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How Clean is your Quench Tower? - Coke Oven Managers ...

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Neil Schofield, Group Environment<br />

<strong>How</strong> <strong>Clean</strong> <strong>is</strong> <strong>your</strong> <strong>Quench</strong> <strong>Tower</strong>?


<strong>Coke</strong>making in Today’s World<br />

HMIP or Alkali Inspectorate<br />

regulated, limits for stack<br />

em<strong>is</strong>sions based on the<br />

Alkali Act 1906<br />

Integrated Pollution Prevention and<br />

Control (IPPC). Introduces BAT and the<br />

BAT reference documents (first time<br />

quench em<strong>is</strong>sion range <strong>is</strong> documented in<br />

UK)<br />

Environmental Protection Act<br />

(EPA) aims to control and<br />

reduce pollution through<br />

author<strong>is</strong>ation of processes and<br />

tighter limits for stack em<strong>is</strong>sions.<br />

Introduces BATNEEC<br />

Industrial Em<strong>is</strong>sions Directive<br />

(IED). Rev<strong>is</strong>ion of BAT<br />

documents and introduction of<br />

BAT-AELs (associated em<strong>is</strong>sion<br />

levels)<br />

1980s 1990s 2000s 2010s<br />

2


BAT for coke quenching<br />

• Reduce dust em<strong>is</strong>sions by using one of the<br />

following techniques:<br />

• using coke dry quenching (CDQ) with the recovery<br />

of sensible heat and the removal of dust from<br />

charging, handling and screening operations by<br />

means of a bag filter<br />

• using em<strong>is</strong>sion-minim<strong>is</strong>ed conventional wet<br />

quenching<br />

• using coke stabil<strong>is</strong>ation quenching (CSQ)<br />

• BAT-AELs for dust are:<br />

< 20 mg/Nm³ (in case of CDQ)<br />

< 25 g/t coke (in case of wet quenching)<br />

• th<strong>is</strong> level <strong>is</strong> based on the use of the non-<strong>is</strong>okinetic<br />

Mohrhauer method (former VDI 2303)<br />

< 10 g/t coke (in case of CSQ)<br />

3


Mohrhauer method (former VDI 2303)<br />

4


Application of the Mohrhauer Method<br />

5


Some UK <strong>Quench</strong> <strong>Tower</strong> Em<strong>is</strong>sions<br />

Plant<br />

Coarse<br />

Particulate<br />

Em<strong>is</strong>sion<br />

(g/t coke)<br />

BREF Range


Loss of Stat<strong>is</strong>tical Life Expectancy (months)<br />

through exposure to fine particulate<br />

7


Measuring Total Particulate Matter (TPM)<br />

8


Application of TPM with Mohrhauer<br />

9


Total Particulate Results (Plants A and F)<br />

Plant<br />

Total<br />

Particulate<br />

Coarse<br />

Particulate<br />

(g/t coke)<br />

Fine<br />

Particulate<br />

Factor<br />

(Total : Coarse)<br />

A 56 12 (44) 5.3<br />

F 684 622 (62) 1.1<br />

Particle Size<br />

D<strong>is</strong>tribution of<br />

Total Particulate<br />

Size Cumulative %<br />

>PM10 100<br />

PM10 5.3<br />

PM2.5 5.0<br />

PM1 3.5<br />

10


Compar<strong>is</strong>on of Em<strong>is</strong>sions (Plants A and F)<br />

Plant A Plant F Plant A Plant F<br />

• Coarse • Fine • PM 10<br />

11


Total Particulate Results<br />

Plant<br />

Total<br />

Particulate<br />

Coarse<br />

Particulate<br />

(g/t coke)<br />

Fine<br />

Particulate<br />

Factor<br />

(Total : Coarse)<br />

A 56 12 (44) 5.3<br />

F 684 622 (62) 1.1<br />

D1 18 14 (4) 1.3<br />

D2 12 4 (8) 3.5<br />

• Factors affecting the em<strong>is</strong>sion of fine particulate<br />

• <strong>Quench</strong> tower height and design?<br />

• <strong>Coke</strong> and/or quench quality?<br />

• <strong>Quench</strong> water quality?<br />

12


Actions to comply with BAT-AEL<br />

• Investment in state of the art quench tower<br />

• Tall tower, multiple baffles, baffle spray cleaning<br />

• Reduction of suspended solids and soluble salts in quench water<br />

• Investment in alternative quenching technologies<br />

• No quench plume with CDQ, only abated stack release<br />

• Understand that level <strong>is</strong> applicable to coarse dust only<br />

• PM 10 <strong>is</strong> a minor component of the quench tower em<strong>is</strong>sion<br />

• Research into the range of fine particulate em<strong>is</strong>sions from quench towers in<br />

order to set an achievable level<br />

13


Summary<br />

• <strong>Coke</strong>making in today’s world <strong>is</strong> subject to ever stringent environmental<br />

regulation<br />

• <strong>Quench</strong> tower em<strong>is</strong>sions have recently become the focus of regulators<br />

and em<strong>is</strong>sion limit values are expected in the future<br />

• <strong>Quench</strong> tower em<strong>is</strong>sions are difficult and costly to achieve, and<br />

standard measurement techniques do not provide the full story<br />

• <strong>Quench</strong> tower em<strong>is</strong>sions have been undertaken in the UK to allow<br />

cost-effective investment dec<strong>is</strong>ions to be made<br />

14


Thank you<br />

Neil Schofield<br />

Knowledge Group Leader<br />

Environmental Engineering and Monitoring<br />

T +44 (0) 1709 825569 (direct)<br />

F +44 (0) 1709 825400<br />

M +44 (0) 7825 522343<br />

neil.schofield@tatasteel.com<br />

Tata Steel Group Environment<br />

Swinden Technology Centre<br />

Moorgate, Rotherham,<br />

South Yorkshire S60 3AR,<br />

United Kingdom<br />

15

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