LYSOFORMIN E 15.07.10.10

Safety data sheet
according to 1907/2006/EG
Page: 1/7
Printed on: 15 th July 2010 Version :4 Revised on: 15 th July 2010
1. Substance / preparation and company designation
Information on the product
Trade name: LYSOFORMIN
Application: Wipe disinfection for surfaces
Manufacturer Lysoform Dr. Hans Rosemann GmbH
Kaiser-Wilhelm-Straße 133
D-12247 Berlin
Telephone: +49 (0) 30/77992-0 Fax: +49 (0) 30/77992-219
www.lysoform.de
Department providing
information
Contact email:
Emergency information
Germany
Toxic emergency number Munich
Toxicological department,
Klinikum rechts der Isar
Ismaninger Str. 22, 81675 München
Telephone: +49 (0) 89/19240
Fax: +49 (0) 89/4140-2467
2. Hazard identification
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Xn Harmful to health
Scientific-technical department
Telephone: +49 (0) 30/77992-285
kontakt@lysoform.de
Special indications of danger for humans and the environment:
The product must be labelled on the basis of the calculation procedure of the "General
classification guideline for preparations of the EU" in the latest valid version.
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R 36/37/38 Irritant to eyes, respiratory tract and skin.
R 40 Limited evidence of carcinogenic effect.
R 41 Risk of serious damage to eyes.
R 42/43 May cause sensitization by inhalation and skin contact.
3. Composition/details about the components
Switzerland
Swiss toxic information centre
Freiestrasse 16
8030 Zürich
Telephone: 0041 44 2515151
Fax: 0041 44 2528833
Chemical characterisation
Description:
Preparation out of the following substances with unharmful added substances.
Solution of aldehydes and surfactant.
Hazardous ingredients:
CAS: 50-00-0 Formaldehyde 6,0%
EINECS: 200-001-8 Carc. Cat. 3; T, C; R 23/24/25-34-40-43
CAS: 68585-34-2 Sodium C 10-C 16 Alkyl Ethoxy Sulfate ≤ 5%
NLP: 500-223-8 Xi; R 36/38
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Safety data sheet
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Trade name: LYSOFORMIN
CAS: 111-30-8 Glutaral 1,8%
EINECS: 203-856-5 T, C, N; R 23/25-34-42/43-50
CAS: 64-17-5 Ethanol ≤ 5%
EINECS: 200-578-6 F; R 11
Regulation (EC) No. 648/2004 on detergents / information on the ingredients
Non-ionic surfactants, perfume (BENZYL BENZOATE, 2-(4-tert-Butylbenzyl) < 5%
propionaldehyd)
Additional information: Please refer to Chapter 16 for the texts of the listed danger indications.
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4. First aid measures
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General information:
Toxic symptoms may only appear many hours later, therefore remain under medical supervision for at least
48 hours after an accident.
After inhalation:
Plenty of fresh air, if unwell seek medical advice.
If unconscious, position and transport in the lateral recumbent position.
After skin contact:
Seek medical advice in case of lasting skin-irritation.
Immediately rinse with soap and plenty of water.
Do not use any solvents.
After eye contact:
Rinse out with plenty of running water with the eyelid held wide open for several minutes.
Seek medical advice immediately.
After swallowing:
Rinse mouth and drink plenty of water. Seek medical advice.
5. Fire-fighting measures
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Suitable extinguishing media:
CO2, extinguishing powder or water jet. Fight larger fires with water jets or alcohol-resistant
foam.
Protective equipment: Wear protective breathing mask.
6. Procedure in case of accidental release
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Personal safety precautions: Wear protective equipment.
Measures for environmental protection: Do not allow to enter the sewer system/surface waters/groundwater.
Cleaning/Collecting procedure:
Absorb using liquid-binding material (sand, kieselguhr, acid binder, universal binder, sawdust).
Dispose contaminated material as waste according to point 13.
Ensure adequate ventilation.
7. Handling and storage
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Handling:
Information about safe handling:
Ensure good ventilation/extraction at the workplace.
