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Safety data sheet 3. Composition/details about the ... - LYSOFORM

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DRR<br />

*<br />

*<br />

<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />

according to 1907/2006/EC<br />

Page: 1/5<br />

Printed on: 28th April 2010 Version :3 Revised on:28th April 2010<br />

1. Product and company identification<br />

Details <strong>about</strong> <strong>the</strong> product<br />

Trade name:<br />

Application:<br />

AHD 2000<br />

Hand and skin disinfection<br />

Manufacturer Lysoform Dr. Hans Rosemann GmbH<br />

Kaiser-Wilhelm-Straße 133<br />

D-12247 Berlin<br />

Telephone: +49 (0) 30/77992-0 Fax: +49 (0) 30/77992-219<br />

www.lysoform.de<br />

Department providing<br />

information<br />

Contact email:<br />

Emergency information<br />

Germany<br />

Toxic emergency number Munich<br />

Toxicological department,<br />

Klinikum rechts der Isar<br />

Ismaninger Str. 22, 81675 München<br />

Telephone: +49 (0) 89/19240<br />

Fax: +49 (0) 89/4140-2467<br />

· 2. Hazard identification:<br />

F Highly inflammable.<br />

Scientific-technical department<br />

Telephone: +49 (0) 30/77992-285<br />

kontakt@lysoform.de<br />

<strong>3.</strong> <strong>Composition</strong>/<strong>details</strong> <strong>about</strong> <strong>the</strong> components<br />

Switzerland<br />

Swiss toxic information centre<br />

Freiestrasse 16<br />

8030 Zürich<br />

Telephone: 0041 44 2515151<br />

Fax: 0041 44 2528833<br />

· Special indications of danger for humans and <strong>the</strong> environment:<br />

The product must be labelled on <strong>the</strong> basis of <strong>the</strong> calculation procedure of <strong>the</strong> "General<br />

classification guideline for preparations of <strong>the</strong> EU" in <strong>the</strong> latest valid version.<br />

R 11 Highly inflammable.<br />

· Chemical characterisation<br />

· Description: Aqueous ethanol solution.<br />

· Hazardous ingredients:<br />

CAS: 64-17-5<br />

EINECS: 200-578-6<br />

Ethanol<br />

F; R 11 75.0%<br />

· Additional information: Please refer to Chapter 16 for <strong>the</strong> texts of <strong>the</strong> listed danger indications.<br />

* 4. First aid measures<br />

· General information: Immediately remove all clothing that has been soiled with <strong>the</strong> product.<br />

· After inhalation: Plenty of fresh air, if unwell seek medical advice.<br />

· After skin contact: Generally <strong>the</strong> product does not irritate <strong>the</strong> skin.<br />

· After eye contact:<br />

Rinse out with plenty of running water with <strong>the</strong> eyelid held wide open for several minutes.<br />

Contact a doctor immediately.<br />

(Continued on page 2)<br />

EN


DR<br />

*<br />

*<br />

<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />

according to 1907/2006/EC<br />

Page: 2/5<br />

Printed on: 28th April 2010 Version :3 Revised on:28th April 2010<br />

Trade name: AHD 2000 (Continued from page 1)<br />

· After swallowing: Drink plenty of water and ensure victim gets fresh air. Seek medical advice immediately.<br />

5. Fire-fighting measures<br />

·<br />

Suitable extinguishing media:<br />

CO2, extinguishing powder or water jet. Fight larger fires with water jets or alcohol-resistant foam.<br />

· Protective equipment: No special measures required.<br />

6. Procedure in case of accidental release<br />

· Personal safety precautions: Wear protective equipment. Keep unprotected people away.<br />

· Measures for environmental protection:<br />

Dilute with plenty of water<br />

Do not allow to enter <strong>the</strong> sewer system/surface waters/groundwater.<br />

· Cleaning/Collecting procedure:<br />

Absorb using liquid-binding material (sand, kieselguhr, acid binder, universal binder, sawdust).<br />

Ensure adequate ventilation.<br />

7. Handling and storage<br />

· Handling:<br />

· Information <strong>about</strong> safe handling: Keep container tightly closed.<br />

