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Spray Drying Technology.pdf - National University of Singapore

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f<br />

( X − X<br />

eq<br />

)<br />

( X − X )<br />

n<br />

⎡ ⎤<br />

= ⎢ ⎥ , X ≤ X<br />

cr<br />

⎢⎣<br />

cr eq ⎥⎦<br />

f = 1 , X > X<br />

cr<br />

On the other hand, the REA visualizes the drying process as an activation<br />

process in which an ‘energy’ barrier has to be overcome for moisture removal<br />

to occur [51] . The drying rate then takes the following form,<br />

d m<br />

dt<br />

h<br />

A<br />

( k P ( T ) − P )<br />

m<br />

= −<br />

v, sat d v,<br />

∞<br />

ms<br />

(5)<br />

The core <strong>of</strong> this model lies in modelling the fracitonality term, k , which should<br />

progressively reduce as moisture is being removed. This fractionality is<br />

expected to be a function <strong>of</strong> moisture and temperature, which can be<br />

approximated by,<br />

⎛ ∆EV<br />

⎞<br />

k = exp ⎜−<br />

⎟<br />

(6)<br />

⎝ RT ⎠<br />

where ∆E v is the apparent activation energy, which is likely to be dependent<br />

on the ‘mean’ or ‘average’ moisture. The original authors proposed the<br />

following function to be taken as the fingerprint <strong>of</strong> a material applicable to all<br />

drying conditions,<br />

∆E<br />

∆E<br />

v<br />

v,<br />

∞<br />

= a e<br />

−b<br />

( X −X<br />

) c<br />

∞<br />

(7)<br />

At high moisture content<br />

∆ E<br />

∆ E<br />

V<br />

V , ∞<br />

→ 0<br />

, k →1<br />

(8)<br />

At low moisture content<br />

∆ E<br />

∆ E<br />

V<br />

V , ∞<br />

→1<br />

, 0 < minimal K value<<br />

1<br />

(9)<br />

Application <strong>of</strong> the REA model in CFD simulations can be found [21][26][27] .<br />

Good comparison was obtained with experimental data. A general<br />

comparison between the two approaches, CDC and REA, can be found in the<br />

review by Chen [52] . With application to CFD simulations, Woo et al. [27] further<br />

showed that both approaches response differently to the initial droplet<br />

moisture. It is important for the reader to assess these differences and<br />

behaviour <strong>of</strong> the models when applying them in their CFD simulations.<br />

Woo, Huang, Mujumdar, Daud – CFD modeling <strong>of</strong> spray dryers 15

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