处 , 尖 锐 点 ( 应 力 集 中 点 ).
API510/570-Exam<br />
4.2.9.4 Affected Units or <strong>Equipment</strong><br />
a) Examples <strong>in</strong>clude <strong>the</strong> mix po<strong>in</strong>ts of hot and cold streams such as hydrogen<br />
mix po<strong>in</strong>ts <strong>in</strong> hydroprocess<strong>in</strong>g units 加 氢 装 置 , and locations where<br />
condensate comes <strong>in</strong> contact with steam systems, such as de-superheat<strong>in</strong>g<br />
or attemporat<strong>in</strong>g equipment 减 温 装 置 (Figures 4-20 and 4-23). 不 同 温 度 流 体<br />
混 合 点 .<br />
b) Thermal fatigue crack<strong>in</strong>g has been a major problem <strong>in</strong> coke drum shells.<br />
Thermal fatigue can also occur on coke drum skirts where stresses are<br />
promoted by a variation <strong>in</strong> temperature between <strong>the</strong> drum and skirt (Figure<br />
4–21 and Figure 4–22). 焦 炭 鼓 裙 边 与 塔 壁 . ( 考 试 题 )<br />
c) In steam generat<strong>in</strong>g equipment, <strong>the</strong> most common locations are at rigid<br />
attachments between neighbor<strong>in</strong>g tubes <strong>in</strong> <strong>the</strong> superheater and reheater.<br />
Slip spacers designed to accommodate relative movement may become<br />
frozen and act as a rigid attachment when plugged with fly ash.<br />
蒸 汽 发 生 装 置 ( 过 热 器 和 再 热 器 管 路 )
Figure 4-20 – Thermal fatigue cracks on <strong>the</strong> <strong>in</strong>side of a heavy wall SS pipe downstream of a<br />
cooler H2 <strong>in</strong>jection <strong>in</strong>to a hot hydrocarbon l<strong>in</strong>e.<br />
API510/570-Exam
Figure 4-21 – Bulg<strong>in</strong>g <strong>in</strong> a skirt of a coke drum.<br />
API510/570-Exam
Figure 4-22 –Thermal fatigue crack<strong>in</strong>g associated with<br />
bulged skirt shown <strong>in</strong> Figure 4-21.<br />
API510/570-Exam
Figure 4-23 – Thermal fatigue of 304L sta<strong>in</strong>less at mix po<strong>in</strong>t <strong>in</strong> <strong>the</strong> BFW preheater<br />
bypass l<strong>in</strong>e around <strong>the</strong> high temperature shift effluent exchanger <strong>in</strong> a hydrogen<br />
reformer. The delta T is 325°F (181°C) at an 8 <strong>in</strong>ch bypass l<strong>in</strong>e ty<strong>in</strong>g <strong>in</strong>to a 14 <strong>in</strong>ch<br />
l<strong>in</strong>e, 3 yrs after startup.<br />
API510/570-Exam
API510/570-Exam<br />
Figure 4-24 – In a carbon steel sample, metallographic section through a <strong>the</strong>rmal fatigue crack<br />
<strong>in</strong>dicates orig<strong>in</strong> at <strong>the</strong> toe of an attachment weld. Mag. 50X, etched.
API510/570-Exam<br />
Figure 4-25 – Older cracks fill with oxide, may stop and restart (note jog part way along <strong>the</strong><br />
crack), and do not necessarily require a change <strong>in</strong> section thickness to <strong>in</strong>itiate <strong>the</strong> crack. Mag.<br />
100X, etched.
API510/570-Exam<br />
d) Tubes <strong>in</strong> <strong>the</strong> high temperature superheater or reheater that penetrate<br />
through <strong>the</strong> cooler water-wall tubes may crack at <strong>the</strong> header connection if<br />
<strong>the</strong> tube is not sufficiently flexible. These cracks are most common at <strong>the</strong><br />
end where <strong>the</strong> expansion of <strong>the</strong> header relative to <strong>the</strong> water-wall will be<br />
greatest. 穿 过 水 冷 冷 却 器 壁 的 过 热 器 , 再 热 器 管 路 .<br />
d) Steam actuated soot blowers may cause <strong>the</strong>rmal fatigue damage if <strong>the</strong> first<br />
steam exit<strong>in</strong>g <strong>the</strong> soot blower nozzle conta<strong>in</strong>s condensate. Rapid cool<strong>in</strong>g of<br />
<strong>the</strong> tube by <strong>the</strong> liquid water will promote this form of damage. Similarly,<br />
water lanc<strong>in</strong>g or water cannon use on water-wall tubes may have <strong>the</strong> same<br />
effect. (1) 蒸 汽 驱 动 的 吹 灰 器 接 触 冷 凝 液 的 热 管 路 , (2) 其 他 接 触 冷 凝 液 的 热 管<br />
路 服 务 .
API510/570-Exam
http://www.slashgear.com/bill-gates-help<strong>in</strong>g-ch<strong>in</strong>a-build-super-safenuclear-reactor-08200894/<br />
API510/570-Exam
API510/570-Exam<br />
4.2.9.5 Appearance or Morphology of <strong>Damage</strong> 破 坏 外 观 形 貌<br />
a) Thermal fatigue cracks usually <strong>in</strong>itiate on <strong>the</strong> surface of <strong>the</strong> component.<br />
They are generally wide and often filled with oxides due to elevated<br />
temperature exposure. Cracks may occur as s<strong>in</strong>gle or multiple cracks.<br />
表 面 发 起 点 , 开 裂 表 面 氧 化 , 裂 缝 可 能 为 单 个 或 多 个 裂 纹 延 伸 .<br />
b) Thermal fatigue cracks propagate transverse to <strong>the</strong> stress and <strong>the</strong>y are<br />
usually dagger-shaped, transgranular, and oxide filled (Figure 4-24 and 4-<br />
25). However, crack<strong>in</strong>g may be axial or circumferential, or both, at <strong>the</strong> same<br />
location. 应 力 方 向 横 向 开 裂 , 穿 晶 , 氧 化 , 刀 纹 状 (?), 开 裂 方 向 为 ; 轴 向 或 圆 周 向<br />
或 并 存 .
API510/570-Exam<br />
c) In steam generat<strong>in</strong>g equipment, cracks usually follow <strong>the</strong> toe of <strong>the</strong> fillet<br />
weld, as <strong>the</strong> change <strong>in</strong> section thickness creates a stress raiser. Cracks<br />
often start at <strong>the</strong> end of an attachment lug and if <strong>the</strong>re is a bend<strong>in</strong>g moment<br />
as a result of <strong>the</strong> constra<strong>in</strong>t, <strong>the</strong>y will develop <strong>in</strong>to circumferential cracks <strong>in</strong>to<br />
<strong>the</strong> tube. 在 蒸 汽 发 生 装 置 , 通 常 开 裂 起 点 在 焊 道 应 力 集 中 点 , 周 圆 的 延 伸 .<br />
d) Water <strong>in</strong> soot blowers may lead to a craz<strong>in</strong>g pattern. The predom<strong>in</strong>ant<br />
cracks will be circumferential and <strong>the</strong> m<strong>in</strong>or cracks will be axial. (Figure 4-<br />
26 to 4-27). 水 助 吹 灰 器 的 裂 纹 一 般 上 体 现 为 纹 状 .
API510/570-Exam<br />
Figure 4-27 – Photomicrograph of <strong>the</strong> failed<br />
superheated steam outlet shown <strong>in</strong> Figure 4-26.<br />
Etched.<br />
Figure 4-26 – Metallographic cross-section of a superheated<br />
steam outlet that failed from <strong>the</strong>rmal fatigue. Unetched.
API510/570-Exam<br />
4.2.9.6 Prevention / Mitigation 预 防 / 缓 解<br />
a) Thermal fatigue is best prevented through design and operation to<br />
m<strong>in</strong>imize <strong>the</strong>rmal stresses and <strong>the</strong>rmal cycl<strong>in</strong>g. Several methods of<br />
prevention apply depend<strong>in</strong>g on <strong>the</strong> application.<br />
1. Designs that <strong>in</strong>corporate reduction of stress concentrators, blend gr<strong>in</strong>d<strong>in</strong>g<br />
of weld profiles, and smooth transitions should be used. 减 少 应 力 集 中 , 焊<br />
缝 节 点 疲 劳 处 理 , 圆 滑 过 渡 .<br />
2. Controlled rates of heat<strong>in</strong>g and cool<strong>in</strong>g dur<strong>in</strong>g startup and shutdown of<br />
equipment can lower stresses. 周 转 ( 开 机 , 关 机 ) 控 制 加 热 和 冷 却 速 率 .<br />
3. Differential <strong>the</strong>rmal expansion between adjo<strong>in</strong><strong>in</strong>g components of dissimilar<br />
materials should be considered. 设 计 阶 段 考 虑 异 种 材 料 之 间 的 差 热 膨 胀 .
API510/570-Exam<br />
b) Designs should <strong>in</strong>corporate sufficient flexibility to accommodate differential<br />
expansion. 设 计 时 考 虑 具 有 足 够 的 灵 活 性<br />
1. In steam generat<strong>in</strong>g equipment, slip spacers should slip and rigid<br />
attachments should be avoided. 滑 动 垫 片 .<br />
2. Dra<strong>in</strong> l<strong>in</strong>es should be provided on soot-blowers to prevent condensate <strong>in</strong><br />
<strong>the</strong> first portion of <strong>the</strong> soot blow<strong>in</strong>g cycle. 吹 灰 器 安 装 排 水 线 避 免 冷 凝 液 聚 集 .<br />
3. In some cases, a l<strong>in</strong>er or sleeve may be <strong>in</strong>stalled to prevent a colder liquid<br />
from contact<strong>in</strong>g <strong>the</strong> hotter pressure boundary wall 安 装 衬 垫 或 套 用 于 防 止<br />
冷 液 体 接 触 热 的 压 力 边 界 墙
API510/570-Exam<br />
4.2.9.7 Inspection and Monitor<strong>in</strong>g 检 查 和 监 督<br />
a) S<strong>in</strong>ce crack<strong>in</strong>g is usually surface connected, visual exam<strong>in</strong>ation, MT and<br />
PT are effective methods of <strong>in</strong>spection. 由 于 裂 缝 通 常 是 表 面 连 接 MT/PT 是<br />
有 效 的 检 查 方 法 .<br />
b) External SWUT <strong>in</strong>spection can be used for non-<strong>in</strong>trusive <strong>in</strong>spection for<br />
<strong>in</strong>ternal crack<strong>in</strong>g and where re<strong>in</strong>forc<strong>in</strong>g pads prevent nozzle exam<strong>in</strong>ation.<br />
切 波 角 度 超 声 可 以 用 于 非 侵 入 性 检 查 , 例 如 : 被 补 强 板 妨 碍 的 容 器 / 管 口 区 域 .<br />
c) Heavy wall reactor <strong>in</strong>ternal attachment welds can be <strong>in</strong>spected us<strong>in</strong>g<br />
specialized ultrasonic techniques. 厚 壁 反 应 器 内 部 连 接 焊 缝 运 用 切 波 角 度 超<br />
声 探 测 法<br />
4.2.9.8 Related <strong>Mechanisms</strong> 相 关 机 制<br />
Corrosion fatigue (see 4.5.2) and dissimilar metal weld crack<strong>in</strong>g (see 4.2.12).<br />
腐 蚀 疲 劳 , 异 种 金 属 焊 缝 开 裂 .
API510/570-Exam
API510/570-Exam
API510/570-Exam
API510/570-Exam
API510/570-Exam<br />
571-4<br />
Charlie Chong/ Fion Zhang
API510/570-Exam
API510/570-Exam
API510/570-Exam
API510/570-Exam
API510/570-Exam
热 疲 劳 学 习 重 点 :<br />
a) 易 感 温 度 : 高 温<br />
b) 原 理 : 热 疲 劳 开 裂 是 由 温 度 变 化 引 起 循 环 应 力 引 起 的 开 裂 ,<br />
c) 易 感 材 质 : 一 切 工 程 材 料 ,<br />
d) 易 感 设 备 : 蒸 汽 发 生 装 置 , 蒸 汽 驱 动 的 吹 灰 器 等 , 高 温 设 备 ,<br />
e) API 510/570 考 试 题 .
4.2.10 Short Term Overheat<strong>in</strong>g Stress Rupture<br />
短 期 过 热 应 力 开 裂<br />
非 API 510/570 考 试 题
Short Term<br />
Overheat<strong>in</strong>g Stress Rupture<br />
Local over-heat<strong>in</strong>g.
4.2.10 Short Term Overheat<strong>in</strong>g – Stress Rupture<br />
4.2.10.1 Description of <strong>Damage</strong> 损 伤 描 述<br />
Permanent deformation occurr<strong>in</strong>g at relatively low stress levels as a result of<br />
localized overheat<strong>in</strong>g. This usually results <strong>in</strong> bulg<strong>in</strong>g and eventually failure<br />
by stress rupture.<br />
4.2.10.2 Affected Materials 影 响 材 质<br />
All fired heater tube materials and common materials of construction.<br />
一 切 建 造 材 料
4.2.10.3 Critical Factors 关 键 因 素<br />
a) Temperature, time and stress are critical factors. 温 度 , 时 间 , 应 力<br />
a) Usually due to flame imp<strong>in</strong>gement or local overheat<strong>in</strong>g. 火 焰 冲 击 或 局 部 过 热<br />
b) Time to failure will <strong>in</strong>crease as <strong>in</strong>ternal pressures or load<strong>in</strong>g decrease.<br />
However, bulg<strong>in</strong>g and distortion can be significant at low stresses, as<br />
temperatures <strong>in</strong>crease. 失 效 时 间 随 着 内 部 压 力 或 负 载 减 少 增 长 .<br />
c) Local overheat<strong>in</strong>g above <strong>the</strong> design temperature. 局 部 过 热<br />
d) Loss <strong>in</strong> thickness due to corrosion will reduce time to failure by <strong>in</strong>creas<strong>in</strong>g<br />
<strong>the</strong> stress. 由 于 腐 蚀 厚 度 损 失 增 加 易 感 性 .
4.2.10.4 Affected Units or <strong>Equipment</strong> 受 影 响 的 单 元 或 设 备<br />
a) All boiler and fired heater tubes are susceptible. 所 有 锅 炉 和 加 热 炉 管<br />
b) Furnaces with cok<strong>in</strong>g tendencies such as crude, vacuum, heavy oil<br />
hydroprocess<strong>in</strong>g and coker units are often fired harder to ma<strong>in</strong>ta<strong>in</strong> heater<br />
outlet temperatures and are more susceptible to localized overheat<strong>in</strong>g. 焦<br />
化 倾 向 的 设 备<br />
c) Hydroprocess<strong>in</strong>g reactors may be susceptible to localized overheat<strong>in</strong>g of<br />
reactor beds due to <strong>in</strong>adequate hydrogen quench or flow mal-distribution.<br />
氢 反 应 器 - 易 受 局 部 过 热 加 反 应 器 床<br />
d) Refractory l<strong>in</strong>ed equipment <strong>in</strong> <strong>the</strong> FCC, sulfur plant and o<strong>the</strong>r units may<br />
suffer localized overheat<strong>in</strong>g due to refractory damage and/or excessive<br />
fir<strong>in</strong>g. 催 化 裂 化 , 硫 磺 厂 与 其 他 可 能 遭 受 局 部 过 热 的 耐 火 材 料 衬 里 的 设 备 .
