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6 N-Acyl ED3A Chelating Surfactants: Properties and Applications in ...

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Alkyl Polyglycosides 41<br />

FIG. 29 Clean<strong>in</strong>g efficiency accord<strong>in</strong>g to IPP.<br />

TABLE 12 Plastics <strong>in</strong> Bathrooms<br />

Plastic sensitve to Plastic less sensitive to<br />

environmental stress crack<strong>in</strong>g environmental stress crack<strong>in</strong>g<br />

Acrylonitrile, butadiene, styrene Cellulose propionate<br />

ABS/polycarbonate Polyamide<br />

Polycarbonate Polymethylene, polyformaldehyde<br />

Polymethacrylate Polypropylene<br />

surfactant components <strong>in</strong>vestigated were C 8/10 -APG, FAEO (8 EO), FAS, SAS,<br />

<strong>and</strong> FAES. Another important performance feature of bathroom cleaners besides<br />

their actual clean<strong>in</strong>g performance is the avoidance of environmental stress crack<strong>in</strong>g<br />

<strong>in</strong> components made of plastic, <strong>in</strong>clud<strong>in</strong>g h<strong>and</strong>les, water overflows <strong>in</strong> bath<br />

tubs, fitt<strong>in</strong>g, or shower holders. Important bathroom plastics are listed accord<strong>in</strong>g<br />

to their sensitivity to environmental stress crack<strong>in</strong>g (ESC) <strong>in</strong> Table 12. By <strong>in</strong>teract<strong>in</strong>g<br />

with the various <strong>in</strong>gredients present <strong>in</strong> bathroom cleaners, plastics can develop<br />

environmental stress cracks which, <strong>in</strong> the past, have resulted <strong>in</strong><br />

considerable claims aga<strong>in</strong>st the manufacturers. In the laboratory, environmental<br />

stress crack<strong>in</strong>g effects can be simulated both by the p<strong>in</strong> impression method <strong>and</strong><br />

by the ben strip method [61]. In the p<strong>in</strong> impression method, the plastic is prestressed<br />

by <strong>in</strong>dentation with a steel p<strong>in</strong> <strong>and</strong> is then immersed <strong>in</strong> the test solution<br />

for 15 m<strong>in</strong>. The plastic is then dried <strong>and</strong> evaluated after 24 hours.<br />

In the ben strip method, plastic strips are prestressed by weights. The test solution<br />

is then allowed to act on the plastic strips for 15 m<strong>in</strong>. The strips are then dried<br />

<strong>and</strong> likewise evaluated after 24 hours. The results obta<strong>in</strong>ed with low-concentration

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