Chapter 6 The polyatomic molecules
Chapter 6 The polyatomic molecules
Chapter 6 The polyatomic molecules
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iii. Bond valence and the cluster geometryb=12(18n−g)Tri-nuclear compoundsMetal cluster compoundsOs 3(CO) 9(μ 3-S) 2g50b2M-M/pmOs-Os,281.3OsOsOsMn 2Fe(CO) 14Fe 3(CO) 12504823Mn-Fe,281.5Fe-Fe,281.5Mn Fe MnFeFeFeOs 3H 2(CO) 104642Os-Os,281.5Os[Mo 3(μ 3-O)(μ 2-O) 3F 9)] 5-Re 3(μ 2-Cl) 3(CH2SiMe 3) 6423669Os=Os,268.0Mo=Mo,250.2Re≡Re,238.7OsMoReMoOsMoReRe