4.2.10.5 Appearance or Morphology of <strong>Damage</strong> 破 坏 外 观 形 貌<br />
a) <strong>Damage</strong> is typically characterized by localized deformation or bulg<strong>in</strong>g on<br />
<strong>the</strong> order of 3% to 10% or more, depend<strong>in</strong>g on <strong>the</strong> alloy, temperature and<br />
stress level. 损 坏 的 典 型 特 征 是 局 部 变 形 或 膨 胀 (3%~10% 或 更 多 )<br />
b) Ruptures are characterized by open “fishmouth” failures and are usually<br />
accompanied by th<strong>in</strong>n<strong>in</strong>g at <strong>the</strong> fracture surface (Figure 4-28 to 4-31).<br />
破 裂 的 特 点 是 在 变 薄 断 裂 面 “ 鱼 嘴 ” 形 象 的 开 裂 的 特 征 .
4.2.10.6 Prevention / Mitigation 预 防 / 缓 解<br />
a) M<strong>in</strong>imize localized temperature excursions. 减 少 局 部 温 度 漂 移<br />
b) Fired heaters require proper burner management and foul<strong>in</strong>g/deposit<br />
control to m<strong>in</strong>imize hot spots and localized overheat<strong>in</strong>g. 火 焰 加 热 器 需 要 适<br />
当 的 燃 烧 器 管 理 / 污 垢 和 沉 积 控 制 以 减 少 局 部 过 热 .<br />
c) Utilize burners which produce a more diffuse flame pattern.<br />
d) In hydroprocess<strong>in</strong>g equipment, <strong>in</strong>stall and ma<strong>in</strong>ta<strong>in</strong> bed <strong>the</strong>rmocouples <strong>in</strong><br />
reactors and m<strong>in</strong>imize <strong>the</strong> likelihood of hot spots through proper design<br />
and operation.<br />
e) Ma<strong>in</strong>ta<strong>in</strong> refractory <strong>in</strong> serviceable condition <strong>in</strong> refractory l<strong>in</strong>ed equipment.
短 期 过 热 应 力 开 裂 学 习 重 点 :<br />
a) 易 感 温 度 : 高 温<br />
b) 原 理 : 热 疲 劳 开 裂 是 由 温 度 变 化 引 起 循 环 应 力 引 起 的 开 裂 ,<br />
c) 易 感 材 质 : 一 切 工 程 材 料 ,<br />
d) 易 感 设 备 : 蒸 汽 发 生 装 置 , 蒸 汽 驱 动 的 吹 灰 器 等 , 高 温 设 备 ,<br />
e) 非 API 510/570 考 试 题 .
4.2.11 Steam Blanket<strong>in</strong>g<br />
蒸 汽 封
Steam Blanket<strong>in</strong>g<br />
Local over-heat<strong>in</strong>g.
4.2.11 Steam Blanket<strong>in</strong>g<br />
4.2.11.1 Description of <strong>Damage</strong><br />
The operation of steam generat<strong>in</strong>g equipment is a balance between <strong>the</strong> heat<br />
flow from <strong>the</strong> combustion of <strong>the</strong> fuel and <strong>the</strong> generation of steam with<strong>in</strong> <strong>the</strong><br />
waterwall or generat<strong>in</strong>g tube. The flow of heat energy through <strong>the</strong> wall of <strong>the</strong><br />
tube results <strong>in</strong> <strong>the</strong> formation of discrete steam bubbles (nucleate boil<strong>in</strong>g) on<br />
<strong>the</strong> ID surface. The mov<strong>in</strong>g fluid sweeps <strong>the</strong> bubbles away. When <strong>the</strong> heat<br />
flow balance is disturbed, <strong>in</strong>dividual bubbles jo<strong>in</strong> to form a steam blanket, a<br />
condition known as Departure From Nucleate Boil<strong>in</strong>g (DNB). Once a steam<br />
blanket forms, tube rupture can occur rapidly, as a result of short term<br />
overheat<strong>in</strong>g, usually with<strong>in</strong> a few m<strong>in</strong>utes.<br />
4.2.11.2 Affected Materials<br />
Carbon steel and low alloy steels.
<strong>in</strong>dividual bubbles jo<strong>in</strong> to form a steam blanket, a condition known as<br />
Departure From Nucleate Boil<strong>in</strong>g (DNB).
<strong>in</strong>dividual bubbles jo<strong>in</strong> to form a steam blanket, a condition known as<br />
Departure From Nucleate Boil<strong>in</strong>g (DNB).
Heat transfer and mass transfer dur<strong>in</strong>g nucleate boil<strong>in</strong>g has a significant effect on <strong>the</strong><br />
heat transfer rate. This heat transfer process helps quickly and efficiently to carry<br />
away <strong>the</strong> energy created at <strong>the</strong> heat transfer surface and is <strong>the</strong>refore sometimes<br />
desirable - for example <strong>in</strong> nuclear power plants, where liquid is used as a coolant.<br />
The effects of nucleate boil<strong>in</strong>g take place at two locations:<br />
• <strong>the</strong> liquid-wall <strong>in</strong>terface<br />
• <strong>the</strong> bubble-liquid <strong>in</strong>terface<br />
http://en.wikipedia.org/wiki/Nucleate_boil<strong>in</strong>g
4.2.11.3 Critical Factors<br />
a) Heat flux and fluid flow are critical factors.<br />
b) Flame imp<strong>in</strong>gement from misdirected or damaged burners can provide a<br />
heat flux greater than <strong>the</strong> steam generat<strong>in</strong>g tube can accommodate.<br />
c) On <strong>the</strong> water side, anyth<strong>in</strong>g that restricts fluid flow (for example, p<strong>in</strong>hole<br />
leaks lower <strong>in</strong> <strong>the</strong> steam circuit or dented tubes from slag falls) will reduce<br />
fluid flow and can lead to DNB conditions.<br />
d) Failure occurs as a result of <strong>the</strong> hoop stress <strong>in</strong> <strong>the</strong> tube from <strong>the</strong> <strong>in</strong>ternal<br />
steam pressure at <strong>the</strong> elevated temperature.
4.2.11.4 Affected Units or <strong>Equipment</strong><br />
All steam-generat<strong>in</strong>g units <strong>in</strong>clud<strong>in</strong>g fired boilers, waste heat exchangers <strong>in</strong><br />
sulfur plants, hydrogen reformers and FCC units. Failures can occur <strong>in</strong><br />
superheaters and reheaters dur<strong>in</strong>g start-up when condensate blocks steam flow.
4.2.11.5 Appearance or Morphology of <strong>Damage</strong><br />
a) These short-term, high-temperature failures always show an open burst<br />
with <strong>the</strong> fracture edges drawn to a near knife-edge (Figure 4-32).<br />
b) The microstructure will always show severe elongation of <strong>the</strong> gra<strong>in</strong><br />
structure due to <strong>the</strong> plastic deformation that occurs at <strong>the</strong> time of failure.<br />
Figure 4-32 – Short-term high-temperature failures from DNB are wideopen<br />
bursts with <strong>the</strong> failure lips drawn to a near knife edge. They are ductile<br />
ruptures. Mag. 25X.
4.2.11.6 Prevention / Mitigation<br />
a) When a DNB condition has developed, tube rupture will quickly follow.<br />
Proper burner management should be practiced to m<strong>in</strong>imize flame<br />
imp<strong>in</strong>gement.<br />
b) Proper BFW treatment can help prevent some conditions that can lead to<br />
restricted fluid flow.<br />
c) Tubes should be visually <strong>in</strong>spected for bulg<strong>in</strong>g.<br />
4.2.11.7 Inspection and Monitor<strong>in</strong>g<br />
Burners should be properly ma<strong>in</strong>ta<strong>in</strong>ed to prevent flame imp<strong>in</strong>gement.
Causes of Caustic Crack<strong>in</strong>g<br />
Caustic is a boiler water additive. It is added to preserve <strong>the</strong> th<strong>in</strong> film of iron oxide to protect <strong>the</strong> boiler from corrosion. The<br />
follow<strong>in</strong>g are <strong>the</strong> causes of concentration of caustics:<br />
1. Small bubbles of steam nucleated at <strong>the</strong> metal surface <strong>in</strong> m<strong>in</strong>ute concentrations of solids <strong>in</strong> <strong>the</strong> boiler water would be<br />
deposited on <strong>the</strong> metal surface. As <strong>the</strong> solids are formed <strong>the</strong>y are simultaneously removed from <strong>the</strong> metal surface by<br />
water which re-dissolves <strong>the</strong>m. However, when <strong>the</strong> rate of bubble formation exceeds <strong>the</strong> rate of dissolution of <strong>the</strong> solids,<br />
concentration of caustics would beg<strong>in</strong> to <strong>in</strong>crease.<br />
2. The deposits of solids shield <strong>the</strong> metal from <strong>the</strong> back water. Steam forms under <strong>the</strong> deposits and escapes leav<strong>in</strong>g beh<strong>in</strong>d a<br />
caustic residue.<br />
3. Caustic also concentrates by evaporation if a water l<strong>in</strong>e exists.<br />
Mechanism<br />
Concentrated caustic dissolves <strong>the</strong> protective magnetite oxides<br />
http://faculty.kfupm.edu.sa/ME/hussa<strong>in</strong>i/Corrosion%20Eng<strong>in</strong>eer<strong>in</strong>g/04.10.01.htm
蒸 汽 封 学 习 重 点 :<br />
a) 易 感 温 度 : 高 温<br />
b) 原 理 : 当 热 流 量 平 衡 被 打 破 , 单 个 气 泡 的 加 入 形 成 蒸 汽 毛 毯 , 一 种 被 称<br />
为 偏 离 泡 核 沸 腾 ,<br />
c) 易 感 材 质 : 碳 钢 和 低 合 金 钢 ,<br />
d) 易 感 设 备 : 所 有 蒸 汽 发 电 机 组 包 括 锅 炉 , 硫 磺 厂 余 热 换 热 器 , 制 氢 转 化 炉 和<br />
催 化 裂 化 装 置 ,<br />
e) 预 防 / 缓 解 : 锅 炉 热 管 理 ( 火 焰 , 锅 炉 水 管 理 ), 锅 炉 管 目 视 检 验 .<br />
f) 非 API 510/570 考 试 题 .
4.2.12 Dissimilar Weld Crack<strong>in</strong>g<br />
异 种 钢 焊 接 开 裂
4.2.12 Dissimilar Metal Weld (DMW) Crack<strong>in</strong>g<br />
4.2.12.1 Description of <strong>Damage</strong><br />
Crack<strong>in</strong>g of dissimilar metal welds occurs <strong>in</strong> <strong>the</strong> ferritic (carbon steel or low<br />
alloy steel) side of a weld between an austenitic (300 Series SS) and a ferritic<br />
material operat<strong>in</strong>g at high temperature.<br />
4.2.12.2 Affected Materials<br />
The most common are ferritic materials such as carbon steel and low alloy<br />
steels that are welded to <strong>the</strong> austenitic sta<strong>in</strong>less steels as well as any<br />
material comb<strong>in</strong>ations that have widely differ<strong>in</strong>g <strong>the</strong>rmal expansion<br />
coefficients.
4.2.12.3 Critical Factors<br />
a) Important factors <strong>in</strong>clude <strong>the</strong> type of filler metal used to jo<strong>in</strong> <strong>the</strong> materials,<br />
heat<strong>in</strong>g and cool<strong>in</strong>g rate, metal temperature, time at temperature, weld<br />
geometry and <strong>the</strong>rmal cycl<strong>in</strong>g.<br />
b) Crack<strong>in</strong>g can occur because of <strong>the</strong> different coefficients of <strong>the</strong>rmal<br />
expansion between ferritic and austenitic (e.g. 300 Series sta<strong>in</strong>less steel<br />
or nickel-base alloys) which differ by about 25 to 30% or more. At high<br />
operat<strong>in</strong>g temperatures, <strong>the</strong> differences <strong>in</strong> <strong>the</strong>rmal expansion leads to<br />
high stress at <strong>the</strong> heat-affected zone on <strong>the</strong> ferritic side (Table 4-4).<br />
c) As <strong>the</strong> operat<strong>in</strong>g temperature <strong>in</strong>creases, differential <strong>the</strong>rmal expansion<br />
between <strong>the</strong> metals results <strong>in</strong> <strong>in</strong>creas<strong>in</strong>g stress at <strong>the</strong> weldment,<br />
particularly if a 300 Series SS weld metal is used. Ferritic/austenitic jo<strong>in</strong>ts<br />
can generate significant <strong>the</strong>rmal expansion/<strong>the</strong>rmal fatigue stresses at<br />
temperatures greater than 510°F (260°C).
Table 4-4: Coefficients of Thermal Expansion for Common Materials
510°F<br />
Ferritic/austenitic jo<strong>in</strong>ts can<br />
generate significant <strong>the</strong>rmal<br />
expansion/<strong>the</strong>rmal fatigue<br />
stresses at temperatures<br />
greater than 510°F (260°C).
d) Thermal cycl<strong>in</strong>g aggravates <strong>the</strong> problem. Stresses dur<strong>in</strong>g start up and shut<br />
down can be significant.<br />
e) Stresses act<strong>in</strong>g on <strong>the</strong> weldment are significantly higher when an austenitic<br />
sta<strong>in</strong>less steel filler metal is used. A nickel base filler metal has a<br />
coefficient of <strong>the</strong>rmal expansion that is closer to carbon steel, result<strong>in</strong>g <strong>in</strong><br />
significantly lower stress at elevated temperatures.<br />
f) For dissimilar welds that operate at elevated temperatures, <strong>the</strong> problem is<br />
aggravated by <strong>the</strong> diffusion of carbon out of <strong>the</strong> heat-affected zone of <strong>the</strong><br />
ferritic material and <strong>in</strong>to <strong>the</strong> weld metal. The loss of carbon reduces <strong>the</strong><br />
creep strength of <strong>the</strong> ferritic material heat-affected zone, <strong>the</strong>reby <strong>in</strong>creas<strong>in</strong>g<br />
<strong>the</strong> crack<strong>in</strong>g probability (Figure 4-35). The temperature at which carbon<br />
diffusion becomes a concern is above 800°F to 950°F (427°C to 510°C) for<br />
carbon steels and low alloy steels, respectively.
