EU-SICHERHEITSDATENBLATT CLO (Claryfied Oil) ABSCHNITT 1 ...

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Heavy Fuel Oil Components9.4. Formulation & (Re)packing of Heavy Fuel Oil – Industrial9.4.1. Exposure ScenarioSection 1 Exposure Scenario Title Heavy Fuel OilTitleFormulation & (Re)packing of Substances and MixturesUse DescriptorSector(s) of Use 3, 10Process Categories 1, 2, 3, 8a, 8b, 15Further information on the mapping and allocation ofPROC codes is contained in Table 9.1Environmental Release Categories 2Specific Environmental Release Category ESVOC SpERC 2.2.v1Processes, tasks, activities coveredFormulation of the substance and its mixtures in batch or continuous operations within closed orcontained systems, including incidental exposures during storage, materials transfers, mixing,maintenance, sampling and associated laboratory activities.Assessment MethodSee Section 3.Section 2 Operational conditions and risk management measuresSection 2.1 Control of worker exposureProduct characteristicsPhysical form of product LiquidVapour pressure (kPa) Liquid, vapour pressure
Heavy Fuel Oil Components(closed systems). or other system to avoid exposure E8. Avoid carrying out activitiesinvolving exposure for more than 4 hours OC28. Wear chemicallyresistant gloves (tested to EN374) in combination with ‘basic’ employeetraining PPE16.CS85 Bulk product storage. Store substance within a closed system E84. Avoid carrying out activitiesinvolving exposure for more than 4 hours OC28. Wear chemicallyresistant gloves (tested to EN374) in combination with ‘basic’ employeetraining PPE16.CS137 Product sampling Sample via a closed loop or other system to avoid exposure E8. Avoidcarrying out activities involving exposure for more than 15 minutes OC26.Wear chemically resistant gloves (tested to EN374) in combination with‘basic’ employee training PPE16.CS36 Laboratory activities Handle within a fume cupboard or implement suitable equivalent methodsCS510 Marine vessel/barge(un)loadingCS511 Road tanker/RailcarloadingCS8 Drum/batch transfersCS39 Equipment cleaningand maintenanceto minimise exposure E12. Wear suitable gloves tested to EN374 PPE15.Transfer via enclosed lines E52 Avoid carrying out activities involvingexposure for more than 4 hours OC28..Clear transfer lines prior to decouplingE39. Retain drain downs in sealed storage pending disposal orfor subsequent recycle ENVT4. Wear chemically resistant gloves (testedto EN374) in combination with ‘basic’ employee training PPE16.Ensure material transfers are under containment or extract ventilationE66. Wear chemically resistant gloves (tested to EN374) in combinationwith ‘basic’ employee training PPE16.Ensure material transfers are under containment or extract ventilationE66. Provide a general ventilation (not less than 3 to 5 air changes perhour) E11, or G9; Ensure operation is undertaken outdoors. E69. Avoidcarrying out activities involving exposure for more than 1 hour OC27.Wear chemically resistant gloves (tested to EN374) in combination with‘basic’ employee training PPE16.Drain down and flush system prior to equipment break-in or maintenanceE55. Wear chemically resistant gloves (tested to EN374) in combinationwith specific activity training PPE17. Retain drain downs in sealed storagepending disposal or for subsequent recycle ENVT4.Additional information on the basis for the allocation of the identified OCs and RMMs iscontained in Appendices 2 to 3Section 2.2 Control of environmental exposureProduct characteristicsSubstance is complex UVCB [PrC3]. Predominantly hydrophobic [PrC4a].Amounts usedFraction of EU tonnage used in region 0.1Regional use tonnage (tonnes/year) 1.1e7Fraction of Regional tonnage used locally2.6e-3Annual site tonnage (tonnes/year) 3.0e4Maximum daily site tonnage (kg/day) 1.0e5Frequency and duration of useContinuous release [FD2].Emission days (days/year) 300Environmental factors not influenced by risk managementLocal freshwater dilution factor 10Local marine water dilution factor 100Other given operational conditions affecting environmental exposureRelease fraction to air from process (after typical onsite RMMs, 2.2e-3consistent with EU Solvent Emissions Directive requirements)Release fraction to wastewater from process (initial release prior to 5.0e-6RMM)Release fraction to soil from process (initial release prior to RMM) 0.0001Technical conditions and measures at process level (source) to prevent release2010-08-10 CSR 131
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Heavy Fuel Oil ComponentsNote: High
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Heavy Fuel Oil Components 68512-6
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Heavy Fuel Oil Components2010-08-10
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Heavy Fuel Oil ComponentsReference
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Industrial: SU3 Industrial:
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ES4-W1 Industrial: SU3
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Heavy Fuel Oil ComponentsThere is a
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Heavy Fuel Oil Components2010-08-10
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Heavy Fuel Oil ComponentsReference
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Industrial: S
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ES4-W1 Industrial:
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Heavy Fuel Oil ComponentsA quantita
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Heavy Fuel Oil Componentsfor subseq
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Heavy Fuel Oil ComponentsThe Petror
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Heavy Fuel Oil Componentsanalysis o
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An Evaluation of the Persistence, B
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Table of ContentsExecutive Summary
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2.0 Outline of PBT/vPvB Assessment
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3.0 Persistence Assessment of Petro
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Figure 2. BioHCwin (Y-axis) vs. exp
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2,3-dimethylheptane 9 7.7 6.2 7.42,
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Figure 5. Half-life predictions for
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criterion. It can be concluded that
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Figure 9. Half-life predictions for
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HydrocarbonC nrBioHCwinPredictedHal
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Figure 13. Half-life predictions fo
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Figure 15. Half-life predictions fo
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HydrocarbonC nrBioHCwinPredictedHal
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enzo[a]pyrene 20 421.6 16.5Table 10
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(see Appendix 2). Since BCF predict
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100001000100101n-ParaffinsBvB00 5 1
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exhibit BMFs near unity (Figure 28)
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2,2,4,4,6,8,8-heptamethyl nonane16
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Hydrocarbon C BMFBCF(Arnot)DietaryB
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10000010000100010010DinaphthenicsBv
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4.5 Polynaphthenic hydrocarbonsRegr
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101Polynaphth. Dietary BMFBMF = 10.
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enzenen-octylbenzene 14 0.034 403 4
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100001000100101NMArBvB05 10 15 20 2
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and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 CYakata
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10000010000100010010NDiArBvB110 15
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1010.1NDiAr Dietary BMFBMF = 10.011
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Hydrocarbon C BMFArnotBCFDietaryBCF
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Hydrocarbon C BMFArnotBCFDietaryBCF
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AcenaphtheneAcenaphthyleneBenz(a)an
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
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8.0 ReferencesAnonymous (2004). Fis
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EMBSI (2007c). Fish, dietary bioacc
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Prince RC, Walters CC. (2007). Biod
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Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29MN 29MN 30 n-Tetracosylcyclohe
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hexahydroindaneDN 20 2,4-dimethyloc
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PN 27Phenanthrene2,6-dimethylheptyl
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24c1cc(CC(C)CCCC(C)CCCCC)c2CC(
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NMAr 29NMAr 29NMAr 29NMAr 29NMAr 29
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26Dimethyloctyl-1,2,3,6,7,8-he
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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SummaryIn conducting a PBT assessme
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment ofC15 stru
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWEAQUATIC TOXICITY PREDICTIONS
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CONTENTS (Continued)SectionPage15 S
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1-2The model predictions include me
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2-1SECTION 22 SUMMARY OF COMPOSITIO
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10-1SECTION 1010 SUMMARY OF COMPOSI
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