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Prediction of batch heat transfer coefficients for pseudoplastic fluids ...

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CHAPTER 2<br />

R,EVIE\rJ OF B,ACKGROD1m l1ATERIAL<br />

PSEUDO PLASTIC FLUIDS<br />

-< -.' "- - - •<br />

wnile Newtonian behavior is only one <strong>of</strong> many rheological<br />

types, the large majority <strong>of</strong> <strong>fluids</strong> h~~dled<br />

industrially<br />

are Newtonian.<br />

Pseudoplastic <strong>fluids</strong> are second<br />

in i1nportance to the NeHtonians (118)..<br />

The Bingham plas tics<br />

are probably third in importance but many <strong>of</strong> these have been<br />

treated as <strong>pseudoplastic</strong>s (126).<br />

There are very few industrial<br />

dilatants, and the time dependent and viscoelastic<br />

fluid groups are small 8nd are <strong>of</strong>ten treated as <strong>pseudoplastic</strong>s<br />

(7, 118, 120, 121, 126, 128, 179, 186). Pseudoplastic <strong>fluids</strong><br />

l.Jere studied in this Hork because <strong>of</strong> their relative importance.<br />

~1elts a..Yld sol'll'tions <strong>of</strong> substances Hi th high mole cular<br />

weight are usually <strong>pseudoplastic</strong> (118, 196) ..<br />

Suspensions<br />

<strong>of</strong> asymmetrie solids are <strong>of</strong>ten in this category. (120, 213).<br />

Typical examples <strong>of</strong> <strong>pseudoplastic</strong>s are polystyrene, copolymers<br />

<strong>of</strong> styrene, low and high pressure polyethylene, rubber<br />

modified styrene polymers, and slurries <strong>of</strong> cement rock in<br />

water (96, 212).<br />

The flm ..! behavior <strong>of</strong> pseudop1astic <strong>fluids</strong> is shov.ffi<br />

graphically in Figure 2-1.<br />

At very lov.T a..Yld very high shear<br />

rates the apparent viscosity is a constant, as shown in<br />

curve A.<br />

Thus in these ranges the fluid acts as a Newtonian<br />

fluid. BetvJeen these two extremes., hOl

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