Austenitic Steel<br />
Ferritic Steel<br />
Creep void due to loss of<br />
Carbon at HAZ<br />
Figure 4-35 – High magnification photomicrograph of a DMW jo<strong>in</strong><strong>in</strong>g a<br />
ferritic alloy (SA213 T-22) used <strong>in</strong> high temperature service. Creep<br />
cracks (black specks) can be observed <strong>in</strong> <strong>the</strong> ferritic alloy heat-affected<br />
zones. Mag. 50X, etched.
g) Dissimilar metal welds on a ferritic steel that are made with a 300 Series SS<br />
weld metal or a nickel based filler metal result <strong>in</strong> a narrow region (mixed<br />
zone) of high hardness at <strong>the</strong> toe of <strong>the</strong> weld, near <strong>the</strong> fusion l<strong>in</strong>e on <strong>the</strong><br />
ferritic steel side. These high hardness zones render <strong>the</strong> material<br />
susceptible to various forms of environmental crack<strong>in</strong>g such as sulfide stress<br />
crack<strong>in</strong>g or hydrogen stress crack<strong>in</strong>g (Figures 4-36 and 4-37). PWHT of <strong>the</strong><br />
weldment will not prevent environmental crack<strong>in</strong>g if <strong>the</strong> weld is exposed to<br />
wet H 2 S conditions.(?)<br />
h) DMW’s for high temperature service <strong>in</strong> hydrogen environments must be<br />
carefully designed and <strong>in</strong>spected to prevent hydrogen disbond<strong>in</strong>g (Figures<br />
4-38 to 4-41).
Environmental Crack<strong>in</strong>g<br />
– Ambient service<br />
Figure 4-36 – Weld detail used to jo<strong>in</strong> a carbon steel elbow (bottom) to a weld overlaid<br />
pipe section (top) <strong>in</strong> high pressure wet H 2<br />
S service. Sulfide stress crack<strong>in</strong>g (SSC) occurred<br />
along <strong>the</strong> toe of <strong>the</strong> weld (arrow), <strong>in</strong> a narrow zone of high hardness.
Environmental Crack<strong>in</strong>g<br />
– Ambient service<br />
Figure 4-37 – High magnification photomicrograph of SSC <strong>in</strong> pipe section shown <strong>in</strong><br />
Figure 4-36.
High temperature service<br />
Blister<br />
Figure 4-38 – Failure of DMW jo<strong>in</strong><strong>in</strong>g 1.25Cr-0.5Mo to Alloy 800H <strong>in</strong> a Hydro-dealkylation<br />
(HAD) Reactor Effluent Exchanger. Crack propagation due to stresses driven at high<br />
temperature of 875°F (468°C) and a hydrogen partial pressure of 280 psig (1.93 MPa).
High temperature service<br />
Blister<br />
Figure 4-39 – High magnification photomicrograph of <strong>the</strong> crack <strong>in</strong> Figure 4-38 show<strong>in</strong>g<br />
blister<strong>in</strong>g and disbondment along <strong>the</strong> weld fusion l<strong>in</strong>e <strong>in</strong>terface.
High temperature service<br />
Figure 4-40 – High magnification photomicrograph of <strong>the</strong> crack shown above <strong>in</strong> Figure 4-39.<br />
Plastic deformation of <strong>the</strong> gra<strong>in</strong> structure can be found at <strong>the</strong> vic<strong>in</strong>ity of <strong>the</strong> blister.
High temperature service<br />
Figure 4-41 – Failure of nickel alloy DMW jo<strong>in</strong><strong>in</strong>g HP40 (Nb modified) tube to 1.25Cr-0.5Mo<br />
flange <strong>in</strong> a Steam Methane Reformer due to cold hydrogen disbond<strong>in</strong>g of <strong>the</strong> butter<strong>in</strong>g layer.<br />
Process temperature 914°-941°F (490o to 505°C), Pressure (2.14 MPA), H2 content 10-20%<br />
(off-gas).
i) In environments that promote liquid ash corrosion, weld crack<strong>in</strong>g problems<br />
may be accelerated by stress-assisted corrosion. The ferritic heat-affected<br />
zone will preferentially corrode due to <strong>the</strong> large <strong>the</strong>rmal stra<strong>in</strong>. The results<br />
are long, narrow, oxide wedges that parallel <strong>the</strong> fusion l<strong>in</strong>e of <strong>the</strong> weld<br />
(Figure 4-42).<br />
j) Poor geometry of <strong>the</strong> weld, excessive undercut, and o<strong>the</strong>r stress<br />
<strong>in</strong>tensification factors will promote crack formation.
Intergranular liquid metal<br />
embrittlement (coal ash<br />
corrosion)<br />
Figure 4-42 – When both liquid phase coal ash corrosion and a DMW exists, stress assisted<br />
corrosion of <strong>the</strong> 2.25 Cr-1Mo heat-affected zone may occur. Note that <strong>the</strong>re is a lack of creep<br />
damage at <strong>the</strong> crack tip. Mag. 25X, etched.
4.2.12.4 Affected Units or <strong>Equipment</strong><br />
a) Dissimilar metal welds are utilized <strong>in</strong> special applications <strong>in</strong> ref<strong>in</strong>eries and<br />
o<strong>the</strong>r process plants.<br />
b) Examples of DMW’s <strong>in</strong>clude:<br />
• Welds used to jo<strong>in</strong> clad pipe <strong>in</strong> locations such as transitions <strong>in</strong><br />
hydroprocess<strong>in</strong>g reactor outlet pip<strong>in</strong>g from overlaid low alloy CrMo nozzles<br />
or pip<strong>in</strong>g to solid 300 Series sta<strong>in</strong>less steel pipe.<br />
• Hydroprocess<strong>in</strong>g exchanger <strong>in</strong>let and outlet pip<strong>in</strong>g.<br />
• Alloy transitions <strong>in</strong>side fired heaters (e.g. 9Cr to 317L <strong>in</strong> a crude furnace)<br />
• Hydrogen reformer furnace 1.25 Cr <strong>in</strong>let pigtails to Alloy 800 sockolets or<br />
weldolets on Hydrogen reformer tubes<br />
• Hydrogen reformer furnace Alloy 800 outlet cones to CS or 1.25 Cr<br />
refractory l<strong>in</strong>ed transfer l<strong>in</strong>es.
• Alloy transitions <strong>in</strong>side fired heaters (e.g. 9Cr to 317L <strong>in</strong> a crude or<br />
vacuum furnace)<br />
• Welds jo<strong>in</strong><strong>in</strong>g clad pipe sections to <strong>the</strong>mselves or to unclad carbon or<br />
low alloy steel pipe (e.g. Alloy C276 clad CS pip<strong>in</strong>g <strong>in</strong> crude unit<br />
overhead system)<br />
• Nickel base alloy welds jo<strong>in</strong><strong>in</strong>g socket weld valves <strong>in</strong> 5 and 9 Cr pip<strong>in</strong>g<br />
systems<br />
• 300 series SS weld overlay <strong>in</strong> numerous ref<strong>in</strong>ery reactors and pressure<br />
vessels<br />
• Similar DMWs have been used <strong>in</strong> FCCU reactors and regenerator<br />
vessels and <strong>in</strong> Coker Units.<br />
c) All superheaters and reheaters that have welds between ferritic<br />
materials (1.25Cr-0.5Mo and 2.25Cr-1Mo) and <strong>the</strong> austenitic materials<br />
(300 Series SS, 304H, 321H and 347H).
4.2.12.5 Appearance or Morphology of <strong>Damage</strong><br />
a) In most cases, <strong>the</strong> cracks form at <strong>the</strong> toe of <strong>the</strong> weld <strong>in</strong> <strong>the</strong> heat-affected<br />
zone of <strong>the</strong> ferritic material (Figure 4-36 to Figure 4-42).<br />
b) Welds jo<strong>in</strong><strong>in</strong>g tubes are <strong>the</strong> most common problem area, but support lugs<br />
or attachments of cast or wrought 300 Series SS to 400 Series SS are<br />
also affected.
4.2.12.6 Prevention / Mitigation 预 防 / 缓 解<br />
a) For high temperature applications, nickel base filler metals which have a<br />
coefficient of <strong>the</strong>rmal expansion closer to carbon steel and low alloy steels<br />
may dramatically <strong>in</strong>crease <strong>the</strong> life of <strong>the</strong> jo<strong>in</strong>t, because of <strong>the</strong> significant<br />
reduction <strong>in</strong> <strong>the</strong>rmal stress act<strong>in</strong>g on <strong>the</strong> steel (ferritic) side of <strong>the</strong> jo<strong>in</strong>t.<br />
Refer to API 577 and API 582 for additional <strong>in</strong>formation on filler metal<br />
selection, weld<strong>in</strong>g procedures and weld <strong>in</strong>spection.<br />
b) If 300 Series SS weld<strong>in</strong>g electrodes are used, <strong>the</strong> dissimilar metal weld<br />
should be located <strong>in</strong> a low temperature region.<br />
c) Consider butter<strong>in</strong>g <strong>the</strong> ferritic side of <strong>the</strong> jo<strong>in</strong>t with <strong>the</strong> SS or nickel base<br />
filler metal and perform PWHT prior to complet<strong>in</strong>g <strong>the</strong> DMW to m<strong>in</strong>imize <strong>the</strong><br />
hardness of <strong>the</strong> mixed weld zone <strong>in</strong> order to m<strong>in</strong>imize susceptibility to<br />
environmental crack<strong>in</strong>g. See Figure 4-34 and 4-35.(Figure 4-33 and 4-34)<br />
d) On buttered jo<strong>in</strong>ts, <strong>the</strong> thickness of <strong>the</strong> weld metal should be a m<strong>in</strong>imum of<br />
0.25 <strong>in</strong>ch (6.35 mm) after <strong>the</strong> bevel is mach<strong>in</strong>ed. Figure 4-35.(Figure 4-34)
Figure 4-33 – Two primary DMW<br />
configurations.<br />
a ) Ferritic steel pipe (left) welded to<br />
clad or weld overlaid pipe (right)<br />
b) Solid Sta<strong>in</strong>less steel pipe (left)<br />
welded to clad or weld overlaid pipe<br />
(right)
Figure 4-34 – Schematic of typical weld detail used to jo<strong>in</strong> a solid sta<strong>in</strong>less steel pipe to a clad or<br />
weld overlaid pipe. The sequence is: 1) Butter <strong>the</strong> weld bevel on <strong>the</strong> ferritic steel side, 2) Perform<br />
PWHT of <strong>the</strong> ferritic side prior to mak<strong>in</strong>g dissimilar weld, 3) Complete <strong>the</strong> dissimilar weld us<strong>in</strong>g<br />
alloy filler metal, 4) Do not PWHT <strong>the</strong> completed dissimilar weld.
e) In steam generat<strong>in</strong>g equipment, <strong>the</strong> weld at <strong>the</strong> high temperature end<br />
should be made <strong>in</strong> <strong>the</strong> penthouse or header enclosure, out of <strong>the</strong> heat<br />
transfer zone.<br />
f) For high temperature <strong>in</strong>stallations, consider Install<strong>in</strong>g a pup piece that has<br />
an <strong>in</strong>termediate <strong>the</strong>rmal expansion coefficient between <strong>the</strong> two materials<br />
to be jo<strong>in</strong>ed.
4.2.12.7 Inspection and Monitor<strong>in</strong>g<br />
a) The follow<strong>in</strong>g elements should be considered for non-destructive<br />
exam<strong>in</strong>ation of critical dissimilar butt welds before <strong>the</strong>y are put <strong>in</strong>to<br />
service:<br />
• 100% PT after butter<strong>in</strong>g and completion<br />
• 100% UT on butter layer after PWHT (check bond<strong>in</strong>g)<br />
•100% RT<br />
• 100% UT – recordable<br />
•PMI<br />
b) For dissimilar welds <strong>in</strong> fired heater tubes, RT and UT shear wave<br />
<strong>in</strong>spection should be performed.<br />
c) Environmental crack<strong>in</strong>g will also result <strong>in</strong> surface break<strong>in</strong>g cracks <strong>in</strong>itiat<strong>in</strong>g<br />
on <strong>the</strong> ID surface exposed to <strong>the</strong> corrosive environment, which can be<br />
detected us<strong>in</strong>g WFMT or external SWUT methods.
4.2.12.8 Related <strong>Mechanisms</strong><br />
Thermal fatigue (see 4.2.9), corrosion fatigue (see 4.5.2), creep (see 4.2.8),<br />
and sulfide stress crack<strong>in</strong>g<br />
(see 5.1.2.3.)
异 种 钢 焊 接 开 裂 学 习 重 点 :<br />
a) 易 感 温 度 : 室 温 与 高 温 两 种<br />
b) 原 理 : (1) 室 温 感 应 - 铁 素 体 混 合 区 高 强 度 导 致 环 境 开 裂 与 氢 裂 , (2) 高 温<br />
感 应 - 铁 素 体 热 影 响 区 脱 碳 导 致 高 温 强 度 降 低 与 蠕 变 强 度 .<br />
c) 易 感 材 质 : 铁 素 体 / 奥 氏 体 异 种 焊 接 ,<br />
d) 非 API510/570 考 试 题
4.2.13 Thermal Shock<br />
热 冲 击
4.2.13 Thermal Shock 温 度 突 变<br />
4.2.13.1 Description of <strong>Damage</strong><br />
A form of <strong>the</strong>rmal fatigue crack<strong>in</strong>g – <strong>the</strong>rmal shock – can occur when high and<br />
non-uniform <strong>the</strong>rmal stresses develop over a relatively short time <strong>in</strong> a piece of<br />
equipment due to differential expansion or contraction. If <strong>the</strong> <strong>the</strong>rmal<br />
expansion/contraction is restra<strong>in</strong>ed, stresses above <strong>the</strong> yield strength of <strong>the</strong><br />
material can result. Thermal shock usually occurs when a colder liquid contacts<br />
a warmer metal surface.<br />
当 的 液 体 接 触 一 个 高 温 的 金 属 表 面 时 , 在 很 短 的 时 间 , 高 和 非 均 匀 的 热 应 力 发 生 .<br />
如 果 热 膨 胀 / 收 缩 受 到 抑 制 , 可 能 会 导 致 材 料 的 屈 服 强 度 以 上 的 应 力 .<br />
4.2.13.2 Affected Materials<br />
All metals and alloys.
