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The Applications of Chemical Analyses of Sediments and Soils in ...

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M<strong>in</strong>istry <strong>of</strong> the Environment <strong>and</strong> nutrient analyses at the University <strong>of</strong> Guelph. pHvalues at the surface usually ranged from 5 to 6 <strong>and</strong> pH 4 lower <strong>in</strong> the soil pr<strong>of</strong>ile.(G.M. Court<strong>in</strong>, Unpublished data).In analyses by MOE (Unpublished) wide variations were found <strong>in</strong> concentrations<strong>of</strong> copper, nickel <strong>and</strong> alum<strong>in</strong>um <strong>in</strong> I:5 ammonium acetate pH 4.8 extracts, Titaniumwas below the detection limit (0.3 ppm) <strong>and</strong> z<strong>in</strong>c <strong>in</strong> low concentrations (usually below1 ppm). Further work is required to determ<strong>in</strong>e if the concentrations <strong>of</strong> heavy metalsnoted above are toxic <strong>and</strong> if there is uptake <strong>in</strong>to the plants.Measurements would also probably be worthwhile <strong>of</strong> parameters such as AcidPotential <strong>and</strong> calcium carbonate requirements. Permeability was reduced dur<strong>in</strong>g thetest period but could be restored by cultivation. Mechanical analyses, measurement <strong>of</strong>total organic matter content <strong>and</strong> characterization <strong>of</strong> the humic material would be <strong>of</strong>assistance.ACID LAKE RECLAMATIONAcid lakes devoid <strong>of</strong> fish <strong>in</strong> the vic<strong>in</strong>ity <strong>of</strong> Sudbury were selected by the M<strong>in</strong>istry<strong>of</strong> the Environment for reclamation through pH adjustment by lim<strong>in</strong>g (Michalski <strong>and</strong>Adamski, 1974). A large number <strong>of</strong> sediment samples from test <strong>and</strong> control lakes havebeen analyzed for nutrients <strong>and</strong> heavy metals. Large changes <strong>in</strong> pH <strong>and</strong> heavy metaldistribution down the pr<strong>of</strong>ile below the sediment-water <strong>in</strong>terface were noted <strong>and</strong> therewere significant differences between test <strong>and</strong> control lakes <strong>and</strong> distance from theSudbury smelters.41

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