download - County Construction Chemicals Ltd

SAFETY DATA SHEET1: IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY /UNDERTAKINGProduct Name: FOSROC PRIMER 13X PART AApplication: Base component of two part epoxy primer system.Company: Fosroc LimitedAddress: Coleshill Road, Tamworth, Staffordshire. B78 3TLTelephone: 01827 262222 (Out of Hours) 01827 265279 Fax: 01827 2624442: COMPOSITION/INFORMATION ON INGREDIENTSComposition:epoxy resin, xylene, butanone.Hazardous Ingredient(s) Symbol Risk Phrases Other Information %epoxy resin (number average Xi, N R36/38, 43, 51/53 Cas No: 25068-38-6 >50molecular weight 10 10

7: HANDLING AND STORAGEHandling:Storage:Maintain good standards of personal hygiene. Use only in well ventilated areas. Avoid breathingvapours. Avoid skin and eye contact. In case of insufficient ventilation, wear suitable respiratoryequipment.Keep containers dry and tightly closed. Store between (ºC) 5 - 25. Store in conformity with local fireregulations.8: EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational Exposure Limits:-Substance 8 Hour TWA STEL Source/Other Informationxylene, mixed isomers 441 mgm -3 662 mgm -3 EH40butan-2-one 600 mgm -3 900 mgm -3 EH40Engineering Control Measures:Personal Protective Equipment:9: PHYSICAL AND CHEMICAL PROPERTIESPhysical State:Colour:Odour:pH(concentrate):Boiling Point/Range (°C): 80Use only in well ventilated areas. Local exhaust ventilation is recommended.Use flameproof equipment and isolate all potential sources of ignition.In case of insufficient ventilation wear suitable respiratory equipment. Avoidskin and eye contact. Impervious gloves (eg PVC). Safety glasses / Goggles.Change contaminated clothing and clean before re-use.Liquid.Straw.Irritating (Irritant)Not applicable (non-aqueous).Flash Point (closed, °C): -7Autoflammability (°C): Autoignition temperature: 490Explosive Properties (%): Lower explosive limit (LEL): 1.8% Upper explosive limit (UEL): 11.5%Vapour Pressure (kPa at 20°C): 10Relative Density (at 20°C): 1.03Water Solubility:Fat Solubility:10: STABILITY AND REACTIVITYStability:Conditions to Avoid:Materials to Avoid:Hazardous Decomposition Products:11: TOXICOLOGICAL INFORMATIONPartially soluble.Not determined.Stable: reacts with compounds containing amino, hydroxyl or carboxylgroups to give stable, cross linked materials. Contains volatile solvent.Any source of ignition.Strong acids. Strong alkalis. Strong oxidising agents.Thermal decomposition:- Oxides of carbon. Irritant fumes.The following toxicological assessment is based on a knowledge of the toxicity of the product's components.Expected oral LD50, rat > 2g/kg.Classified as a skin sensitiser.Health EffectsOn Eyes: Irritating and may injure eye tissue if not removed promptly.On Skin: Harmful by absorption through the skin. Irritation. May cause sensitisation.By Inhalation:By Ingestion:Chronic:Harmful by inhalation. Vapours may cause headaches, dizziness and central nervous systemdepression.May cause irritation of mouth, throat and digestive tract.Repeated and prolonged skin contact may lead to skin disorders.Issue No: 04 Date: 12.05.97 FOSROC PRIMER 13X PART A Page: 2 of 4

12: ECOLOGICAL INFORMATIONEnvironmental Assessment:Mobility:Persistence and Degradability: Not readily biodegradable.Bioaccumulative Potential:Ecotoxicity:13: DISPOSAL CONSIDERATIONSWhen used and disposed of as intended, no adverse environmental effects areforeseen. Contains volatile organic compounds.Mobile liquid. Partially soluble in waterHas the potential to bioaccumulate.Ecotoxic to fish/daphnia/algae.Disposal must be in accordance with local and national legislation.Unused Product:Used/Contaminated Product:Packaging:14: TRANSPORT INFORMATIONClassified as a special waste. Dispose of through an authorised waste contractorto a licensed site.As for Unused product.Contains hazardous residues, must be disposed of through an authorised wastecontractor.UN Number: 1866IMO: Class: 3.2 Packing Group: II Marine Pollutant: NoIATA/ICAO: Class: 3 Packing Group: IIADR: Class: 3 Item:5(b)Transport Name: Resin SolutionHazchem/Kemler Code: 3WE / 3315: REGULATORY INFORMATIONHazard Label Data:-Named Ingredients: epoxy resin (number average molecular weight