4.2.13.3 Critical Factors<br />
a) The magnitude of <strong>the</strong> temperature differential and <strong>the</strong> coefficient of<br />
<strong>the</strong>rmal expansion of <strong>the</strong> material determ<strong>in</strong>e <strong>the</strong> magnitude of <strong>the</strong> stress.<br />
b) Cyclic stresses generated by temperature cycl<strong>in</strong>g of <strong>the</strong> material may<br />
<strong>in</strong>itiate fatigue cracks.<br />
c) Sta<strong>in</strong>less steels have higher coefficients of <strong>the</strong>rmal expansion than<br />
carbon and alloy steels or nickel base alloys and are more likely to see<br />
higher stresses.<br />
d) High temperature exposure dur<strong>in</strong>g a fire.<br />
e) Temperature changes that can result from water quench<strong>in</strong>g as a result of<br />
ra<strong>in</strong> deluges.
f) Fracture is related to constra<strong>in</strong>t on a component that prevents <strong>the</strong><br />
component from expand<strong>in</strong>g or contract<strong>in</strong>g with a change <strong>in</strong> temperature.<br />
g) Crack<strong>in</strong>g <strong>in</strong> cast components such as valves may <strong>in</strong>itiate at cast<strong>in</strong>g flaws on<br />
<strong>the</strong> ID and progress through <strong>the</strong> thickness.<br />
h) Thick sections can develop high <strong>the</strong>rmal gradients.
4.2.13.4 Affected Units or <strong>Equipment</strong><br />
a) FCC, cokers, catalytic reform<strong>in</strong>g and high severity hydroprocess<strong>in</strong>g units<br />
are high temperature units where <strong>the</strong>rmal shock is possible.<br />
b) High temperature pip<strong>in</strong>g and equipment <strong>in</strong> any unit can be affected.<br />
c) Materials that have lost ductility, such as CrMo equipment (temper<br />
embrittlement) are particularly susceptible to <strong>the</strong>rmal shock.<br />
d) <strong>Equipment</strong> subjected to accelerated cool<strong>in</strong>g procedures to m<strong>in</strong>imize<br />
shutdown time.
4.2.13.5 Appearance or Morphology of <strong>Damage</strong><br />
Surface <strong>in</strong>itiat<strong>in</strong>g cracks may also appear as “craze” cracks.<br />
4.2.13.6 Prevention / Mitigation<br />
a) Prevent <strong>in</strong>terruptions <strong>in</strong> <strong>the</strong> flow of high temperature l<strong>in</strong>es.<br />
b) Design to m<strong>in</strong>imize severe restra<strong>in</strong>t.<br />
c) Install <strong>the</strong>rmal sleeves to prevent liquid imp<strong>in</strong>gement on <strong>the</strong> pressure<br />
boundary components.<br />
d) M<strong>in</strong>imize ra<strong>in</strong> or fire water deluge situations.<br />
e) Review hot/cold <strong>in</strong>jection po<strong>in</strong>ts for potential <strong>the</strong>rmal shock.
4.2.13.7 Inspection and Monitor<strong>in</strong>g<br />
a) This type of damage is highly localized and difficult to locate.<br />
b) PT and MT can be used to confirm crack<strong>in</strong>g.<br />
4.2.13.8 Related <strong>Mechanisms</strong><br />
Thermal fatigue (see 4.2.9).
高 温 突 变 学 习 重 点 :<br />
a) 易 感 温 度 : 高 温<br />
b) 原 理 : 当 冷 液 体 接 触 高 温 的 金 属 表 面 时 , 高 和 非 均 匀 的 热 应 力 发 生 . 在 热 膨<br />
胀 / 收 缩 受 到 抑 制 下 形 成 屈 服 强 度 以 上 的 应 力 , 导 致 材 料 开 裂 .<br />
c) 易 感 材 质 : 一 切 工 程 材 料 ,<br />
d) 易 感 设 备 : 高 温 设 备 ,<br />
e) 非 API 510/570 考 试 题
4.2.14 Erosion/ Erosion Corrosion<br />
冲 刷 腐 蚀<br />
API510/570-Exam
API510/570-Exam<br />
4.2.14 Erosion/Erosion – Corrosion 冲 蚀 / 冲 蚀 - 腐 蚀<br />
4.2.14.1 Description of <strong>Damage</strong><br />
a) Erosion is <strong>the</strong> accelerated mechanical removal of surface material as a<br />
result of relative movement between, or impact from solids, liquids, vapor or<br />
any comb<strong>in</strong>ation <strong>the</strong>reof.<br />
b) Erosion-corrosion is a description for <strong>the</strong> damage that occurs when<br />
corrosion contributes to erosion by remov<strong>in</strong>g protective films or scales, or by<br />
expos<strong>in</strong>g <strong>the</strong> metal surface to fur<strong>the</strong>r corrosion under <strong>the</strong> comb<strong>in</strong>ed action<br />
of erosion and corrosion.<br />
• 冲 蚀 - 当 材 料 表 面 ( 固 体 , 液 体 , 气 体 或 它 们 的 任 何 组 合 ) 之 间 的 相 对 运 动 / 撞 击<br />
的 影 响 而 加 速 材 料 表 面 机 械 去 除 .<br />
• 冲 蚀 - 腐 蚀 - 腐 蚀 导 致 侵 金 属 表 面 保 护 膜 / 氧 化 皮 的 丢 失 , 冲 蚀 机 表 面 去 除 , 冲 蚀 -<br />
腐 蚀 的 协 作 效 应 加 深 便 面 损 坏 .<br />
4.2.14.2 Affected Materials<br />
All metals, alloys and refractory.
API510/570-Exam<br />
4.2.14.3 Critical Factors<br />
a) In most cases, corrosion plays some role so that pure erosion (sometimes<br />
referred to as abrasive wear) is rare. It is critical to consider <strong>the</strong> role that<br />
corrosion contributes.<br />
b) Metal loss rates depend on <strong>the</strong> velocity and concentration of impact<strong>in</strong>g<br />
medium (i.e., particles, liquids, droplets, slurries, two-phase flow), <strong>the</strong> size<br />
and hardness of impact<strong>in</strong>g particles, <strong>the</strong> hardness and corrosion resistance<br />
of material subject to erosion, and <strong>the</strong> angle of impact.<br />
c) Softer alloys such as copper and alum<strong>in</strong>um alloys that are easily worn from<br />
mechanical damage may be subject to severe metal loss under high velocity<br />
conditions.<br />
d) Although <strong>in</strong>creas<strong>in</strong>g hardness of <strong>the</strong> metal substrate is a common approach<br />
to m<strong>in</strong>imize damage, it is not always a good <strong>in</strong>dicator of improved resistance<br />
to erosion, particularly where corrosion plays a significant role.
API510/570-Exam<br />
e) For each environment-material comb<strong>in</strong>ation, <strong>the</strong>re is often a threshold<br />
velocity above which impact<strong>in</strong>g objects may produce metal loss. Increas<strong>in</strong>g<br />
velocities above this threshold result <strong>in</strong> an <strong>in</strong>crease <strong>in</strong> metal loss rates as<br />
shown <strong>in</strong> Table 4-5. This table illustrates <strong>the</strong> relative susceptibility of a<br />
variety of metals and alloys to erosion/corrosion by seawater at different<br />
velocities.<br />
f) The size, shape, density and hardness of <strong>the</strong> impact<strong>in</strong>g medium affect <strong>the</strong><br />
metal loss rate.<br />
g) Increas<strong>in</strong>g <strong>the</strong> corrosivity of <strong>the</strong> environment may reduce <strong>the</strong> stability of<br />
protective surface films and <strong>in</strong>crease <strong>the</strong> susceptibility to metal loss. Metal<br />
may be removed from <strong>the</strong> surface as dissolved ions, or as solid corrosion<br />
products which are mechanically swept from <strong>the</strong> metal surface.<br />
h) Factors which contribute to an <strong>in</strong>crease <strong>in</strong> corrosivity of <strong>the</strong> environment,<br />
such as temperature, pH, etc., can <strong>in</strong>crease susceptibility to metal loss.
API510/570-Exam<br />
4.2.14.4 Affected Units or <strong>Equipment</strong><br />
a) All types of equipment exposed to mov<strong>in</strong>g fluids and/or catalyst are subject<br />
to erosion and erosion corrosion. This <strong>in</strong>cludes pip<strong>in</strong>g systems, particularly<br />
<strong>the</strong> bends, elbows, tees and reducers; pip<strong>in</strong>g systems downstream of<br />
letdown valves and block valves; pumps; blowers; propellers; impellers;<br />
agitators; agitated vessels; heat exchanger tub<strong>in</strong>g; measur<strong>in</strong>g device<br />
orifices; turb<strong>in</strong>e blades; nozzles; ducts and vapor l<strong>in</strong>es; scrapers; cutters;<br />
and wear plates.<br />
b) Erosion can be caused by gas borne catalyst particles or by particles<br />
carried by a liquid such as a slurry. In ref<strong>in</strong>eries, this form of damage occurs<br />
as a result of catalyst movement <strong>in</strong> FCC reactor/regenerator systems <strong>in</strong><br />
catalyst handl<strong>in</strong>g equipment (valves, cyclones, pip<strong>in</strong>g, reactors) and slurry<br />
pip<strong>in</strong>g (Figure 4-43); coke handl<strong>in</strong>g equipment <strong>in</strong> both delayed and fluidized<br />
bed cokers (Figure 4-44); and as wear on pumps (Figure 4-45),<br />
compressors and o<strong>the</strong>r rotat<strong>in</strong>g equipment.
API510/570-Exam<br />
c) Hydroprocess<strong>in</strong>g reactor effluent pip<strong>in</strong>g may be subject to erosion-corrosion<br />
by ammonium bisulfide. The metal loss is dependent on several factors<br />
<strong>in</strong>clud<strong>in</strong>g <strong>the</strong> ammonium bisulfide concentration, velocity and alloy corrosion<br />
resistance.<br />
d) Crude and vacuum unit pip<strong>in</strong>g and vessels exposed to naph<strong>the</strong>nic acids <strong>in</strong><br />
some crude oils may suffer severe erosion-corrosion metal loss depend<strong>in</strong>g<br />
on <strong>the</strong> temperature, velocity, sulfur content and TAN level.
API510/570-Exam<br />
4.2.14.5 Appearance or Morphology of <strong>Damage</strong><br />
a) Erosion and erosion-corrosion are characterized by a localized loss <strong>in</strong><br />
thickness <strong>in</strong> <strong>the</strong> form of pits, grooves, gullies, waves, rounded holes and<br />
valleys. These losses often exhibit a directional pattern.<br />
b) Failures can occur <strong>in</strong> a relatively short time.
API510/570-Exam<br />
4.2.14.6 Prevention / Mitigation<br />
a) Improvements <strong>in</strong> design <strong>in</strong>volve changes <strong>in</strong> shape, geometry and materials<br />
selection. Some examples are: <strong>in</strong>creas<strong>in</strong>g <strong>the</strong> pipe diameter to decrease<br />
velocity; streaml<strong>in</strong><strong>in</strong>g bends to reduce imp<strong>in</strong>gement; <strong>in</strong>creas<strong>in</strong>g <strong>the</strong> wall<br />
thickness; and us<strong>in</strong>g replaceable imp<strong>in</strong>gement baffles.<br />
b) Improved resistance to erosion is usually achieved through <strong>in</strong>creas<strong>in</strong>g<br />
substrate hardness us<strong>in</strong>g harder alloys, hardfac<strong>in</strong>g or surface-harden<strong>in</strong>g<br />
treatments. Erosion resistant refractories <strong>in</strong> cyclones and slide valves have<br />
been very successful.
API510/570-Exam<br />
c) Erosion-corrosion is best mitigated by us<strong>in</strong>g more corrosion-resistant alloys<br />
and/or alter<strong>in</strong>g <strong>the</strong> process environment to reduce corrosivity, for example,<br />
deaeration, condensate <strong>in</strong>jection or <strong>the</strong> addition of <strong>in</strong>hibitors. Resistance is<br />
generally not improved through <strong>in</strong>creas<strong>in</strong>g substrate hardness alone.<br />
d) Heat exchangers utilize imp<strong>in</strong>gement plates and occasionally tube ferrules<br />
to m<strong>in</strong>imize erosion problems.<br />
e) Higher molybdenum conta<strong>in</strong><strong>in</strong>g alloys are used for improved resistance to<br />
naph<strong>the</strong>nic acid corrosion.
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4.2.14.7 Inspection and Monitor<strong>in</strong>g<br />
a) Visual exam<strong>in</strong>ation of suspected or troublesome areas, as well as UT<br />
checks or RT can be used to detect <strong>the</strong> extent of metal loss.<br />
b) Specialized corrosion coupons and on-l<strong>in</strong>e corrosion monitor<strong>in</strong>g electrical<br />
resistance probes have been used <strong>in</strong> some applications.<br />
c) IR scans are used to detect refractory loss on stream.<br />
4.2.14.8 Related <strong>Mechanisms</strong><br />
Specialized term<strong>in</strong>ology has been developed for various forms of erosion and<br />
erosion-corrosion <strong>in</strong> specific environments and/or services. This term<strong>in</strong>ology<br />
<strong>in</strong>cludes cavitation, liquid imp<strong>in</strong>gement erosion, frett<strong>in</strong>g and o<strong>the</strong>r similar<br />
terms.
Figure 4-43 – Erosion Corrosion of a 1.25Cr 300 # valve flange on an FCC<br />
Catalyst withdrawal l<strong>in</strong>e.<br />
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Figure 4-44 – Erosion of a 9Cr-1Mo coker heater return bend.<br />
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Figure 4-45 – Erosion-Corrosion of is ASTM A48 Class 30<br />
Cast Iron Impeller <strong>in</strong> recycle water pump.<br />
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定 义 :<br />
Corrosion 腐 蚀 – 化 学 现 象<br />
Erosion 冲 蚀 - 机 械 现 象<br />
Erosion- corrosion 冲 蚀 - 腐 蚀 - 化 学 与 机 械 组 合 现 象<br />
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金 属 可 能 从 表 面 以 (1) 溶 解 离 子 腐 蚀 或 作 为 (2) 固 体 机 械 扫 冲 蚀<br />
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Flow Direction
Flow Direction<br />
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Flow Direction<br />
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Flow Direction<br />
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Imp<strong>in</strong>gement<br />
po<strong>in</strong>t<br />
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Flow Direction
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冲 蚀 / 冲 蚀 - 腐 蚀 学 习 重 点 :<br />
a) 易 感 温 度 : 操 作 温 度 ,<br />
b) 原 理 : 设 备 溶 液 流 动 ( 液 体 , 气 体 , 固 体 或 其 组 合 ) 导 致 机 械 磨 损 与 通 过 保 护<br />
性 氧 化 膜 机 械 去 除 加 剧 表 面 腐 蚀 .<br />
c) 易 感 材 质 : 一 切 工 程 材 料 ,<br />
d) 易 感 设 备 : ,<br />
e) API 510/570 考 试 题 .