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Safety data sheet
according to 1907/2006/EG
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Printed on: 15 th July 2010 Version :4 Revised on: 15 th July 2010
Trade name: LYSOFORMIN
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Avoid the formation of aerosol.
Information about fire and explosion prevention:
No special measures required.
Storage:
Requirements made of storage rooms and containers:
Use containers made out of polyolefin.
Store in original container only.
Joint storage information:
Keep away from foodstuff.
Other information about storage conditions:
Store in well-closed packaging in a cool, dry place.
Storage class: LGK 8 (acc. to VCI)
8. Exposure limitation and control / personal protectionn
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Additional information about the design of technical systems: No further data, see item 7
Components with critical values that require monitoring at the working place:
50-00-0 Formaldehyde
MAK Short-time value: 0,74 mg/m³, 0,6 ml/m³
Long-time value: 0,37 mg/m³, 0,3 ml/m³
111-30-8 Glutaral
MAK Short-time value: 0,42 mg/m³, 0,1 ml/m³
Long-time value: 0,21 mg/m³, 0,05 ml/m³
64-17-5 Ethanol
MAK Short-time value: 1920 mg/m³, 1000 ml/m³
Long-time value: 960 mg/m³, 500 ml/m³
Additional information: This is based on the lists that were valid when this data sheet was generated.
Personal protective equipment:
General precautions and hygienic measures:
Keep away from foodstuff.
Immediately remove any soiled, saturated clothing.
Wash hand in the breaks and at the end of work.
Avoid contact with skin.
Avoid contact with eyes and skin.
Respiration protection:
Unnecessary if good ventilation is ensured.
For short-term or low exposure respiration filter device; for intensive or longer exposure
use a respiration filter device that operates independent of the circulating air.
Hand protection:
Protective gloves
The material of the gloves must be impermeable and resistant to the product/ stuff/ preparation.
As compatibility tests are not available no recommendation can be made for the gloves suitable for the
product.
Choice of gloves under consideration of perforation time, permeation rate and degradation of the material.
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Safety data sheet
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Trade name: LYSOFORMIN
Glove material:
Butyl rubber
Nitrile rubber
The selection of the suitable glove not only depends on the material but also on other
quality features and varies from manufacturer to manufacturer. As the · product is a mixture of
several substances, the resistance of the glove materials cannot be calculated in advance and therefore
needs to be checked again before use.
Recommended material thickness: 0,33/ rsp 2,0 mm
Penetration time of the glove material:
Ask the manufacturer about the exact penetration time and comply with this.
The penetration time for the mixture of chemicals listed below must be at least 480 minutes
(permeation acc. to EN 374 Part 3: Level 6).
Eye protection:
Tight-fitting goggles
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Body protection: Protective clothing
9. Physical and chemical properties
General information
Form: Liquid
Colour: Colourless
Smell: Scented
Change of state
Melting point/melting range: Not determined.
Boiling point/boiling range: Not determined.
Flash point: Not applicable.
Self-ignition: The product is not self-igniting.
Risk of explosion: The product is not explosive.
Vapour pressure at 20 °C: Not determined
Density at 20 °C: approx. 1,03 g/cm 3
Solubility in/ mixability with
water: Completely mixable.
pH-value (50 g/l) at 20 °C: approx. 7
Viscosity:
Dynamic at 20°C: 5 mPas
Contents of solvent:
Organic solvents: 7,5 %
Water: approx. 86,0 %
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Safety data sheet
according to 1907/2006/EG
Page: 5/7
Printed on: 15 th July 2010 Version :4 Revised on: 15 th July 2010
Trade name: Lysoformin
10. Stability and reactivity
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Thermal decomposition / conditions to be avoided:
No decomposition if used properly.
Dangerous reactions: No dangerous reactions known.
Dangerous products of decomposition: No dangerous decomposition products known.
11. Toxicological information
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Acute toxicity:
Classification relevant LD/LC50 values:
50-00-0 Formaldehyde
Oral LD50 >200 mg/kg (rat)
111-30-8 Glutaral
Oral LD50 134 mg/kg (rat)
Dermal LD50 2560 mg/kg (rabbit)
Lysoformin oral: 2,1 ml/kg (rat)
inhalative: without effect (rat)
Primary irritation:
on skin: Irritating to skin and mucous membranes.
in eyes: Irritating with risk of serious damage to eyes.