16: OTHER INFORMATIONAlso refer to the Safety Data Sheet(s) for information on other components of this product.The data and advice given apply when the product is used for the stated application or applications. The product is not sold as suitable for any otherapplication. Use of the product for applications other than as stated in this sheet may give rise to risks not mentioned in this sheet. The product shouldnot be used other than for the stated application or applications without seeking advice from Fosroc Ltd.If this product has been purchased for supply to a third party for use at work, it is the purchaser's duty to take all necessary steps to secure that any personhandling or using the product is provided with the information in this sheet.It is the responsibility and duty of the employer to inform employees and others who may be affected of any hazards described in this sheet and of anyprecautions which should be taken.This sheet does not constitute or substitute for the users own assessment of workplace risk, as required by other health and safety legislation.Further copies of this Safety Data Sheet may be obtained from Fosroc Limited.Date Printed: 13/01/1999 SDS Reference: 3247 239/P13X AREVISIONSupersedes issue no: 03 dated: 01.10.96Sections updated/revised - no(s): 1 , 8.Issue No: 04 Date: 12.05.97 FOSROC PRIMER 13X PART A Page: 4 of 4

SAFETY DATA SHEET1: IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY /UNDERTAKINGProduct Name: FOSROC PRIMER 13X PART BApplication: Hardener component of two part epoxy primer system.Company: Fosroc LimitedAddress: Coleshill Road, Tamworth, Staffordshire. B78 3TLTelephone: 01827 262222 (Out of Hours) 01827 265279 Fax: 01827 2624442: COMPOSITION/INFORMATION ON INGREDIENTSComposition:polyaminoamide adduct, xylene, butanone, butanol.Hazardous Ingredient(s) Symbol Risk Phrases Other Information %butanone F,Xi R11, 36/37 Cas No: 78-93-3 >25 25 2.5

7: HANDLING AND STORAGEHandling:Storage:Maintain good standards of personal hygiene. Use only in well ventilated areas. Avoid breathingvapours. Avoid skin and eye contact. In case of insufficient ventilation, wear suitable respiratoryequipment.Keep containers dry and tightly closed. Store between (ºC) 5 - 25. Store in conformity with local fireregulations.8: EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational Exposure Limits:-Substance 8 Hour TWA STEL Source/Other Informationxylene, mixed isomers 441 mgm -3 662 mgm -3 EH40butan-2-one 600 mgm -3 900 mgm -3 EH40butan-1-ol - - - 154 mgm -3 EH40Engineering Control Measures:Personal Protective Equipment:9: PHYSICAL AND CHEMICAL PROPERTIESPhysical State:Colour:Odour:pH(concentrate):Boiling Point/Range (°C): 80Use only in well ventilated areas. Local exhaust ventilation is recommended.Use flameproof equipment and isolate all potential sources of ignition.In case of insufficient ventilation wear suitable respiratory equipment. Avoidskin and eye contact. Impervious gloves (eg PVC). Safety glasses / Goggles.Change contaminated clothing and clean before re-use.Liquid.Straw / Brown.Irritating (Irritant)Not applicable (non-aqueous).Flash Point (closed, °C): -7Autoflammability (°C): Autoignition temperature: 490Explosive Properties (%): Lower explosive limit (LEL): 1.0% Upper explosive limit (UEL): 11.5%Vapour Pressure (kPa at 20°C): 10Relative Density (at 20°C): 0.88Water Solubility:Fat Solubility:10: STABILITY AND REACTIVITYStability:Conditions to Avoid:Materials to Avoid:Hazardous Decomposition Products:11: TOXICOLOGICAL INFORMATIONPartially soluble.Not determined.Contains volatile solvent.Any source of ignition.Strong acids. Strong alkalis. Strong oxidising agents.Thermal decomposition:- Oxides of carbon. Nitrogen compounds,in some fire circumstances, hydrogen cyanide.The following toxicological assessment is based on a knowledge of the toxicity of the product's components.Expected oral LD50, rat > 2g/kg.Health EffectsOn Eyes: Irritating and may injure eye tissue if not removed promptly. Vapour may cause irritation.On Skin: Harmful by absorption through the skin. Irritation.By Inhalation:By Ingestion:Chronic:Harmful by inhalation. Vapours may cause headaches, dizziness and central nervous systemdepression.May cause irritation of mouth, throat and digestive tract.Repeated and prolonged skin contact may lead to skin disorders.Issue No: 04 Date: 12.05.97 FOSROC PRIMER 13X PART B Page: 2 of 4