4.2.15 Cavitation<br />
气 穴 现 象
4.2.15 Cavitation<br />
4.2.15.1 Description of <strong>Damage</strong><br />
• 当 液 体 受 压 波 动 , 在 压 力 的 快 速 变 化 时 , 小 气 空 会 在 低 压 区 域 产 生 , 这 无 数<br />
小 气 泡 形 成 , 瞬 间 在 高 压 区 域 崩 溃 . 上 述 的 崩 溃 的 气 泡 产 生 严 重 的 局 部 冲 击<br />
力 , 可 导 致 金 属 损 失 的 侵 蚀 现 象 , 这 叫 做 气 穴 现 象 .<br />
a) Cavitation is a form of erosion caused by <strong>the</strong> formation and <strong>in</strong>stantaneous<br />
collapse of <strong>in</strong>numerable t<strong>in</strong>y vapor bubbles.<br />
b) The collaps<strong>in</strong>g bubbles exert severe localized impact forces that can<br />
result <strong>in</strong> metal loss referred to as cavitation damage.<br />
c) The bubbles may conta<strong>in</strong> <strong>the</strong> vapor phase of <strong>the</strong> liquid, air or o<strong>the</strong>r gas<br />
entra<strong>in</strong>ed <strong>in</strong> <strong>the</strong> liquid medium.<br />
4.2.15.2 Affected Materials<br />
• Most common materials of construction <strong>in</strong>clud<strong>in</strong>g copper and brass, cast<br />
iron, carbon steel, low alloy steels, 300 Series SS, 400 Series SS and<br />
nickel base alloys.
4.2.15.3 Critical Factors<br />
a) In a pump, <strong>the</strong> difference between <strong>the</strong> actual pressure or head of <strong>the</strong> liquid<br />
available (measured on <strong>the</strong> suction side) and <strong>the</strong> vapor pressure of that liquid<br />
is called <strong>the</strong> Net Positive Suction Head (NPSH) available. The m<strong>in</strong>imum<br />
head required to prevent cavitation with a given liquid at a given flow rate is<br />
called <strong>the</strong> net positive suction head required. Inadequate NPSH can result <strong>in</strong><br />
cavitation.<br />
b) Temperatures approach<strong>in</strong>g <strong>the</strong> boil<strong>in</strong>g po<strong>in</strong>t of <strong>the</strong> liquid are more likely to<br />
result <strong>in</strong> bubble formation than lower temperature operation.<br />
c) The presence of solid or abrasive particles is not required for cavitation<br />
damage but will accelerate <strong>the</strong> damage.
4.2.15.4 Affected Units or <strong>Equipment</strong><br />
a) Cavitation is most often observed <strong>in</strong> pump cas<strong>in</strong>gs, pump impellers (low<br />
pressure side) and <strong>in</strong> pip<strong>in</strong>g downstream of orifices or control valves.<br />
b) <strong>Damage</strong> can also be found <strong>in</strong> restricted-flow passages or o<strong>the</strong>r areas<br />
where turbulent flow is subjected to rapid pressure changes with<strong>in</strong> a<br />
localized region. Examples of affected equipment <strong>in</strong>clude heat exchanger<br />
tubes, venturis, seals and impellers.<br />
4.2.15.5 Appearance or Morphology of <strong>Damage</strong><br />
Cavitation damage generally looks like sharp-edged pitt<strong>in</strong>g but may also have<br />
a gouged appearance <strong>in</strong> rotational components. However, damage occurs<br />
only <strong>in</strong> localized low-pressure zones (see Figure 4-46, Figure 4-47 to<br />
Figure 4-49).
4.2.15.6 Prevention / Mitigation<br />
a) Resistance to cavitation damage <strong>in</strong> a specific environment may not be<br />
significantly improved by a material change. A mechanical modification,<br />
design or operat<strong>in</strong>g change is usually required.<br />
b) Cavitation is best prevented by avoid<strong>in</strong>g conditions that allow <strong>the</strong><br />
absolute pressure to fall below <strong>the</strong> vapor pressure of <strong>the</strong> liquid or by<br />
chang<strong>in</strong>g <strong>the</strong> material properties.<br />
Examples <strong>in</strong>clude:<br />
1. Streaml<strong>in</strong>e <strong>the</strong> flow path to reduce turbulence.<br />
2. Decrease fluid velocities.<br />
3. Remove entra<strong>in</strong>ed air.<br />
4. Increase <strong>the</strong> suction pressure of pumps.<br />
5. Alter <strong>the</strong> fluid properties, perhaps by add<strong>in</strong>g additives.<br />
6. Use hard surfac<strong>in</strong>g or hardfac<strong>in</strong>g.<br />
7. Use of harder and/or more corrosion resistant alloys.
c) Attack is accelerated by <strong>the</strong> mechanical disruption of protective films at <strong>the</strong><br />
liquid-solid <strong>in</strong>terface (such as a protective corrosion scale or passive films).<br />
Therefore, chang<strong>in</strong>g to a more corrosion resistant and/or higher hardness<br />
material may not improve cavitation resistance. Excessively hard materials<br />
may not be suitable if <strong>the</strong>y lack <strong>the</strong> toughness required to withstand <strong>the</strong> high<br />
local pressures and impact (shear loads) of <strong>the</strong> collaps<strong>in</strong>g bubbles.
4.2.15.7 Inspection and Monitor<strong>in</strong>g<br />
a) Cavitat<strong>in</strong>g pumps may sound like pebbles are be<strong>in</strong>g thrashed around <strong>in</strong>side.<br />
a) Techniques <strong>in</strong>clude limited monitor<strong>in</strong>g of fluid properties as well as acoustic<br />
monitor<strong>in</strong>g of turbulent areas to detect characteristic sound frequencies.<br />
a) Visual exam<strong>in</strong>ation of suspected areas, as well as external UT and RT can<br />
be used to monitor for loss <strong>in</strong> thickness.<br />
4.2.15.8 Related <strong>Mechanisms</strong><br />
Liquid imp<strong>in</strong>gement or erosion (see 4.2.14).
气 穴 腐 蚀 学 习 重 点 :<br />
a) 易 感 温 度 : 操 作 温 度<br />
b) 原 理 : 当 液 体 受 压 波 动 , 在 压 力 的 快 速 变 化 时 , 小 气 空 会 在 低 压 区 域 产 生 ,<br />
这 无 数 小 气 泡 形 成 , 瞬 间 在 高 压 区 域 崩 溃 . 上 述 的 崩 溃 的 气 泡 产 生 严 重 的<br />
局 部 冲 击 力 , 可 导 致 金 属 损 失 的 侵 蚀 现 象 , 这 叫 做 气 穴 现 象 .<br />
c) 易 感 材 质 : 一 切 工 程 材 料 ,<br />
d) 易 感 设 备 : 泵 , 限 流 通 道 或 其 他 湍 流 流 动 设 备 与 管 道 .<br />
e) 预 防 / 缓 解 : 更 改 设 计 以 减 少 湍 流 , 提 高 泵 的 吸 入 压 力 , 改 变 流 体 的 性 质 如<br />
通 过 加 入 添 加 剂 , 增 加 材 料 硬 度 等 .<br />
f) 非 API 510/570 考 试 题 .
4.2.16 Mechanical Fatigue<br />
机 械 疲 劳<br />
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4.2.16 Mechanical Fatigue 机 械 疲 劳<br />
4.2.16.1 Description of <strong>Damage</strong><br />
a) Fatigue crack<strong>in</strong>g is a mechanical form of degradation that occurs when a<br />
component is exposed to cyclical stresses for an extended period, often<br />
result<strong>in</strong>g <strong>in</strong> sudden, unexpected failure. 长 期 的 循 环 应 力 造 成 破 坏 .<br />
b) These stresses can arise from ei<strong>the</strong>r (1) mechanical load<strong>in</strong>g or (2) <strong>the</strong>rmal<br />
cycl<strong>in</strong>g and are typically well below <strong>the</strong> yield strength of <strong>the</strong> material.<br />
通 常 低 于 屈 服 强 度 的 机 械 载 荷 或 循 环 热 应 力<br />
4.2.16.2 Affected Materials<br />
• All eng<strong>in</strong>eer<strong>in</strong>g alloys are subject to fatigue crack<strong>in</strong>g although <strong>the</strong> stress<br />
levels and number of cycles necessary to cause failure vary by material.
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4.2.16.3 Critical Factors<br />
Geometry, stress level, number of cycles, and material properties (strength, hardness,<br />
microstructure) are <strong>the</strong> predom<strong>in</strong>ant factors <strong>in</strong> determ<strong>in</strong><strong>in</strong>g <strong>the</strong> fatigue resistance of a<br />
component.<br />
a) Design: Fatigue cracks usually <strong>in</strong>itiate on <strong>the</strong> surface at notches or stress raisers under<br />
cyclic load<strong>in</strong>g. For this reason, design of a component is <strong>the</strong> most important factor <strong>in</strong><br />
determ<strong>in</strong><strong>in</strong>g a component’s resistance to fatigue crack<strong>in</strong>g. Several common surface<br />
features can lead to <strong>the</strong> <strong>in</strong>itiation of fatigue cracks as <strong>the</strong>y can act as stress<br />
concentrations. Some of <strong>the</strong>se common features are:<br />
1. Mechanical notches (sharp corners or groves);<br />
2. Key holes on drive shafts of rotat<strong>in</strong>g equipment;<br />
3. Weld jo<strong>in</strong>t, flaws and/or mismatches;<br />
4. Quench nozzle areas;<br />
5. Tool mark<strong>in</strong>gs;<br />
6. Gr<strong>in</strong>d<strong>in</strong>g marks;<br />
7. Lips on drilled holes;<br />
8. Thread root notches;<br />
9. Corrosion.
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b) Metallurgical Issues and Microstructure<br />
1. For some materials such as titanium, carbon steel and low alloy steel, <strong>the</strong> number of<br />
cycles to fatigue fracture decreases with stress amplitude until an endurance limit<br />
reached. Below this stress endurance limit, fatigue crack<strong>in</strong>g will not occur,<br />
regardless of <strong>the</strong> number of cycles.<br />
2. For alloys with endurance limits, <strong>the</strong>re is a correlation between Ultimate Tensile<br />
Strength (UTS) and <strong>the</strong> m<strong>in</strong>imum stress amplitude necessary to <strong>in</strong>itiate fatigue<br />
crack<strong>in</strong>g. The ratio of endurance limit over UTS is typically between 0.4 and 0.5.<br />
Materials like austenitic sta<strong>in</strong>less steels and alum<strong>in</strong>um that do not have an endurance<br />
limit will have a fatigue limit def<strong>in</strong>ed by <strong>the</strong> number of cycles at a given stress<br />
amplitude.<br />
3. Inclusions found <strong>in</strong> metal can have an accelerat<strong>in</strong>g effect on fatigue crack<strong>in</strong>g. This is<br />
of importance when deal<strong>in</strong>g with older, “dirty” steels or weldments, as <strong>the</strong>se often<br />
have <strong>in</strong>clusions and discont<strong>in</strong>uities that can degrade fatigue resistance.<br />
4. Heat treatment can have a significant effect on <strong>the</strong> toughness and hence fatigue<br />
resistance of a metal. In general, f<strong>in</strong>er gra<strong>in</strong>ed microstructures tend to perform better<br />
than coarse gra<strong>in</strong>ed. Heat treatments such as quench<strong>in</strong>g and temper<strong>in</strong>g, can improve<br />
fatigue resistance of carbon and low alloy steels.
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For alloys with endurance limits, <strong>the</strong>re is a correlation between Ultimate<br />
Tensile Strength (UTS) and <strong>the</strong> m<strong>in</strong>imum stress amplitude necessary to<br />
<strong>in</strong>itiate fatigue crack<strong>in</strong>g. The ratio of endurance limit over UTS is typically<br />
between 0.4 and 0.5. Materials like austenitic sta<strong>in</strong>less steels and alum<strong>in</strong>um<br />
that do not have an endurance limit will have a fatigue limit def<strong>in</strong>ed by <strong>the</strong><br />
number of cycles at a given stress amplitude.<br />
疲 劳 极 限 合 金 : 引 发 疲 劳 开 裂 最 小 应 力 振 幅 和 材 料 抗 拉 强 度 存 在 相 关 性 , 这 通<br />
常 在 0.4 和 0.5UTS 之 间 .<br />
奥 氏 体 不 锈 钢 和 铝 材 料 , 没 有 引 发 疲 劳 开 裂 极 限 的 最 小 应 力 振 幅 .
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c) Carbon Steel and Titanium: These materials exhibit an endurance limit<br />
below which fatigue crack<strong>in</strong>g will not occur, regardless of <strong>the</strong> number of<br />
cycles.<br />
d) 300 Series SS, 400 Series SS, alum<strong>in</strong>um and most o<strong>the</strong>r non-ferrous alloys:<br />
1. These alloys have a fatigue characteristic that does not exhibit an<br />
endurance limit. This means that fatigue fracture can be achieved under<br />
cyclical load<strong>in</strong>g eventually, regardless of stress amplitude.<br />
2. Maximum cyclical stress amplitude is determ<strong>in</strong>ed by relat<strong>in</strong>g <strong>the</strong> stress<br />
necessary to cause fracture to <strong>the</strong> desired number of cycles necessary<br />
<strong>in</strong> a component’s lifetime. This is typically 10 6 to 10 7 cycles.
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4.2.16.4 Affected Units or <strong>Equipment</strong><br />
a) Thermal Cycl<strong>in</strong>g<br />
1. <strong>Equipment</strong> that cycles daily <strong>in</strong> operation such as coke drums.<br />
2. <strong>Equipment</strong> that may be auxiliary or on cont<strong>in</strong>uous standby but sees <strong>in</strong>termittent<br />
service such as auxiliary boiler.<br />
3. Quench nozzle connections that see significant temperature deltas dur<strong>in</strong>g operations<br />
such as water wash<strong>in</strong>g systems.<br />
b) Mechanical Load<strong>in</strong>g<br />
1. Pressure Sw<strong>in</strong>g Absorbers on hydrogen purification units.<br />
2. Rotat<strong>in</strong>g shafts on centrifugal pumps and compressors that have stress concentrations<br />
due to changes <strong>in</strong> radii and key ways.<br />
3. Components such as small diameter pip<strong>in</strong>g that may see vibration from adjacent<br />
equipment and/or w<strong>in</strong>d. For small components, resonance can also produce a cyclical<br />
load and should be taken <strong>in</strong>to consideration dur<strong>in</strong>g design and reviewed for potential<br />
problems after <strong>in</strong>stallation.<br />
4. High pressure drop control valves or steam reduc<strong>in</strong>g stations can cause serious<br />
vibration problems <strong>in</strong> connected pip<strong>in</strong>g.
a) Thermal Cycl<strong>in</strong>g<br />
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b) Mechanical Load<strong>in</strong>g<br />
Amplitude
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4.2.16.5 Appearance or Morphology of <strong>Damage</strong><br />
a) The signature mark of a fatigue failure is a “clam shell” type f<strong>in</strong>gerpr<strong>in</strong>t that<br />
has concentric r<strong>in</strong>gs called “beach marks” emanat<strong>in</strong>g from <strong>the</strong> crack <strong>in</strong>itiation<br />
site (Figure 4-50 and Figure 4-51). This signature pattern results from <strong>the</strong><br />
“waves” of crack propagation that occur dur<strong>in</strong>g cycles above <strong>the</strong> threshold<br />
load<strong>in</strong>g. These concentric cracks cont<strong>in</strong>ue to propagate until <strong>the</strong> crosssectional<br />
area is reduced to <strong>the</strong> po<strong>in</strong>t where failure due to overload occurs.<br />
b) Cracks nucleat<strong>in</strong>g from a surface stress concentration or defect will typically<br />
result <strong>in</strong> a s<strong>in</strong>gle “clam shell” f<strong>in</strong>gerpr<strong>in</strong>t (Figure 4-52 to Figure 4-56).<br />
c) Cracks result<strong>in</strong>g from cyclical overstress of a component without significant<br />
stress concentration will typically result <strong>in</strong> a fatigue failure with multiple<br />
po<strong>in</strong>ts of nucleation and hence multiple “clam shell” f<strong>in</strong>gerpr<strong>in</strong>ts. These<br />
multiple nucleation sites are <strong>the</strong> result of microscopic yield<strong>in</strong>g that occurs<br />
when <strong>the</strong> component is momentarily cycled above its yield strength.