· Information <strong>about</strong> fire and explosion prevention:<br />

Keep away from ignition sources – Do not smoke.<br />

Take precautions against electrostatic charging.<br />

· Storage:<br />

· Requirements made of storage rooms and containers:<br />

· Joint storage information:<br />

·<br />

·<br />

Do not store with foodstuff.<br />

Do not store near oxidizing agents.<br />

O<strong>the</strong>r information <strong>about</strong> storage conditions:<br />

Store in well-closed packagings in a cool and dry place.<br />

Storage class: LGK 3 A (acc. to VCI)<br />

Store in a cool place.<br />

8. Exposure limitation and control / Personal protectionn<br />

· Additional information <strong>about</strong> <strong>the</strong> design of technical systems: No fur<strong>the</strong>r <strong>data</strong>, see item 7.<br />

· Components with critical values that require monitoring at <strong>the</strong> working place:<br />

64-17-5 Ethanol<br />

MAC Short-time value: 1920 mg/m³, 1000 ml/m³<br />

Long-time value: 960 mg/m³, 500 ml/m³<br />

· Additional information: This information is based on <strong>the</strong> lists that were valid when this <strong>data</strong> <strong>sheet</strong> was generated.<br />

· Personal protective equipment:<br />

· General precautions and hygienic measures: Wash hand before breaks and at <strong>the</strong> end of work.<br />

· Respiration protection: Not required.<br />

(Continued on page 3)<br />

EN


DRR<br />

*<br />

*<br />

<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />

according to 1907/2006/EC<br />

Page: 3/5<br />

Printed on: 28th April 2010 Version :3 Revised on:28th April 2010<br />

Trade name: AHD 2000 (Continued from page 2)<br />

· Eye protection:<br />

Tight-fitting goggles<br />

9. Physical and chemical properties<br />

· General information<br />

·<br />

· Flash point:<br />

· Ignition temperature:<br />

· Self -ignition:<br />

· Risk of explosion:<br />

·<br />

· Vapour pressure at 20°C:<br />

· Density at 20°C:<br />

·<br />

· pH-value (50 g/l) at 20°C:<br />

·<br />

·<br />

Form:<br />

Colour:<br />

Smell:<br />

Change of state<br />

Melting point/melting range:<br />

Boiling point/boiling range:<br />

Explosion limits:<br />

Lower:<br />

Upper:<br />

Solubility in / mixability with<br />

water:<br />

Viscosity:<br />

Dynamic at 20°C:<br />

Contents of solvent:<br />

Organic solvents:<br />

Water:<br />

10. Stability and reactivity<br />

Liquid<br />

No colour<br />

Perfumed<br />

Not determined<br />

78°C (DIN 51751)<br />

19°C (DIN 51755)<br />

Not determined<br />

The product is not self-igniting.<br />

The product is not explosive, however formation of<br />

explosive vapours/air mixtures may be formed.<br />

Not determined<br />

Not determined<br />

Not determined<br />

approx. 0.85 g/cm³<br />

Completely mixable.<br />

approx. 7<br />

Not determined<br />

-<br />

approx. 20 %<br />

· Thermal decomposition / conditions to be avoided<br />

No decomposition if used properly.<br />

· Dangerous reactions: No dangerous reactions known.<br />

· Dangerous products of decomposition: No dangerous decomposition products known.<br />

11. Toxicological information<br />

· Acute toxicity:<br />

· Classification relevant LD/LC50 values:<br />

AHD 2000 dermal: > 10 ml/kg (rat)<br />

AHD 2000 oral : practically non-toxic (rat)<br />

(Continued on page 4)<br />

EN


DR<br />

*<br />

*<br />

*<br />

<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />

according to 1907/2006/EC<br />

Page: 4/5<br />

Printed on: 28th April 2010 Version :3 Revised on:28th April 2010<br />

Trade name: AHD 2000 (Continued from page 3)<br />

· Primary irritation:<br />

· on skin: No irritation.<br />

· in eyes: No irritation.<br />

· Sensitisation: No sensitisation known.<br />

12. Ecological information<br />

· Information <strong>about</strong> elimination (persistence and degradability): Biodegradable<br />