Sensitisation:
May cause sensitisation by inhalation.
May cause sensitisation by skin contact.
Further toxicological information:
Due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the
latest valid version, the product has the following risks:
Dangerous to health
Irritating
Sensitization: May cause sensitization by inhalation and skin contact.
12. Ecological information
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Information about elimination (persistence and degradability):
Biodegradable
The surfactant in this preparation satisfies the conditions of the biological degradability as defined
in the regulations (EU) No. 648/2004 resp. CH in the ChemRRV on detergents.
General information:
Water hazard class (German legislation) 2 (self-classification): hazardous for water
Do not allow to enter the groundwater, waters or the sewer system.
There is a risk to drinking water even if minute quantities escape into the ground.
13. Disposal consideration
Product:
Recommendation:
May not be disposed of together with the household waste. Do not allow to enter the sewer system.
Handover to special waste collector or bring to a special waste collection point.
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Safety data sheet
according to 1907/2006/EG
Page: 6/7
Printed on: 15 th July 2010 Version :4 Revised on: 15 th July 2010
Trade name: LYSOFORMIN
European Waste Code
07 04 01 washing liquids and mother lye
Soiled packaging:
Recommendation: Dispose of in accordance with the official regulations.
14. Transport information
Land transport ADR/RID and GGVS/GGVE (cross-border/Germany):
ADR/RID-GGVS/E class: 8 Ätzende Stoffe
Kemler-Number: 80
UN-Number: 1903
Packaging group: III
Danger markings and labels: 8
Name of goods: DISINFECTANT, LIQUID, CORROSIVE, N.O.S. (glutaral, formaldehyde)
Limited quantities (LQ): LQ 7
Tunnel restriction code: E
Sea transport IMDG/GGVSee:
IMDG/GGVSea class: 8
UN-Number: 1903
Label: 8
Packaging group: III
EMS-Number: F-A,S-B
Marine pollutant: No
Correct technical name: DISINFECTANT, LIQUID, CORROSIVE, N.O.S. (glutaral, formaldehyde)
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA-class: 8
UN/ID-Number: 1903
Label: 8
Packaging group: III
Correct technical name: DISINFECTANT, LIQUID, CORROSIVE, N.O.S. (glutaral, formaldehyde)
15. Regulatory information
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Labelled according to the EEC Directives:
The product has been classified and identified according to the EC Directives/Hazardous Goods Ordinance.
Code letter and danger indication of the product:
Xn Dangerous to health
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Hazardous components for labelling:
Formaldehyde
Glutaral
R-phrases:
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
36/37/38 Irritant to eye, respiratory tract and skin.
40 Limited evidence of carcinogenic effect.
41 Risk of serious damage to eyes.
42/43 May cause sensitization by inhalation and skin contact.
S-phrases:
1/2 Keep locked away out of the reach of children.
28 In case of contact with the skin rinse immediately with plenty of water.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36/37/39 Wear suitable protective clothing, protective gloves and goggles/face mask when working.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
National regulations:
Other regulations, restrictions and prohibitions
Medical device. Cl. IIa CE 0482 acc. to German MPG
acc. to EU-RL 93/42/EEC
16. Other information
The information contained herein is based on the present state of our knowledge. It does not represent a
guarantee of the properties of the product or form the basis for a legal position.
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Relevant R-phrases
11 Highly inflammable.
23/24/25 Toxic if inhaled, swallowed, or on contact with skin.
23/25 Toxic if inhaled and swallowed.
34 Causes burns.
36/38 Irritating to eyes and skin.
40 Limited evidence of a carcinogenic effect.
41 Liable to cause serious eye damage.
42/43 May cause sensitisation by inhalation and skin contact.
43 May cause sensitisation by skin contact
50 Very toxic to aquatic organisms.
Area issuing the data sheet: Department Product Safety
Contact partner: Dr. G. Cielusek
* Data changed compared to previous version
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