Figure 4-50 – Schematic of a fatigue fracture surface show<strong>in</strong>g “beach marks”.<br />
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Figure 4-51 – Compressor rod fracture surface show<strong>in</strong>g “beach marks”<br />
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Figure 4-52 – Higher magnification view of figure above show<strong>in</strong>g “beach marks”.<br />
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Figure 4-53 – Fatigue fracture surface of a carbon steel pipe.<br />
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Figure 4-54 – Fatigue crack <strong>in</strong> a 16-<strong>in</strong>ch pipe-to-elbow weld <strong>in</strong> <strong>the</strong> fill l<strong>in</strong>e of<br />
crude oil storage tank after 50 years <strong>in</strong> service.<br />
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Figure 4-55 – A cross-section through <strong>the</strong> weld show<strong>in</strong>g <strong>the</strong> crack location.<br />
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Figure 4-56 – The surface of <strong>the</strong> fracture faces of <strong>the</strong> crack shown <strong>in</strong><br />
Figure 4-54 and Figure 4-55.<br />
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The signature mark of<br />
a fatigue failure is a<br />
“clam shell 蛤 壳 ”type<br />
f<strong>in</strong>gerpr<strong>in</strong>t that has<br />
concentric r<strong>in</strong>gs called<br />
“beach marks”<br />
emanat<strong>in</strong>g from <strong>the</strong><br />
crack <strong>in</strong>itiation site
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http://www.efunda.com/formulae/solid_mechanics/fatigue/fatigue_lowcycle.cfm<br />
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530.352 Materials Selection<br />
Lecture #23 Fatigue<br />
Tuesday<br />
November 8 th , 2005<br />
http://www.me.jhu.edu/hemker/MatSel/lectures/23%20Fatigue.ppt<br />
159
Failure even at low Stresses<br />
• Failure often occurs even when:<br />
applied < fracture<br />
yield<strong>in</strong>g<br />
and<br />
applied <<br />
• 90% of all mechanical failures are<br />
related to dynamic load<strong>in</strong>g.<br />
• Dynamic Load<strong>in</strong>g -> > Cyclic Stresses<br />
160
Examples of Fatigue Failures<br />
Plastic Tricycle:<br />
161
Examples of Fatigue Failures<br />
Door Stop:<br />
162
Examples of Fatigue Failures<br />
Railway Accidents:<br />
• Versailles 1842<br />
• first fatigue problem<br />
• axial failure<br />
• Today<br />
• flaws <strong>in</strong> 10% of<br />
rails.<br />
163
Types of Fatigue<br />
• Fatigue of uncracked components<br />
• No pre-cracks; <strong>in</strong>itiation controlled fracture<br />
• Examples : most small components: p<strong>in</strong>s, gears,<br />
axles, ...<br />
• High cycle fatigue<br />
• fatigue<br />
• Low cycle fatigue<br />
< yield ; N f > 10,000<br />
• fatigue<br />
> yield ; N f < 10,000<br />
164
Types of Fatigue:<br />
Fatigue of cracked structures<br />
–Pre-cracks exist: propagation<br />
controls fracture<br />
–Examples : most large components,<br />
particularly those conta<strong>in</strong><strong>in</strong>g welds:<br />
bridges, airplanes, ships, pressure<br />
vessels, ...<br />
165
Cyclic Load<strong>in</strong>g<br />
<br />
Weight<br />
+<br />
time<br />
-<br />
166
Basic Fatigue Term<strong>in</strong>ology:<br />
+<br />
max<br />
<br />
0<br />
-<br />
mean<br />
m<strong>in</strong><br />
time<br />
max m<strong>in</strong> <br />
mean max m<strong>in</strong> <br />
amplitude max m<strong>in</strong> <br />
N = number of fatigue cycles<br />
N f = number of cycles<br />
to failure<br />
167
High Cycle Fatigue<br />
S-N Curves<br />
• Apply controlled <br />
applied < ~ 2 / 3 yield<br />
• Stress is elastic<br />
on gross scale.<br />
• Locally <strong>the</strong> metal<br />
deforms plastically.<br />
Stress<br />
50<br />
40<br />
30<br />
10<br />
0<br />
Mild Steel<br />
Al alloys<br />
10 5 10 6 10 7 10 8 10 9<br />
N failure<br />
Fatigue limit<br />
168
Low Cycle Fatigue<br />
• Apply controlled amounts of <br />
• total = elastic + <br />
plastic<br />
total<br />
• Empirical Observations and Rules<br />
• Coff<strong>in</strong>-Manson Law<br />
• M<strong>in</strong>er’s s Rule<br />
169
Coff<strong>in</strong>-Manson Law<br />
For low cycle fatigue:<br />
plastic N failure<br />
1/2<br />
= Const.<br />
log pl<br />
y = y /E<br />
~10 4<br />
log N failure<br />
170
M<strong>in</strong>er’s s Rule<br />
Rule of Accumulative damage:<br />
N 1 N 2 N 3<br />
<br />
N i<br />
= N 1<br />
failure @ i<br />
Fraction of life time @ i<br />
171
• Crack <strong>in</strong>itiation<br />
The Fatigue Process<br />
• early development of damage<br />
• Stage I crack growth<br />
• deepen<strong>in</strong>g of <strong>in</strong>itial crack on shear planes<br />
• Stage II crack growth<br />
• growth of well def<strong>in</strong>ed crack on planes normal<br />
to maximum tensile stress<br />
• Ultimate Failure<br />
172
Crack <strong>in</strong>itiation<br />
Cracks start at:<br />
• Surfaces<br />
• Inclusions<br />
• Exist<strong>in</strong>g<br />
cracks<br />
Alternate stresses -> slip bands<br />
-> surface rumpl<strong>in</strong>g<br />
173
Crack Initiation:<br />
174
Crack Growth<br />
Striation <strong>in</strong>dicat<strong>in</strong>g<br />
steps <strong>in</strong> crack<br />
advancement.<br />
175
Propagation <strong>in</strong> Cracked<br />
Structures<br />
a o ~ a detectible < a critical<br />
a o -> a critical = FAILURE !!!<br />
K = K -K max m<strong>in</strong><br />
= (a) 1/2<br />
da = A K m<br />
1<br />
dN<br />
log da/dN<br />
threshold<br />
l<strong>in</strong>ear<br />
Fast fracture<br />
log K<br />
176
Real world comparisons:<br />
log da/dN<br />
threshold<br />
l<strong>in</strong>ear<br />
Fast fracture<br />
log K<br />
177
Fracture surfaces:<br />
178
Fracture Surfaces:<br />
Initiation<br />
site<br />
Fatigue<br />
crack<strong>in</strong>g<br />
F<strong>in</strong>al fracture<br />
179
API510/570-Exam<br />
机 械 疲 劳 学 习 重 点 :<br />
a) 易 感 温 度 : 操 作 温 度 ,<br />
b) 原 理 : 长 期 的 循 环 应 力 造 成 破 坏 .<br />
c) 易 感 材 质 : 一 切 工 程 材 料 ,<br />
d) 易 感 设 备 : 温 度 循 环 设 备 , 机 械 振 动 设 备 ,<br />
e) 预 防 / 缓 解 : 通 过 设 计 减 少 振 动 与 温 度 循 环 .<br />
f) API 510/570 考 试 题 .
4.2.17 Vibration Induced Fatigue<br />
振 动 疲 劳<br />
API 570-Exam
API 570-Exam<br />
4.2.17 Vibration-Induced Fatigue 振 动 引 起 的 疲 劳<br />
4.2.17.1 Description of <strong>Damage</strong><br />
A form of mechanical fatigue <strong>in</strong> which cracks are produced as <strong>the</strong> result of<br />
dynamic load<strong>in</strong>g due to vibration, water hammer, or unstable fluid flow.<br />
4.2.17.2 Affected Materials<br />
All eng<strong>in</strong>eer<strong>in</strong>g materials.<br />
4.2.17.3 Critical Factors<br />
a) The amplitude and frequency of vibration as well as <strong>the</strong> fatigue<br />
resistance of <strong>the</strong> components are critical factors. 振 动 的 振 幅 和 频 率<br />
b) There is a high likelihood of crack<strong>in</strong>g when <strong>the</strong> <strong>in</strong>put load is<br />
synchronous or nearly synchronizes with <strong>the</strong> natural frequency of <strong>the</strong><br />
component. 共 鸣 ( 同 步 ) 频 率<br />
c) A lack of or excessive support or stiffen<strong>in</strong>g allows vibration and<br />
possible crack<strong>in</strong>g problems that usually <strong>in</strong>itiate at stress raisers or<br />
notches. 局 部 应 力 集 中 或 缺 口
API 570-Exam<br />
4.2.17.4 Affected Units or <strong>Equipment</strong><br />
a) Socket welds and small bore pip<strong>in</strong>g at or near pumps and compressors that<br />
are not sufficiently gusseted.<br />
b) Small bore bypass l<strong>in</strong>es and flow loops around rotat<strong>in</strong>g and reciprocat<strong>in</strong>g<br />
equipment.<br />
c) Small branch connections with unsupported valves or controllers.<br />
d) Safety relief valves are subject to chatter, premature pop-off, frett<strong>in</strong>g and<br />
failure to operate properly.<br />
e) High pressure drop control valves and steam reduc<strong>in</strong>g stations.<br />
f) Heat exchanger tubes may be susceptible to vortex shedd<strong>in</strong>g.
API 570-Exam<br />
4.2.17.5 Appearance or Morphology of <strong>Damage</strong><br />
a) <strong>Damage</strong> is usually <strong>in</strong> <strong>the</strong> form of a crack <strong>in</strong>itiat<strong>in</strong>g at a po<strong>in</strong>t of high stress or<br />
discont<strong>in</strong>uity such as a thread or weld jo<strong>in</strong>t (Figure 4-57 and Figure 4-58).<br />
b) A potential warn<strong>in</strong>g sign of vibration damage to refractories is <strong>the</strong> visible<br />
damage result<strong>in</strong>g from <strong>the</strong> failure of <strong>the</strong> refractory and/or <strong>the</strong> anchor<strong>in</strong>g<br />
system. High sk<strong>in</strong> temperatures may result from refractory damage.
API 570-Exam<br />
4.2.17.6 Prevention / Mitigation<br />
a) Vibration-<strong>in</strong>duced fatigue can be elim<strong>in</strong>ated or reduced through design and<br />
<strong>the</strong> use of supports and vibration dampen<strong>in</strong>g equipment. Material upgrades<br />
are not usually a solution.<br />
b) Install gussets or stiffeners on small bore connections. Elim<strong>in</strong>ate<br />
unnecessary connections and <strong>in</strong>spect field <strong>in</strong>stallations.<br />
c) Vortex shedd<strong>in</strong>g can be m<strong>in</strong>imized at <strong>the</strong> outlet of control valves and safety<br />
valves through proper side branch siz<strong>in</strong>g and flow stabilization techniques.<br />
d) Vibration effects may be shifted when a vibrat<strong>in</strong>g section is anchored.<br />
Special studies may be necessary before anchors or dampeners are<br />
provided, unless <strong>the</strong> vibration is elim<strong>in</strong>ated by remov<strong>in</strong>g <strong>the</strong> source.
API 570-Exam<br />
4.2.17.7 Inspection and Monitor<strong>in</strong>g<br />
a) Look for visible signs of vibration, pipe movement or water hammer.<br />
b) Check for <strong>the</strong> audible sounds of vibration emanat<strong>in</strong>g from pip<strong>in</strong>g<br />
components such as control valves and fitt<strong>in</strong>gs.<br />
c) Conduct visual <strong>in</strong>spection dur<strong>in</strong>g transient conditions (such as startups,<br />
shutdowns, upsets, etc.) for <strong>in</strong>termittent vibrat<strong>in</strong>g conditions.<br />
d) Measure pipe vibrations us<strong>in</strong>g special monitor<strong>in</strong>g equipment.<br />
e) The use of surface <strong>in</strong>spection methods (such as PT, MT) can be effective<br />
<strong>in</strong> a focused plan.<br />
f) Check pipe supports and spr<strong>in</strong>g hangers on a regular schedule.<br />
g) <strong>Damage</strong> to <strong>in</strong>sulation jacket<strong>in</strong>g may <strong>in</strong>dicate excessive vibration. This<br />
can result <strong>in</strong> wett<strong>in</strong>g <strong>the</strong> <strong>in</strong>sulation which will cause corrosion.
API 570-Exam<br />
4.2.17.8 Related <strong>Mechanisms</strong><br />
Mechanical fatigue (see 4.2.16) and refractory degradation (see 4.2.18).
Figure 4-57 – Vibration <strong>in</strong>duced fatigue of a 1-<strong>in</strong>ch socket weld flange <strong>in</strong> a<br />
<strong>the</strong>rmal relief system shortly after startup.<br />
API 570-Exam
Figure 4-58 – Cross-sectional view of <strong>the</strong> crack <strong>in</strong> <strong>the</strong> socket weld <strong>in</strong> Figure 4-57.<br />
API 570-Exam
API 570-Exam
API 570-Exam
振 动 引 起 的 疲 劳 学 习 重 点 :<br />
a) 易 感 温 度 : 操 作 温 度<br />
b) 原 理 : 热 疲 劳 开 裂 是 由 振 动 引 起 循 环 应 力 引 起 的 开 裂 ,<br />
c) 易 感 材 质 : 一 切 工 程 材 料 ,<br />
d) 易 感 设 备 : 小 口 径 管 路 , 高 压 力 差 管 路 ,<br />
e) 预 防 / 缓 解 : 设 计 控 制 , 振 动 阻 尼 装 置 , 支 撑 ,<br />
f) API 570 考 试 题 .