· General information:<br />

Water pollutant class (German legislation) 1 (self-classification): Slightly water polluting<br />

Do not allow to enter <strong>the</strong> groundwater, waters or <strong>the</strong> sewer system, if undiluted or in large<br />

quantities.<br />

1<strong>3.</strong> Disposal consideration<br />

· Product:<br />

· Recommendation:<br />

Handover to special waste collector or bring to a special waste collection point.<br />

May not be disposed of toge<strong>the</strong>r with <strong>the</strong> household waste. Do not allow to enter <strong>the</strong> sewer system.<br />

·<br />

European Waste Code<br />

07 01 04 o<strong>the</strong>r organic solvents, washing liquids and mo<strong>the</strong>r lye.<br />

· Soiled packaging:<br />

· Recommendation:Dispose of in accordance with <strong>the</strong> official regulations.<br />

· Recommended cleaning agent: Water, if necessary with detergent additives.<br />

14. Transport information<br />

· Land transport ADR/RID and GGVS/GGVE (cross-border/Germany):<br />

·<br />

·<br />

·<br />

·<br />

·<br />

·<br />

·<br />

ADR/RID-GGVS/E class:<br />

Kemler number:<br />

UN-Number:<br />

Packaging group:<br />

3 Flammable liquid materials<br />

33<br />

1170<br />

II<br />

Danger markings and labels: 3<br />

Name of goods:<br />

1170 ETHANOL (ETHYL ALCOHOL), solution<br />

Limited quantities (LQ): LQ 4<br />

Tunnel restriction code: D/E<br />

Sea transport IMDG/GGVSee:<br />

· IMDG/GGVSea-class: 3<br />

· UN-Number:<br />

1170<br />

· Label<br />

3<br />

· Packaging group: II<br />

· EMS-Number:<br />

F-E,S-D<br />

Marine pollutant: No<br />

Correct technical name: ETHANOL (ETHYL ALCOHOL), solution<br />

(Continued on page 5)<br />

EN


DRR<br />

<strong>Safety</strong> <strong>data</strong> <strong>sheet</strong><br />

according to 1907/2006/EC<br />

Page: 5/5<br />

Printed on: 28th April 2010 Version :3 Revised on:28th April 2010<br />

Trade name: AHD 2000 (Continued from page 4)<br />

Air transport ICAO-TI and IATA-DGR:<br />

· ICAO/IATA-class:<br />

· UN/ID-Number:<br />

· Label<br />

· Packaging group:<br />

· Correct technical name<br />

15. Regulatory information<br />

·<br />

·<br />

·<br />

·<br />

3<br />

1170<br />

3<br />

II<br />

ETHANOL (ETHYL ALCOHOL), solution<br />

Labelled according to <strong>the</strong> EEC Directives:<br />

The product has been classified and identified according to <strong>the</strong> EC Directives/Hazardous Goods Ordinance.<br />

Code letter and danger indication of <strong>the</strong> product:<br />

F Highly inflammable.<br />

R-phrases:<br />

11 Highly inflammable.<br />

S-phrases:<br />

2 Keep out of <strong>the</strong> reach of children.<br />

7/9 Keep <strong>the</strong> container tightly closed and store in a well ventilated place.<br />

16 Keep away from sources of ignition - no smoking.<br />

46 If swallowed, seek medical advice immediately and show this container or label.<br />

56 Dispose of this product and its container to <strong>the</strong> special waste collection point.<br />

60 This product and its container must be disposed of as hazardous waste.<br />

* 16 O<strong>the</strong>r information<br />

The information contained herein is based on <strong>the</strong> present state of our knowledge. It does not represent a guarantee<br />

of <strong>the</strong> properties of <strong>the</strong> product or form <strong>the</strong> basis for a legal position.<br />

·<br />

Relevant R-phrases<br />

11 Highly inflammable.<br />

· Area issuing <strong>the</strong> <strong>data</strong> <strong>sheet</strong>: Department Product <strong>Safety</strong><br />

· Contact partner: Dr. G. Cielusek<br />

· * Data changed in comparison to previous version<br />

EN

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