Intermittent dynamics of confined fluids, first passage statistics and diffusionprocess in colloidal and porous media.P. Levitz 11 PECSA, University Pierre et Marie Curie- CNRS, Paris FranceINTRODUCTION: Porous materials,concentrated colloidal suspensions are example ofconfining systems developing large specificsurface, presenting a rich variety of shapes andexhibiting complex and irregular morphologies ona large length scale. Such a confinement stronglyinfluences the molecular dynamics of embeddedfluids and the diffusive motion of particlesentrapped inside these materials. The particletrajectory can be described as an alternatesuccession of surface adsorption steps andconfining bulk relocations. The full transportprocess appears as an intermittent dynamics. Thisquestion related to a first passage problem isdiscussed in this presentationSPECTRAL ANALYSIS OF THEINTERMITTENT DYNAMICS: The timedependence of the intermittent dynamics of aconfined fluid near a pore interface can beanalysed using the density probability distribution(p.d.f.) of the time either spend in the bulk be<strong>for</strong>e areadsorption on the surface or characterizing theway that an adsorbed molecules is released in thebulk [1,2]. These two p.d.f. reflect two firstpassage statistics, one <strong>for</strong> the surface adsorptionthe other <strong>for</strong> the bulk relocation. A spectralanalysis of this dynamics is discussed <strong>for</strong> severalinterfacial geometries [1-3]. Direct comparisonswith recent molecular dynamics simulationsper<strong>for</strong>med <strong>for</strong> confined liquid water inside variouspore shapes are discussed [4].PROBING INTERMITTENT DYNAMICS:The Nuclear Magnetic Relaxation Dispersiontechnique (NMRD) is an effective experimentalmethod to follow an intermittent dynamics near aninterface. Under some general conditions ofrelaxation [1]; the related spin-lattice relaxationrate R 1 (ω) provides a direct evaluation of thespectral density of the intermittent dynamics. Inthis part, we will present several experimentalstudies of the water intermittent dynamics, usingNMRD. Various colloidal and/or porous interfaceswill be dicussed (plaster pastes [5], flat colloidalclay particles [1], long and stiff nanometric strands[3]) with a special emphasis on the fluid-surfaceinteraction ( “nano-wettability” [5]).DISCUSSION & CONCLUSIONS: The <strong>for</strong>meranalysis of the intermittent dynamics provides asimple description of the local exploration of aninterfacial medium by a particle and/or a molecule.This coarse grained description allows to quantifythe influence of the “local” confining geometryand also to estimate the degree of interactionduring the adsorption step. On larger length scale,real interfacial media such as pore networks orconcentrated colloidal suspensions generallyexhibit a complex interfacial geometry. Atraditional way to follow the geometrical upscalingis to look first at the pore scale, second, at a porenetwork, etc… Iteration of the intermittent processat these different levels of organization can bepursued using First Passage Time statistics.Finally, another important aspect of theintermittent dynamics is related to its efficiency tooptimize the research of a surface target [6], whichputs <strong>for</strong>ward a general mechanism of enhancementand regulation of chemical reactivity. We willemphasis these two topics and comment somepreliminary results.REFERENCES:1 P. Levitz; 2005; J. Phys.Condens. Matt. 17: S4059 2 P. Levitz, D. S.Grebenkov, M. Zinsmeister, K. Kolwankar; B.Sapoval, 2006; Phys. Rev. Lett. 96: 180601 3 P.Levitz, M. Zinsmeister, P. Davidson, D.Constantin, and O. Poncelet; 2008; Phys. Rev. E78: 030102 (R) 4 P. A. Bonnaud, B. Coasne and R.J.-M. Pellenq, J. 2010, Phys. Condens.Mat., 22:284110 5 J-P Korb and P Levitz;2008; Magnetic Resonance in Porous Media. 1081;55-58 6 O. Bénichou, D. Grebenkov, P. Levitz, C.Loverdo and R. Voituriez; 2010; PRL 105:150606ACKNOWLEDGEMENTS: This work wasper<strong>for</strong>med in several collaborations with M.Zinsmeister, J-P Korb, D. Grebenkov, O.Benichou, M Han, M. Fleury, P. Bonnaud, P.-A.Cazade, R. J.-M. Pellenq 2,3 , and B. Coasne. Manythanks to all of them.20
Diffusion in soft particle suspensions near jammingCraig E. MaloneyCivil & Environmental EngineeringCarnegie Mellon UniversityPittsburgh, PA 15213-3890, USASuspensions of soft particles exhibit a remarkable bifurcation at the random closepacking volume fraction, [1]. There is a yield stress above but not below. Weper<strong>for</strong>m numerical simulations of soft-particle suspensions under shear near . Wefind that above at sufficiently low shearing rates, the effective diffusion constant,, scales with length of the simulation cell in the flow-gradient direction, . Thisis in agreement with the size-dependent diffusion constant observed in lowtemperatureLennard-Jones glasses. Furthermore, the value of can beunderstood in terms of organized lines of slip and is independent of the <strong>for</strong>m of therepulsive interactions between the particles and the precise way in which the viscousdrag of the suspending fluid is modeled in the particle-scale simulations.[1] Microfluidic Rheology of Soft Colloids above and below Jamming. K. N.Nordstrom, E. Verneuil, P. E. Arratia, A. Basu, Z. Zhang, A. G. Yodh, J. P. Gollub,and D. J. Durian. Phys. Rev. Lett. 105, 175701 (2010)How do yield stress materials start to flow?Sébastien MannevilleUniversité de Lyon, Laboratoire de Physique, École Normale Supérieure de Lyon,CNRS UMR 5672 - 46 Allée d'Italie, 69364, Lyon cedex 07, FranceInstitut Universitaire de France, FranceYield stress materials are viscoelastic solids at rest but behave as viscous liquidswhen stressed above their yield stress. In soft jammed systems, yielding can be seenas an instance of an unjamming transition driven by the shear stress. The question ofwhether this shear-induced fluidization displays universal features, in a way similar tojamming driven by temperature or by volume fraction, has triggered much researchef<strong>for</strong>t in the recent years. Experimentally, difficulties arise from the need to measurede<strong>for</strong>mations and flows close to yielding at vanishingly small shear rates withsufficient spatial and temporal resolutions.In this talk, I will first review the current state of research on the steady state reachedby a soft glassy system above yielding. It is now established that some "simple"materials undergo a continuous yielding transition characterized by homogeneousflows while others display flow heterogeneities, e.g. shear bands, at steady state. Iwill then concentrate on the spatiotemporal fluidization dynamics of a "simple" yieldstress material, namely a carbopol microgel, that presents negligible aging andthixotropy. Through long experiments combining standard rheology and ultrasonic21