4.2.18 Refractory Degradation<br />
耐 火 垫 退 化
4.2.18 Refractory Degradation 耐 火 材 料 退 化<br />
4.2.18.1 Description of <strong>Damage</strong><br />
Both <strong>the</strong>rmal <strong>in</strong>sulat<strong>in</strong>g and erosion resistant refractories are susceptible to<br />
various forms of mechanical damage (crack<strong>in</strong>g, spall<strong>in</strong>g and erosion) as well<br />
as corrosion due to oxidation, sulfidation and o<strong>the</strong>r high temperature<br />
mechanisms.<br />
4.2.18.2 Affected Materials<br />
Refractory materials <strong>in</strong>clude <strong>in</strong>sulat<strong>in</strong>g ceramic fibers, castables, refractory<br />
brick and plastic refractories.
4.2.18.3 Critical Factors<br />
a) Refractory selection, design and <strong>in</strong>stallation are <strong>the</strong> keys to m<strong>in</strong>imiz<strong>in</strong>g<br />
damage.<br />
b) Refractory l<strong>in</strong>ed equipment should be designed for erosion, <strong>the</strong>rmal shock<br />
and <strong>the</strong>rmal expansion.<br />
c) Dry out schedules, cure times and application procedures should be <strong>in</strong><br />
accordance with <strong>the</strong> manufacturer’s specifications and <strong>the</strong> appropriate<br />
ASTM requirements.<br />
d) Anchor materials must be compatible with <strong>the</strong>rmal coefficients of expansion<br />
of <strong>the</strong> base metal.<br />
e) Anchors must be resistant to oxidation <strong>in</strong> high temperature services.
f) Anchors must be resistant to condens<strong>in</strong>g sulfurous acids <strong>in</strong> heaters and<br />
flue gas environments.<br />
g) Refractory type and density must be selected to resist abrasion and erosion<br />
based on service requirements.<br />
h) Needles and o<strong>the</strong>r fillers must be compatible with <strong>the</strong> process environment<br />
composition and temperature.
4.2.18.4 Affected Units or <strong>Equipment</strong><br />
a) Refractories are extensively used <strong>in</strong> FCC reactor regenerator vessels,<br />
pip<strong>in</strong>g, cyclones, slide valves and <strong>in</strong>ternals; <strong>in</strong> fluid cokers; <strong>in</strong> cold shell<br />
catalytic reform<strong>in</strong>g reactors; and <strong>in</strong> waste heat boilers and <strong>the</strong>rmal reactors<br />
<strong>in</strong> sulfur plants.<br />
b) Boiler fire boxes and stacks which also use refractory are affected.
4.2.18.5 Appearance or Morphology of <strong>Damage</strong><br />
a) Refractory may show signs of excessive crack<strong>in</strong>g, spall<strong>in</strong>g or lift-off from<br />
<strong>the</strong> substrate, soften<strong>in</strong>g or general degradation from exposure to moisture.<br />
b) Coke deposits may develop beh<strong>in</strong>d refractory and promote crack<strong>in</strong>g and<br />
deterioration.<br />
c) In erosive services, refractory may be washed away or th<strong>in</strong>ned, expos<strong>in</strong>g<br />
<strong>the</strong> anchor<strong>in</strong>g system. (Figure 4-59)<br />
4.2.18.6 Prevention / Mitigation<br />
Proper selection of refractory, anchors and fillers and <strong>the</strong>ir proper design and<br />
<strong>in</strong>stallation are <strong>the</strong> keys to m<strong>in</strong>imiz<strong>in</strong>g refractory damage.
4.2.18.7 Inspection and Monitor<strong>in</strong>g<br />
a) Conduct visual <strong>in</strong>spection dur<strong>in</strong>g shutdowns.<br />
b) Survey cold-wall equipment onstream us<strong>in</strong>g IR to monitor for hot spots to<br />
help identify refractory damage.<br />
4.2.18.8 Related <strong>Mechanisms</strong><br />
Oxidation (see 4.4.1), sulfidation (see 4.4.2) and flue gas dew po<strong>in</strong>t corrosion<br />
(see 4.3.7).
Figure 4-59 – <strong>Damage</strong>d refractory and ferrules.
耐 火 材 料 退 化 学 习 重 点 :<br />
a) 易 感 温 度 : 高 温<br />
b) 原 理 : 机 械 或 腐 蚀 引 起 退 化 ,<br />
c) 易 感 材 质 : 耐 火 材 料 ,<br />
d) 易 感 设 备 : 耐 火 材 料 设 备 ,<br />
e) 预 防 / 缓 解 : 锚 杆 材 料 必 须 与 基 体 金 属 的 热 膨 胀 系 数 相 兼 容 , 锚 栓 必 须 耐 高<br />
温 氧 化 ,<br />
f) 非 API 510/570 考 试 题 .
4.2.19 Reheat Crack<strong>in</strong>g<br />
再 热 裂 纹
4.2.19 Reheat Crack<strong>in</strong>g<br />
4.2.19.1 Description of <strong>Damage</strong><br />
由 于 再 次 受 热 产 生 的 应 力 松 弛 的 金 属 开 裂<br />
Crack<strong>in</strong>g of a metal due to stress relaxation dur<strong>in</strong>g Post Weld Heat Treatment<br />
(PWHT) or <strong>in</strong> service at elevated temperatures. It is most often observed <strong>in</strong><br />
heavy wall sections.<br />
4.2.19.2 Affected Materials<br />
Low alloy steels as well as 300 Series SS and nickel base alloys such as<br />
Alloy 800H. (ferritic & Austenitic)<br />
4.2.19.8 Related <strong>Mechanisms</strong><br />
Reheat crack<strong>in</strong>g has also been referred to <strong>in</strong> <strong>the</strong> literature as “stress relief<br />
crack<strong>in</strong>g” and “stress relaxation crack<strong>in</strong>g”. 应 力 松 弛 开 裂
再 热 裂 纹<br />
Reheat crack<strong>in</strong>g occurs at elevated temperatures when creep ductility is<br />
<strong>in</strong>sufficient to accommodate <strong>the</strong> stra<strong>in</strong>s required for <strong>the</strong> relief of<br />
applied or residual stresses. The gra<strong>in</strong> size has an important <strong>in</strong>fluence on<br />
<strong>the</strong> high temperature ductility and on <strong>the</strong> reheat crack<strong>in</strong>g susceptibility.<br />
A large gra<strong>in</strong> size result <strong>in</strong> less ductile heat affected zones, mak<strong>in</strong>g <strong>the</strong><br />
material more susceptible to reheat crack<strong>in</strong>g.<br />
在 升 高 的 温 度 下 , 再 热 裂 纹 发 生 ; 当 蠕 变 延 性 不 足 以 容 纳 , 所 需 的 ” 应 用 ” 或 ” 残 余<br />
应 力 ” 松 弛 变 化 . 大 粒 径 的 晶 粒 , 焊 接 热 影 响 区 韧 性 较 差 , 这 造 成 焊 接 热 影 响 易<br />
受 再 热 开 裂 .
4.2.19.3 Critical Factors<br />
Important parameters <strong>in</strong>clude <strong>the</strong> type of material (chemical composition,<br />
impurity elements), gra<strong>in</strong> size, residual stresses from fabrication (cold<br />
work<strong>in</strong>g, weld<strong>in</strong>g), section thickness (which controls restra<strong>in</strong>t and stress<br />
state), notches and stress concentrators, weld metal and base metal<br />
strength, weld<strong>in</strong>g and heat treat<strong>in</strong>g conditions. From <strong>the</strong> various <strong>the</strong>ories<br />
of reheat crack<strong>in</strong>g for both 300 Series SS and low alloy steels, crack<strong>in</strong>g<br />
features are as follows:<br />
a) Reheat crack<strong>in</strong>g requires <strong>the</strong> presence of high stresses and is <strong>the</strong>refore<br />
more likely to occur <strong>in</strong> thicker sections and higher strength materials.<br />
b) Reheat crack<strong>in</strong>g occurs at elevated temperatures when creep ductility is<br />
<strong>in</strong>sufficient to accommodate <strong>the</strong> stra<strong>in</strong>s required for <strong>the</strong> relief of applied or<br />
residual stresses. 蠕 变 延 性 不 足 以 适 应 (1) 应 用 或 (2) 残 余 应 力 缓 减 , 所 需 的<br />
伸 张 .
c) In <strong>the</strong> first half of 2008, numerous cases of reheat crack<strong>in</strong>g occurred<br />
dur<strong>in</strong>g 2 ¼ Cr-1 Mo-V reactor fabrication. The cracks were <strong>in</strong> weld metal<br />
only, transverse to <strong>the</strong> weld<strong>in</strong>g direction, and <strong>in</strong> only SAW welds. It was<br />
traced to a contam<strong>in</strong>ant <strong>in</strong> <strong>the</strong> weld<strong>in</strong>g flux.<br />
d) Reheat crack<strong>in</strong>g can ei<strong>the</strong>r occur dur<strong>in</strong>g PWHT or <strong>in</strong> service at high<br />
temperature. In both cases, cracks are <strong>in</strong>tergranular and show little or no<br />
evidence of deformation.<br />
e) F<strong>in</strong>e <strong>in</strong>tragranular precipitate particles make <strong>the</strong> gra<strong>in</strong>s stronger than <strong>the</strong><br />
gra<strong>in</strong> boundaries and force <strong>the</strong> creep deformation to occur at <strong>the</strong> gra<strong>in</strong><br />
boundaries.<br />
f) Stress relief and stabilization heat treatment of 300 Series SS for<br />
maximiz<strong>in</strong>g chloride SCC and PTASCC resistance can cause reheat<br />
crack<strong>in</strong>g problems, particularly <strong>in</strong> thicker sections.
http://www.hydrocarbonprocess<strong>in</strong>g.com/Article/27<br />
64339/How-to-fabricate-reactors-for-severeservice.html
https://etd.ohiol<strong>in</strong>k.edu/ap/0?0:APPLICATION_PROCESS%3DDOWNLOAD_ET<br />
D_SUB_DOC_ACCNUM:::F1501_ID:osu1188419315%2C<strong>in</strong>l<strong>in</strong>e
http://www.staff.ncl.ac.uk/s.j.bull/mmm373/WFAULT/sld017.htm
4.2.19.4 Affected Units or <strong>Equipment</strong><br />
a) Reheat crack<strong>in</strong>g is most likely to occur <strong>in</strong> heavy wall vessels <strong>in</strong> areas of<br />
high restra<strong>in</strong>t <strong>in</strong>clud<strong>in</strong>g nozzle welds and heavy wall pip<strong>in</strong>g.<br />
b) HSLA steels are very susceptible to reheat crack<strong>in</strong>g.<br />
4.2.19.5 Appearance or Morphology of <strong>Damage</strong><br />
a) Reheat crack<strong>in</strong>g is <strong>in</strong>tergranular and can be surface break<strong>in</strong>g or embedded<br />
depend<strong>in</strong>g on <strong>the</strong> state of stress and geometry. It is most frequently<br />
observed <strong>in</strong> coarse-gra<strong>in</strong>ed sections of a weld heat affected zone.<br />
b) In many cases, cracks are conf<strong>in</strong>ed to <strong>the</strong> heat-affected zone, <strong>in</strong>itiate at<br />
some type of stress concentration, and may act as an <strong>in</strong>itiation site for<br />
fatigue. Figure 4-60 to 4-63.
Figure 4-60 – Samples removed from a cracked 12-<strong>in</strong>ch NPS 321SS<br />
elbow <strong>in</strong> hot recycle H2 l<strong>in</strong>e that operated at 985°F <strong>in</strong> hydrocracker.
Figure 4-61 – Crack at weld from SS321 elbow shown <strong>in</strong> <strong>the</strong> Figure 4-60.
Figure 4-62 – Cross-section through <strong>the</strong> weldment show<strong>in</strong>g <strong>the</strong> crack <strong>in</strong> Figure 4-61.
Figure 4-63 –<br />
Photomicrographs of <strong>the</strong><br />
weldment area.
4.2.19.6 Prevention / Mitigation<br />
a) Jo<strong>in</strong>t configurations <strong>in</strong> heavy wall sections should be designed to m<strong>in</strong>imize<br />
restra<strong>in</strong>t dur<strong>in</strong>g weld<strong>in</strong>g and PWHT. Adequate preheat must also be applied.<br />
b) The gra<strong>in</strong> size has an important <strong>in</strong>fluence on <strong>the</strong> high temperature ductility and<br />
on <strong>the</strong> reheat crack<strong>in</strong>g susceptibility. A large gra<strong>in</strong> size results <strong>in</strong> less ductile<br />
heat-affected zones, mak<strong>in</strong>g <strong>the</strong> material more susceptible to reheat crack<strong>in</strong>g.<br />
c) Metallurgical notches aris<strong>in</strong>g from <strong>the</strong> weld<strong>in</strong>g operation are frequently <strong>the</strong><br />
cause of heat-affected zone crack<strong>in</strong>g (at <strong>the</strong> boundary between <strong>the</strong> weld and<br />
<strong>the</strong> heat-affected zone).<br />
d) In design and fabrication, it is advisable to avoid sharp changes <strong>in</strong> cross<br />
section, such as short radius fillets or undercuts that can give rise to stress<br />
concentrations. Long-seam welds are particularly susceptible to mismatch<br />
caused by fitup problems.
e) For 2 ¼ Cr-1 Mo-V SAW weld materials, prequalification screen<strong>in</strong>g tests for<br />
reheat crack<strong>in</strong>g such as high temperature (650 o C) Gleeble tensile tests<br />
should be considered.<br />
f) For Alloy 800H, <strong>the</strong> risk of <strong>in</strong>-service crack<strong>in</strong>g can be reduced by us<strong>in</strong>g base<br />
metal and match<strong>in</strong>g weld metal with Al+Ti 540 o C, <strong>the</strong> material may need to be<br />
purchased with a <strong>the</strong>rmal stabilization heat treatment, and with PWHT of<br />
welds and cold worked sections. Welds should be made with match<strong>in</strong>g Alloy<br />
800H filler material and should be stress relieved. Refer to ASME Section VIII,<br />
Div. 1 Code <strong>in</strong> UNF-56(e) for additional <strong>in</strong>formation.<br />
h) For thick-wall SS pip<strong>in</strong>g, PWHT should be avoided whenever possible.