12: ECOLOGICAL INFORMATIONEnvironmental Assessment:When used and disposed of as intended, no adverse environmental effects areforeseen. Contains volatile organic compounds.Mobility:Mobile liquid. Partially soluble in waterPersistence and Degradability: Expected to be not readily biodegradable.Bioaccumulative Potential: Not determined.Ecotoxicity:13: DISPOSAL CONSIDERATIONSExpected to be ecotoxic to fish/daphnia/algae.Disposal must be in accordance with local and national legislation.Unused Product:Used/Contaminated Product:Packaging:14: TRANSPORT INFORMATIONClassified as a special waste. Dispose of through an authorised waste contractorto a licensed site.As for Unused product.Contains hazardous residues, must be disposed of through an authorised wastecontractor.UN Number: 1866IMO: Class: 3.2 Packing Group: II Marine Pollutant: NoIATA/ICAO: Class: 3 Packing Group: IIADR: Class: 3 Item:5(b)Transport Name: Resin SolutionHazchem/Kemler Code: 3WE / 3315: REGULATORY INFORMATIONHazard Label Data:-Named Ingredients:UN Number: 1866Symbol(s):F, XnRisk Phrases:Safety Phrases:EC Directives:Statutory Instruments:xylene (mixture of isomers).Highly flammableHarmful by inhalation and in contact with skinIrritating to eyes, respiratory system and skinKeep away from sources of ignition - No smoking.Avoid contact with skin and eyes.Wear suitable gloves and eye/face protection.Use only in well ventilated areasDangerous Substances Directive, 67/548/EEC and adaptations.Dangerous Preparations Directive, 88/379/EEC.Safety Data Sheets Directive, 91/155/EEC.Chemicals (Hazard Information and Packaging for Supply) (Amendment) Regs. 1996 (SI1092).Control of Substances Hazardous to Health Regs. 1994 (SI 3246).Health & Safety at Work, etc. Act 1974.Highly Flammable Liquids & Liquefied Petroleum Gases Regs. 1972 (SI 917).Environmental Protection Act 1990.Codes of Practice: Waste Management. The Duty of Care.Guidance Notes: Occupational skin diseases: health and safety precautions (EH 26).The storage of highly flammable liquids (CS 2).Occupational exposure limits (EH 40).The above publications are available from HMSO16: OTHER INFORMATIONAlso refer to the Safety Data Sheet(s) for information on other components of this product.Issue No: 04 Date: 12.05.97 FOSROC PRIMER 13X PART B Page: 3 of 4

The data and advice given apply when the product is used for the stated application or applications. The product is not sold as suitable for any otherapplication. Use of the product for applications other than as stated in this sheet may give rise to risks not mentioned in this sheet. The product shouldnot be used other than for the stated application or applications without seeking advice from Fosroc Ltd.If this product has been purchased for supply to a third party for use at work, it is the purchaser's duty to take all necessary steps to secure that any personhandling or using the product is provided with the information in this sheet.It is the responsibility and duty of the employer to inform employees and others who may be affected of any hazards described in this sheet and of anyprecautions which should be taken.This sheet does not constitute or substitute for the users own assessment of workplace risk, as required by other health and safety legislation.Further copies of this Safety Data Sheet may be obtained from Fosroc Limited.Date Printed: 13/01/1999 SDS Reference: 3248 239/P13X BREVISIONSupersedes issue no: 03 dated: 01.10.96Sections updated/revised - no(s): 1 . 8.Issue No: 04 Date: 12.05.97 FOSROC PRIMER 13X PART B Page: 4 of 4