4.2.19.7 Inspection and Monitor<strong>in</strong>g<br />
a) Surface cracks can be detected with UT and MT exam<strong>in</strong>ation of carbon<br />
and low alloy steels<br />
b) UT and PT exam<strong>in</strong>ation can be used to detect cracks <strong>in</strong> 300 Series SS<br />
and nickel base alloys.<br />
c) Embedded cracks can only be found through UT exam<strong>in</strong>ation.<br />
d) Inspection for reheat crack<strong>in</strong>g <strong>in</strong> 2 ¼ Cr-1 Mo-V reactors dur<strong>in</strong>g<br />
fabrication is typically done with TOFD or manual shear wave UT with<br />
<strong>the</strong> demonstration block hav<strong>in</strong>g defects as small as 3 mm side drilled<br />
holes<br />
4.2.19.8 Related <strong>Mechanisms</strong><br />
Reheat crack<strong>in</strong>g has also been referred to <strong>in</strong> <strong>the</strong> literature as “stress relief<br />
crack<strong>in</strong>g” and “stress relaxation crack<strong>in</strong>g”.
http://www.twi-global.com/technical-knowledge/job-knowledge/defectsimperfections-<strong>in</strong>-welds-reheat-crack<strong>in</strong>g-048/
http://www.staff.ncl.ac.uk/s.j.bull/mmm373/WFAULT/sld017.htm
再 热 裂 纹 学 习 重 点 :<br />
a) 易 感 温 度 : 高 温<br />
b) 原 理 : 蠕 变 延 性 不 足 以 适 应 (1) 应 用 或 (2) 残 余 应 力 缓 减 , 所 需 的 伸 张 引<br />
起 的 开 裂 ,<br />
c) 易 感 材 质 : 铁 素 体 , 奥 氏 体 , 厚 壁 钢 材 ,<br />
d) 易 感 设 备 : 高 温 服 务 , 厚 壁 设 备 ,<br />
e) 非 API 510/570 考 试 题 .
4.2.20 GOX-Enhanced Ignition & Combustion<br />
气 化 氧 - 增 强 燃 烧
4.2.20 Gaseous Oxygen-Enhanced Ignition and Combustion<br />
气 态 氧 增 强 的 点 火 和 燃 烧<br />
4.2.20.1 Description of <strong>Damage</strong><br />
Many metals are flammable <strong>in</strong> oxygen and enriched air (>25% oxygen)<br />
services even at low pressures, whereas <strong>the</strong>y are non-flammable <strong>in</strong> air. The<br />
spontaneous ignition or combustion of metallic and nonmetallic components<br />
can result <strong>in</strong> fires and explosions <strong>in</strong> certa<strong>in</strong> oxygen-enriched gaseous<br />
environments if not properly designed, operated and ma<strong>in</strong>ta<strong>in</strong>ed. Once ignited,<br />
metals and non-metals burn more vigorously with higher oxygen purity,<br />
pressure and temperature
4.2.20.2 Affected Materials<br />
a) Carbon steels and low alloy steels are flammable <strong>in</strong> low pressure oxygen,<br />
greater than about 15 psig (0.103 MPa). With special precautions, <strong>the</strong>se<br />
materials are safely used <strong>in</strong> high pressure oxygen.<br />
b) Austenitic sta<strong>in</strong>less steels (300 series) have better resistance to low pressure<br />
oxygen and are generally difficult to ignite at pressures below about 200 psig<br />
(1.38 MPa).<br />
c) Copper alloys (with >55% copper) and nickel alloys (with >50% nickel) are<br />
very fire resistant and are generally considered non-flammable. Because of<br />
<strong>the</strong>ir excellent oxygen “compatibility” <strong>the</strong>y are often selected for imp<strong>in</strong>gement<br />
and turbulent services such as valves and <strong>in</strong>strumentation (Figure 4-69).<br />
Alloy 400 is highly resistant.
d) Although widely used for oxygen cyl<strong>in</strong>ders and <strong>in</strong> oxygen manufactur<strong>in</strong>g<br />
plants, alum<strong>in</strong>um is usually avoided for flow<strong>in</strong>g oxygen. If ignited it burns<br />
quickly and with a large energy release.<br />
e) The easiest materials to ignite are plastics, rubbers, and hydrocarbon<br />
lubricants and <strong>the</strong>se are m<strong>in</strong>imized <strong>in</strong> oxygen systems.<br />
f) Titanium alloys are generally avoided <strong>in</strong> oxygen and oxygen-enriched<br />
service because <strong>the</strong>y have low ignition energies and release a large<br />
amount of energy dur<strong>in</strong>g combustion. Tests <strong>in</strong>dicate that titanium can<br />
susta<strong>in</strong> combustion at oxygen pressure as low as 7 kPa (1 psi) absolute.<br />
Most <strong>in</strong>dustry documents caution aga<strong>in</strong>st <strong>the</strong> use of titanium <strong>in</strong> oxygen<br />
systems (References 6 and 7).<br />
Note: These are general guidel<strong>in</strong>es and should not be considered for design.
4.2.20.3 Critical Factors<br />
a) Many factors affect <strong>the</strong> likelihood of combustion and ignition <strong>in</strong> oxygen<br />
services <strong>in</strong>clud<strong>in</strong>g <strong>the</strong> system pressure, oxygen content of <strong>the</strong> stream,<br />
l<strong>in</strong>e velocity, component thickness, design and pip<strong>in</strong>g configuration,<br />
cleanl<strong>in</strong>ess and temperature.<br />
b) The primary concern under high velocity oxygen flow conditions is <strong>the</strong><br />
entra<strong>in</strong>ment of particulate and <strong>the</strong>ir subsequent imp<strong>in</strong>gement on a<br />
surface, such as at a pipe bend. Oxygen velocities <strong>in</strong> carbon steel and<br />
sta<strong>in</strong>less steel pip<strong>in</strong>g should comply with <strong>in</strong>dustry limits as shown <strong>in</strong><br />
Reference 1. Allowable velocity is a function of pressure and flow<br />
condition (direct imp<strong>in</strong>gement or non-imp<strong>in</strong>gement).
c) The temperature of a material affects its flammability. As temperature<br />
<strong>in</strong>creases, a lower amount of additional energy is required for ignition and<br />
susta<strong>in</strong>ed combustion. The m<strong>in</strong>imum temperature at which a substance will<br />
support combustion, under a specific set of conditions is referred to as <strong>the</strong><br />
ignition temperature. Published ignition temperatures for most alloys are<br />
near <strong>the</strong> alloy’s melt<strong>in</strong>g temperature. However, <strong>the</strong>se are measured <strong>in</strong> nonflow<strong>in</strong>g<br />
conditions. Actual systems can suffer ignition and combustion at<br />
room temperature (and lower) due to particle impact and o<strong>the</strong>r mechanisms.<br />
d) System cleanl<strong>in</strong>ess is important for <strong>the</strong> safe operation of oxygen systems.<br />
Contam<strong>in</strong>ation of with metallic f<strong>in</strong>es or hydrocarbons such as oils and<br />
greases dur<strong>in</strong>g construction or ma<strong>in</strong>tenance activities can lead to fires<br />
dur<strong>in</strong>g subsequent start up of <strong>the</strong> unit. These materials are easy to ignite<br />
and can lead to a large fire and breach of <strong>the</strong> system.
e) Imp<strong>in</strong>gement areas such as sharp elbows, tees and valves have a higher<br />
risk of ignition than straight pipe. Particles <strong>in</strong> <strong>the</strong> flow<strong>in</strong>g oxygen can strike<br />
<strong>the</strong>se areas and cause ignition. Operation of valves and regulators (open<strong>in</strong>g<br />
/ clos<strong>in</strong>g) cause high turbulence and imp<strong>in</strong>gement and only components<br />
selected and cleaned specifically for oxygen service should be used.
4.2.20.4 Affected Units or <strong>Equipment</strong><br />
a) These guidel<strong>in</strong>es apply to any unit that uses oxygen or enriched air for<br />
combustion or o<strong>the</strong>r process reasons.<br />
b) Oxygen is sometimes used <strong>in</strong> sulfur recovery units (SRU) and fluid catalytic<br />
crack<strong>in</strong>g units (FCCU), Gasification, and Partial Oxidation (POX) units.<br />
Figures 4-64 to 4-66.<br />
c) Oxygen pip<strong>in</strong>g systems especially valves, regulators, and o<strong>the</strong>r imp<strong>in</strong>gement<br />
areas are potentially vulnerable. Non-metals such as those used for seats<br />
and seals, are easier to ignite than metals (Figure 4-69).
4.2.20.5 Appearance or Morphology of <strong>Damage</strong><br />
a) In some cases a small component will burn, such as a valve seat, without<br />
k<strong>in</strong>dl<strong>in</strong>g o<strong>the</strong>r materials and without any outward sign of fire damage. It is<br />
noticed when <strong>the</strong> component is removed because it is not function<strong>in</strong>g<br />
properly. Figure 4-67 to 4-68.<br />
b) Also, external heat damage (glow<strong>in</strong>g pipe or heat t<strong>in</strong>t) is a strong <strong>in</strong>dication<br />
of an <strong>in</strong>ternal fire. This can be caused by accumulation of flammable debris<br />
at a low po<strong>in</strong>t or o<strong>the</strong>r location and combustion or smolder<strong>in</strong>g of <strong>the</strong> debris.<br />
c) The worst situation is when <strong>the</strong> pressure envelope is breached because of<br />
fire. Oxygen fires can cause significant burn<strong>in</strong>g of metal components and<br />
extensive structural damage (Figure 4-68).
4.2.20.6 Prevention / Mitigation<br />
Refer to <strong>in</strong>dustry recommended guidel<strong>in</strong>es <strong>in</strong>cluded <strong>in</strong> <strong>the</strong> references listed below.<br />
Some general considerations are as follows:<br />
a) Oxygen fires are a sudden occurrence and not a progressive degradation or<br />
weaken<strong>in</strong>g of <strong>the</strong> material. Prevention is best accomplished be keep<strong>in</strong>g<br />
systems clean, or clean<strong>in</strong>g <strong>the</strong>m after ma<strong>in</strong>tenance or <strong>in</strong>spections.<br />
b) Ma<strong>in</strong>ta<strong>in</strong> velocity with<strong>in</strong> recommended limits. If practical, avoid velocities that<br />
are nom<strong>in</strong>ally above 100 feet/second (30 m/sec) <strong>in</strong> gaseous oxygen.<br />
c) Ensure that replacement components are suitable for oxygen service.<br />
d) Oxygen systems should be thoroughly cleaned after ma<strong>in</strong>tenance.<br />
e) M<strong>in</strong>imize lubricants and use only “oxygen compatible” lubricants.<br />
f) Do not unnecessarily open oxygen systems for visual or o<strong>the</strong>r <strong>in</strong>spections as<br />
this could <strong>in</strong>troduce contam<strong>in</strong>ation.
g) A thorough review is needed before modify<strong>in</strong>g oxygen systems to operate at<br />
higher pressures, temperatures, or velocities.<br />
h) M<strong>in</strong>imize sudden changes <strong>in</strong> pressure <strong>in</strong> <strong>the</strong> system. If high pressure oxygen<br />
suddenly enters a system <strong>in</strong>itially at low pressure by quick operation of a<br />
valve, <strong>the</strong> “dead end” of that system experiences heat<strong>in</strong>g from adiabatic<br />
compression of <strong>the</strong> oxygen. Adiabatic compression heat<strong>in</strong>g can ignite<br />
plastics and rubbers, but will not ignite metals. Valve seats, seals, nonmetallic<br />
hoses, etc can be ignited by this mechanism.<br />
i) Do not use plastic pipe <strong>in</strong> oxygen pip<strong>in</strong>g systems.<br />
j) Personnel activities near oxygen pip<strong>in</strong>g and systems should be m<strong>in</strong>imized<br />
dur<strong>in</strong>g start ups.
4.2.20.7 Inspection and Monitor<strong>in</strong>g<br />
a) Most commercial oxygen is dry and non-corrosive at normal ambient<br />
temperatures. Because of <strong>the</strong> sudden catastrophic ignition of metals under<br />
certa<strong>in</strong> conditions this type of damage is difficult to <strong>in</strong>spect for <strong>in</strong> advance.<br />
b) Tell-tale signs of a m<strong>in</strong>or fire such as external heat damage, or signs of<br />
malfunction<strong>in</strong>g valves or o<strong>the</strong>r components conta<strong>in</strong><strong>in</strong>g non-metallic<br />
components may be <strong>in</strong>dicative of a problem.<br />
c) Blacklights can be used to check for hydrocarbon contam<strong>in</strong>ation.<br />
4.2.20.8 Related <strong>Mechanisms</strong><br />
Not applicable.
Figure 4-64 – Thermal combustor<br />
on <strong>the</strong> front end of a reaction<br />
furnace on a sulfur recovery unit.
Figure 4-65 – Same as figure above after<br />
damage due to oxygen combustion result<strong>in</strong>g<br />
from oxygen <strong>in</strong>jection <strong>in</strong>to <strong>the</strong> <strong>the</strong>rmal<br />
combustor on <strong>the</strong> front end of <strong>the</strong> reaction<br />
furnace.
Figure 4-66 – Same as figure<br />
above when viewed from a<br />
different angle.
Figure 4-67 – Photograph of a burned 304 SS elbow. The fire started <strong>in</strong> an upstream<br />
sta<strong>in</strong>less steel wire filter (due to particle impact) and <strong>the</strong> burn<strong>in</strong>g filter material<br />
impacted <strong>the</strong> elbow and ignited it. Th<strong>in</strong> sta<strong>in</strong>less steel components (e.g., filter) are much<br />
more flammable than thicker SS. Th<strong>in</strong> SS (
Figure 4-68 – Photograph illustrat<strong>in</strong>g burn through of a brass pressure gage.<br />
Brass is generally suitable for oxygen service. However, <strong>the</strong> gauge was not<br />
was not <strong>in</strong>tended for oxygen service and was not “oil free”. Hydrocarbon<br />
contam<strong>in</strong>ation, probably from manufacture, caused <strong>the</strong> fire.
Figure 4-69 – Burn-through of<br />
a PTFE-l<strong>in</strong>ed sta<strong>in</strong>less steel<br />
hose <strong>in</strong> high pressure gaseous<br />
oxygen (GOX) service. Grease<br />
contam<strong>in</strong>ation ignited and<br />
penetrated <strong>the</strong> hose.
气 化 氧 - 增 强 燃 烧 学 习 重 点 :<br />
a) 易 感 温 度 : 操 作 温 度<br />
b) 原 理 : 氧 气 导 致 燃 烧 ,<br />
c) 易 感 材 质 : 铁 素 体 , 奥 氏 体 , 其 他 ,<br />
d) 易 感 设 备 : 气 态 氧 设 备 ,<br />
e) 预 防 / 缓 解 : 正 确 材 料 选 择 , 清 洁 度 , 流 速 ( 避 免 冲 击 ), 外 来 固 体 ,<br />
f) 非 API 510/570 考 试 题 .